超高效液相色谱-串联质谱法测定柑橘中的草甘膦及其代谢物残留

本研究首次建立了一种超高效液相色谱-串联质谱法(UHPLC-MS/MS)同时测定柑橘中草甘膦及其代谢物N-乙酰草甘膦?氨甲基磷酸(AMPA)和N-乙酰AMPA?样品经过0.5%甲酸水提取, 以十八烷基硅烷键合硅胶柱(C18)净化, 利用水和200 mmol/L碳酸氢铵溶液(含0.1%氨水)作为流动相梯度洗脱, 在多反应监测模式下定量分析?结果表明, 草甘膦及其代谢物在0.05~1 mg/kg范围内线性关系良好, 相关系数均大于0.99; 草甘膦及其3个代谢物在柑橘全果和果肉基质中3个加标水平下回收率为 70.5%~109.5%, 相对标准偏差(RSD)为0.6%~10.1%, 定量限为0.05 mg/kg?本方法的前处理样品无需衍生, 简便?快捷?高效?准确可靠, 可用于柑橘中草甘膦及其代谢物N-乙酰草甘膦?AMPA和N-乙酰AMPA的定量检测?     

Mental health in the veterinary profession: an individual or organisational focus?

The veterinary profession is experiencing a shortage of veterinarians, with attrition recognised as a substantial contributor. Research has also indicated increased levels of mental ill health and alarming suicide rates in practitioners. The primary aim of this study was to investigate the impact of eleven modifiable workplace factors on mental health outcomes, job appreciation and intention to leave the veterinary profession. The second aim was to ascertain whether workplace factors influence mental health outcomes after controlling for individual resilience. An online survey was completed by 73 practising Australian veterinarians. Unfavourable workplace factors correlated with adverse outcomes including depression, stress, reduced job appreciation and increased likelihood of leaving both the role and the profession. Workplace factors remained linked with the outcomes of job appreciation, depression and stress whilst controlling for practitioner resilience. Job appreciation was a significant predictor of intention to leave both the current role and the profession. Via multiple linear regression, two categories were identified as associated with improved psychological outcomes and job appreciation. These were workplace factors that represent breaks from workload and control or decision latitude in the workplace. Whilst resilience represents a key area for intervention, workplace factors potentially represent an easier-to-modify area for intervention.     

弱光条件下桃光合作用的动态变化及品种差异分析

就日光温室桃树光合生理进行了详尽的研究,结果表明:1d中叶温与气温以14:00时较高。遮阴明显地降低了到达叶片表面的有效光合辐射、叶温与气温。桃叶片的光合速率日变化为双峰曲线,峰值大约出现在上午10:00与下午14:00时;不同品种弱光下的光合速率有明显的差异,以NJN较高,其次为五月火与麦香。遮阴降低了桃叶片的光合速率,以NJN光合速率降低的较少,说明NJN能适应设施栽培。气孔阻力与蒸腾速率则随着遮阴程度的增加而增加。桃中位叶的光合速率较幼叶高。     

Respond of Stock Trading Volume to Earning Report

Earning report is a main accounting report that transmits earning information to users. It is the core of financial reports system. Earning information is significant to users' decision making. This paper studies the respond of stock trading volume to earning report and draws the curve of trading volume before and after earning report. This paper further does a regression analysis of accidental earning and abnormal return rate, and draws the relation curve of them on the earning report date to prove stock trading volume does have remarkable respond to earning report. This research is significant to either lessen small investors blindness investment and help them make reasonable forecast to markets and regulate the disclosure of listed companies.     

Analysis on Sustained Release of Protein from Microcapsule Prepared by Alginate

The paper studies a drug deliversy system for protein and find the optimum preparation condition.Cross-linked alginate(Alg) microcapsule was used to prepare microcapsule for protein,using bovine serum album(BSA) as a model drug.Effect of different cations and content of protein on configuration,size and enveloped rate of microcapsule were investigated.It is shown that Ba-Alg microcapsule has steady configuration,homogeneous size and high-enveloped rate.Also electrophoresis of native BSA before microencapsulation and after microencapsulation is measured by(SDS-PAGE),it is found that no significant change is observed BSA integrity.Release of BSA from microcapsule in vitro presents sustained release in some extent,and initial burst effect is significantly obvious.Microenpsulation drug in alginate will be a wishful drug delivery system.     

Spline Boundary Element Method for Calculating Three-Dimensional Electrostatic Fields

Based on [l].this paper presents a new spline-BEM for calculating 3-D electrostatic fields,in which bi-cubic B-splines are used as basis functions. The corner problem in BEM and the extreme conditions for splines are circumvented. The numerical results presented show that the global approximation .convergence and stability of the method are satisfactory.     

The Application of Relevant Homology in the Unified Representation of Electromagnetic Potentials and Gauge Transformation

Electromagnetic potentials and gauge transformation are derived for non-cloSedexterior differential forms with the help of relevant homology.Since de Rham ccahomology is sure-ly a relavant homology. potentials for both closed and non-closed forms and the gauge transforma-tion ean be unified in terms of relavent homology.