Emamectin,a novel insecticide for controlling field crop pests

Emamectin is a macrocyclic lactone insecticide with low toxicity to non-target organisms and the environment, and is considered an important component in pest-management programmes for controlling field crop pests. It is a powerful compound for controlling the cotton bollworm Helicoverpa armigera (Hübner). A spray concentration of 25 mg AI litre-1 in a cotton field resulted in over 90% suppression of H armigera larvae up to day 28 after treatment, while similar mortality of the Egyptian cotton leafworm Spodoptera littoralis Boisduval, under the same conditions, was maintained for 3 days only. Emamectin is a potent compound for controlling the western flower thrips Frankliniella occidentalis (Pergande) under both laboratory and field conditions and its activity on adults was over 10-fold greater than that of abamectin. Spray concentrations of 10 and 50 mg AI litre-1 in Ageratum houstonianum Mill flowers resulted in total suppression of adults up to day 11 and of larvae up to day 20 after treatment. Under standard laboratory conditions, emamectin exhibits a considerable activity on the whitefly Bemisia tabaci (Gennadius) and the leafminer Liriomyza huidobrensis (Blanchard). Further studies are required to evaluate its potential activity on the latter pests under field conditions.     

Molecular characterization of Pseudomonas syringae isolates from fruit trees and raspberry in Serbia

Infection of fruit trees by Pseudomonas syringae is a potentially serious problem that may limit the establishment and sustained productivity of pome and stone fruit orchards in Serbia. To estimate possible diversity of Pseudomonas syringae fruit trees strains, we collected a set of strains in several areas of Serbia. The samples were taken from infected orchards with raspberry, plum, cherry, sour cherry, peach, pear and apple trees. Genetic diversity of P. syringae strains isolated from fruit trees was determined by using SpeI macrorestriction analysis of genomic DNAs by pulsed-field gel electrophoresis (PFGE) and REP-PCR. Molecular analysis showed that most of isolates had unique profiles, with the exception of isolates from plum and cherry that displayed profiles identical to each other and similar to P. syringae pv. morsprunorum. The study presented here clearly demonstrates the discriminative power of molecular techniques in enabling a detailed analysis of the genetic variations between strains of P. syringae from different pome and stone fruit hosts in Serbia.     

Plant contamination by heavy metals in the impact zone of Novocherkassk Power Station in the south of Russia

Journal of Soils and Sediments - The aim of this study is the assessment of Ni, Mn, Cd, Cu, Pb, Cr and Zn accumulation by different herbaceous species and soils on the technogenic areas around...     

Capturing ultrasmall EMT zeolite from template-free systems

Small differences between the lattice energies of different zeolites suggest that kinetic factors are of major importance in controlling zeolite nucleation. Thus, it is critical to control the nucleation kinetics in order to obtain a desired microporous material. Here, we demonstrate how careful investigation of the very early stages of zeolite crystallization in colloidal systems can provide access to important nanoscale zeolite phases while avoiding the use of expensive organic templates. We report the effective synthesis of ultrasmall (6- to 15-nanometer) crystals of the large-pore zeolite EMT from template-free colloidal precursors at low temperature (30°C) and very high yield.     

Ecological evaluation of polymetallic soil quality: the applicability of culture-dependent methods of bacterial communities studying

Purpose

This work aimed to study the effect of long-term polymetallic contamination on the state and parameters of soil bacterial communities, including the abundance of different groups of culturable bacteria and the activity of nitrification.

Materials and methods

Monitoring plots were located in the dry lake and surrounding area, which had been formerly used for the discharge of industrial waste. The soils in the 16 plots were characterized by extremely high levels of heavy metal pollution. This study evaluated the main soil physicochemical properties by various methods, total metal contents by X-ray analysis, mobile metal content by atomic absorption spectrophotometry, the abundance of chosen groups of culturable bacteria by inoculation on solid media, and nitrification activity from ammonium and nitrite oxidation rates.

Results and discussion

High adaptation capacity of microbial communities to long-term pollution was revealed through marked lack of decrease in the abundance of some of the bacterial groups in soils with high contamination levels. Among the bacteria determined by the colony count method, copiotrophic and spore-forming bacteria were the least sensitive to contamination, and actinomycetes were the most sensitive. The high levels of soil pollution with heavy metals had pronounced adverse effects on nitrification activity. The decrease in activity was strongly correlated with pollutant concentrations. The oxidation of nitrite was shown to be more affected by pollution that the oxidation of ammonium.

Conclusions

Some groups and parameters of culturable microorganisms can be used for soil status estimation under pollution conditions even though they are only a small fraction of the microbial community. The most sensitive parameter was the nitrification rate, while the number of actinomycetes was found to be most promising parameter among the groups of bacteria determined by plate counts. The use of sensitive groups of culturable microorganisms for bioindication purposes is a method, which may provide a cheap and sufficiently reliable tool for large-scale soil monitoring studies.

     

Petroleum Products and Phenols in Snow Cover in Khabarovsk, Southern Russian Far East

To have a better understanding of the industrial organic contamination of the city of Khabarovsk, southern Russian Far East, snow cover of the winter seasons of 2009?C2010 and 2010?C2011 was sampled at the end of March of 2010 and 2011 at six sites (and at eight sites in 2011) of the urban area and on the adjacent snow cover of the Amur River. The samples were analyzed by high-performance liquid chromatography and gas chromatography/mass spectrometry techniques for petroleum products and phenols. The main groups of the detected pollutants were n-alkanes, isoalkanes, paraffins, phenols, and phthalates. The total concentration of the petroleum products was 0.08?C2.84?mg/L, volatile phenols 0.17?C3.61???g/L. 4-Nitrophenol has been found among the phenols (0.22?C1.65???g/L). The minimum toxicant concentrations were found in background sites (first hundred meters) off the urban highways, and the maximum, in dumps of snow from the urban highways and the vicinities of Heat Power-3. Of aromatic compounds, insignificant amounts of isopropylbenzene (0.5???g/L) and xylenes (0.2?C0.3???g/L) and a high content of ethylbenzene (1.3???g/L) originated from local emission were found. For the unpolluted sites, identification of n-alkanes revealed high-molecular paraffins C₂₆?CC₃₃ (50?% of the total n-alkane content); fractions in the range of C₁₉?CC₂₁ and C₂₄ were found for the snow dumps, 55.0?% and 90.0?% of the total alkane content in 2010 and 2011, correspondingly. These compounds originated most probably from the wasted diesel fuel and mineral greases (derivatives). The study indicated the dangerous level of the Khabarovsk urban atmosphere deterioration with a range of organic pollutants of transport and industrial origin. The snow (and rain) urban runoff may affect the local soil and water ecosystems subsequently.