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11.
Summary To elucidate biochemical features leading to p-hydroxyphenyl-rich lignin in gymnosperm reaction wood the activities of the following five enzymes involved in the biosynthesis of p-hydroxyphenyl lignin were compared in reaction and opposite woods: phenylalanine ammonialyase (EC 4.3.1.5), cinnamate 4-hydroxylase (EC 1.14.13.11), p-hydroxycinnamate: CoA ligase (EC 6.2.1.12), cinnamyl alcohol dehydrogenase (EC 1.1.1.-) and peroxidase (EC 1.11.1.7). The enzyme activities in the reaction woods of Thuja orientalis and Metasequoia glyptostroboides were remarkably higher than those in the opposite woods, reflecting the higher contents of p-hydroxyphenyl lignin in reaction wood.This work was partly supported by the Grant-in-Aid for Scientific Research (548047) from the Ministry of Education, Science and Culture of Japan. We thank the Ministry of Education for the support 相似文献
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As a measure of estimating humidity control capacity of materials in an airtight room under sinusoidal temperature variation,
we used the Cb value, which is the ratio of the range of variation in relative humidity in a steel box lined with the material of interest
to the range in an empty steel box. In order to clarify the factors that affect the Cb value, we focused on both the temperature variation rate and the area that is lined in the box. It was found that changing
the rate of temperature variation over one period strongly affected the Cb value, although the amplitude of temperature variation did not. We further noticed that the difference between the time when
peak temperature was reached and the time when peak absolute humidity was reached (peak time difference), was found to be
useful for estimating the humidity control capacity of materials. Knowing the difference between the phase when peak temperature
was reached and the phase when peak absolute humidity was reached (phase angle difference) was also useful. Because the Cb value was affected by both the variation period and the lined area in the box, we can draw a contour diagram of the period
and the lined area for materials to give an overview of the humidity control capacity of a material. The materials of primary
interest in this study were Japanese cedar and porous ceramics. 相似文献
14.
A split-root apparatus for examining the effects of hydraulic lift by trees on the water status of neighbouring crops 总被引:1,自引:0,他引:1
We describe a split-root system for examining the effects of hydraulic lift by trees on crop growth. In this system, upper
lateral tree roots were grown in a container set on the ground through which the taproot of the tree could penetrate into
the moist soil below. The container, with a radius of 0.5 m and a height of 0.20 m, consisted of two compartments divided
by a waterproof barrier. A markhamia tree (Markhamia lutea (Benth.) Schumann) and upland rice (Oryza sativa (L.)) plants were planted in one compartment, with only rice plants planted in the other compartment. Irrigation of the container
was ceased at the start of the experiment. The stomatal conductance of the rice plants in the associated side, in which both
trees and rice plants were grown, declined more rapidly during the first drying period than in the rice-only compartment,
suggesting that there was competition for water between the tree and the crop plants. However, during the later drying period,
the rice plants in the associated side were green and viable, while those in the rice-only side became desiccated. Rice roots
were seen intermingling with tree roots, and the soil water content in the associated site tended to be higher than in the
rice-only side. It is likely that hydraulic lift occurred in the associated side and that water that had been transferred
to the surface roots was released into the soil, enabling the rice plants in this compartment to remain viable. This novel
system is useful for examination of the effects of hydraulic lift by trees on the growth of neighbouring crops.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
15.
In order to develop a fireproof wooden material, the synergic effect of fire-retardant chemicals and wood coatings was studied.
The fire performance was evaluated by cone calorimeter. Impregnation of fire retardants including polyphosphatic carbamate,
and ceramic coatings including alkoxy metal salt improved the fire performance of wooden materials. This treatment made it
possible to meet the guidelines for fire performance of noncombustible materials in Japan. In addition to the vacuum-pressure
impregnation treatment, hot-and-cold-bath impregnation treatment is an effective way to develop fire-retardant wood by impregnating
fire retardant and ceramic coating. The weatherability of the developed material was also investigated. The ceramic coating
was resistant to light and moisture.
Part of this report was presented at 54th Annual Meeting (Sapporo, August 2004) and the 55th Annual Meeting (Kyoto, March
2005) of the Japan Wood Research Society 相似文献
16.
Naruyuki Kamo Mitsuo Higuchi Takehiro Yoshimatsu Yukiko Ohara Mitsuhiro Morita 《Journal of Wood Science》2002,48(6):491-496
This study reexamined the kinetics of the condensation reactions of hydroxymethylphenols with the purpose of elucidating the reaction mechanisms. This report discusses experimental results on the self-condensations of 2,4-dihydroxymethylphenols (2,4-DHMP) and 2,4,6-trihydroxymethylphenol (THMP), focusing on the order of reaction. The relations between the initial rates of reaction and the initial concentrations of reactants were investigated. Results quite different from those of previous reports were obtained. The order of reaction of the selfcondensation of 2,4-DHMP was found to be 1.1, which did not change with the alkali/2,4-DHMP molar ratio. The order of reaction of the self-condensation of THMP was found to vary with both the concentration of THMP and the alkali/THMP molar ratio. In the region of THMP concentrations above 1.5mol/l, the order of reaction was confirmed to be 2.0, which did not change with the alkali/THMP molar ratio. In the region of THMP concentrations below 1.0mol/l, the order of reaction varied with the alkali/THMP molar ratio, showing fractional numbers of 1.2–1.6. These results indicate that unimolecular reaction(s) and bimolecular reaction(s) take place simultaneously as the ratedetermining step in the condensation reactions of 2,4-DHMP and THMP and that the reaction mechanism changes with the species of reactant and, in some cases, with the reaction conditions.Part of this study was presented at the Wood Adhesives 2000 symposium, South Lake Tahoe, Nevada, USA, June 2000 相似文献
17.
Naruyuki?Kamo Hiroyuki?Okamura Mitsuo?Higuchi Mitsuhiro?MoritaEmail author 《Journal of Wood Science》2004,50(3):236-241
Propylene carbonate (PC) is known as one of the cure accelerators for alkaline phenol–formaldehyde resins. To elucidate the cure-acceleration mechanisms, the effects of PC on the condensation reactions of monomeric hydroxymethylphenols (HMPs) were investigated and compared with those of PC hydrolysate, sodium bicarbonate (NaHCO3) and ethyl formate. Immediately after the reaction started, PC, decomposing itself simultaneously, accelerated the formation of the ortho-para methylene-bonded dimer of 2,4,6-trihydroxymethylphenol. This effect of PC was very similar to that of ethyl formate. To the contrary, PC hydrolysate accelerated the formation of the para-para methylene-bonded dimer throughout the course of the reaction. This effect of PC hydrolysate was identical to that of NaHCO3. These results indicate that PC increases the reactivity of the ortho-hydroxymethyl group, presumably through transesterification. On the other hand, NaHCO3 is formed by the hydrolysis of PC or decomposition of the transesterified HMPs and it increases the reactivity of the para-hydroxymethyl group. 相似文献
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Patricia Yumi Morimoto Kofuji Atsushi Akimoto Hidetsuyo Hosokawa & Toshiro Masumoto 《Aquaculture Research》2005,36(7):696-703
Seasonal variations in pepsin, trypsin and chymotrypsin activities and protein digestibility were studied in yellowtails (Seriola quinqueradiata) reared for 1 year with extruded diets containing different levels of protein. Trypsin and chymotrypsin storage levels in the digestive tissues of starved fish were affected by seasonal changes in water temperature. Actual digestion activities of trypsin and chymotrypsin were low at lower water temperatures, but pepsin activity in the stomach tissue was not affected by low temperatures. On the other hand, trypsin and chymotrypsin activities in the intestinal contents were higher during lower water temperature months, while pepsin activity in the stomach contents was low at lower water temperatures. Apparent protein digestibility (APD) did not differ among the dietary treatments in the higher water temperature months, while in colder months it was higher in fish fed diet 1 than in fish fed diets 2 and 3. The APD values reflected pepsin activity in the stomach contents in all sampling months. Therefore, lower APD in colder months seems to be attributed to lower protease activity in the gastric digesta, implying that enhanced pepsin secretion from the stomach tissue might improve protein digestibility and growth performance in yellowtails during winter. 相似文献