基于纳米压痕技术的木材胶合界面力学行为

【目的】研究木材胶合界面的静态和动态力学行为,探讨树脂渗透对木材管胞壁层力学性能的影响,为木质复合材料制造工艺优化和增强改性提供理论依据。【方法】采用纳米压痕静态和动态力学测试技术(Nano-DMA),对针叶材火炬松与酚醛树脂(PF)、脲醛树脂(UF)胶黏剂所形成胶合界面区域各相材料的静态弹性模量、硬度、蠕变性能以及储能模量和损耗模量等力学行为进行分析。【结果】静态力学行为方面,在界面区域,PF和UF渗透进入管胞壁层后,木材管胞壁的弹性模量( E r)和硬度( H )提高;经PF渗透后,木材管胞壁的 E r和 H 分别增加7%和26%;Burgers蠕变力学模型可有效描述胶合界面区域管胞壁的纳米压痕蠕变特性,经树脂渗透后,木材管胞壁的瞬时弹性模量增加,黏弹性模量和黏性系数减小;在保载初期,PF界面区域木材管胞壁的蠕变柔量约下降60%,UF界面区域木材管胞壁的蠕变柔量约下降58%。动态力学行为方面,随着加载频率增加,界面材料的储能模量( E ′ r)逐渐增大,而损耗模量( E ″ r)和损耗因子(tan δ)呈减小趋势;当加载频率为10 Hz时,PF和UF树脂渗透使得管胞壁层的储能模量分别增加16%和29%。【结论】胶合界面区域胶黏剂进入管胞壁层,对木材管胞的静态力学性能具有增强作用,同时胶黏剂可提高管胞壁的短期抗蠕变能力;木材管胞壁具有较高的储能模量和损耗模量,而树脂的储能模量和损耗模量较低,经树脂渗透后,木材管胞壁的储能模量增加,但损耗模量和损耗因子呈下降趋势,可能对界面传递和分散应力产生不利影响。     

Mechanism for deformation of wood as a honeycomb structure II: First buckling mechanism of cell walls under radial compression using the generalized cell model

Coniferous woods were modeled as honeycomb cellular solids consisting of hexagonal-prism tracheids to examine the mechanism for radial compression. Because of the abrupt breaks of radial cell walls, it was assumed that the flrst break followed Euler's equation of buckling. The nominal stress at the buckling of the radial cell wall was theoretically obtained based on this assumption, and the actual nominal stress was obtained experimentally. The theoretical stress was found to correspond almost to the experimental value. This finding suggests that the abrupt first break that occurs in wood under radial compression can be mainly attributed to the buckling of radial cell walls.Part of this work was presented at the 47th annual meeting of the Japan Wood Research Society, Kochi, April 1997 and at the 1997 meeting of the Research Society of Rheology in the Japan Wood Research Society, Tsukuba, December 1997     

Piezoelectric behavior of wood under combined compression and vibration stresses I: Relation between piezoelectric voltage and microscopic deformation of a Sitka spruce (Picea sitchensis Carr.)

This study investigated the relation between piezoelectric behavior and the deformation of trachieds in real time under combined compression and vibration stresses. Scanning electron microscope images were recorded directly into a video recorder. Two types of microscopic destruction were observed in the specimens. With the first type, although a small uprush around the boundary of the annual ring was observed, the specimens were broken only by shearing fracture in the 45° direction. With the second type, the specimens were finally broken by shearing fracture after repeated buckling. In these cases the piezoelectric voltage increased almost linearly in the elastic region, proceeded to the maximal point, and then decreased gradually. Finally a clear peak appeared in the buckling and shearing fracture. There is a curved relation between the specific gravity and the piezoelectric parameter when the influence of voids is considered, and there is a linear relation between the dynamic Young's modulus and the piezoelectric parameter when the stress is considered.Part of this paper was presented at the 46th annual meeting of the Japan Wood Research Society in Kumamoto, April 1996     

Variation in density of Picea sitchensis in relation to within-tree trends in tracheid diameter and wall thickness

The influences of cambial age and ring width on density of Sitkaspruce (Picea sitchensis (Bong.) Carr) were analysed in relationto within-tree trends in tracheid diameter and cell wall thickness.Discs were sampled at breast height from a total of 24 trees,from seven stands at three contrasting sites in Wales, and atbreast height, 30 per cent and 60 per cent total tree heightfrom one of the stands. Across the juvenile wood, ring density decreased with ring numberfrom the pith while radial tracheid diameter increased. Theseoverall trends were considered to be inherent to tree growth,presumably associated with cambial ageing, since they occurredin all trees on all sites. In juvenile wood, density also variedwith site growth rate (as indicated by ring width) at similarcambial age, wider rings being associated with more rapidrateof change in tracheid diameter with ring number and with decreasein tracheid wall thickness. Consequently, on a site having treeswith high growth rate density decreased more rapidly acrossthe juvenile wood, down to a lower minimum value, than on siteswith a slower growth rate. In mature wood, the decrease in densitywith increase in ring width was associated with differencesin both tracheid diameter and wall thickness. Density was slightly(though not significantly) higher at breast height than in comparablerings at 30 per cent total height, associated with significantlythicker tracheid walls at breast height. Changes in radial tracheid diameter (with ring number, or withring width) were associated with greater differences in theearlywood than towards the latewood end of each growth ring,while variations in wall thickness with ring width were associatedwith rate of increase in wall thickness towards the latewoodend. This may account for some previously conflicting reportson influence of silvicultural management on density, for densityis likely to vary with influence of environment on the seasonalcycle of cambial activity. The extent of the juvenile wood as delimited by the inner coreof wide growth rings does not necessarily correspond to theregion of varying tracheid dimensions in Sitka spruce.     

Radial dislocations in the fibre wall of Eucalyptus regnans trees of high growth stress

Summary Microscopical examination of the xylem of straight Eucalyptus regnans trees of high growth stress revealed the presence of radial dislocations in the secondary wall of many of the fibres. These features were characterized by a localized disruption in the microfibrillar orientation of the cellulose and were evident in both unlignified and lignified cell walls. Dislocations were not detected in trees having low peripheral growth stress. The origin of these features was suggested to lie in the expansion of the cell wall during the relaxation of longitudinal growth stresses following removal of the sample from the tree. A similar origin of the typically convoluted form of the gelatinous layer of tension wood fibres is discussed.The author expresses his appreciation to Dr. J. D. Boyd for helpful discussions.     

日本落叶松无性系木材性质的遗传变异

对10个10年生日本落叶松无性系的木材基本密度、管胞参数进行了测定.结果表明:木材基本密度,早、晚材管胞宽度和早材长宽比无性系间差异显著;木材基本密度,早、晚材管胞长度,早晚材管胞宽度和早晚材长宽比径向变异模式相似,即从髓心向外以曲线形式不断增加,有时亦有起伏;早材从髓心向外以近似直线的形式缓慢增加,晚材从髓心向外以曲线形式增加,初期增加幅度较大,到一定年龄后趋于水平变化并略有波动;材质性状与树木年轮间的关系以对数方程、幂函数方程、指数方程拟合效果较好;除了晚材壁腔比和早材壁厚外,其它木材性质的重复力均在0.5以上,受中度或中度以上的遗传制约,按照20%的选择率,长宽比和晚材管胞长能获得较高的遗传增益.     

Tangential pitting in black spruce tracheids

Tangential pit features were studied in a 55-year old black spruce (Picea mariana (Mill) B.S.P.) tree by means of light and electron microscopy.It was found that tangential pitting is lacking from the greatest part of the growth ring, except for the last four tangential rows of latewood tracheids and the first row of early wood tracheids. The average number of pits per tangential wall of a 3.55-mm-long tracheid is 234, 144, 28, 4 and zero, respectively, in the last 5 tangential rows of latewood tracheids, starting at the growth-ring boundary.On the average, tangential pits measure 5.4 m in diameter, possess oval to elliptical apertures, and are randomly distributed uniformly over the tangential tracheid wall. All tangential intertracheid pits are bordered and in that respect are similar to those in the radial walls. Although most of the pits contain membranes with tori, some at the growth-ring boundary lack tori and exhibit randomly oriented microfibrillar structure.     

Control of tracheid cross-sectional dimensions in Norway spruce and Scots pine wood raw material

Abstract

Wood properties, including tracheid cross-sectional dimensions, show a large degree of variation. To improve the properties of products made from wood, different methods to control variation have been developed. This study aims to determine the theoretical efficiency of three control strategies: the fractionation of pulped tracheids into earlywood and latewood, the separation of juvenile and mature wood, and sorting of logs according to tree size. The efficiency of each method was studied by first constructing virtual trees from measured tracheid cross-sectional dimensions, then simulating the efficiency of above-mentioned methods. The tracheid dimension data include Norway spruce (Picea abies (L.) Karst.) and Scots pine (Pinus sylvestris L.). The simulations show that separation into earlywood and latewood classes has the highest theoretical efficiency and yields the lowest variances in raw material. Classification into juvenile and mature wood groups is the second most efficient method, and the sorting of logs according to the size class of the tree is the least efficient method. It was also concluded that the variation in cell-wall thickness and radial diameter mainly originates from differences between earlywood and latewood, whereas the variation in tangential diameter mainly originates from differences between mature and juvenile wood.     

Initial shapes of stress-strain curve of wood specimen subjected to repeated combined compression and vibration stresses and the piezoelectric behavior

This study investigated the relationship between the initial shape of the stress (σ)-strain (ε) curve of a Chamaecyparis obtusa wood specimen subjected to repeated combined compression and vibration stresses at various angles between the fiber direction and load direction and the piezoelectric behavior. The main findings of the study are: (1) the σ-ε curve became convex initially, and then the stress was proportional to the strain. The σ-ε curve had almost the same shape during both loading and unloading. (2) The σ-piezoelectric voltage (P) curve was nonlinear, with a maximal point or cusp on the curve, which had almost the same shape during both loading and unloading, as was also observed for the σ-ε curve. (3) The plot of the first derivative of the stress [dσ/dε (= σ′)] against ε was nonlinear. The σ′-ε and P-ε curves at various angles were fairly similar. (4) The stress at the maximal point (or cusp) of the σ-P curve decreased with an increase in the angle between the fiber direction and load direction. The tendency of the stresses was very similar to that of Young’s modulus and compression strength calculated from Hook’s law and Hankinson’s law, respectively.     

Longitudinal hardness and Young's modulus of spruce tracheid secondary walls using nanoindentation technique

Summary Using a mechanical properties microprobe, measurements of hardness and elastic modulus of tracheid walls in the longitudinal direction of spruce wood were obtained by continuously measuring force and displacement as a diamond indenter impressed a cell wall. Maximum mechanical properties were found at the edges of the walls of angular shaped tracheids. Both the hardness and elastic modulus of latewood cell walls were higher than cell walls in the earlywood. The high spatial resolution of this new concept of mechanical testing allows a direct comparison with ultrastructural and microchemical parameters of lignified cells which opens a wider area of applications for the understanding of intrinsic wood properties.This work was conducted while the senior author was a Visiting Scientist at the Oak Ridge National Lab, Oak Ridge, TN 37831, USA partly with joint fundings from the Austrian Science Foundation (Schrödinger scholarship J799-BIO)     

针叶树木材细胞力学及纵向弹性模量的计算--试件纵向弹性模量的预测

依据针叶树木材管胞和射线细胞的结构模型。使用计算机抽样模拟解剖结构参数。以及使用针叶树木材纵向弹性模量计算公式和方法,计算人工林杉木,马尾松幼龄材和成熟材试件纵向弹性模量,计算结果与常温条件下气干试件测定结果十分符合。在试件晚材率和管胞解剖结构参数改变的条件下。计算预测了人工林杉木,马尾松幼龄材和成熟材纵向弹性模量的变化。结果表明：试件纵向弹性模量随晚材率,管胞长度,管胞壁厚度的增加而增加,而试件纵向弹性模量随管胞直径增加而减小。本文提出的纵向弹性模量计算的预测方法,对于运用现代生物技术控制和改变针叶树木材的材质,材性有实际意义。     

湿地松15个家系木材材性遗传变异及优良家系评估

对浙江产湿地松15个家系的基本材性进行了测定与分析。结果表明：家系间管胞长度、管胞宽度、气干密度、抗弯强度、抗弯弹性模量、顺纹抗压强度差异极显著,管胞壁厚差异显著,胞壁率、冲击韧性差异未达显著水平。家系内管胞长度、管胞宽度、管胞壁厚差异均显著且高于家系间的差异,但气干密度、顺纹抗压强度、胞壁率和冲击韧差异不显著,表明在家系水平上进行木材气干密度、力学强度和管胞形态的家系选择可取得良好的效果。15个家系木材管胞长度、管胞宽度、管胞壁厚和胞壁率的广义遗传力分别为0．5466、0．3910、0．7173、0．1598,说明湿地松家系木材管胞性状(胞壁率除外)受中度或中下度遗传控制,通过一定强度的选择能获得较高的遗传增益。综合评定结果表明,04-28、06-17、06-20、08-7和08-9,5个家系为适用于培育纸浆材的优良家系,04-25、04-28、06-17、06-20和08-16,5个家系为适用于培育建筑材的优良家系。     

S3 lignin concentration in radiata pine tracheids

Summary Lignin concentration in the S3 layer of the tracheid wall of radiata pine was determined by making porosity measurements of hydrolysed cell walls using interference microscopy, with appropriate corrections for swelling. The mean S3 lignin concentration was approximately 53% v/v. The degree of swelling of different wall layers as a result of hydrolysis was proportional to the lignin concentration in that layer with values of 1.645 for the S2 layer, 1.357 for the S3 layer and 1.053 for the compound middle lamella.     

Fractography of shear failure surface of softwood decayed by brown-rot fungus

In order to investigate shear failure surface of decayed wood, wood pieces of ezomatsu (Picea jezoensis) were exposed to brown-rot fungus (Fomitopsis palustris), and standard shear test in radial plane was conducted. The failure surfaces were examined by scanning electron microscopy and surface roughness measurements were also conducted. Transwall failure that the crack elongated parallel to the tracheid axis was observed in the earlywood region through all phases of decay. Intrawall failure principally occurred in the latewood region on the early phase of decay. When decay progressed considerably, transwall failure that the crack elongated perpendicularly to the tracheid axis occurred. And transwall failure was also dominant failure morphology in the latewood region. Fragments of tracheids which were partly peeled out from S₂ layers were observed in some specimens. Size and appearance frequency of fragments of tracheid were smaller and lower when decay progressed. Arithmetic average roughness, which was the index of fragment size and appearance frequency, had positive correlation to shear strength ratio. Especially, line surface roughness of radial direction, which was measured across the radial files of tracheid, had the highest correlation to the shear strength ratio. The surface roughness would be a good indicator to evaluate the decay degree.     

Arrangement of cortical microtubules in compression wood tracheids of Taxus cuspidata visualized by confocal laser microscopy

Cortical microtubules (MTs) in differentiating compression wood tracheids of Taxus cuspidata stems were visualized by confocal laser microscopy. They were oriented obliquely at an angle of about 45° to the tracheid axis during formation of the secondary wall. Artificial inclination altered the pattern of alignment of MTs. Banding MTs were helically oriented late during the formation of the secondary walls. These results indicate that MTs might control the orientation and localized deposition of cellulose microfibrils in the secondary walls of compression wood tracheids.Part of this report was presented at the 46th annual meeting of the Japan Wood Research Society, Kumamoto, April 1996     

Tracheid length in relation to seedling height in conifers

Summary Changes in tracheid length during the development of primary and secondary xylem are analysed in relation to the division and elongation of cambial initials, in first year seedlings ofPinus sylvestris andPicea sitchensis. During primary and early secondary growth tracheid length varies with leaf internode length, but this relationship soon becomes obscured during later secondary growth. Correlations between seedling height and tracheid length thus depend on variation in tracheid length with radial xylem increment before and after terminal bud production. Since the relation between shoot and tracheid length is a complex one, the clonseness of the correlation varies with environmental treatment, but overall, a doubling of shoot length increased tracheid length by about 10%.I am grateful to ProfessorS. D. Richardson andDr. G. K. Elliott for many helpful suggestions. This work was financed by a grant from the Natural Environment Research Council. Plants were grown from seed kindly supplied by the Forestry Commission Research Division (Scotland and North England).     

人工林班克松木材材质径向变异规律研究

以人工林班克松的木材解剖性质为研究对象,分析研究其株内木材材质径向变异模式,对其幼龄材和成熟材进行初步界定。结果表明：早材管胞径弦向直径和晚材胞壁率的变化符合PashinⅠ模型,早材胞壁率的变化符合PanshinⅢ模型;回归分析中早材拟合度较晚材好;幼龄材和成熟材的初步界定年限为9-11a。     

Electron microscopic study on the development of the bordered pit in coniferous tracheids

Summary The observations of the inner surface of Japanese red pine (Pinus densiflora Sieb. et Zucc.) earlywood tracheid wall in the various stages of the differentiation allowed the study of the development of the bordered pit. The process of the formation of the bordered pit membrane and the deposition of the cell wall layers in the pit border region were examined in detail by electron microscopy using the replication preparation technique. The microfibrillar structure of the margo and torus, which is characteristic of the bordered pit membrane of this species, was detected in the later stage of primary wall formation. The bordered pit membrane was shown to have the same microfibrillar structure as that of the matured one even at this stage of differentiation, although it was embedded in matrix substances. It appeared that the matrix substances were removed immediately after the warty layer had been formed in the tracheid wall.The initiation of pit border development was observed as the deposition of circularly oriented microfibrils around the vicinity of the pit annulus in the later stage of the primary wall formation. The deposition of the S₁-layer was indicated to contribute to the pit border formation until the diameter of the pit aperture reached its final size, simultaneously with the apposition of the layer of so-called B. T. or initial border thickening. So both the S₁-layer and initial border thickening were assumed to be formed supplementing each other. In the period of the S₁-layer formation, the transversely deposited microfibrils in the tracheid inner surface were detected to generally curve around the pit aperture and some of them extend to the outer surface of the developing pit border beyond the pit aperture. From these observations of replicas of the inner surface of the differentiating tracheid, a concept concerning pit border formation is proposed.The authors are indebted to members in Kyoto University Forest for providing the samples and to Dr. H. Saiki and other members of Wood Structure Laboratory in Department of Wood Science and Technology at Kyoto University for their assistance during this study. They also express their appreciation to Dr. W. A. Cote, Jr. (State University, College of Forestry, N. Y.) and Dr. W. Liese (Universität Hamburg) for their considerate advice.     

Study on tracheid variation ofPicea koraiensis (nakai) in natural stand and plantation

Tracheid characteristics ofPicea koraiensis from natural stand in Liangshui area and plantation in Mao'ershan area were studied. The results of variance analysis showed that the tracheid length, diameter, and thickness of tracheid wall were significant differences between the growth rings. All those characteristics tend to increase from heart-center to bark. In natural stand, it has positive correlation between the characteristics. In plantation, the tracheid length has positive correlation with the trachied diameter, while both the trachied length and the trachied diameter has negative correlation with the thickness of trachied wall. The tracheid length and diameter have no significant difference in growth between natural stand and plantations. The thickness of tracheid wall from the plantation is a little thicker than that from the natural stand before 15 years. Foundation item: This paper was part of State 9th Five-Year Plan project of “Early Mensuration ofPicea koraiensis (nakai)”. Biography: REN Xu-qin (1973-), female, graduate student in Northeast Forestry University, Harbin 150040, P. R. China. Responsible editor: Song Funan     

Variation Within Trees of Wood Anatomical Properties in Chinese-Fir Plantation and Their Relationship Modeling Equations

A comprehensive analysis on the variation pattern of early- and latewood tracheid morphological parameters along tree (Cunninghamia lanceolata Hook.) height, including length and width, wall thickness, tissue proportion, cell wall percentage, width of growth rings, and on the relationship among them are conducted. The results indicate an initially rapid and then gentle increase of tracheid length and width, thickness of the radial wall and tangential wall of tracheid, area percentage of tracheid from pith to outward, while S2 microfibril angle (Mfa) of tracheid, and rays percentage gradually decrease and then tend to be stable. The variation of all anatomical parameters but earlywood cell wall thickness shows no significance along tree height. The radial variation pattern of width of growth rings is characterized with initially slight decrease followed immediately by a rapid and then much more gentle increase from pith to outward. The delimitation age between juvenile and mature wood is 14-16 years. Com