An approach to rheometry in soil mechanics—Structural changes in bentonite, clayey and silty soils

Rheology is regarded as the science of flow behaviour, where, based on isothermic equations, the deformation of fluids and plastic bodies subjected to external stresses may be described. Hooke's law of elasticity, Newton's law for ideal fluids (viscosity), Mohr-Coulomb's equation, and finally, Bingham's yielding are well known relationships and parameters in the field of rheology.

Rheometry is a well established measurement technique to determine the specific rheological properties of fluid and plastic bodies. However, the application of this technique in soil mechanical investigations is yet relatively uncommon. In order to explain point contact processes and strength an extrapolation of such findings to data of triaxial, direct shear or oedometer tests is still missing. Thus, this paper aims to introduce rheometry as a suitable method to determine the mechanical behaviour of soils and mineral suspensions when subjected to external stresses. To do this a Na-bentonite, Ibeco Seal-80 (IS-80) has been used as a testing material, and the suspensions were equilibrated with NaCl solutions in different concentrations in order to determine the ionic strength effects on interparticle strength and changes in mechanical properties. Furthermore a vertisol, a clayey oxisol, both from Brazil, and loess material from Israel, saturated with NaCl in several concentrations were analysed.

A parallel-plate-rheometer MCR 300 (Modular Compact Rheometer, Paar Physica, Ostfildern, Germany) has been used to conduct oscillatory tests. From the stress–strain relationship parameters and specific characteristics as thixotropy, storage modulus G′ and loss modulus G″, viscosity η, yield stress τ_y and the linear viscoelastic deformation (LVE) range including a limiting value γ_L were determined and calculated, respectively. With aspect to salt effects, amplitude sweep tests on CaCO₃ rich Avdat loess show an increasing stability due to higher NaCl concentrations. In a comparative test of Avdat loess and Ibeco Seal-80, turbulent versus sliding shear behaviour could be illustrated. To demonstrate clay mineralogy effects or textural effects clay rich substrates from Brazil, a smectitic vertisol and a kaolinitic oxisol were compared, showing a higher level of stored elasticity (stability) in case of smectites and a lower value in regard to kaolinites. These preliminary results of amplitude sweep tests show that rheometry is a potential method of investigating microstructural characteristics of mineral suspensions and of clayey or silty soils.     

Ecosystem UV-B experiments in terrestrial communities: a review of recent findings and methodologies

Ecosystem-level UV-B experiments have revealed a variety of responses in terrestrial communities. These include decreases in the growth of some plant species (usually small changes but occasionally >25%), both decreases and increases in herbivory, occasional altered decomposition patterns, changes in populations of fungi and invertebrates, and morphological changes in the growth patterns of mosses. These field experiments have been pursued both with solar UV-B exclusion using selective filters and with supplementation of UV-B using lamps. For UV-B-exclusion studies it is critical that the UV-B-excluding and UV-B-transmitting filters pass the same amount of photosynthetically active radiation (PAR, 400–700 nm) and also infrared. Canopy photosynthesis models indicate that even small differences in PAR transmittance can, under many circumstances, have significant effects on plant carbon gain. It is also important that filters in UV-B-exclusion studies allow precipitation to pass uniformly to the plots unless there is some form of irrigation underneath the filters. For UV-B-supplementation studies with lamps, many factors are involved in the realism of the ozone depletion simulation. We believe the major lamp-system error is excessive supplementation of UV-B by timer-controlled lamps when weather conditions (primarily clouds) decrease ambient solar UV-B irradiance. The choice of biological spectral weighting functions (BSWF) used in adjusting lamp flux is also critical in determining the level of ozone depletion simulated. In addition, shading by the lamp arrays influences plant growth and becomes particularly important when BSWF with substantial weighting in the UV-A are employed.     

Cooking behavior of rice in relation to kernel physicochemical and structural properties

A set of 27 rice varieties were evaluated for their morphological grain characteristics (length, width, thickness, thousand kernel weight, TKW), chemical composition (amylose, protein, and ash content) and starch properties (gelatinization temperature and enthalpy, amylose-lipid complex). In addition, cell walls were characterized by the arabinoxylan and beta-glucan contents. A rapid method for determining optimum rice cooking time was developed based on the swelling ratio; a fixed value of 2.55 gave a gelatinization level of 95% assessed by differential scanning calorimetry and translucence testing. Optimum cooking time appears positively correlated with kernel thickness and TKW but also with ash content. Confocal laser and scanning electron microscope observation of uncooked rice grains revealed different structural features (cell size) and fracture behavior: for some cultivars, the fracture showed ruptured cells, whereas for others most cells were intact. These structural differences, which may be linked to pectin content, could partly explain rice kernel cooking behavior.     

Investigation of serum survivin in dogs suffering from cancer: a multicenter study

BackgroundIn contrast to human medicine, only a small number of serum tumor markers are established in veterinary medicine even though they are a non-invasive diagnostic tool.ObjectivesThis study examined whether survivin could be suitable as a potential canine serum tumor marker.MethodsThis study measured the serum survivin concentrations of dogs with mammary tumors (n = 33), squamous cell carcinoma (n = 9), soft-tissue sarcoma (n = 18) and multicentric lymphoma (n = 22), using a commercially available, competitive immunoassay kit (BlueGene). The serum survivin concentrations were compared with those of a healthy control group (n = 20) and a control group of dogs with non-neoplastic diseases (n = 17).ResultsDogs with malignant tumors had serum survivin concentrations between 15 and 5,906 pg/mL (median, 72 pg/mL), those in the healthy group ranged from 7 to 99 pg/mL (median, 21 pg/mL) and those in the group of dogs suffering from non-neoplastic diseases from 15 to 93 pg/mL (median, 42 pg/mL). The differences in the survivin concentrations between the healthy dogs and dogs with malignant tumors and between the dogs with non-neoplastic diseases and those with malignant tumors were significant (p < 0.001 and p = 0.006, respectively).ConclusionsThe serum survivin concentrations in dogs with malignant tumors, with some exceptions, are higher than in dogs with benign tumors and dogs that do not suffer from a malignancy. Therefore, survivin can provide information on the presence of malignant tumors and be used as a tumor marker in dogs.     

Seroprevalence of hepatitis E virus in dogs in Switzerland

Hepatitis E virus (HEV) is the causative agent of an acute and in most cases self‐limiting hepatitis. Of the four major HEV genotypes that infect humans, genotype 3 and 4 are zoonotic and have been identified in humans but predominantly in pigs and wild boar, which are considered the main reservoirs. However, the known host range of zoonotic HEV may be increasing to comprise additional species, including companion animals. Several studies have identified contact with dogs as a risk factor for HEV infection in humans, yet information on the occurrence of HEV in Swiss dogs is lacking. To examine a possible risk of exposure, this study was designed to assess the seroprevalence of HEV in 84 Swiss dogs. Serum and plasma samples collected from four veterinary clinics were screened for HEV‐specific antibodies by HEV‐antibody ELISA test kit. In addition, information of 22 dogs regarding the country of origin, the type of dog feed and any history of hunting was recorded. Samples from seropositive animals were also screened for the presence of HEV RNA by quantitative real‐time RT‐PCR (qRT‐PCR). Overall, 38% (32 of 84) of the dogs tested seropositive for anti‐HEV, indicating exposure to HEV. Among the 22 dogs for which information was available, HEV‐specific antibodies were detected in three of five dogs that were born abroad, in one of two dogs that were fed a raw meat‐based diet, and in one hunting dog. No viral RNA could be detected in any of the serum and plasma samples; thus, the genotype of the strains remained undetermined. This study provides further evidence for canine exposure and susceptibility to HEV and highlights the need to further assess the risks of HEV transmission to humans with contact to dogs.     

Effektive Durchwurzelungstiefe,Sickerwasserbildung und Nitratverlagerung in tiefgründigen Lößböden eines Trockengebietes

Effective rooting depth, percolation water, and nitrate leaching in deeply developed loess soils of a water‐shortage area In 14 deeply developed loess soils, high amounts of mineral nitrogen (N) were measured within the first meter, whereas several nitrate depth profiles up to more than three meters resulted in low and medium nitrate values. The maximum depth of water uptake was measured in two years on four representative sites with regard to soil and crop properties. The maximum depth of water uptake was always considerably deeper than 200 cm, with a maximum of 290 cm (alfalfa). It is assumed that roots take up nitrogen even in this depth. The calculation of the effective rooting depth resulted in noticeably higher values (for wheat between 160 cm and 185 cm) than those given by the ”︁German Instructions for Soil Mapping” (AG Boden, 1994), the ”︁Regulations of the German Organisation for Water Management and Land Improvement” (DVWK, 1995) or the ”︁German Institute for Standardization” (DIN, 1998). As a result of low annual precipitation (normally less than 600 mm), only a minor part of the high amounts of nitrate within the root zone was leached into deeper soil layers. We conclude that it is not possible to predict the potential groundwater pollution with nitrate on the basis of the mineral N content in the first meter of the soil profile.     

The spatial-temporal evolution of urban development patterns in Chinese cities: Dynamics and interpretations

This paper examines the spatial-temporal evolution of urban spatial structure across 269 Chinese prefectural cities from 2002 to 2019. Our analysis identifies a consistent trend toward a more polycentric configuration in the 25 Chinese mega-cities during this period, primarily due to population growth and a supportive policy environment. However, the evolutionary pathways of small- and medium-sized cities unfolded in a rather complex and diverse manner, with some becoming more polycentric while the majority adhering to a monocentric trajectory. In these cases, population growth is usually associated with a more monocentric pattern, characterized by rapid expansion of the urban core, while polycentric development is primarily attributed to specific spatial policies that support the emergence of subcenters. We conclude that polycentric development, while potentially suitable for mega-cities to alleviate diseconomies of scale, may be less appropriate for small- and medium-sized cities as it may constrain growth associated with agglomeration economies. We suggest that the development and implementation of regional spatial policy should be considerate of local historical paths and contextual factors. Finally, we propose a stylized framework to more accurately reflect the diverse and complex nature of urban spatial structure evolution in Chinese prefectural cities.