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61.
A highly effective zirconium-modified activated sludge (Zr(IV)-AS) adsorbent was prepared from activated sludge and applied to remove phosphate from aqueous solutions by batch and column experiments. Characterized results revealed that zirconium was successfully loaded onto the activated sludge (AS), and the specific surface area and pore volume were substantially improved after zirconium loading on the AS. Zr(IV)-AS exhibited a high adsorption affinity for phosphate and the maximum adsorption amount was 27.55 mg P·g?1 at 25 °C. Adsorption isotherms of phosphate could be described by the Langmuir model, and the adsorption kinetics were well described by the pseudo-second-order model. Phosphate adsorption on Zr(IV)-AS increased monotonically with decreasing solution pH. The presence of SO42? in water resulted in slightly decreased phosphate adsorption on the adsorbent even at a high concentration (25 mmol/L), and a greater influence of HCO3? on adsorption could be ascribed to the increased solution pH with the addition of the HCO3?. Column adsorption experimental results showed that the adsorbent has excellent phosphate adsorption properties and that the effluent can meet the requirement of phosphorus in the national wastewater discharge standard of China. Phosphate-saturated Zr(IV)-AS can be effectively desorbed in 0.1 mol L?1 NaOH solution, and the regenerated adsorbent still possessed the high capacity. The adsorption between the adsorbent and the phosphate is due to the electrostatic interaction and anionic exchange at the surface of the Zr(IV)-AS. Furthermore, this approach provides a possibility of treating wastewater with waste and has the potential for industrial applications for the removal of phosphate from wastewater. 相似文献
62.
Katriina Kyllönen Hannele Hakola Heidi Hellén Markku Korhonen Matti Verta 《Water, air, and soil pollution》2012,223(3):1171-1182
Total gaseous mercury (TGM) fluxes from the forest floor and a boreal wetland were measured by a flux chamber technique coupled
with an automatic mercury vapour analyser. The fluxes were measured at three sampling sites in southern Finland, 61°14′ N,
25°04′ E in summer 2007, with additionally in situ TGM concentrations in the air at one of the sites and mercury bulk deposition
at another. Most of the flux data were collected during the daytime. At one of the sites, diurnal flux behaviour was studied,
and a clear cycle with an afternoon maximum and a night minimum was observed. The highest emissions (up to 3.5 ng m−2 h−1) were observed at the forest floor site having a moss and grass cover. At the wetland and litter-rich forest floor sites,
the emissions were below 1 ng m−2 h−1 and sometimes negative (down to −1.0 ng m−2 h−1), indicating mercury uptake. The measured average fluxes in August were 0.9 ± 1.1 and 0.2 ± 0.3 ng m−2 h−1 for the forest floor sites and wetland sites, respectively. The flux data were compared with the mercury bulk deposition,
which proved to be of the same magnitude, but opposite in sign. At the mossy forest floor site, the extrapolated TGM emissions
were 130% of the Hg deposition in August 2007. Comparison with other studies showed that the fluxes in background areas are
relatively uniform, regardless of measurement site location and method used. Airborne TGM remained at the background level
during the study, with an average value of 1.3 ± 0.2 ng m−3; it frequently showed a diurnal cycle pattern. 相似文献
63.
Soon-An Ong Li-Ngee Ho Yee-Shian Wong Komalathevi Raman 《Water, air, and soil pollution》2012,223(4):1615-1623
Combinations of sequential anaerobic and aerobic process enhance the treatment of textile wastewater. The aim of this study
was to investigate the treatment of diazo dye Reactive Black 5 (RB5)-containing wastewater using granular activated carbon
(GAC)–biofilm sequencing batch reactor (SBR) as an integration of aerobic and anaerobic process in a single reactor. The GAC–biofilm
SBR system demonstrated higher removal of COD, RB5 and aromatic amines. It was observed that the RB5 removal efficiency improved
as the concentration of co-substrate in the influent increased. The alternative aeration introduced into the bioreactor enhanced
mineralization of aromatic amines. Degradation of RB5 and co-substrate followed second-order kinetic and the constant (k
2) values for COD and RB5 decreased from 0.002 to 0.001 and 0.004 to 0.001 l/mg h, respectively, as the RB5 concentration increased
from 100 to 200 mg/l in the GAC–biofilm SBR system. 相似文献
64.
Lee KH Cho JY Lee HJ Ma YK Kwon J Park SH Lee SH Cho JA Kim WS Park KH Moon JH 《Journal of agricultural and food chemistry》2011,59(18):10124-10128
Two novel caffeoylmalic acid methyl esters, 2-O-(trans-caffeoyl)malic acid 1-methyl ester (6) and 2-O-(trans-caffeoyl)malic acid 4-methyl ester (7), were isolated from pear (Pyrus pyrifolia Nakai cv. Chuhwangbae) fruit peels. In addition, 5 known hydroxycinnamoylmalic acids and their methyl esters were identified: 2-O-(trans-coumaroyl)malic acid (1), 2-O-(cis-coumaroyl)malic acid (2), 2-O-(cis-coumaroyl)malic acid 1-methyl ester (3), 2-O-(trans-coumaroyl)malic acid 1-methyl ester (4), and 2-O-(trans-caffeoyl)malic acid (phaselic acid, 5). The chemical structures of these compounds were determined by spectroscopic data from ESI MS and NMR. Of all the isolated compounds, five hydroxycinnamoylmalic acids and their methyl esters (2-4, 6, 7) were identified in the pear for the first time. 相似文献
65.
Background, Aim and Scope The distribution of sediments in estuarine beaches is controlled by the interactions between sediment supply, hydrodynamic
processes and human intervention. The main purpose of this study is to characterize the sediments of Tagus estuarine beaches
in order to understand their origin and to contribute to a better knowledge of the Tagus estuary sediment budget.
Methods Surface sediment samples were collected across beach profiles and sand grain size analysis was performed by dry sieving. Grain
size statistics for the median (d50) and standard deviation (SDM) were obtained using the Moment method. This study was complemented by a qualitative evaluation
of the sediment composition. Cross-shore topographic surveys were conducted for selected sampling sites.
Results Tagus estuarine beach sediments are mainly composed of quartz sand particles which are fine-grained and well sorted near the
mouth of the estuary and medium to coarse-grained and moderately sorted in the inner domain. Compositional results show evidence
of active anthropogenic sediment sources, especially in the coarser fractions.
Discussion The analysis of the textural and compositional characteristics of beach sediments in the inner estuarine domain is compatible
with local sedimentary sources, while a marine signature is present at the mouth and inlet channel sediments. In the inner
domain, differences in the sedimentary processes are represented by the textural characteristics of the sediments, such as
the sorting degree and the gravel content. Sediment characteristics also reflect human intervention in the system, with the
introduction of anthropogenic and allochthonous particles and the mixture of sediments from different sources.
Conclusions The sediments of the inner Tagus estuarine beaches are derived from local Plio-Pleistocene outcrops while inlet and outer
estuary beaches reveal a dominant marine source. Beach textural variability observed in the inner domain is not related to
wave forcing gradients, but mainly to variations in the sedimentary processes along the estuarine margins and to human intervention.
Results show that the Tagus estuarine beaches depended, almost exclusively, on sediment input from local sources until the
last century. With increasing human occupation, sediment transfers became dominated by anthropogenically related activities
mainly connected with the occupation of estuarine margins and dredging.
Recommendations and Perspectives Further studies should extend the present level of knowledge in what concerns sand transport patterns through additional compositional
and geochemical analysis, and the development of new techniques in order to allow the quantitative evaluation of the impact
of human activities on the sediment budget. 相似文献
66.
There are several strategies that can be applied in SNP discovery as for example the locus-specific amplification of target genome regions 《分子植物育种》2007,5(2):248-249
There are several strategies that can be applied in SNP discovery, as for example the locus-specific amplification of target genome regions (Primmer et al., 2002; Van et al., 2004) or simultaneous assembly of anonymous sequences which are the product of whole genome shotgun sequencing (Webber and Myers, 1997) or reduced representation shotgun sequencing (Altshuler et al., 2000). The majority of these methods are highly cost-prohibitive, however, and there is a necessity for development of new strategies that would be more suitable for small and medium-scale laboratories. 相似文献
67.
The mechanism that controls the proportion of cannabichromene (CBC), a potential pharmaceutical, in the cannabinoid fraction
of Cannabis sativa L. is explored. As with tetrahydrocannabinol (THC) and cannabidiol (CBD), CBC is an enzymatic conversion product of the precursor
cannabigerol (CBG). CBC is reported to dominate the cannabinoid fraction of juveniles and to decline with maturation. This
ontogeny was confirmed in inbred lines with different mature chemotypes. A consistent CBC presence was found in early leaves
from a diverse clone collection, suggesting that CBC synthase is encoded by a fixed locus. Morphological variants possessing
a ‘prolonged juvenile chemotype’ (PJC), a substantial proportion of CBC persisting up to maturity, are presented. PJC is associated
with a reduced presence of floral bracts, bracteoles, and capitate-stalked trichomes. Genetic factors causing these features
were independent of the allelic chemotype locus B that was previously postulated and regulates THC and CBD synthesis and CBG accumulation. In contrast to previously described
Cannabis chemotypes, the cannabinoid composition of PJCs showed plasticity in that reduced light levels increased the CBC proportion.
The ability of PJC plants to enable the production of pharmaceutical raw material with high CBC purity is demonstrated. 相似文献
68.
Flavonoid constituents of Chorizanthe diffusa with potential cancer chemopreventive activity 总被引:11,自引:0,他引:11
Chung HS Chang LC Lee SK Shamon LA van Breemen RB Mehta RG Farnsworth NR Pezzuto JM Kinghorn AD 《Journal of agricultural and food chemistry》1999,47(1):36-41
An ethyl acetate-soluble extract of Chorizanthe diffusa was found to exhibit significant antioxidant activity, as judged by scavenging stable 1,1-diphenyl-2-picrylhydrazyl (DPPH) free radicals and inhibition of 12-O-tetradecanoylphorbol 13-acetate (TPA)-induced free radical formation with cultured HL-60 cells. Bioassay-directed fractionation of this extract using the DPPH antioxidant assay as a monitor led to the isolation of five structurally related flavonoids (1-5), including the novel compound 5,8,3',4',5'-pentahydroxy-3, 7-dimethoxyflavone (1). Isolates 1-5 demonstrated varying degrees of antioxidant or antimutagenic activity. Two of the compounds, 5,7,3', 4'-tetrahydroxy-3-methoxyflavone (2) and quercetin (4), were subsequently found to inhibit carcinogen-induced preneoplastic lesions in a mouse mammary organ culture model. Inhibitory activity of this type is known to correlate with cancer chemopreventive effects in full-term models of tumorigenesis. 相似文献
69.
Loss of pendimethalin in runoff and leaching from turfgrass land under simulated rainfall 总被引:2,自引:0,他引:2
A field study was undertaken to investigate runoff and leaching loss of the herbicide pendimethalin in turfgrass land of loamy sand soil. A series of plots constructed in a golf course fairway were surface-applied with pendimethalin SC formulation at the rate of 2. 25 or 4.50 kg a.i./ha and subjected to simulated rainfall at 2.0 cm/day for 10 consecutive days. Runoff losses of pendimethalin were the highest at the first rainfall and then gradually decreased with time. The first runoff event contained pendimethalin in its highest concentration, and in subsequent runoff samples the concentration decreased exponentially. The ranges of pendimethalin concentration were 80.9-18.2 and 177.4-48.6 microgram/L in the standard and double doses, respectively. Total losses by 20 cm of rainfall for 10 days reached 0.81 and 1.22% of the initial deposits at 2.25 and 4.50 kg a. i./ha, respectively. Pendimethalin concentration in the leachate collected at 30-cm soil depth was quite lower than that in the runoff, and the concentration rapidly decreased from 4.3-4.7 to 0. 2-0.4 microgram/L during the 10 days of rainfall treatment. Soil residue analysis at 45 and 90 days after pendimethalin treatment showed that more than 90% of the residue remained at the top 10 cm of soil depth. Low runoff and leaching confirmed that lateral and downward movement of the herbicide should be limited in turf soil. The half-life of pendimethalin under field conditions was 23-30 days and was not affected by application dose and rainfall treatment, but longer persistence was observed under laboratory conditions. Considering low runoff and leaching, as well as relatively short persistence in soil, it is concluded that little environmental carryover of pendimethalin would be expected in turfgrass land. 相似文献
70.