Dynamic Mechanical Properties of Wood Powder /Polypropylene Composites

The dynamic mechanical properties of wood powder/polypropylene composites with different wood content treated and untreated with the compatibilizer have been studied. It has been found that addition of wood powders and the compatibilizer can both improve the viscoelasticity of composites. Glass transition temperature (Tg) of appropriate wood powder-filled composites decreased. The value for the storage modulus (G') increased gradually with increasing wood powder content. The addition of the compatibilizer made glass transition temperature shift to a higher temperature. DSC (Differential Scanning Calorimetry) results showed that, for pure PP, the addition of the compatibilizer decreased its melting point, and increased its Calorie of Melt at the same time. For the composite with 50 % wood powder treated with the compatibilizer, the melting point was almost unchanged, but its Calorie of Melt decreased.     

日本北海道地区森林、牧场、草原和玉米田温室气体排放及模型研究

Information on the most influential factors determining gas flux from soils is needed in predictive models for greenhouse gases emissions.We conducted an intensive soil and air sampling along a 2 000 m transect extending from a forest,pasture,grassland and corn field in Shizunai,Hokkaido (Japan),measured CO 2 ,CH 4 ,N 2 O and NO fluxes and calculated soil bulk density (ρ b ),air-filled porosity (f a ) and total porosity (Φ).Using diffusivity models based on either f a alone or on a combination of f a and Φ,we predicted two pore space indices: the relative gas diffusion coefficient (D s /D o ) and the pore tortuosity factor (τ).The relationships between pore space indices (D s /D o and τ) and CO 2 ,CH 4 ,N 2 O and NO fluxes were also studied.Results showed that the grassland had the highest ρ b while f a and Φ were the highest in the forest.CO 2 ,CH 4 ,N 2 O and NO fluxes were the highest in the grassland while N 2 O dominated in the corn field.Few correlations existed between f a ,Φ,ρ b and gases fluxes while all models predicted that D s /D o and τ significantly correlated with CO 2 and CH 4 with correlation coefficient (r) ranging from 0.20 to 0.80.Overall,diffusivity models based on f a alone gave higher D s /D o ,lower τ,and higher R 2 and better explained the relationship between pore space indices (D s /D o and τ) and gases fluxes.Inclusion of D s /D o and τ in predictive models will improve our understanding of the dynamics of greenhouse gas fluxes from soils.D s /D o and τ can be easily obtained by measurements of soil air and water and existing diffusivity models.     

Detection of nitrate leaching through bypass flow using pan lysimeter,suction cup,and resin capsule

Abstract

We compared the use of mixed-bed ion exchange resin capsules (RC), suction cups (SC), pan lysimeters (PL), and subsurface drainage (DR) for the detection of nitrate movement through a clayey soil where onion (Allium cepa L.) had been cultivated over a period of seven months. At the topsoil level, solutions collected with SC showed higher concentrations of NO₃ ^? than the PL-collected samples. At 80-cm depth, however, the concentrations of NO₃ ^? were higher for the DR and PL samples than for the SC samples, suggesting that bypass or macropore flow was the primary mechanism of NO₃ ^? transport to subsurface drainage or groundwater, while solutions collected by SC mostly represented solutions inside soil aggregates. The use of the resin capsule method resulted in higher values of NO₃ ^? at 15- than at 50-cm depth initially but the trend was reversed after sufficient leaching and plant uptake. High and significant correlations were obtained between the amount of NO₃ ^? adsorbed on RC at 15-cm depth and the mean concentration of NO₃ ^? in the DR samples during the RC installation period and between the NO₃ ^? adsorbed on RC at 50-cm depth and the mean NO₃ ^? concentration of PL samples at 80-cm depth. Such results indicate that the RC method which enables the detection of nitrate transport via macropore flow is a promising technique for nitrate leaching measurements.     

Soil respiration and methane flux in adjacent forest,grassland, and cornfield soils in Hokkaido,Japan

Soil respiration and methane flux from adjacent forest, grassland, and cornfield were measured by using the closed chamber method from June to November, 1999 in Shizunai, Hokkaido, Japan, where the soil was an Aquic Humic Udivitrands derived from volcanic ash. The forest soil absorbed methane, at arate ranging from -0.12 to -0.02 mg C m_-2 h_-1, while the grassland soil emitted methane, at a rate ranging from undetectable levels to 0.18 mg C m_-2 h_-1. In the cornfield soil methane flux ranged from -0.01 to 0.04 mg C m_-2 h_-1. The soil respiration rate varied from 3 to 230 mg C m_-2 h_-1, 27 to 372 mg C m_-2 h_-1, and 29 to 156 mg C m_-2 h_-1 for the cornfield, grassland, and forest soils, respectively. Linear regression analysis demonstrated that the methane flux rate was positively correlated with the soil water-filled pore space (WFPS), and negatively correlated with the relative gas diffusion coefficient (D/D _o) and air-filled pore space (AFPS). Soil respiration rates were positively correlated with the soil temperature at all the sites. The Q ₁₀ value was 4.8, 3.3, and 1.9 for the cornfield, grassland, and forest soils, respectively.     

Characteristics of nutrient load in a stream flowing through a livestock farm during spring snowmelt

We investigated the stream water quality during the snowmelt period in a livestock farm, located in Shizunai, southern Hokkaido, Japan. The water quality was very different between the early stage of the snowmelt period (March 15–21) and the later stage (March 22–April 5) in 2001. The load of nutrients (NH₄ ⁺-N, T-P, K⁺) was large along with the increase of the flow rate and nutrient concentrations during the early stage of the snowmelt period. The molar ratios of Si / T-N and Si / T-P of the stream water, as an index of eutrophication, were also under the threshold values (2.7, 64.3, respectively) during the early stage of the snowmelt period. In addition, the relationship between the Si and nutrient concentrations (NH₄ ⁺-N, T-P, K⁺) showed a significantly negative correlation (R ² = 0.65), which indicated that the amount of nutrient load might be derived from surface runoff. Consequently both the quantity and quality of the stream water during snowmelt may exert an adverse effect on coastal waters, leading to eutrophication. Furthermore, since the main effluent source appeared to be surface runoff at the early stage of the snowmelt period, attention should be paid to land management before and during the snow covering period.     

Magnitude of nitrogen pollution in stream water due to intensive livestock farming practices

Abstract

This study was conducted to evaluate the magnitude of nitrogen (N) pollution in stream water associated with intensive livestock farming practices. An extensive water sampling was carried out from stream tributaries, open channels, drainages, and seepages during the snow-melting season in 2001. Total nitrogen (TN) concentration was determined and water flow was measured. The lowest concentration of TN in the headwater of tributary ‘A’ was as low as 0.39 mg N L^?1 (0.03 g s^?1 of N load), and the concentration reached a value of 5 mg N L^?1 in the outlet of the stream, which resulted in a N load of 1.37 g s^?1. The increase in the N load (1.34 g s^?1) was mainly due to drainage from a constructed wetland for livestock wastes, other drainages, and seepages from around the livestock sheds. The maximum concentration of TN in the drainage and seepage water from the constructed wetland was very high, 63 mg N L^?1, which resulted in a N load of 0.53 g s^?1 into the open channel that reached tributary ‘A.’ About 40% of the increased N load in the main tributary in the intensive livestock farming area was occupied by a single constructed wetland confirming that the drainage from this facility acted as the point source of pollution in the area.     

Evaluation of greenhouse gas emissions in a Miscanthus sinensis Andersson-dominated semi-natural grassland in Kumamoto,Japan

Increasing greenhouse gas emissions from anthropogenic activities continue to be a mounting problem worldwide. In the semi-natural Miscanthus sinensis Andersson; grasslands of Aso, Kumamoto, Japan, which have been managed for thousands of years, we measured soil methane (CH₄) and nitrous oxide (N₂O) emissions before and after annual controlled burns. We estimated annual soil carbon (C) accumulation, and CH₄ and N₂O emissions induced by biomass burning in 2009 and 2010, to determine the impacts of this ecosystem and its management on global warming. Environmental factors affecting soil CH₄ and N₂O fluxes were unknown, with no effect of annual burning observed on short-term soil CH₄ and N₂O emissions. However, deposition of charcoal during burning may have enhanced CH₄ oxidation and N₂O consumption at the study site, given that emissions (CH₄: ?4.33 kg C ha^?1 yr^?1, N₂O: 0.17 kg N ha^?1 yr^?1) were relatively lower than those measured in other land-use types. Despite significant emission of CH₄ and N₂O during yearly burning events in early spring, the M. sinensis semi-natural grassland had a large annual soil C accumulation, which resulted in a global warming potential of ?4.86 Mg CO₂eq ha^?1 yr^?1. Consequently, our results indicate that long-term maintenance of semi-natural M. sinensis grasslands by annual burning can contribute to the mitigation of global warming.