Mineralization of Triadimefon Fungicide in Water by Electro-Fenton and Photo Electro-Fenton

The complete mineralization of the conazole fungicide triadimefon in water at pH 3 using electrochemical advanced oxidation processes, electro-Fenton and photo electro-Fenton, was achieved. The electrochemical system consisted of a one-compartment electrochemical cell of 100?mL provided with a glassy carbon mesh electrode (cathode) and a concentric outer steel mesh as anode. The electrolysis was realized at constant current. The most remarkable features are as follows: (1) photo electro-Fenton process reaches a complete mineralization of triadimefon after 2?h of electrolysis with respect to electro-Fenton method; and (2) 4-chlorophenol, hydroquinone, carboxylic acids, and inorganic ions were detected as intermediates of degradation processes, which end with the complete mineralization of triadimefon to CO₂?+?H₂O. (3) A reaction pathway for the oxidation of triadimefon fungicide by hydroxyl radicals that accounts for almost all detected intermediates is proposed.     

Recovery rate and quality of rotary peeled veneer from 30-year-old Pinus taeda L. logs

??Context

In the construction sector, wood is facing competition with other materials such as concrete, steel or plastics. Therefore, there is a need for more efficiency in the forest–wood chain by improving silvicutural management and wood processing technologies.

??Aims

The objective of the study is to analyse the influence of log diameter and quality to recovery rate, veneer quality and economic benefit.

??Methods

The trees used in the study came from a 30-year-old Pinus taeda L. thinning trial in Southern Brazil. In total, 57 logs (20.7 to 67.0 cm) were peeled following the standard industrial processing methods of the plywood mill.

??Results

Average recovery rate was 54 % ranging from 35 to 72.6 %, with a linear trend (R ²?=?0.48) of increasing recovery with an increment on the log small-end diameter. Results show that the gap between theoretically possible and real recovery was lower in the logs with bigger diameters, indicating their higher efficiency in industrial processing. Moreover, the economic analysis detected that the current prices for log assortments reflect only the industrial potential of low-quality pruned logs. An optimised pruning strategy would result in higher industrial efficiency, which would allow higher log prices.

??Conclusion

The results indicate that the recovery rate of bigger logs is higher in terms of volume of peeled veneer. The quality and therefore the value obtained from each log were negatively influenced by inadequate pruning strategies. Management of pines for higher value utilisation requires optimized thinning and pruning strategies in order to meet high growth rates and proportionally bigger dimensions of clear wood.     

Crop-tree interactions in alley cropping systems on alluvial soils of the Upper Amazon Basin

A crop/hedgerow interface design was used to test three leguminous species,Inga edulis, Leucaena leucocephala andErythrina sp., for their potential use for alley cropping on alluvial soils in the upper Amazon Basin. Prunings were applied as mulch at three rates 0, 3.3 and 6.7 Mg dry matter/ha/crop. Competition, crop yields, nutrient budgets, and weed control were monitored for three consecutive crops of upland rice. Crop yield reductions were evident up to 1.5 m from each of the hedgerow species, but were more pronounced withLeucaena hedgerows. Additional mulch was able to compensate for these reduced yields close to the hedges inLeucaena leucocephala andErythrina but not inInga edulis systems. In general rice yields were higher withLeucaena leucocephala andErythrina mulch as compared toInga mulch, perhaps because of higher levels of available N provided by the rapidly decomposing leaves ofLeucaena leucocephala andErythrina sp. as compared toInga. Weed control was greater, however, with the slowly decomposingInga mulch. For all three hedgerow/crop systems there was a net export of P from the system which was exhibited by declining soil P levels and decreasing crop yields.

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Resumen Un diseño de interfase cultivo/hilera de árboles se uso para ensayar tres especies leguminosas:Inga edulis, Leucaena leucocephala, y Erythrina sp. con el propósito de conocer su potencial para ser usadas en cultivos en callejones en suelos aluviales de la parte alta de la cuenca amazónica. Se aplicaron podas en 3 cantidades, 0. 3.3, y 6.7 Mg ha^–1 por cultivo. El efecto de competencia, rendimiento del cultivo, balance de nutrientes y control de malezas fueron medidos durante tres cultivos consecutivos de arroz de altura. Reductiones en el rendimiento del cultivo fueron evidenctes hasta 1.5 m de distancia de las hileras de árboles, las reducciones fueron mayores con hileras deLeucaena eInga. Incrementos de las cantidades de podas aplicada fueron capaces de incrementar los rendimientos cerca de las hileras deLeuceana leucocephala yErythrina pero no deInga. En general los rendimientos de arroz fueron más altos con podas deLeucaena yErythrina en comparación con podas deInga, debido quizás a los niveles más altos de nitrógeno disponible proveído por las podas deLeucaena yErythrina, que son de más rápida descomposición. Para las 3 especies estudiadas en interfase, hubo una exportación neta de nutrientes con el grano y rastrojo de arroz que se observó en el declinar de los niveles de P en el suelo y en el declinar de los rendimientos.