Zusammensetzung und Speziierung der Bodenlösung eines mit Schwermetallen belasteten kalkreichen Bodens

Composition and Speciation of Soil Solution collected in a Heavy Metal polluted calcareous Soil Close to a brass foundry, which had emitted heavy metal containing dusts for over 80 years, soil water was collected in the topsoil (18 cm) and in the subsoil (40 cm) of a severely polluted Calcic Fluvisol by means of polyethylen suction cups over a period of 2 years. The total metal content of the topsoil (extracted with 2M HNO₃ at 100 °C for 2 hours) was 38 nmol g^?1, 24 μmol g^?1, and 25 μmol g^?1 for Cd, Cu, and Zn, respectively. The mean heavy metal concentrations of the soil solution were 0.5 mol L^?1, 300 nmol L^?1, and 200 nmol L^?1 in the topsoil and 0.6 nmol L^?1, 90 nmol L^?1, and 30 nmol L^?1 in the subsoil for Cd, Cu, and Zn, respectively. Solubility calculations showed that the soil solutions were undersaturated with respect to heavy metal carbonates as well as to hydroxides. It seems that the heavy metal concentration is determined by sorption processes rather than by precipitation. The composition of the soil solution has been shown to be governed by the presence, of calcite, by the soil temperature and by the partial pressure of CO₂ in the soil air. The pCO₂ in the soil air (in both depths) has been estimated at 2 mbar during the winter term and at 20 mbar during the summer term. A corresponding increase of the concentration of macroelements (Ca, Mg, Na) as well as of total dissolved carbonate and of dissolved organic matter (DOC) has been measured in the summer half year. No significant seasonal variations of the heavy metal concentrations were detected and no correlations with concentrations of other components could be found.     

Sample size and power determination for detecting interactions in mixtures of chemicals

In the analysis of mixtures of drugs/chemicals it is often of interest to test for the presence of interaction. If the hypothesis of no interaction (additivity) is not rejected, then the analyst may reasonably claim additivity if and only if the study is powered to a desired (e.g., biologically meaningful) level. The objective of this article is to address the sample size and power issues related to testing the hypothesis of additivity at specified mixture points. The study of disinfectant by-products (DBPs) found in drinking water, described in earlier literature, is used to illustrate the procedures for estimating power and sample sizes for detecting interactions at specified mixtures. The four trihalomethanes used in the study are bromodichloromethane (BDCM), chlorodibromomethane (CDBM), chloroform (CHCl₃), and bromoform (CHBr₃)     

The waldrapp, Geronticus eremita (Linnaeus, 1758): Historical review, taxonomic history, and present status

The Waldrapp ibis, Geronticus eremita Linnaeus, 1758, is known historically from Ancient Egypt, the Alps in southern Europe, the Near and Middle East, Morocco, and Algeria. This paper summarises what is known about the species from archaeological findings and historical expeditions to these regions, and outlines the taxonomic confusion which characterised this bird for four centuries—the 16th to 19th.

The ancient and recent decline of populations of the Waldrapp is discussed. The birds are at present restricted to about twelve breeding sites, totalling only about 400 individuals, in Turkey and Morocco, with an additional 400-plus specimens in captivity in zoos of the world. A plea is made for the conservation of this endangered species.     

Handling missingness when modeling the force of infection from clustered seroprevalence data

Modeling infectious diseases data is a relatively young research area in which clustering and stratification are key features. It is not unlikely for these data to have missing values. If values are missing completely at random, the analysis on the complete cases is valid. However, in practice this assumption is usually not fulfilled. This article shows the effect of ignoring missing data in modeling the force of infection of the bovine herpesvirus-1 in Belgian cattle and proposes the use of weighted generalized estimating equations with constrained fractional polynomials as a flexible modeling tool.     

Impacts from Deposition on Swedish Forest Ecosystems Identified by Integrated Monitoring

Integrated monitoring of ecosystems (IM) is an international co-operative programme (ICP) to control effects of air pollution and climate change on water, soil and biological systems. It is a part of the Convention on Long-Range Transboundary Air Pollution (CLRTAP) of the United Nations Economic Commission of Europe (UN/ECE). The ICP-IM is undertaken on sites/catchments to investigate acidification, eutrophication and heavy metals with an integrated approach. In Sweden, long-term time series from forest ecosystems, with a long and stable continuity, will reveal trends and changes in processes and enable modelling to be undertaken. Investigations of acidity/alkalinity in relation to mineral and organic acids indicated the importance of atmospheric deposition. Recent results show very high inorganic nitrogen retention (99%), a net loss of sulphur originating mainly from organic horizons, and a high inorganic aluminium content in the illuvial soil horizons which could be detrimental to forests. Forest deficiency could also be caused by an observed ongoing translocation of Zn to deeper soil layers implying a movement towards increased release to surface waters.     

Acidic deposition and its effects in southwestern China

The emissions of SO₂ in China correspond at present to 8–10 TgSyr^?1. The rapid industrialization has caused a dramatic increase in the emissions in recent years and this increase is likely to continue. This paper describes studies of concentrations and effects of acidifying substances in parts of the Guizhou and the Sichuan provinces where the S-emissions are large. A small catchment about 10 km from Guiyang centre was equipped with instruments for studies of soils, soil water and streamwater chemistry. The molar ratio Al/(Ca+Mg) is > 0.8 in soil water in some places. Two small streams have median pH-values about 4.6 and 5.1. Laboratory studies with selected Chinese soils showed that the anion adsorption was low. These studies gave also important information on soil sensitivity. The studies confirm that acid deposition may affect soils in parts of south-western China, but the sensitivity varies dramatically and there is a strong need for more information.     

Water allocation and management in an emerging spate irrigation system in Makanya catchment, Tanzania

Although spate irrigation systems are risk-prone, they can be an important component for livelihood security in semi-arid areas. Spate uses water (flood water), which upstream users often do not require, as rainfall during these periods is more than sufficient. The use of this flood water for spate irrigation is therefore a good opportunity to convert water with a low opportunity cost to high value water. As more rivers are closing, due to socio-economic and climate changes, spate irrigation may become increasingly relevant in semi-arid areas. Spate irrigation systems pose institutional and technical challenges: collective action is challenged by complex upstream-downstream interactions between users within the system, and the high labour demands for regular reconstruction of temporary diversion weirs and intake structures. This paper describes a spate irrigation system in Makanya village, Tanzania that emerged in response to increased upstream water use. We use three of the four dimensions (hydrological, hydraulic and sociological) of spate irrigation proposed by Van Steenbergen (1997) to assess the Makanya spate irrigation system. The Makanya spate irrigation system has an organisational structure that is similar to the canal irrigation (furrow) committees located upstream, and effectively deals with the institutional demands of managing water in spate irrigation systems. Water allocation is reminiscent to the water sharing arrangements existing in the full irrigation system, which previously was in place at the site and in the high- and midlands of the Makanya catchment and therefore set this system apart from the traditional spate irrigation practice elsewhere. Technically, a major challenge is the reconstruction of the head works after each flood. Another aspect is the changes in the river bed. Flash floods carry sediments that deposit on the fields, raising the elevation of the irrigated land every year and making it increasingly difficult for the river water to enter the plots. Improving system efficiency through modernisation of the diversion and distribution structures in this case is not feasible due to the huge amounts of sediments delivered to the system each year. Instead investments in conjunctive use of groundwater could be the solution because it involves a relatively small intervention, minimises the physical disturbance of the system, and therefore is likely to respect the existing locally developed water management arrangements.     

Generation of spatially coherent light at extreme ultraviolet wavelengths

We present spatial coherence measurements of extreme ultraviolet (EUV) light generated through the process of high-harmonic up-conversion of a femtosecond laser. With a phase-matched hollow-fiber geometry, the generated beam was found to exhibit essentially full spatial coherence. The coherence of this laser-like EUV source was shown by recording Gabor holograms of small objects. This work demonstrates the capability to perform EUV holography with a tabletop experimental setup. Such an EUV source, with low divergence and high spatial coherence, can be used for experiments involving high-precision metrology, inspection of optical components for EUV lithography, and microscopy and holography with nanometer resolution. Furthermore, the short time duration of the EUV radiation (a few femtoseconds) will enable EUV microscopy and holography to be performed with ultrahigh time resolution.     

Water solubility in aluminous orthopyroxene and the origin of Earth's asthenosphere

Plate tectonics is based on the concept of rigid lithosphere plates sliding on a mechanically weak asthenosphere. Many models assume that the weakness of the asthenosphere is related to the presence of small amounts of hydrous melts. However, the mechanism that may cause melting in the asthenosphere is not well understood. We show that the asthenosphere coincides with a zone where the water solubility in mantle minerals has a pronounced minimum. The minimum is due to a sharp decrease of water solubility in aluminous orthopyroxene with depth, whereas the water solubility in olivine continuously increases with pressure. Melting in the asthenosphere may therefore be related not to volatile enrichment but to a minimum in water solubility, which causes excess water to form a hydrous silicate melt.