A rapid method to determine cation exchange capacity and exchangeable bases in calcareous,gypsiferous, saline and sodic soils

Summary

A simple, single‐step extraction with LiEDTA for the estimation of CEC and exchangeable bases in soils has been developed. Multivalent cations are stripped from the soil adsorption sites by the strongly chelating agent EDTA, and are replaced by Li. In soils without CaCO₃ or water soluble salts, exchangeable divalent cations (Ca, Mg) are chelated by EDTA and exchangeable monovalent cations (Na, K) are replaced in a single extraction step using 0.25–2.5 g of soil and 10.0 ml of extractant.

In calcareous soils the CEC can be determined in the same way, but for the extraction of exchangeable Ca and Mg, another separate extraction is needed because dissolution of calcite by EDTA is unavoidable. This extraction is done with as much NaEDTA as needed to extract only exchangeable Ca and Mg in a 1:2 (m/V) soil/alkaline‐50% (V/V) aethanolic solution to minimize dissolution of calcite.

In gypsiferous soils gypsum is transformed into insoluble BaSO₄ and soluble CaEDTA by LiBaEDTA thus avoiding interference of Ca from dissolution of gypsum, which renders the traditional methods for determining CEC unsuitable for such soils. To determine exchangeable Ca and Mg, Na₄EDTA is used as for calcareous soils.

In saline/sodic soils replacement of Na by Li is incomplete but the Na/Li‐ratio at the complex after extraction is proportional to the molar Na/Li‐ratio in the extracts, so that the CEC and original exchangeable sodium (ESP) content can be calculated. Additional analysis of Cl and, if necessary, SO₄ in the extracts of saline soils can be used to correct for the effect of dissolution of the salts on the sum of exchangeable cations.

This new method is as convenient as the recently developed AgTU (silverthiourea), but is better suitable for calcareous and gypsiferous soils.     

Soil property changes following conversion of acacia woodland into grazing and farmlands in the Rift Valley area of Ethiopia

Continued conversion of woodlands into grazing and farmland is seriously undermining the natural ecosystem of the dry and fragile Rift Valley areas of Ethiopia. This study investigated the effects of land‐use change on soil organic carbon (SOC), total nitrogen (N), pH, exchangeable bases, cation exchange capacity (CEC) and base saturation (per cent) in three adjacent land‐use types: controlled grazing, open‐grazing and farmland. A total of 81 soil samples were collected and analysed. Contents of SOC and total N decreased drastically in open‐grazing and farmland (p < 0·001), and were significantly higher in the top 0·2 m than in the subsurface soil layer. Compared with the controlled grazing, reductions in the contents of SOC and total N in the top 1 m soil layer were 22–30 and 19 per cent, respectively, due possibly to the decrease in plant biomass input into the soil and the fast decomposition of organic materials. Long‐term cultivation had significantly increased the concentration of exchangeable K. Exchangeable Na was high in the lower layers, while Mg was higher in the top surface soil. CEC also varied with soil depth (p = 0·016); it was higher in the topsoil than in the subsurface soil, which may be, among others, due to the differences in soil organic matter distribution with depth. Although these semi‐arid soils are known to have low organic carbon and CEC levels, the values from the current study area are critically low, and may indicate the further impoverishment of the soils under high agricultural and grazing pressures. Copyright © 2010 John Wiley & Sons, Ltd.     

Soil morphological and chemical properties in homegardens on sandy beach ridges along the east coast of Peninsular Malaysia

The morphological and chemical properties of homegardens in the beach ridges with interspersed swales (BRIS) soils were evaluated in order to find a clue for developing sustainable agricultural management. Field survey and soil sampling were conducted at the homegardens and secondary forests in Sungai Ular Village and in the experimental farm of Malaysian Agriculture Research Institute (MARDI), Cherating Station. Chemical fertilizers including ash, charcoal waste and plant litter were applied to the homegardens in both the inland-ward area (HG-I) and in the shoreline area (HG-S). Manure was applied in HG-I and seafood waste from fish processing was buried in the soils in HG-S. High correlation was found between total carbon (T-C) and cation exchange capacity (CEC), indicating soil organic matter was the determinant factor for CEC in the very sandy BRIS soils. The levels of T-C, total nitrogen (T-N), and CEC at 0–10 cm in HG-I in parallel with increasing ages of homegardens. The soils in 0–10 cm and 20–30 cm showed higher levels of T-C and T-N with higher C/N ratios in HG-I than in HG-S and the MARDI farm. The high levels of exchangeable Ca, Mg, and K in HG-I compared with the MARDI farm, suggesting that improved CEC with increasing soil organic matter in HG-I heighten the retention of basic cations supplied as chemical fertilizer, ash, and manure. The level of available P was higher in HG-S than HG-I, attributed by the seafood waste application in the shoreline area. Thus, on the BRIS, the levels of soil organic matter and nutrients can be sustained by the homegarden management although it cannot be regarded as a closed system compared with those in the other tropical regions because chemical fertilizer was used and a certain amounts of nutrients seemed to leach down beyond plant rooting depth.     

Assessing the plant minimal exchangeable potassium of a soil

The plant minimal exchangeable K (E_Pl,min) defines the lower accessible limit of the most available pool of soil K to plants. It is also an index of long‐term K reserve in soils. However, its estimation by the classical method of exhaustion cropping is laborious. This study aimed at comparing E_Pl,min values obtained by the exhaustion cropping method with E_Pl,min values estimated by an alternative approach based on the cationic exchange capacity (CEC) of the infinitely high selective sites for K (i.e., always saturated with K) in the K‐Ca exchange (E_K‐Ca,min). A set of 45 soil samples, corresponding to the various fertilization K treatments of 15 long‐term K fertilization trials, was used in this study. The selected soil samples presented a wide range of texture, CEC, and exchangeable K. The plant minimal exchangeable K was found more or less independent of the K treatment, whereas E_K‐Ca,min increased when the soil exchangeable K content increased. The plant minimal exchangeable K was systematically lower than E_K‐Ca,min, showing that E_K‐Ca,min is at least partially available to the plant. Hence, E_K‐Ca,min is not a surrogate of E_Pl,min. Conversely, the plant minimal exchangeable K was strongly, positively correlated to soil CEC (measured at soil pH; r² = 0.90^***). This soil property can consequently be used as a proxy of E_Pl,min.     

Characterization of Spatial Variability of Soil Parameters in Apple Orchards of Himalayan Region Using Geostatistical Analysis

ABSTRACT

Knowledge of spatial variability in soil properties is critical for effective nutrient management plan in crop production. Poor productivity of apple orchards in Indian Himalayan Region (IHR) is due to lack of information on the variability of soil properties important for enhancing productivity in the region. The study was conducted in apple orchards with the hypothesis that spatial variability of soil properties is high due to adoption of varied management and passive soil factors. The major objectives of the study were to assess the spatial variability of soil parameters, viz. soil pH, electrical conductivity, soil organic carbon along with plant available soil nitrogen (N), phosphorus (P), potassium (K), exchangeable calcium (Ca), and exchangeable magnesium (Mg) at a regional scale through geostatistical methods. Coefficient of variation (CV) indicated that the fertility parameters varied from medium to high in heterogeneity (CV > 20%). Available N was found critical/medium in 69.6% of soil samples and might be one of the limiting nutrients for crop growth, P and K were in high, and OC in very high range. Significant correlation was found between OC with N; pH with K, Ca and Mg and EC with OC, P and K. The semivariogram parameters indicated that the spatial distribution of soil fertility parameters were inconsistent and showed strong to weak degree of spatial dependence for all parameters. The study highlighted the importance of delineation of soil fertility management zones in the apple growing region as a guide for precise and site-specific nutrient.     

我国华南地区不同利用条件下土壤演变对障碍因子的影响

华南地区不同土壤利用条件下土壤性质演变和障碍因子的识别,对该地区土壤发生过程和管理利用有重要参考价值。本文根据中国土壤系统分类的检索原则,在收集华南9省土种志典型剖面资料的基础上,确定了系统分类的土壤类型,并基于此,研究了不同利用条件下,土壤性质的演变,分析了土壤障碍因子及其影响程度。总的来看,发育在林地条件下的土壤,粉粒、pH、阳离子交换量(CEC)、盐基饱和度(BS)、速效磷、速效钾都明显低于旱耕地土壤,有机质、全氮则相反。林地土壤随着风化作用增强,从雏形土、淋溶土、富铁土到铁铝土,土壤黏粒含量逐渐增加,而土壤pH、CEC、有效CEC(ECEC)、有机质、全氮、速效磷、速效钾等逐渐降低。对旱耕地而言,各种土壤性质基本具有与林地土壤性质一致的变化趋势,但是增加或减少的程度有所不同。结合主成分中土壤性质的组合特征来分析土壤障碍,结果表明华南地区土壤在不同土壤利用和类型下都存在养分贫瘠化、酸化、黏化、磷和钾供应能力低下的主要障碍因子,但各障碍因子发生的次序不同,随着风化作用加强,土壤黏化成为最主要的障碍因子。因此,在土壤利用和管理过程中应因土制宜,根据土壤类型来确定适当的改良措施。     

Morphological,chemical, and physical characteristics of shrink‐swell soils in a mediterranean semiarid region

Abstract

Heavy clay soils with swell‐shrink properties comprise most of the arable land in northern Jordan. These soils are classified as Vertisols. Vertisols occupy a large and important part of the agricultural land in Jordan where rainfed agriculture is practiced. Five sites were selected to represent Vertisols occurring in different precipitation zones. Soil characterization was carried out to provide useful information to understand the genesis and behavior of these soils. Vertisols in northern Jordan occur on flat to gently sloping plains. Clay, silt, and sand fractions were uniformly distributed indicating active pedoturbation. Clay content is moderate to high, and the higher the rainfall the higher the clay content. The high cation exchange capacity (CEC)/clay ratio suggest montmorillonitic and mixed mineralogy. Calcium (Ca) was the most dominant extractable cation followed by magnesium (Mg), sodium (Na), and potassium (K). The similar patterns of distribution for the electrical conductivity values and soluble cations throughout the studied soil sites indicate the low leaching rate, eluviation, and illuviation processes within these studied sites. All soils belong to the Haploxererts soil great group.     

日光温室栽培对土壤养分累积及交换性养分含量和比例的影响

研究了日光温室栽培下陕西关中地区不同土壤养分累积及交换性养分含量及比例的变化,结果表明：日光温室栽培下土壤有机质、硝态氮、有效磷和速效钾等养分显著累积,土壤阳离子交换量明显增加,而土壤pH却出现下降趋势。日光温室土壤交换性K^＋含量显著增加;日光温室和大田土壤交换性Ca^2＋含量相比无明显差异,而日光温室土壤交换性Mg^2＋的含量及其离子饱和度有所提高。日光温室土壤钙饱和度、Ca/K和M g/K均明显低于大田土壤。认为日光温室栽培下大量施用钾肥,是土壤钙离子饱和度及Ca/K和M g/K比例降低的主要原因,建议在评价日光温室土壤养分有效性时,应综合考虑交换性养分的含量、饱和度及离子间的比例关系。     

Management of Grazing Intensity in the Semi‐Arid Rangelands of Southern Australia: Effects on Soil and Biodiversity

Overgrazing contributes to rangeland degradation altering plant community composition, erosion and biodiversity. Little unanimity in the literature exists on the effects of livestock grazing on soil carbon and biodiversity, in part, due to uncontrolled grazing pressure from native and feral animals. Paired paddock contrasts at three, long‐term (>8 years) study locations in the southern Australian rangelands were used to examine the effects of managing grazing intensity through the use of exclusion fencing and rotational grazing on soil organic carbon (SOC), soil nitrogen (TN), ground cover and biodiversity (flora and invertebrates). Grazing management had no effect on SOC or TN on grey soils (Vertisols), but for red soils (Lixisols), significantly higher levels of SOC were found for both the 0 to 5 and 5 to 10‐cm soil depths (0·3% and 0·27% respectively) and associated with increased TN. We found strong and consistent relationships among SOC and higher perennial (p < 0·001), higher litter (p < 0·05) cover and close proximity to trees (p < 0·05). Managing grazing intensity resulted in significantly higher perennial ground cover (p < 0·001) on Vertisols (8·9 to 11%) and Lixisols (12·5 to 15%) and higher plant diversity (both native and exotic) but negatively impacted invertebrate diversity, indicating trade‐offs between production and resources. We provide evidence that the effects of grazing management on SOC are mediated by ground cover and increased organic matter supply and/or reduced soil carbon redistribution (erosion), which indicates that the management of grazing intensity may provide a tool to avoid soil carbon loss in rangelands. Copyright © 2016 John Wiley & Sons, Ltd.     

Use of hydraulic conductivity to evaluate the suitability of Vertisols for deep-rooted crops in semiarid parts of central India

Abstract. Detailed morphological, physical, chemical, mineralogical and micromorphological studies were carried out to identify properties that influence the yield of deep-rooted crops in 29 Vertisols of semiarid central India, since existing land evaluation methods are not adequate to explain the yield of cotton obtained by farmers. The studies indicated that among the soil parameters, CaCO₃ in the clay fraction, the exchangeable Ca/Mg ratio, exchangeable sodium percentage (ESP) and saturated hydraulic conductivity (HC) were the yield-influencing factors. The pedogenetic relationships between the semiarid climate, formation of pedogenic calcium carbonate, exchangeable Ca/Mg, ESP and HC have been established. In view of the pedogenetic processes that ultimately impair the drainage of soils, evaluation of Vertisols for deep-rooted crops on the basis of HC alone may help in planning and management of soils, not only in the Indian semiarid tropics, but also in similar climatic areas elsewhere.     

城郊结合区蔬菜种植地土壤性质特征

Human activity and urbanization result in urban-rural environmental gradients.Undersanding effect of the gradients on soil properties is necessary for management of the soils around urban areas.In this study,soil quality of some vegetable fields was characterized along an urban-rural gradient in shaoxing County,Zhejiang Province.Fifteen soilphysical and chemical properties were evaluated by using principal component analysis.Results showed that there was a great variation in the soil quality along the gradient.From rural to urban zones,soil organic matter,water-stable aggregates,cation exchangeable capacity(CEC),total N and P,and available K increased,whereas soil pH value decreased.In addition,Pb,Cu,Ni,Co,Zn and Cr in the soils tended to be accumulated toward the urban zone.Sequential chemical extraction showed that mobility of all the heavy metals in the soils tended toincrease from the rural to the urban zones.The variation of soil properties accounted for by the first principal component was significantly explained bythe difference in application rates of municipal wastes.     

Landscape and Land‐Use Effects on the Spatial Variation of Soil Chemical Properties

The current study addressed the spatial variation of soil organic matter (SOM), total nitrogen (TN), extractable phosphorus (EP), and extractable potassium (EK) in agricultural soils of a representative region, northeast China. Soil cation exchange capacity (CEC) and the effects of landscape attributes and land use were also investigated. The techniques used included conventional statistics, geostatistics, and geographic information systems (GIS). Our study demonstrated that EP had the greatest coefficient of variation (CV), and CEC had the least CV. The experimental semivariograms of the five soil chemical properties included in this study were all fitted with exponential models. The five soil variables all showed moderate spatial dependence. The SOM, EK, and CEC decreased with increasing altitude. Significant negative relationships were found between the slope gradient and EP, EK, and CEC. Relatively steeper slopes might result in greater soil erosion, which leads to a decline in soil nutrients. Soil types had significant impacts on all soil chemical properties, which reflect the effect of the parent soil material. In general, the mean values of soil variables for vegetable land were statistically greater than those for upland and paddy fields. After being divided into two parts along the Yinma River, soil samples of the western part have statistically greater SOM, EP, EK, and CEC values than those collected from the eastern part.     

Biomass and Phosphorus Uptake Responses of Maize to Phosphorus Application in Three Acid Soils from Southern Cameroon

Abstract

A phosphorus (P) greenhouse experiment was carried out with maize (Zea Mays L.) using surface horizons of three contrasted acid soils from southern Cameroon. The objectives were (i) to assess causal factors of maize differential growth and P uptake and (ii) to explore plant–soil interactions in acid soils under increasing P supply. Shoot and root dry‐matter yield and P uptake were significantly influenced by soil type and P rate (P<0.000), but the interaction was not significant. Soil properties that significantly (P<0.05) influenced maize growth variables were available P, soil pH, exchangeable bases [calcium (Ca), magnesium (Mg)], and exchangeable aluminium (Al). Data ordination through principal‐component analysis highlighted a four‐component model that accounted for 88.1% of total system variance (TSV) and summarized plant reaction in acid soil condition. The first component, associated with 36.1% of TSV, pointed at increasing root–shoot ratio with increasing soil acidity and exchangeable Al. The second component (24.6% of TSV) highlighted soil labile P pool increase as a function of P rate. The third and fourth components reflected nitrogen (N) accumulation in soils and soil texture variability, respectively.     

Regional and local scale variations in soil organic carbon stocks in West Greenland

The soil organic carbon (SOC) pool of the Northern Hemisphere contains about half of the global SOC stored in soils. As the Arctic is exceptionally sensitive to global warming, temperature rise and prolonged summer lead to deeper thawing of permafrost‐affected soils and might contribute to increasing greenhouse gas emissions progressively. To assess the overall feedback of soil organic carbon stocks (SOCS) to global warming in permafrost‐affected regions the spatial variation in SOCS at different environmental scales is of great interest. However, sparse and unequally distributed soil data sets at various scales in such regions result in highly uncertain estimations of SOCS of the Northern Hemisphere and here particularly in Greenland. The objectives of this study are to compare and evaluate three controlling factors for SOCS distribution (vegetation, landscape, aspect) at two different scales (local, regional). The regional scale reflects the different environmental conditions between the two study areas at the coast and the ice margin. On the local scale, characteristics of each controlling factor in form of defined units (vegetation units, landscape units, aspect units) are used to describe the variation in the SOCS over short distances within each study area, where the variation in SOCS is high. On a regional scale, we investigate the variation in SOCS by comparing the same units between the study areas. The results show for both study areas that SOCS are with 8 kg m^?2 in the uppermost 25 cm and 16 kg m^?2 in the first 100 cm of the soil, i.e., 3 to 6 kg m^?2 (37.5%) higher than existing large scale estimations of SOCS in West Greenland. Our approach allows to rank the scale‐dependent importance of the controlling factors within and between the study areas. However, vegetation and aspect better explain variations in SOCS than landscape units. Therefore, we recommend vegetation and aspect for determining the variation in SOCS in West Greenland on both scales.     

Small-distance variation of carbon and nitrogen storage in mineral Antarctic Cryosols near Casey Station (Wilkes Land)

In the antarctic summer 1996 top soils and whole profiles were collected systematically near the Australian Casey Station (Wilkes Land) in order to specify the carbon and nitrogen storage in permafrost-affected mineral soils (Cryosols) of coastal areas of Antarctica. Cryorthents, Cryaquepts and Haplocryods are the main soil units observed. The organic matter accumulation in mineral soils of the ice-free coastal Antarctic region is similar to that of comparable Arctic regions. A small-distance storage variation is mainly due to the patch pattern of topography, geomorphology and especially soil geography. Haplocryods are important sinks of carbon and nitrogen, whereas the storage in the Cryaquepts is of minor importance. In addition, large parts of the landscape are characterized by Lilhic Cryonhents. which store nearly 50% of the organic carbon and 40% of the nitrogen. A high variability in the C and N concentration and storage complicates a calculation of soil C and N storage of the total landscape necessary for developing ecosystem models. However, the survey on landscape level suggests that in 75% of the landscape sites the soil carbon and nitrogen stock is very similar, but a wide-spread podzolization and/or extraordinary organic matter accumulation increases the stocks to a great extent. For this reason a storage estimation could be improved by a proper soil survey.     

Remediation of a Magnesium‐Contaminated Soil by Chemical Amendments and Leaching

The deposition of magnesium (Mg)‐rich dust from magnesite mining activities has resulted in serious land degradation. However, the main factors limiting plant growth in Mg‐contaminated soils are unclear. Moreover, little information is available on the remediation of Mg‐contaminated soils. In this study, remediation of soils contaminated with Mg‐rich dust was investigated in a pot experiment using maize as the indicator plant. There were five treatments: (i) control; (ii) leaching; (iii) application of CaCl₂; (iv) leaching + CaCl₂ application; and (v) application of Ca(H₂PO₄)₂ · H₂O. Soil properties and growth of maize (Zea mays L.) seedlings were measured. Leaching alone significantly decreased soluble Mg concentration. Leaching + CaCl₂ application greatly increased exchangeable Ca concentration and decreased soil pH by 0·3 units. Application of CaCl₂ alone increased soluble Mg concentration sharply, which directly inhibited the germination of maize seeds. Application of Ca(H₂PO₄)₂ · H₂O significantly increased the concentrations of exchangeable Ca and available phosphorus and decreased soil pH by 1·7 units. The biomass of maize seedlings increased in the order of control = leaching < leaching + CaCl₂ < < Ca(H₂PO₄)₂ · H₂O. These results suggested that the plant growth in Mg‐contaminated soils was limited primarily by Ca deficiency and secondarily by high soil pH when exchangeable Ca was sufficient. High soil pH suppressed plant growth probably mainly by inhibiting phosphate uptake from the soil. Applying acid Ca salt with low solubility is an attractive option for the remediation of Mg‐contaminated soils. Copyright © 2015 John Wiley & Sons, Ltd.     

Assessment of Spatial Distribution of Selected Soil Properties using Geospatial Statistical Tools

To gain additional knowledge and better understand forest soil management on a small scale, geostatistical analytical tools were employed to examine the spatial distribution in dry aggregate mean weight diameter (MWD) and other selected soil properties and to assess the possible relationships between MWD and other soil properties. Selected properties of forest soils collected along a 300-m transact in the Nimbia Forest Reserve of Nigeria exhibited moderate to high variability in distribution with sodium ion displaying the greatest variability [coefficient of variation (CV, 91.2%)] and principal component analysis revealed the exchange complex cluster as influencing total variation of field soil properties. The autocorrelation function showed significant spatial correlation from 1 lag in soil organic carbon up to 17 lags (51 m) in soil moisture content (θ). The spherical and Gaussian semivariogram models described the spatial structure of most soil properties; however, for clay, cation exchange capacity (CEC), and soil organic carbon (SOC), an exponential model analyzed their spatial dependence.     

Soil variability in map units delineated by aerial photo-interpretation: a case study in Anambra State, Nigeria

Abstract. The variability of five soil series developed in sedimentary formations in southeastern Nigeria and mapped from aerial photographs was investigated in relation to texture, soil reaction, organic carbon, total nitrogen, exchangeable bases, exchangeable acidity, cation exchange capacity and available phosphorus. Air photo delineation of the five soil series was based on terrain physiography alone. Most of the soil series were very variable in available phosphorus, but the coefficients of variation for other soil properties were less than the 33%) threshold adopted for within-series homogeneity critical for land use management. Soil series mapping at 1:50000 scale based on aerial photographs is therefore a cheap, rapid technique, which gives a satisfactory basis for land management to improve productivity and decrease soil degradation in Nigeria.     

Comparison of methods for evaluating the suitability of Vertisols for Gossypium hirsutum (Bt cotton) in two contrasting agro-ecological regions

Cotton (Gossypium sp.) is a major crop grown under rainfed conditions in Vertisols and associated soils in semi-arid tropical (SAT) regions of Peninsular India. In recent years, cotton productivity has declined due to various biophysical factors including pest and diseases, seasonal water stress soil degradation and poor crop management practices. In this study, we compare two methods for evaluating the suitability of Vertisols for cotton in contrasting two agro-ecological regions viz., sub-humid moist (SHM) region and semi-arid dry(SAD) were characterized. Twelve cotton growing Vertisols (seven from SHM and five from SAD) were evaluated for their suitability for cotton cultivation using soil quality index (SQI) and modified Sys-FAO method. SQIs were calculated using the weighted additive index from transformed scores of selected indicators by principal component analysis. For Sys-FAO method both biophysical and soil characteristics were considered for suitability evaluation. We found that the soils of SHM region were moderately suitable for cotton cultivation with soil moisture as the major limiting factor, whereas the soils of SAD region are marginally suitable due to high exchangeable sodium percentage and poor hydraulic conductivity. From this, it may be concluded that the weighted SQI has better agreement with the cotton yield.     

Nutrients, Trace Elements and Net N Mineralization in Acidic Kenyan Soils

The nutrients status and properties in Kenyan soils (Kiambu, Mbeere Districts) are reported with the aim to elucidate the factors of productivity decline. According to the FAO (1988) system the studied soils were classified as humic Nitisols, haplic Acrisols or luvic Arenosols. The soils were found acidic, as a result of leaching of exchangeable cations and they are poor in organic carbon. Cation exchange capacity was extremely low in the sandy soils of Mbeere. Available phosphorus and exchangeable K⁺ were low inducing a crucial problem of soil fertility. Among the micronutrients, manganese extracted by DTPA was most abundant element, while micronutrients extracted by 4 M HNO₃ ranked as follows: Fe>Mn>Zn>Cu. Copper (DTPA) was low and manganese was extremely high in Kiambu. Iron content varied greatly, while decreased zinc was observed in Mbeere. Nitrogen mineralization over an incubation period of 30 weeks ranged from 54.64 to 145.50 mg kg⁻¹ and represents 4.53–21.09% of the total soil nitrogen. Soil nitrogen was associated to soil organic carbon and was strongly correlated to total soil N. Water harvesting, liming, and improved management of composting and manure are amongst the measures to restore soil fertility.