High-flux solar-driven thermochemical dissociation of CO2 and H2O using nonstoichiometric ceria

Because solar energy is available in large excess relative to current rates of energy consumption, effective conversion of this renewable yet intermittent resource into a transportable and dispatchable chemical fuel may ensure the goal of a sustainable energy future. However, low conversion efficiencies, particularly with CO(2) reduction, as well as utilization of precious materials have limited the practical generation of solar fuels. By using a solar cavity-receiver reactor, we combined the oxygen uptake and release capacity of cerium oxide and facile catalysis at elevated temperatures to thermochemically dissociate CO(2) and H(2)O, yielding CO and H(2), respectively. Stable and rapid generation of fuel was demonstrated over 500 cycles. Solar-to-fuel efficiencies of 0.7 to 0.8% were achieved and shown to be largely limited by the system scale and design rather than by chemistry.     

Stand dynamics and tree quality response to precommercial thinning in a northern hardwood forest of the Acadian forest region: 23 years of intermediate results

In the late 1980s, large forest companies began precommercial thinning (PCT) operations in young northern hardwood cutovers in New Brunswick, Canada. To provide supporting growth and yield information, an industrial experiment was established at residual stand densities of 1300, 1600, 1900, and 2200?stems?ha^?1. Stand responses were examined for measurements recorded at 0 (1987), 5 (1992), 10 (1997), 16 (2003), and 23 (2010) years after establishment. Average diameter at breast height, quadratic mean diameter, stand basal area, and stand total volume growth increased as stem density decreased from PCT. There were significant linear differences for many of these variables between treatments and time periods (year). No significant differences were detected in tree height between treatments. In 2010, the four PCT thinning treatments did not exhibit any differences in potential sawlogs at 2.4?m (8?ft) and 3.6?m (12?ft) lengths. Significant differences were observed for 4.9?m (16?ft) sawlogs that were produced at the least dense spacing (1300?stems?ha^?1). Results from this study and recommendations from the European literature suggest that value-added timber products may be produced from more intense PCT treatments than are currently being practiced on sites dominated by yellow birch (Betula alleghaniensis Britt.).     

Effects of cryptic mortality and the hidden costs of using length limits in fishery management

Fishery collapses cause substantial economic and ecological harm, but common management actions often fail to prevent overfishing. Minimum length limits are perhaps the most common fishing regulation used in both commercial and recreational fisheries, but their conservation benefits can be influenced by discard mortality of fish caught and released below the legal length. We constructed a computer model to evaluate how discard mortality could influence the conservation utility of minimum length regulations. We evaluated policy performance across two disparate fish life‐history types: short‐lived high‐productivity (SLHP) and long‐lived low‐productivity (LLLP) species. For the life‐history types, fishing mortality rates and minimum length limits that we examined, length limits alone generally failed to achieve sustainability when discard mortality rate exceeded about 0.2 for SLHP species and 0.05 for LLLP species. At these levels of discard mortality, reductions in overall fishing mortality (e.g. lower fishing effort) were required to prevent recruitment overfishing if fishing mortality was high. Similarly, relatively low discard mortality rates (>0.05) rendered maximum yield unobtainable and caused a substantial shift in the shape of the yield response surfaces. An analysis of fishery efficiency showed that length limits caused the simulated fisheries to be much less efficient, potentially exposing the target species and ecosystem to increased negative effects of the fishing process. Our findings suggest that for overexploited fisheries with moderate‐to‐high discard mortality rates, reductions in fishing mortality will be required to meet management goals. Resource managers should carefully consider impacts of cryptic mortality sources (e.g. discard mortality) on fishery sustainability, especially in recreational fisheries where release rates are high and effort is increasing in many areas of the world.     

Enzymatic discoloration and phenolic content of potato tubers from cultivars resistant and susceptible to the golden nematode

Phenolic content and discoloration were determined for 13 commercial potato cultivars and 6 potato clones grown at 2 locations over a period of 5 successive years. Tubers from 6 potato cultivars and 5 potato clones resistant to the golden nematode were compared with tubers from 7 potato cultivars and 1 clone known to be susceptible to the golden nematode. Tubers from resistant plants were lower in phenols and discolored less than tubers from susceptible plants.     

Economic evaluation of financial and non-financial costs and benefits in agroforestry development and the value of sustainability

Financial appraisal of agroforestry is not different in kind from appraisals applied to pure forestry. Existing techniques for valuing non-market effects may also be applied. Effects on hydrological and carbon fluxes might be less favourable than those of pure forests. In the confusing field of biodiversity valuation too, only limited and specific claims can be made for agroforestry. Amenity valuation techniques developed for trees and woodlands encounter additional problems of interpretation in an agroforestry context. Agroforestry may offer a quantifiable value in short-term sustainability, and might meet recent economic definitions of long-term sustainable development, without encountering the full dangers to future generations embodied in conversion of natural to human capital.