全文获取类型
收费全文 | 19195篇 |
免费 | 241篇 |
专业分类
林业 | 3843篇 |
农学 | 1390篇 |
基础科学 | 143篇 |
3231篇 | |
综合类 | 875篇 |
农作物 | 2245篇 |
水产渔业 | 2104篇 |
畜牧兽医 | 2327篇 |
园艺 | 1158篇 |
植物保护 | 2120篇 |
出版年
2023年 | 42篇 |
2022年 | 89篇 |
2021年 | 167篇 |
2020年 | 164篇 |
2019年 | 154篇 |
2018年 | 2841篇 |
2017年 | 2802篇 |
2016年 | 1306篇 |
2015年 | 182篇 |
2014年 | 159篇 |
2013年 | 191篇 |
2012年 | 1000篇 |
2011年 | 2338篇 |
2010年 | 2189篇 |
2009年 | 1336篇 |
2008年 | 1441篇 |
2007年 | 1712篇 |
2006年 | 156篇 |
2005年 | 186篇 |
2004年 | 191篇 |
2003年 | 231篇 |
2002年 | 125篇 |
2001年 | 37篇 |
2000年 | 81篇 |
1999年 | 27篇 |
1998年 | 17篇 |
1997年 | 15篇 |
1996年 | 6篇 |
1995年 | 10篇 |
1993年 | 17篇 |
1992年 | 11篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 17篇 |
1988年 | 17篇 |
1987年 | 5篇 |
1986年 | 7篇 |
1985年 | 11篇 |
1984年 | 6篇 |
1983年 | 8篇 |
1982年 | 5篇 |
1980年 | 6篇 |
1977年 | 5篇 |
1974年 | 4篇 |
1971年 | 8篇 |
1970年 | 6篇 |
1969年 | 9篇 |
1968年 | 9篇 |
1967年 | 7篇 |
1900年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
The dependence of the acidolysis reaction of a C6-C3 dimeric nonphenolic β-O-4 type lignin model compound, 2-(2-methoxyphenoxy)-1-(3,4-dimethoxyphenyl) propane-1,3-diol (veratrylglycerol-β-guaiacyl ether, VG), on the type of acid applied was examined using three different acids [0.2 mol/l HCl, 0.2 mol/l HBr,
and 0.1 mol/l (0.2 N) H2SO4 in 82% aqueous 1,4-dioxane at 85°C]. In the HCl system, the major reaction modes of the corresponding benzyl cation-type
intermediate (BC), which is produced by protonation of the α-hydroxyl group of VG and successive release of the water molecule, are the abstraction of the β-proton and hydride transfer from the β-to the α-position. The liberation of formaldehyde from the γ-hydroxymethyl group of BC is the predominant reaction mode in the H2SO4 system. Apparently, an unknown reaction mode or modes is operative in the early stage of the HBr system that causes rapid
disappearance of VG accompanied by the quantitative formation of 2-methoxyphenol without affording the common counterpart
of a Hibbert’s ketone, 1-hydroxy-3-(3,4-dimethoxyphenyl) propan-2-one. The reaction mode in the HBr system changes with the
progress of the reaction and is the same as that in the HCl system after the early stage. 相似文献
992.
Chihiro Kayo Seiji Hashimoto Atsunori Numata Masanori Hamada 《Journal of Wood Science》2011,57(3):234-240
We compared the greenhouse gas (GHG) emissions from a log pile (LP) to those from a sand compaction pile (SCP) and from cement
deep mixing (CDM) as measures against soil liquefaction, assuming that forest and waste management scenarios influence the
GHG (CO2, CH4, and N2O) balance of wood. We found little difference between the LP and SCP methods with respect to GHG emissions from fossil fuel
and limestone consumption. However, GHG emissions from the CDM method were seven times higher than emissions from the LP method.
In the GHG balance of wood, when the percentage of CH4 emissions from carbon in underground wood was lower than 3.3%, permanent storage in the log achieved greater reductions in
GHG emissions than using the waste log as fuel in place of coal or heavy oil. In order to obtain reductions in GHG emissions
by replacing SCPs or CDM with LPs, sustainable forest management with reforestation and prevention of CH4 emissions from the underground log are essential. Using reforestation, permanent storage of the log, no CH4 emission from the log, and using logging residues instead of coal, the LP can achieve reductions in GHG emissions of 121
tonnes of CO2 per 100 m2 of improvement area by replacing CDM. 相似文献
993.
Kana Yamashita Yasuhiko Hirakawa Shuetsu Saito Hiroshi Nakatani Motoyoshi Ikeda 《Journal of Wood Science》2011,57(5):363-370
To evaluate the bow variation in boxed-heart square timber of sugi (Cryptomeria japonica), bows from kiln-dried timber for five sugi cultivars with different longitudinal shrinkage trends were compared for two
stem heights. Two general trends were observed, depending on the cultivar: (1) either the bow was larger at the lower than
at the upper part of the stem, or (2) the bows at the lower and the upper parts of the stem were similar. In timber that had
larger bow values, the gradients of longitudinal shrinkage were large across the radius and along the length of the timber.
There was a positive relationship between the bow and longitudinal shrinkage. These results suggest that the bow variation
between the timbers was caused by a variation in longitudinal shrinkage, which was affected by the microfibril angle. Furthermore,
the bow was inversely proportional to the modulus of elasticity, which suggests that timber with a low modulus of elasticity
is susceptible to a large bow due to large longitudinal shrinkage. 相似文献
994.
To improve its overall performance, fast-growing poplar was modified using the vacuum-pressure-vacuum impregnation method
with a urea-formaldehyde resin-sodium montmorillonite intercalation as the modification solution. The results showed that
considerable amounts of urea-formaldehyde resin and montmorillonites entered the poplar tracheid, and some entered the microporous
wood. These substances formed bonds with the active groups in timber, causing reduced crystallinity in the amorphous region
of the poplar, a decreased level of free hydroxyl, and an enhanced association with hydroxyl and ether bonds. The density,
dimensional stability, and mechanical properties of poplar were markedly improved. The best results were obtained with 14%
sodium montmorillonite and 20% ureaformaldehyde resin: the bending resistance, compressive resistance, and elastic modulus
increased by 19.37%, 30.24%, and 50.06%, respectively. With elevated levels of sodium montmorillonite, the impact toughness
and wear rate decreased. 相似文献
995.
To improve the properties of particleboard, boards were produced using a sealed press. With the sealed press, boards were
processed under high-temperature and high-pressure steam. This increased the saturation temperature, causing a dramatic rise
in temperature inside the board, faster curing of the binder, and a shorter pressing time. The boards were bonded with urea
formaldehyde resin, melamine urea formaldehyde resin, or poly(methylene diphenyl diisocyanate) (PMDI). The sealed press improved
the internal bond strength and thickness swelling of boards regardless of the binder used during the reduced pressing time.
The increased bonding strength improved the board properties, allowing PMDI with a lower resin content to be used for bonding
the boards. 相似文献
996.
Mendes-Pinto MM Silva Ferreira AC Caris-Veyrat C Guedes de Pinho P 《Journal of agricultural and food chemistry》2005,53(26):10034-10041
Carotenoids and chlorophyll-derived compounds in grapes and Port wines were investigated by HPLC-DAD and HPLC-DAD-MS (ESP+) analysis. A total of 13 carotenoid and chlorophyll-derived compounds are formally reported in grapes, 3 are identified for the first time, pheophytins a and b and (13Z)-beta-carotene, and 3 others remain unknown. In Port wines 19 compounds with carotenoid or chlorophyll-like structures are present, 8 still unidentified. The young wines showed higher total carotenoid content and chlorophyll-like compounds compared to aged Ports, with lutein and beta-carotene as major carotenoids. Among samples analyzed of monovarietal Vitis vinifera L. cultivar wines produced with the five most important Douro varieties, Tinta Roriz contained the highest levels of carotenoids and Touriga Franca the lowest. The forced-aging study indicated that lutein was more sensitive to temperature than beta-carotene. Additionally, aged wines showed higher ratios of beta-carotene/lutein concentrations compared to new Ports. Rates of degradation of chlorophyll derivative compounds were higher than those for carotene and lutein. 相似文献
997.
Growth,P uptake and rhizosphere properties of wheat and canola genotypes in an alkaline soil with low P availability 总被引:1,自引:0,他引:1
Zakaria Solaiman Petra Marschner Dongmei Wang Zed Rengel 《Biology and Fertility of Soils》2007,44(1):143-153
The aim of the present study was to assess the role of soil type on growth, P uptake and rhizosphere properties of wheat and
canola genotypes in an alkaline soil with low P availability. Two wheat (Goldmark and Janz) and two canola genotypes (Drum
and Outback) were grown in a calcareous soil (pH 8.5) at two P levels [no P addition (0P) or addition of 200 mg kg−1 P as Ca3(PO4)2 (200P)] and harvested at flowering or maturity. Shoot and root dry weight, root length and shoot P content were greater in
the two canola genotypes than in wheat. There were no consistent differences in available P, microbial P and phosphatase activity
in the rhizosphere of the different genotypes. Shoot P content was significantly positively correlated with root length, pH
and phosphatase activity in the rhizosphere. The microbial community composition, assessed by fatty acid methylester analysis,
of the canola genotypes differed strongly from that of the wheat genotypes. The weight percentage bacterial fatty acids, the
bacteria/fungi (b/f) ratio and the diversity of fatty acids were greater in the rhizosphere of the canolas than in the rhizosphere of the wheat
genotypes. In contrast to the earlier studies in an acidic soil, only small differences in growth and P uptake between the
genotypes of one crop were detected in the alkaline soil used here. The results confirmed the importance of root length for
P uptake in soils with low P availability and suggest that the rhizosphere microbial community composition may play a role
in the better growth of the canola compared to the wheat genotypes. 相似文献
998.
Yuyou Zhi Peng Li Jiachun Shi Lingzao Zeng Laosheng Wu 《Journal of Soils and Sediments》2016,16(2):467-475
Purpose
Cadmium (Cd) is regarded as one of the most toxic heavy metals in the environment and can undermine the ecosystem function and human health at trace level due to its high toxicity. In order to reduce the anthropogenic Cd input into agricultural soil, it is of utmost importance to pinpoint the sources of Cd in soils and apportion their respective contributions.Materials and methods
One hundred twenty-seven topsoil samples and 21 subsoil samples were collected from croplands of Meishan Basin, Changxing County, Zhejiang Province, Eastern China, and analyzed for concentrations of Cd and other heavy metals. Finite mixture distribution model (FMDM) was employed to fit the data to obtain the local soil Cd threshold value, a critical indicator to assess soil heavy metal contamination. Then, principal component analysis (PCA) and geographic information system (GIS) were used to identify the potential sources of Cd. Finally, positive matrix factorization (PMF) was applied to apportion the source contributions.Results and discussion
Among the 127 topsoil samples, 71 were subject to Cd contamination with a mean concentration of 0.66 mg kg?1 while the others were considered as background with a lower mean concentration of 0.145 mg kg?1, close to the local background concentration of 0.142 mg kg?1. Further, three components were extracted by PCA and interpreted as natural background, lead-acid battery manufacturing plants, and construction material associated activities, respectively. Additionally, most of the topsoil samples around the lead-acid battery manufacturing plants, construction material plants, and limestone/marble quarries were classified as Cd contaminated. However, PMF failed to get a successful portioning.Conclusions
Lead-acid battery manufacturing plants and construction material associated activities were the main anthropogenic sources of soil Cd contamination. With the help of FMDM, it is possible to distinguish the contaminated soil and estimate the contribution of anthropogenic sources to soil Cd. The apportionment by PMF was not successful in this paper due to the high skewness or outliers of Cd concentration in sampling sites and violation of the assumption that all samples have the same sources.999.
Yalong Liu Ping Wang Genxing Pan David Crowley Lianqing Li Jinwei Zheng Xuhui Zhang Jufeng Zheng 《Journal of Soils and Sediments》2016,16(5):1460-1471
Purpose
Rice paddy soils undergo pedogenesis driven by periodic flooding and drainage cycles that lead to accumulation of organic matter and the stratification of nutrients and oxygen in the soil profile. Here, we examined the effects of continuous rice cultivation on microbial community structures, enzyme activities, and chemical properties for paddy soils along a chronosequence representing 0–700 years of rice cropping in China.Materials and methods
Changes in the abundance and composition of bacterial and fungal communities were characterized at three depths (0–5, 5–10, and 10–20 cm) in relation to organic carbon, total nitrogen, dissolved organic carbon, microbial biomass carbon/nitrogen, and activities of acid phosphatase, invertase, and urease.Results and discussion
Both soil organic carbon and total nitrogen increased over time at all three depths, while pH generally decreased. Microbial abundance (bacteria and fungi) and invertase and urease activity significantly increased with the duration of rice cultivation, especially in the surface layer. Fungal abundance and acid phosphatase activity declined with depth, whereas bacterial abundance was highest at the 5–10-cm soil depth. Profiles of the microbial community based on PCR-DGGE of 16S rRNA indicated that the composition of fungal communities was strongly influenced by soil depth, whereas soil bacterial community structures were similar throughout the profile.Conclusions
Soil bioactivity (microbial abundance and soil enzymes) gradually increased with organic carbon and total nitrogen accumulation under prolonged rice cultivation. Microbial activity decreased with depth, and soil microbial communities were stratified with soil depth. The fungal community was more sensitive than the bacterial community to cultivation age and soil depth. However, the mechanism of fungal community succession with rice cultivation needs further research.1000.
Peres C Gomes da Silva MD Barreiros S 《Journal of agricultural and food chemistry》2003,51(7):1884-1888
The esterification reaction of geraniol with acetic acid catalyzed by Novozym was studied in supercritical ethane (sc-ethane) and in supercritical carbon dioxide (sc-CO(2)). Water activity (a(W)) had a very strong effect on enzyme activity, with reaction rates increasing up to a(W) = 0.25 and then decreasing for higher a(W). Salt hydrate pairs could not prevent changes in a(W) during the course of reaction but were able to control a(W) to some extent and had a beneficial effect on both initial rates of esterification and conversion in sc-ethane. The enzyme was more active in sc-ethane than in sc-CO(2), confirming the deleterious effect of the latter already observed with some enzymes. Temperatures between 40 and 60 degrees C did not have a strong effect on initial rates of esterification, although reaction progress declined considerably in that temperature range. For the mixture of 50 mM acetic acid plus 200 mM geraniol, 100% conversion was achieved at a reaction time of 10 h at 40 degrees C, 100 bar, an a(W) of incubation of 0.25, and a Novozym concentration of 0.55 mg cm(-)(3) in sc-ethane. Conversion was below 50% in sc-CO(2) at otherwise identical conditions. With an equimolar mixture of the two substrates (100 mM), 98% conversion was reached at 10 h of reaction in sc-ethane (73% conversion in sc-CO(2)). 相似文献