土壤的农业化学研究的任务

在米丘林文库中,保留着一篇未完的论文稿:“向科学家要求些什么”。在这篇论文里,米丘林对于那些不能给最需要的农业问题以适当解決的学者,愤怒地写道:“例如,第一个问题:园艺家应该知道,这个区域的土壤是否适宜栽种这些植物?土壤中缺乏什么?它需要加入那些物质?并且,土壤中有什么是过多的?”     

伟大的战略 跨世纪的工程

<正>在全党和全国人民正以饱满的热情迎接党的十五大召开之际,江泽民总书记、李鹏总理等党和国家领导人就治理水土流失,建设生态农业问题作了重要批示,要求“再造一个山川秀美的西北地区”,黄土高原水土流失治理“争取15年初见成效,30年大见成效.”江泽民总书记和李鹏总理的批示,高瞻远瞩,高屋建瓴,涵盖历史,充分肯定和高度赞扬了延安、榆林地区及黄土高原治理水土流失,建设生态在业所取得的巨大成就,并对今后进一步加快水土流失治理开发步伐,改善生态环境,促进区域经济持续、快速、协调发展指明了方向,提出了殷切的希望和要求.这充分体现了党的第三代领导集体对水土保持工作的重视、支持和关心,对水土流失区广大人民群众的巨大关怀,是对全国特别是对水土流失区广大干部群众的巨大鼓舞和鞭策.我们一定要认真学习、深刻领会、坚决贯彻执行.     

被土壤吸附的六价铬的最佳提取剂的选取

通过研究土壤中磷酸盐与Ｃｒ（Ⅵ）的竞争吸附作用，查明０．１ｍｏｌ／ＬＫＨ２ＰＯ４－Ｋ２ＨＰＯ４溶液是提取被土壤吸附的Ｃｒ（Ⅵ）的最佳提取剂。     

氨的固定对土壤微生物氮的测定的影响

The effect of ammonium fixation on the estimation of soil microbial biomass N was studied by the standard fumigation-incubation(FI) and fumigation-extraction (FE) methods,NO3-N content of fumigated soil changed little during incubation,while the fixed NH4^ in soils capable of fixing NH4^ increased with the increase of K2SO4-extractable NH4-N.one day fumigation increased both extractable NH4^ and fixed NH4^ ,However,prolonged fumigation gave no further increase.One day fumigation caused significant loss of NO3-N,while prolonged fumigation caused no further loss.For soils tested,the net increases of fixed NH4^ in fumigated soil equaled to 0-94% of NH4-N flush measured by the FI metod,and 1-74% of extractable N measured by the FE method.depending on different soils.It is concluded that the ammonium fixation was one of the processes taking place in soils during fumigation as well as incubation ofter fumigation and should not be neglected in the estimation of microbial biomass nitrogen by either FI or FE method.     

施用重金属含量高的污泥的土壤重金属的有效性

<正> 为了确定Cd、Cu、Ni和Zn对生长在施用污泥的土壤上的玉米的有效性,于1984年,在就地侧渗能控制的小区进行田间试验。这些小区设在三种土壤上。这三种土壤为Bojac壤质砂土,Davidson粘壤土和Grosecloge细壤土。来自主要处理工业废水的     

土壤Se的分级与Se的植物有效性的关系

Nine soils with distinct properties and Se levels were selected to test a fractionation procedure of soil Se based on sequential extraction. Soil Se was fractionated into readily available Se (fraction Ⅰ, extracted by 0.5 M NaHCO₃), slowly available Se (fraction Ⅱ, extracted by 0.1 M NaOH-0.1 M Na₄P₂O₇), amorphous oxide-occluded Se (fraction Ⅲ, extracted by acid ammonium oxalate), free oxide-occluded Se (fraction Ⅵ, extracted by dithionite-citrate-bicarbonate buffer solution) and residual Se (fraction Ⅴ, determined by HNO₃-HClO₄ digestion of the final soil residue). The recovery of soil Se (the sum of all fractions over total soil Se determined independently) by this procedure was from 88.1% to 110.9%, mean 99.2%±6.4% for the test soils. The sum of fractions Ⅰ and Ⅱ, provided a good measure of available Se in soils and the percentage of fraction Ⅰ plus Ⅱ over the total soil Se, tentatively defined as Se availability index, could be used to indicate soil Se status and predict Se deficiency.     

基于模糊控制的温室加热器的研究

该文分析了现有温室加热设备的不足，提出了将模糊控制原理应用于温室加温设备的新方法，并成功地研制了一种工作效率高、使用方便，基于模糊控制的温室加热器。试验结果表明，该温室加热器性能稳定可靠，自适应能力强，节能效果显著，具有较好的推广价值。     

提高罐藏蘑菇的得率的研究

为了探讨提高罐藏蘑菇得率的更好方法，用正交试验设计方法进一步分析浸泡-冷藏-浸泡处理与浸泡-冷藏-真空水合处理方法中各因素以及蘑菇的预煮时间、预煮液中的柠檬酸浓度对罐藏蘑菇的得率的影响。试验结果表明，在浸泡-冷藏-浸泡处理与浸泡-冷藏-真空水合处理方法中，只有冷藏处理显著影响罐藏蘑菇的得率。蘑菇的预煮时间与预煮液中的柠檬酸浓度对罐藏蘑菇的得率也有较显著的影响。将蘑菇在2℃的条件下作20～24 h的冷藏处理后再预煮，并适当延长预煮时间可提高罐藏蘑菇的得率。     

农药降解的灰色预测模型的改进

针对常规灰色预测模型之ＧＭ（１,１）模型存在的不足,提出改进,并以实例表征改进ＧＭ（１,１）模型较常规模型更能提高精度,符合农药降解研究之要求。     

土壤添加沼渣对温室气体排放及小麦生长的影响

Digestate, the product obtained after anaerobic digestion of organic waste for biogas production, is rich in plant nutrients and might be used to fertilize crops. Wheat(Triticum spp. L.) was fertilized with digestate, urea, or left unfertilized and cultivated in the greenhouse for 120 d. Emissions of greenhouse gasses(carbon dioxide(CO_2), methane(CH_4), and nitrous oxide(N_2O)) were monitored and plant growth characteristics were determined at harvest. The digestate was characterized for heavy metals, pathogens, and C and N mineralization potential in an aerobic incubation experiment. No Salmonella spp., Shigella spp., or viable eggs of helminths were detected in the digested pig slurry, but the number of faecal coliforms was as high as 3.6 × 10~4colony-forming units(CFU) g-~(1)dry digestate. The concentrations of heavy metals did not surpass the upper limits established by US Environmental Protection Agency(EPA). After 28 d, 17% of the organic C(436 g kg~(-1)dry digestate) and 8% of the organic N(6.92 g kg~(-1)dry digestate)were mineralized. Emissions of CO_2 and CH_4 were not significantly affected by fertilization in the wheat-cultivated soil, but digestate significantly increased the cumulative N_2O emission by 5 times compared to the urea-amended soil and 63 times compared to the uncultivated unfertilized soil. It could be concluded that digestate was nutrient rich and low in heavy metals and pathogens, and did not affect emissions of CH_4 and CO_2 when applied to a soil cultivated with wheat, but increased emission of N_2O.     

Hydrochar amendment promotes microbial immobilization of mineral nitrogen

Hydrochars and biochars are products of the carbonization of biomass in different conversion processes. Both are considered suitable soil amendments, though they differ greatly in chemical and physical composition (e.g., aromaticity, inner surface area) due to the different production processes (pyrolysis, hydrothermal carbonization), thus affecting their degradability in soil. Depending on the type, char application may provide soil microorganisms with more (hydrochars) or less (biochars) accessible C sources, thus resulting in the incorporation of nitrogen (N) into microbial biomass. A soil‐incubation experiment was conducted for 8 weeks to determine the relationship between mineral‐N concentration in the soil solution and microbial‐biomass development as well as soil respiration. An arable topsoil was amended with two hydrochars from feedstocks with different total N contents. Biochars from the same feedstocks were used for comparison. Both char amendments significantly decreased mineral‐N concentration and promoted microbial biomass compared to the nonamended control, but the effects were much stronger for hydrochar. Hydrochar application increased soil respiration significantly during the first week of incubation, simultaneous with the strongest decrease in mineral‐N concentration in the soil and an increase in microbial biomass. The amount of N detected in the microbial biomass in the hydrochar treatments accounted for the mineral N “lost” from the soil during incubation. This shows that microbial immobilization is the main sink for decreasing mineral‐N concentrations after hydrochar application. However, this does not apply to biochar, since the amount of N recovered in microorganisms was much lower than the decrease in soil mineral‐N concentration. Our results demonstrate that while both chars are suitable soil amendments, their properties need to be considered to match the application purpose (C sequestration, organic fertilizer).     

草甸草原模拟氮沉降抑制甲烷吸收、促进氧化亚氮排放

Few studies are conducted to quantify the effects of enhanced N deposition on soil nitrous oxide (N2O) emission and methane (CH4) uptake in the meadow steppe of Inner Mongolia,China.A two-year field experiment was conducted to assess the effects of nitrogen (N) deposition rates (0,10,and 20 kg N ha-1 year-1 as (NH4)2SO4) on soil N2O and CH4 fluxes.The seasonal and diurnal variations of soil N2O and CH4 fluxes were determined using the static chamber-gas chromatography method during the two growing seasons of 2008 and 2009.Soil temperature,moisture and mineral N (NH4+-N and NO3--N) concentration were simultaneously measured.Results showed that low level of (NH4)2SO4 (10 kg N ha-1 year-1) did not significantly affect soil CH4 and N2O fluxes and other variables.High level of (NH4)2SO4 (20 kg N ha-1 year-1) significantly increased soil NO3--N concentration by 24.1％ to 35.6％,decreased soil CH4 uptake by an average of 20.1％,and significantly promoted soil N2O emission by an average of 98.2％.Soil N2O emission responded more strongly to the added N compared to CH4 uptake.However,soil CH4 fluxes were mainly driven by soil moisture,followed by soil NO3--N concentration.Soil N2O fluxes were mainly driven by soil temperature,followed by soil moisture.Soil inorganic N availability was a key integrator of soil CH4 uptake and N2O emission.These results suggest that the changes of availability of inorganic N induced by the increased N deposition in soil may affect the CH4 and N2O fluxes in the cold semi-arid meadow steppe over the short term.     

The extent of methane (CH4) emissions after fertilisation of grassland with digestate

Methane (CH₄) emissions following surface application of liquid digestate were measured on agricultural grassland. The total extent of emissions was estimated by curve fitting and integration. The temporal pattern of the CH₄ efflux was well described by fitting double-phase decay curves ( $ J(T) = B \times {\text{EXP}}( - iT) + C \times {\text{EXP}}( - jT) $ ). Total emissions were found to be small in all cases (7.3–11.5?mg CH₄?L^?1). From a greenhouse gas perspective, this level of CH₄ emissions represents only a few per cent of the global warming potential of the nitrous oxide emissions which may occur following application of the digestate.     

Nitrous oxide emissions from cattle-impacted pasture soil amended with nitrate and glucose

There is little information concerning N₂O fluxes in the pasture soil that has received large amounts of nutrients, such as urine and dung, for several years. The aims of this study were to (1) experimentally quantify the relationship between mineral N input and N₂O emissions from denitrification, (2) describe the time course of N₂O fluxes resulting in N inputs, and (3) find whether there exists an upper limit of the amount of nitrogen escaping the soil in the form of N₂O. The study site was a grassland used as a cattle overwintering area. It was amended with KNO₃ and glucose corresponding to 10–1,500 kg N and C per hectare, covering the range of nutrient inputs occurring in real field conditions. Using manual permanent chambers, N₂O fluxes from the soil were monitored for several days after the amendments. The peak N₂O emissions were up to 94 mg N₂O–N m⁻² h⁻¹, 5–8 h after amendment. No upper limit of N₂O emissions was detected as the emissions were directly related to the dose of nutrients in the whole range of amendments used, but the fluxes reflected the soil and environmental conditions, too. Thus, in three different experiments performed during the season, the total cumulative losses of N₂O–N ranged from 0.2 to 5.6% of the applied 500kg ha⁻¹. Splitting of high nutrient doses lowered the rate of N₂O fluxes after the first amendment, but the effect of splitting on the total amount of N₂O–N released from the soil was insignificant, as the initial lower values of emissions in the split variants were compensated for by a longer duration of gas fluxes. The results suggest that the cattle-impacted soil has the potential to metabolize large inputs of mineral nitrogen over short periods (∼days). Also, the emission factors for did not exceed values reported in literature.     

土壤生物炭的生产：三种窑模型的比较研究

Biochar has potentials for soil fertility improvement, climate change mitigation and environmental reclamation, and charred biomass can be deliberately incorporated into soil for long-term carbon stabilization and soil amendment. Many different methods have been used for biochar production ranging from laboratory to industrial scales. However, in countryside of developing countries,biomass is generally used for cooking but not charred. Biochar production techniques at farmer scale have remained poorly developed.We developed and tested biochar production kilns for farmers with a dimension of 50.8 cm × 38.1 cm(height × diameter), using three different setups for optimizing oxygen(O2) limitation and syngas circulation: airtight with no syngas circulation(Model I),semi-airtight with external syngas circulation(Model II) and semi-airtight with internal syngas circulation(Model III). A comparative assessment of these biochar production kiln models was made considering biochar pyrolysis time, fuel to biomass ratio, biochar to feedstock ratio and thermogravimetric index(TGI). Among the models, the best quality biochar(TGI = 0.15) was obtained from Model I kiln taking the longest time for pyrolysis(12.5 h) and the highest amount of fuel wood(1.22 kg kg-1biomass). Model III kiln produced comparatively good quality biochar(TGI = 0.11), but with less fuel wood requirement(0.33 kg kg-1biomass) and shorter pyrolysis time(8.5 h). We also tested Model III kiln in a three times larger size under two situations(steel kiln and pit kiln). The biochar to feedstock ratio(0.38) and quality(TGI = 0.14) increased slightly for the larger kilns. Quality of biochar was found to be mainly related to pyrolysis time. The costs for the biochar stove and pit kiln were US$ 65–77, while it was US$ 154 for the large size steel kiln. Model III kiln can potentially be used for both cooking and biochar production at farmer scale.     

Fungal and bacterial growth following the application of slurry and anaerobic digestate of livestock manure to temperate pasture soils

How land-application of digestate sourced from anaerobic digestion (AD) of animal waste influences the functioning of a mixed pasture agroecosystem is not well characterised, particularly with regard to the response of the actively growing microbial community. We studied the impact of the liquid AD digestate on the decomposer community in two different soils, seeded with two different common grassland crops; a mixture of either grass or grass/clover in a greenhouse experiment. We studied bacterial (leucine incorporation into bacteria) and fungal (acetate incorporation into ergosterol) growth responses to AD cattle slurry digestate, undigested cattle slurry, mineral fertiliser (NPK and N) added at a rate equivalent to 150?kg?N?ha^?1, and a no-fertiliser control treatment. Differences in fungal and bacterial growth were evident between the soil and sward types. However, the fertilisers consistently stimulated a higher bacterial growth than the no-fertiliser control, and liquid digestate resulted in a level of bacterial growth higher or equal to that of mineral fertiliser, whilst undigested slurry resulted in lower bacterial growth. These fertiliser effects on bacterial growth mirrored the effects on plant growth. In contrast, the fungal community responded only marginally to fertiliser treatments. We conclude that the application of digestate stimulates the bacterial decomposer community in a similar way to that of mineral fertilisers. Our results suggest that mineral fertiliser can be exchanged for liquid digestate with limited impact on the actively growing soil microbial community that, in turn, regulate important soil processes including nutrient cycling in agricultural soils.     

Hydrochars derived from sewage sludge: effects of pre-treatment with water on char properties,phytotoxicity and chemical structure

Large amounts of labile compounds are adsorbed to the surface of chars produced by hydrothermal carbonization (HTC). The aim of this study was to characterize the core and adsorbed fractions of hydrochars and to gain knowledge about the possibility to remove phytotoxic compounds by washings with water. Chars were produced by HTC of sewage sludge at different temperatures (180 – 200 °C) and over different periods of time (4 – 8 h). For comparison one pyrolysis char produced by thermocatalytic low temperature conversion (LTC) at 400 °C for 1 h was included in the study. The chars and their feedstocks were treated varying the duration (1 x 15, 1 × 30 and 1 × 60 min) and number (2 x 60 and 3 × 60 min) of washings. Physicochemical properties, including the molecular structure of the test materials, and their effects on germination and plant growth were analysed. Element concentrations and phytotoxic effects were reduced and the number of washings had a stronger effect than their length of time. Intensive washings with water reduced the hydrochars’ portion of biodegradable compounds significantly. However, also plant available nutrients were lost by washing with water, decreasing the value of hydrochars as a soil amendment.     

Anaerobic co‐digestion of perennials: Methane potential and digestate nitrogen fertilizer value

Co‐digestion of crop biomass improves the traditional manure‐based biogas yield due to an increased content of easily degradable carbon compounds. In this study, the methane potential of three perennials (grass, legumes, and grass+legume) was determined using various amounts together with animal manure. The nitrogen (N) mineralization dynamics in soil and the N‐fertilizer value of the derived digestates were subsequently tested in both a soil incubation study and a pot experiment with spring barley. Digestion of all tested perennials together with a manure‐based inoculum increased the cumulative methane yield four to five times compared to digestion of the inoculum alone, with the highest increases observed with pure grass. However, the methane potential decreased along with increasing grass biomass concentration. In the plant pot experiment, all tested digestates increased barley shoot biomass by 40–170%, to an extent statistically comparable to mineral N fertilizer. However, the application of the digestate originating from fermentation with pure grass resulted in lower plant growth and a more fluctuating soil mineral N content throughout the incubation study compared to the other digestates. Considering the high dry matter and methane yield ha^?1, the possibility to substitute mineral N fertilizer inputs by leguminous biological N₂ fixation capacity, and the digestate fertilizer value, the integration of grass–legume mixtures or sole legumes into anaerobic digestion systems as co‐substrate for manure seems to be promising. This could furthermore contribute to the diversification of cropping systems for bioenergy production.     

Wood ash effects on chemical and microbiological properties of digestate- and manure-amended soils

A field study was carried out to evaluate the potential of wood ash as a fertilizer in grassland systems in combination with enriched N organic wastes. Six treatments including manure or digestate, each combined with wood ash at 0, 1, and 3 t?ha^?1 were spread onto the soil to an amount equivalent to 120 kg?N ha^?1. Three soil samplings and one cutting was carried out within one growing season (3 months). A higher pH value was found in manure-treated plots, the pH rise being proportional to the amount of wood ash added. Those plots amended with digestate were characterized by a larger content of total C, NH₄ ⁺, and total P (TP) regardless of the amount of ashes. Microbial activity, assessed by basal respiration and microbial biomass carbon of the differently treated soils, was not affected neither by the nature of the organic waste nor by the amount of wood ash added. However, amending soil with digestate resulted in a more efficient soil microbial community, as shown by the lower values of the metabolic quotient. Such effects were accompanied by a higher percentage of plant cover, particularly of leguminous plants in digestate-treated plots. The time of sampling (seasonal effects) was found to influence the soil pH and electrical conductivity (EC), as well as the nutrient content (total N, NH₄ ⁺, and NO₃ ^?). Overall, the combined use of wood ash and biogas digestate can constitute an efficient way for the disposal and recycling of both products and additionally, it may constitute an environmentally friendly alternative to mineral fertilizers for acid soils.