东方蝼蛄膜翅表面形态与润湿性

利用扫描电镜分析了东方蝼蛄膜翅的表面形态.在OCA20型接触角测量仪上测量了水与东方蝼蛄膜翅展开表面各部位的接触角,分析了东方蝼蛄膜翅表面几何微结构与润湿性的关系.研究表明,东方蝼蛄膜翅展开后各部位的几何微结构各不相同,水与东方蝼蛄膜翅展开表面各部位的接触角平均值为94.4°～118.6°,表现出疏水性能.东方蝼蛄膜翅表面几何微结构与疏水性能的综合作用是其折叠后表面不沾土壤和水的重要机理.     

QuEChERS-高效液相色谱法测定果蔬中多菌灵残留

建立了一种以高效液相色谱（HPLC）测定果蔬中多菌灵残留的方法,该方法采用QuEChERS技术为前处理方法,以乙腈作为提取溶剂,以PSA（Primary Secondary Amine,N-丙基乙二胺）和C18填料作为净化材料。试验结果表明:多菌灵标准品在0.1～10.0 mgL范围内线性相关系数为1.000;方法定量限为0.1 mg/kg（SN=10）;加标浓度为0.5和5.0 mg/L的平行5次测试结果相对标准偏差分别为2.98%和1.72%;0.1、0.5和5.0 mg/L 3个不同浓度的加标回收率在96%~110%之间。      

基于热重法的植物油氧化动力学-甘油三酯相关性研究

通过热重(TG)及微商热重(DTG)法研究了6种常见植物油的热氧化特性,分析了不同温控程序对质量变化曲线的影响,通过微商热重曲线确定了不同升温速率下的氧化起始温度(T_(on))和氧化峰值温度(T_p),结合OzawaFlynn-Wall等转化率法对油脂的氧化动力学特性进行推导,并对油脂热氧化特性与其甘油三酯组成与分布的相关性进行了分析。研究结果表明:随着升温速率的增加,T_(on)和T_p均随之升高且T_p变化更为敏感;植物油的热力学特性与其甘三酯组成间具有不同程度的相关性,其中,T_(on)及T_(on)处活化能与高饱和度甘三酯呈正相关而与高不饱和度甘三酯呈负相关,T_p及T_p处活化能与各组分间具有相似的关系但相关性略有减弱,具体相关性与甘油骨架上脂肪酸链的种类有关。热重分析法所需样品微量、操作快捷、灵敏度高,在油脂加工及质量检测领域具有广阔的应用前景。     

Google Maps在农业WebGIS中的应用探索

针对目前国内农业WebGIS存在的信息单一、功能单调等问题,提出了将标准的地理信息系统开发平台和Google Maps同时应用于农业WebGIS的方法。利用Google Maps提供的开放地图接口自定义GoogleMap类可以为农业WebGIS系统提供详细的地理位置信息的显示、标注以及路线查询等功能。最后通过SuperMap.IS.NET开发平台与Google Maps实现对小汤山农业基地的信息管理,证明该方法实用可行。     

Evaluating eddy covariance method by large-scale weighing lysimeter in a maize field of northwest China

Accurate determination of evapotranspiration (ET) is useful to develop precise irrigation scheduling. Although eddy covariance (EC) is a direct method which is widely used to measure ET, its performance in arid region of northwest China is not clear. In this study, ET measured by EC (ET_EC) was compared with that by large-scale weighing lysimeter (ET_L) during the whole growing season of maize in 2009. Energy balance ratio was 0.84 for daytime fluxes, indicating that lack of energy balance closure occurred, so daytime ET_EC was adjusted by Bowen-ratio forced closure method. Compared to the corresponding ET_L, half-hourly daytime ET_EC was underestimated by 21.8% without the adjustment and 4.8% with the adjustment. Furthermore, nighttime ET_EC was adjusted using filtering/interpolation method. Mean error between half-hourly nighttime ET_EC and ET_L decreased from 30.2% without the adjustment to 10.3% with the adjustment. After such adjustment of day and night measurements, daily ET_EC was underestimated by 6.2% compared to ET_L. These results indicated that the adjusted ET_EC well matched with the ET_L. Moreover, the discrepancy of adjusted total ET_EC and ET_L was decreased to 3.2% after subtracting the overestimated ET by lysimeter resulting from irrigation and heavy rainfall events. Thus, after appropriate adjustments of observations, eddy covariance method is accurate in estimating maize ET in the arid region of northwest China.     

稻麦轮作制中秸秆钾与化肥钾利用的研究

采用盆栽试验,研究秸秆钾和化肥钾两种不同来源的钾素在作物和土壤中的吸收利用情况.结果表明:施用秸秆钾与化肥钾,稻麦轮作制中两季作物总产量基本相当;作物对秸秆钾与化肥钾的两季利用情况有较大差异,但两季总吸收量与利用率相差不大;作物施用秸秆钾当季应加强氮素的配合施用,特别是在小麦上;作物所吸收的秸秆钾与化肥钾有约80%以上贮存于秸秆中,只有约10%左右通过籽粒带走,另有约5%存在根茬.     

氮肥用量及施用时间对土体中硝态氮移动的影响

土连续两年小麦—玉米轮作条件下 ,播前一次施氮量 130～ 5 2 0kghm-2 a-1时 ,氮肥用量对硝态氮在土体中的移动深度没有影响 ,但土壤剖面中残留的硝态氮量随施氮量增加显著增加。播前一次施用氮肥 ,差减法计算的肥料氮表观回收率 (作物携出量和土壤硝态氮的残留量 )为 6 2 %～ 82 7% ;就作物而言小麦的携出率高于玉米 ,在玉米生长季节有更多的硝态氮可能被淋移至土壤剖面的下层。小麦—玉米轮作一年 ,不同的施氮时间对肥料氮的表观回收率以及硝态氮在土壤剖面中的分布、累计没有明显影响。土区合适的氮肥用量是控制硝态氮向深层移动的主要措施     

陕西省农田土壤硫含量空间变异特征及亏缺评价

陕西省 13种耕地土壤 30 5个表层 (0～ 2 0cm)土壤样点分析结果表明 :该省土壤全硫和用0 0 1molL-1Ca(H2 PO4) 2 浸提的有效硫含量分别为 33～ 76 9mgkg-1(均值 36 0mgkg-1)和 4 6～ 15 7 3mgkg-1(均值 2 9 3mgkg-1) ,其中黑垆土 (普通干润均腐土 )、绵砂土 (灌淤湿润砂质新成土 )的有效硫平均含量最低。土壤全硫具有中等空间相关性 ,有效硫空间相关性较差。土壤全硫和有效硫分布具有渐变性 ,其最大相关距离分别为 5 31km和 34km。全硫以较大区域变异为主 ;有效硫以小区域变异为特征。陕西省耕地土壤有效硫含量低于硫亏缺临界值 (18 5mgkg-1)的占总面积的 13 9% ,相当于 5 3 7万hm2 农田缺硫。陕西省中部地区 ,尤其是延安西部地区土壤硫亏缺风险较大     

Fractal features of soil particle size distribution and the implication for indicating desertification

Some of the effects of land desertification on soil properties are manifested by the coarsening of the soil particlesize distribution (PSD) and the losses in organic C and nutrients. The changes and characteristics of PSD and selected chemical properties in soils at the 0-15 cm plough layer from different degrees of desertified croplands are analyzed in the semiarid Horqin Sandy Land, northern China. The fractal dimension of the PSD is emanated to characterize the patterns of PSD. The relationships between the fractal dimension of the PSD and selected soil properties are discussed. The results show that: (1) in the transformation from potential desertified cropland to extremely desertified cropland, the sand content at the 0-15 cm soil increased from 69% to 93%, organic C and total N contents decreased by 65% and 69%, respectively; (2) the fractal dimension of PSD ranged from 2.179 to 2.611, the more the contents of sand, the lower the fractal dimension and the higher the desertified degree of farmland. In the desertification process within the studied area, the mean fractal dimension decreased from 2.555 for the potential desertified soils to 2.298 for extremely desertified soils; (3) there existed considerable linear relationships between fractal dimension and soil properties. It was shown that fractal dimensions of PSD are useful parameters able to monitor soil degradation and to estimate the degree of soil desertification.     

硅灰石纤维填充超高分子量聚乙烯基复合材料干滑动摩擦磨损的BP神经网络分析

超高分子量聚乙烯及其复合材料由于其优良的自润滑和防黏性能可用于农业工程装备中的滑动接触部件和触土部件。基于人工神经网络在复杂系统建模问题上的优越性,考察了几种因素对硅灰石纤维增强复合材料的摩擦和磨损性能影响的模型。考虑到输入、输出数据个数,调试设计了一个3×10×2的BP神经网络,其输入层由3个神经元构成,分别为硅灰石纤维的处理方法、硅灰石纤维的加入量和试验过程中的法向载荷。隐含层有10个神经元。输出层2个神经元分别为材料的摩擦系数和磨损量。基于上述BP神经网络对硅灰石纤维增强超高分子量聚乙烯基复合材料的干滑动摩擦磨损性能进行了模拟和预测。对神经网络的训练和检验表明该BP神经网络能够较好地预测影响因素对复合材料的干滑动摩擦和磨损的作用,大部分数据的预测值与试验值的误差在10%以内,其仿真精度能够满足实际的摩擦磨损预测要求。