Linear alkane polymerization on a gold surface

In contrast to the many methods of selectively coupling olefins, few protocols catenate saturated hydrocarbons in a predictable manner. We report here the highly selective carbon-hydrogen (C-H) activation and subsequent dehydrogenative C-C coupling reaction of long-chain (>C(20)) linear alkanes on an anisotropic gold(110) surface, which undergoes an appropriate reconstruction by adsorption of the molecules and subsequent mild annealing, resulting in nanometer-sized channels (1.22 nanometers in width). Owing to the orientational constraint of the reactant molecules in these one-dimensional channels, the reaction takes place exclusively at specific sites (terminal CH(3) or penultimate CH(2) groups) in the chains at intermediate temperatures (420 to 470 kelvin) and selects for aliphatic over aromatic C-H activation.     

The ‘Bavarian Turnip’ — a rediscovered local vegetable variety of <Emphasis Type="Italic">Brassica rapa</Emphasis> L. em. Metzg. var. <Emphasis Type="Italic">rapa</Emphasis>

The Bavarian Turnip (Bayerische Rübe, Brassica rapa L. em. Metzg. var. rapa) is a nearly lost crop today. Until 1900, this local variety was commonly grown in Bavaria for human consumption. The special and very distinct characters of this variety in comparison with recent breeds are preferred by the farmers families and assured the persistence and survival of this turnip in situ (on farm). In the region of Dachau and Freising, located north of Munich, only four farms are known, where this old crop is still grown and maintained. Urgent measures have to be taken to safe this cultural relict for future generations.     

Long-range interactions within a nonnative protein

Protein folding and unfolding are coupled to a range of biological phenomena, from the regulation of cellular activity to the onset of neurodegenerative diseases. Defining the nature of the conformations sampled in nonnative proteins is crucial for understanding the origins of such phenomena. We have used a combination of nuclear magnetic resonance (NMR) spectroscopy and site-directed mutagenesis to study unfolded states of the protein lysozyme. Extensive clusters of hydrophobic structure exist within the wild-type protein even under strongly denaturing conditions. These clusters involve distinct regions of the sequence but are all disrupted by a single point mutation that replaced residue Trp62 with Gly located at the interface of the two major structural domains in the native state. Thus, nativelike structure in the denatured protein is stabilized by the involvement of Trp62 in nonnative and long-range interactions.     

Heralded entanglement between widely separated atoms

Entanglement is the essential feature of quantum mechanics. Notably, observers of two or more entangled particles will find correlations in their measurement results that cannot be explained by classical statistics. To make it a useful resource, particularly for scalable long-distance quantum communication, the heralded generation of entanglement between distant massive quantum systems is necessary. We report on the creation and analysis of heralded entanglement between spins of two single rubidium-87 atoms trapped independently 20 meters apart. Our results illustrate the viability of an integral resource for quantum information science, as well as for fundamental tests of quantum mechanics.     

Taxonomy and evolution of cultivated plants: Literature review 1977/1978

Summary Important papers on taxonomy and evolution of cultivated plants published in 1977 and 1978 were put together and briefly discussed.

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Taxonomie und Evolution der Kulturpflanzen: Literaturübersicht 1977/1978

Zusammenfassung Wichtige Arbeiten über Taxonomie und Evolution der Kulturpflanzen aus den Jahren 1977–1978 wurden zusammengestellt und kurz kommentiert.

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: 1977 1978

, 1977–1978 . .

     

Simulated long-term effects of different soil management regimes on the water balance in the Loess Plateau, China

A soil management regime that improves water use efficiency (WUE) is urgently required to increase the sustainability of the winter wheat-summer fallow system in the Loess Plateau, China. However, the long-term partitioning of the water balance must be understood in order to evaluate the viability of possible soil management regimes. Therefore, an ecosystem model (CoupModel) was used to explore the effects on components of the water balance of five types of soil management regimes: conventional practice, wheat straw mulching, incorporation of high organic matter contents, compaction, and use of a harvested fallow crop. Three variants of the fallow crop approach were also considered, in which the crop was harvested 15, 30 and 45 days before sowing the wheat (designated Fallow-15d, Fallow-30d and Fallow-45d, respectively). Simulations were used to identify the relative magnitude of soil evaporation, wheat transpiration and deep percolation and to elucidate the temporal variability in these components for a selected location using climate records spanning 45 years. However, the soil management regime significantly influenced the magnitude of every component of the water balance (in terms of minimum, maximum and mean values) over the long periods considered. Consequently, wheat yield and WUE differed significantly among the simulated treatments. Mulching led to significantly lower soil evaporation, higher transpiration, and more frequent and extensive deep percolation than other regimes, thereby improving fallow efficiency (percentage of rainfall stored in the soil during the fallow period at the end of the fallow period), wheat yields and WUE. In contrast, soil compaction gave the opposite results, leading to the most unfavourable partitioning of the water balance reflected in the lowest wheat yield and WUE values of all the regimes. In 90% of the years no deep percolation occurred in the soil compaction simulations. Use of a fallow crop with optimal harvest timing (Fallow-30d) improved partitioning of the water balance (decreased soil evaporation) and did not significantly reduce wheat yield compared with conventional practice. High organic matter contents in the soil also had a positive influence on the water balance and improved wheat yield and WUE relative to conventional practice. Therefore, mulching appears to be the best management practice for the winter wheat-summer fallow system in the Loess Plateau, according to the simulations. Increasing soil organic matter may be the best option if mulching cannot be implemented. The ideal time for harvesting a fallow crop for use as green manure or fodder appears to be ca. 30 days before sowing the winter wheat.