Photocatalytic Removal of the Antibiotic Cefotaxime on TiO<Subscript>2</Subscript> and ZnO Suspensions Under Simulated Sunlight Radiation

This study presents the main results about the removal of the antibiotic cefotaxime (CTX) under simulated sunlight radiation using heterogeneous photocatalysis with titanium dioxide (TiO₂) and zinc oxide (ZnO) in aqueous solutions. The effects of pH and catalyst initial load on pollutant removal were assessed considering the response surface methodology and a central composite circumscribed experimental design, which allowed to determine the optimized conditions that lead to a higher substrate elimination. Experimental results indicated that evaluated parameters have a significant effect on antibiotic removal in both TiO₂ and ZnO suspensions. In addition, the role of photogenerated holes, hydroxyl, and superoxide anion radicals on CTX degradation was evaluated to clarify the reaction mechanism. Finally, analysis of the dissolved organic carbon content in solutions and the antibacterial activity of treated samples showed that photocatalytic treatments were able to reduce a considerable portion of the organic matter present in the systems and its antimicrobial activity.     

Kinetic and Thermodynamic Studies of Chlorinated Organic Compound Degradation by Siderite-Activated Peroxide and Persulfate

The efficacy of two oxidant systems, iron-activated hydrogen peroxide (H₂O₂) and iron-activated hydrogen peroxide coupled with persulfate (S₂O₈ ^2?), was investigated for treatment of two chlorinated organic compounds, trichloroethene (TCE) and 1,2-dichloroethane (DCA). Batch tests were conducted at multiple temperatures (10–50 °C) to investigate degradation kinetics and reaction thermodynamics. The influence of an inorganic salt, dihydrogen phosphate ion (H₂PO₄ ^?), on oxidative degradation was also examined. The degradation of TCE was promoted in both systems, with greater degradation observed for higher temperatures. The inhibition effect of H₂PO₄ ^? on the degradation of TCE increased with increasing temperature for the iron-activated H₂O₂ system but decreased for the iron-activated hydrogen peroxide-persulfate system. DCA degradation was limited in the iron-activated hydrogen peroxide system. Conversely, significant DCA degradation (87% in 48 h at 20 °C) occurred in the iron-activated hydrogen peroxide-persulfate system, indicating the crucial role of sulfate radical (SO₄ ^??) from persulfate on the oxidative degradation of DCA. The activation energy values varied from 37.7 to 72.9 kJ/mol, depending on the different reactants. Overall, the binary hydrogen peroxide-persulfate oxidant system exhibited better performance than hydrogen peroxide alone for TCE and DCA degradation.     

Impact of an Urban Environment on Trace Element Concentrations in Domestically Produced Lettuce (<Emphasis Type="Italic">Lactuca sativa L.</Emphasis>)

Urban horticulture is gaining more and more attention in the context of sustainable food supply. Yet, cities are exposed to (former) industrial activities and traffic, responsible for emission of contaminants. Trace elements were monitored in soils located in the urban environment of Ghent (Belgium) and 84 samples of Lactuca satica L. lettuce grown on it. The effects of cultivation in soil versus trays, neighbouring traffic and washing of the lettuce before consumption were studied. The 0–30 cm top layer of soils appeared heterogenic in composition and enriched in Co, Cd, Ni and Pb within 10 m from the nearest road. Yet, no similar elevated concentrations could be found in the crops, except for As. Besides uptake from the roots, the presence of trace elements in the plants is also caused by the atmospheric deposition of airborne particulate matter on the leaf surface. Correlation analysis and principal component analysis (PCA) revealed that this latter transport pathway might particularly be the case for Pt, Pd and Rh. Concentrations of Cd did not exceed the 0.2 mg kg^?1 (fresh weight) threshold for Cd in leafy vegetables set by the European Commission. Measurements to reduce the health risks include the washing of lettuce, which effectively reduced the number of samples trespassing the maximum Pb level of 0.3 mg kg^?1 (fresh weight). Also, cultivation in trays resulted in a lower As content in the plants. Taking into account a vigilance on crop selection, cultivation substrate and proper washing before consumption are considered essential steps for safe domestic horticulture in urban environments.     

石油烃污染土壤生物修复工程实例

针对江苏某原油管道泄露石油污染土壤开展了修复治理工程,修复土方量共计4902.5m3,工程采用异位生物修复对石油烃污染土壤进行了无害化处理,所用生物修复药剂为森诺公司自主研发的营养盐。工程结果表明:对于该项目初始浓度约为45000mg/kg的石油烃污染土壤,通过森诺自研发营养元素刺激土著菌的生长,在适宜条件下,土壤中的石油烃能够达到项目的修复目标值(≤4500mg/kg)。工程项目石油烃污染土壤生物降解最优条件为:药剂投加比为2%,pH值为中性7,含水率为35%,降解时间为90d;增加药剂投加量和降解时间能提高污染土壤中石油烃的去除率,在土壤含水率为20%～50%或pH值为6～8的范围内,过高或过低的土壤含水率和pH值会抑制生物对土壤中石油烃的微生物降解。     

华北地区经济树种蚧害研究

对华北地区经济树种蚧虫的种类区系、发生和分布规律及为害特点进行了系统研究。据调查，现已知华北经济树种蚧虫共有９科１２２种。随纬度增高、立地条件恶化、植物群落简单、人为活动频繁、管理水平粗放，蚧虫种类增多，为害严重。一般情况下，观赏树木受害普遍，温室植物受害严重，果树及平原地区林木部分受害，山地森林受害轻微。     

纵向刨切生产薄木中刀具与产品质量的关系

本文探讨了纵向刨切机生产薄木过程中刀具的材料、形状及刀具与压尺的相对位置等因素对产品质量的影响。     

基于GIS的老挝-中国边境土地适用性评估

对老挝-中国边境林地使用变更进行了评估,并提出了茶叶的土地适用性。建立一个综合的基于GIS的分析系统（IGAS）,该系统支持老挝-中国边境的林地使用和土地适用性的评估研究。采用多标准分析和系统动态技术评估林地使用和土地适用性,同时预测了潜在的茶叶用地。收集到的土地数据和数据分析表明,整体研究区域为10325.07 km2,当前的森林覆被由1992年的6337.33 km2（占61.38%）减少到2002年的5106.28 km2（占49.46%）。当前的森林主要被转为潜在林地和专门的永久农业用地,甚至国家生物多样性保护区域被转为橡胶种植区。林地使用转变的主要原因是贫穷。为了解决这个问题,根据多标准方法,我们对研究区域中适用茶叶种植土地提出了2种分类方案。     

Limited response to nursery-stage mycorrhiza inoculation of <Emphasis Type="Italic">Shorea</Emphasis> seedlings planted in rubber agroforest in Jambi,Indonesia

We transplanted Shorea selanica and Shorea lamellata seedlings that either had or had not received ectomycorrhiza (EcM) Scleroderma columnare inoculum, commercially available and prescribed as standard practice in nursery, into rubber gardens of different age and plot history. The objective was to assess whether or not absence of fungal inoculants restricted seedling survival, growth, nutrient uptake and EcM formation in the first 2 years after out-planting in Jambi. Inoculation with EcM fungi in nursery had only limited positive effects on growth in height and diameter or N and P uptake, but it enhanced survival in the period 6–24 months after outplanting in all plots. With or without nursery stage inoculation, S. selanica and S. lamellata can be used for enrichment planting or reforestation in Sumatra as the species respond well to high light intensities. Presence of up to five morphotypes of EcM confirmed the availability of inoculum also in second generation rubber agroforests. Internal transcribe spacer sequencing revealed no S. columnare could be identified from the ectomycorrhizal roots of S. lamellata and S. selanica.     

Scots pine stand establishment with special emphasis on uncertainty and cost-effectiveness,the case of northern Finland

The effect of uncertainty on the cost-effectiveness of alternative chains of stand establishment in northern Finland was examined. The data were from a reforestation study of Scots pine (Pinus sylvestris L.) consisting of 288 sample plots, which were measured with respect to regeneration success. The study design included four site-preparation methods (patch scarification, ploughing, prescribed burning and disk trenching) combined with three reforestation methods (sowing, planting with containerized seedlings and planting with bare-rooted transplants). Initial reforestation density was 2,500 spots or seedlings per hectare, and the regeneration success was modeled as probability with two thresholds, namely 500 and 1,100 saplings. On formerly spruce-dominated as well as pine-dominated sites the most cost-effective chain was ploughing and planting with containerized seedlings, when threshold was 1,100 saplings per hectare. However, with threshold of 500 saplings the best performer was ploughing and direct sowing on both sites.     

Veterinary antibiotic sorption to agroforestry buffer,grass buffer and cropland soils

The potential of veterinary antibiotics (VAs) to impact human and environmental health requires the development and evaluation of land management practices that mitigate VA loss from manure-treated agroecosystems. Vegetative buffer strips (VBS) are postulated to be one management tool that can reduce VA transport to surface water resources. The objectives of this study were to (1) investigate oxytetracycline (OTC) and sulfadimethoxine (SDT) sorption to agroforestry buffer, grass buffer, and cropland soils, (2) evaluate differences in VA sorption to soils collected from different vegetative management and soil series, and (3) elucidate relationships between soil properties and VA sorption. Sorption/extraction isotherms for OTC were well-fitted by the Freundlich isotherm model (r ² > 0.86). OTC was strongly adsorbed by all soils and the VA was not readily extractable. OTC and SDT solid to solution partition coefficients (K _d) values are significantly greater for soils planted to VBS relative to grain crops. Significant differences in OTC and SDT K _d values were also noted among the soil series studied. Linear regression analyses indicate that clay content and pH were the most important soil properties controlling OTC and SDT adsorption, respectively. Results from this study suggest that agroforestry and grass buffer strips may effectively mitigate antibiotic loss from agroecosystems, in part, due to enhanced antibiotic sorption properties.