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The use of semi-natural grasslands for the production of renewable energy through conventional conversion techniques faces major limitations because of chemical and physical properties of the biomass. A new conversion procedure was developed which separates the biomass, as silage, into a liquid phase for biogas production and into a solid fraction to be used as fuel. Separation (mechanical dehydration) is carried out with a screw press after mashing with water (hydrothermal conditioning). The effect of hydrothermal conditioning at different temperatures (5, 60 and 80°C) and mechanical dehydration on mass flows of plant compounds into the press fluid was investigated for five grassland pastures typical of mountain areas of Germany. Results show that 0·18 of the crude fibre was transferred into the fluid, whereas more digestible organic compounds, such as crude protein and nitrogen-free extract, showed mass flows of 0·40 and 0·31 respectively. While 0·52–0·89 of potassium (K), magnesium (Mg) and chloride (Cl), which are detrimental for the combustion of the press cake, were transferred into the press fluid, more than 0·50 of calcium, which has positive combustion properties, remained in the press cake. Significantly ( P < 0·05) higher mass flows were detected at conditioning temperatures of 60°C (K and Mg) and 80°C (crude fibre and nitrogen-free extract) compared with the 5°C treatment. Because of the separation of solids and liquids, high proportions of P (0·61–0·74) and K (0·64–0·85) but only 0·32–0·45 of nitrogen exported from the grassland would be recycled with an application of the digestates from the anaerobic digestion of the press liquid. 相似文献
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The complexity of biomineralized structures suggests the potential of organic constituents for controlling energetic factors during crystal synthesis. Atomic force microscopy was used to investigate the thermodynamic controls on carbonate growth and to measure the dependence of step speed on step length and the dependence of critical step length on supersaturation in precisely controlled solutions. These data were used to test the classic Gibbs-Thomson relationship and provided the step edge free energies and free energy barriers to one-dimension nucleation for calcite. Addition of aspartic acid, a common component in biomineralizing systems, dramatically affected growth morphology and altered the magnitude of the surface energy. 相似文献
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PM Lundquist R Wortmann C Geletneky RJ Twieg M Jurich VY Lee CR Moylan DM Burland 《Science (New York, N.Y.)》1996,274(5290):1182-1185
The performance of amorphous organic photorefractive (PR) materials in applications such as optical data storage is generally limited by the concentration of active molecules (chromophores) that can be incorporated into the host without forming a crystalline material with poor optical quality. In polymeric PR systems described previously, performance has been limited by the necessity of devoting a large fraction of the material to inert polymer and plasticizing components in order to ensure compositional stability. A new class of organic PR materials composed of multifunctional glass-forming organic chromophores is described that have long-term stability and greatly improved PR properties. 相似文献