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1.
Sunghee Bang Jaekyeong Kim Jiwon Oh Ji-Seok Kim Seong-Ryong Yu Stephen Deyrup Yong-Sun Bahn Sang Hee Shim 《Marine drugs》2022,20(3)
Six new β-resorcylic acid derivatives (1–5 and 7) were isolated from a halophyte-associated fungus, Colletotrichum gloeosporioides JS0419, together with four previously reported β-resorcylic acid lactones (RALs). The relative and absolute stereochemistry of 1 was completely established by a combination of spectroscopic data and chemical reactions. The structures of the isolated compounds were elucidated by analysis of HRMS and NMR data. Notably, compounds 1–3 had a β-resorcylic acid harboring a long unesterified aliphatic side chain, whereas the long aliphatic chains were esterified to form macrolactones in 4–9. Among the isolated compounds, monocillin I and radicicol showed potent antifungal activities against Cryptococcus neoformans, comparable to clinically available antifungal agents and radicicol showed weak antifungal activity against Candida albicans. These findings provide insight into the chemical diversity of fungal RAL-type compounds and their pharmacological potential. 相似文献
2.
Protective effect of anthocyanins from black soybean seed coats on UVB-induced apoptotic cell death in vitro and in vivo 总被引:1,自引:0,他引:1
Tsoyi K Park HB Kim YM Chung JI Shin SC Shim HJ Lee WS Seo HG Lee JH Chang KC Kim HJ 《Journal of agricultural and food chemistry》2008,56(22):10600-10605
UVB radiation proves to be one of the most relevant environmental risks because of its hazardous effects, such as premature skin aging and especially skin photocarcinogenesis. Anthocyanins, water-soluble pigments present in plants, are known to be powerful antioxidants that help protect plants from UV damage. In this study, we aimed at investigating the protective effect of anthocyanins from black soybean [Glycine max (L.) Merr] seed coats on UVB-induced apoptosis, and furthermore, we investigated the molecular mechanism responsible for regulation of apoptosis in vitro and in vivo. Pretreatment with anthocyanins reduced UVB-induced reactive oxygen species levels and inhibited UVB-induced apoptotic cell death through the prevention of caspase-3 pathway activation and reduction of proapoptotic Bax protein levels. UVB irradiation induced apoptotic cell death, which was inhibited by topical application of anthocyanins in hairless mice. It is concluded that anthocyanins from the seed coat of black soybeans may be useful compounds to modulate UVB-induced photoaging. 相似文献
3.
Production of a desirable Brassica oleracea CMS line using an alloplasmic B. rapa CMS line carrying Diplotaxis erucoides cytoplasm as a bridge plant 下载免费PDF全文
Yoshiaki Fujita Keita Sunaga Su‐Hyeun Shim Wataru Yamada Takayuki Ohnishi Sang Woo Bang 《Plant Breeding》2018,137(2):162-170
In Brassica oleracea, production of F1 hybrid seeds mainly makes use of the improved Ogura cytoplasmic male sterile (CMS) line. However, reliance on one particular line is a risk, and it would be advantageous to develop other CMS lines. In this study, we transferred Diplotaxis erucoides cytoplasm to B. oleracea cultivars using an alloplasmic B. rapaCMS line as a bridge plant to avoid incompatibility between donor and recipient plants. The new B. oleraceaCMS lines, which were derived by four generations of backcrossing, had small rudimentary anthers with no pollen grain and showed complete male sterility. There was no functional defect in other floral organs, and the ability to receive normal pollen did not appear to be impaired. Moreover, the B. oleraceaCMS lines carrying D. erucoides cytoplasm had larger leaf areas and a normal plastochron. As a consequence, the B. oleraceaCMS lines carrying D. erucoides cytoplasm have the potential to be valuable alternatives for use in commercial B. oleracea hybrid seed production. 相似文献
4.
B Gui YY Shim RS Datla PS Covello SL Stone MJ Reaney 《Journal of agricultural and food chemistry》2012,60(35):8571-8579
Cyclolinopeptides are a group of naturally occurring hydrophobic cyclic peptides found in flaxseed and flax oil that have immunosuppressive activity. This study describes the measurement of flaxseed cyclolinopeptide concentrations using an internal standard HPLC method. In addition, the concentration of cyclolinopeptides in the seed of Canadian flax cultivars grown at two locations over two years is reported. The data are consistent with the formation of flaxseed cyclolinopeptides from two ribosome-derived precursors. Each precursor protein includes the sequences corresponding to three cyclolinopeptides from which those cyclolinopeptides are presumably derived by precursor processing. The concentrations of cyclolinopeptides C and E, which are encoded by the same gene sequence, are highly correlated, and the concentrations of cyclolinopeptides D, F, and G, which are encoded by a second gene sequence, are also highly correlated. The strong correlation between the cyclolinopeptides arising from the same gene may prove to be important in understanding how peptide concentration is controlled. Additional research may lead to approaches to improve flax either as a platform for peptide production or as a source of oil with improved drying properties and flavor. 相似文献
5.
The methanol extracts of five tropical plants, Baeckea frutescens, Glycyrrhiza glabra, Kaempferia pandurata, Physalis angulata and Quercus infectoria, exhibited potent antibacterial activity against the cariogenic bacterium Streptococcus mutans. In particular, G. glabra, K. pandurata and P. angulata conferred fast killing bactericidal effect against S. mutans in 2 min at 50 microg/ml of extract concentration. 相似文献
6.
7.
担子菌中牛磺酸的检测 总被引:2,自引:0,他引:2
Shim.M.J Park.T 《安徽农业大学学报》1999,26(3):302-305
利用基于离子交换色谱原理氨基酸自动分析仪检测了一些常见食用菌中牛磺酸的含量。牛磺酸在磷酸丝氨酸及磷酸乙醇胺洗脱液中经色谱分析可得到清晰的对称峰。灵芝的牛磺酸含量为每100g干重含3.7~83umol。火菇在所检蘑菇中牛磺酸含量高,每100g湿重含(83.2±6.6)umol,与陆生植物相近。双孢蘑菇与香菇的牛磺酸含量相对较高,每100g湿重含量约49~55umol,牡蛎蘑菇及糙皮侧耳的鲜重含量分别为(8.9±0.712)umol、(3.7±0.3)umol,木耳及甘露地衣的干重含量分别为(19.5±2.1)umol、(9.3±1.5)umol。高牛磺酸、无胆固醇的蘑菇有望作为低胆甾醇类食物的替代品。 相似文献
8.
We report measurements of synchronization in two nanomechanical beam oscillators coupled by a mechanical element. We charted multiple regions of frequency entrainment or synchronization by their corresponding Arnold's tongue diagrams as the oscillator was driven at subharmonic and rational commensurate frequencies. Demonstration of multiple synchronized regions could be fundamentally important to neurocomputing with mechanical oscillator networks and nanomechanical signal processing for microwave communication. 相似文献
9.
Goudah A Sher Shah S Shin HC Shim JH Abd El-Aty AM 《Journal of veterinary medicine. A, Physiology, pathology, clinical medicine》2007,54(10):607-611
The aim of this investigation was to examine the pharmacokinetics and mammary excretion of erythromycin administered to lactating ewes (n = 6) by the intravenous (i.v.), intramuscular (i.m.) and subcutaneous (s.c.) routes at a dosage of 10 mg/kg. Blood and milk samples were collected at pre-determined times, and a microbiological assay method was used to measure erythromycin concentrations in serum and milk. The concentration-time data were analysed by compartmental and non-compartmental kinetic methods. The serum concentration-time data of erythromycin were fit to a two-compartment model after i.v. administration and a one-compartment model with first-order absorption after i.m. and s.c. administration. The elimination half-life (t(1/2beta)) was 4.502 +/- 1.487 h after i.v. administration, 4.874 +/- 0.296 h after i.m. administration and 6.536 +/- 0.151 h after s.c. administration. The clearance value (Cl tot) after i.v. dosing was 1.292 +/- 0.121 l/h/kg. After i.m. and s.c. administration, observed peak erthyromycin concentrations (Cmax) of 0.918 +/- 0.092 microg/ml and 0.787 +/- 0.010 microg/ml were achieved at 0.75 and 1.0 h (Tmax) respectively. The bioavailability obtained after i.m. and s.c. administration was 91.178 +/- 10.232% and 104.573 +/- 9.028% respectively. Erythromycin penetration from blood to milk was quick for all the routes of administration, and the high AUC milk/AUC serum (1.186, 1.057 and 1.108) and Cmax-milk/Cmax-serum ratios reached following i.v., i.m. and s.c. administration, respectively, indicated an extensive penetration of erythromycin into the milk. 相似文献
10.
S.B. Shim I.H. Williams M.W.A. Verstegen 《Acta Agriculturae Scandinavica, Section A - Animal Sciences》2013,63(2-3):91-97
Abstract An experiment was conducted to investigate changes in the lumen and wall of the intestinal tract of weaned pigs caused by fructo-oligosaccharides (FOS) and consequences for growth. Twelve male pigs weaned at 24 days were individually housed and fed either control, 0.25% FOS, or 3% FOS diets for 21 days after weaning. The pH of chyme in the caecum and proximal colon were lower (p<0.001) in 3% FOS compared to other treatments. Mean molar proportions (%) of total SCFA values along the large intestine were significantly affected by FOS diet. Acetic acid was significantly higher in control compared with other treatments. Butyric acid and isobutyric acid were significantly increased in 0.25 and 3% FOS compared to the control. Feed intake, empty body weight gain, disaccharidase activities and villous height in the small intestine were not significantly affected by FOS. It was concluded that dietary FOS stimulates fermentation in the large intestine, but does not significantly affect enzyme activity, ammonia content, villous height and growth. 相似文献