Replacing inorganic fertilizer with anaerobic digestate may maintain agricultural productivity at less environmental cost

We applied digestate generated from the anaerobic digestion of slurry, undigested slurry, or inorganic N (ammonium nitrate) or NPK compound fertilizer to pots of grass and a grass–clover mix grown in two soils. Crop yields were equal or enhanced with digestate, and analysis of soil water showed that there was less potential for loss of nutrients via leaching. Replacing inorganic fertilizer with digestate may therefore maintain grassland productivity but with less impact on the environment.     

Molecular borromean rings

The realization of the Borromean link in a wholly synthetic molecular form is reported. The self-assembly of this link, which is topologically achiral, from 18 components by the template-directed formation of 12 imine and 30 dative bonds, associated with the coordination of three interlocked macrocycles, each tetranucleating and decadentate overall, to a total of six zinc(II) ions, is near quantitative. Three macrocycles present diagonally in pairs, six exo-bidentate bipyridyl and six endo-diiminopyridyl ligands to the six zinc(II) ions. The use, in concert, of coordination, supramolecular, and dynamic covalent chemistry allowed the highly efficient construction, by multiple cooperative self-assembly processes, of a nanoscale dodecacation with an approximate diameter of 2.5 nanometers and an inner chamber of volume 250 A(3), lined with 12 oxygen atoms.