长期不同施肥模式对日光温室土壤硝态氮时空分布及累积的影响

通过连续7 年的定位试验, 研究了日光温室生产中不同施肥模式(常规模式、无公害模式和有机模式)对土壤NO₃^--N 时空分布及累积的影响。结果表明, 随着种植年限的增加, 3 种施肥模式土壤剖面各层次NO₃^--N含量均呈上升趋势, 年增加量顺序为常规施肥模式＞无公害施肥模式＞有机施肥模式。受氮素输入量(施肥)的影响, NO₃^--N 主要分布在0~40 cm 土层, 0~60 cm 土层NO₃^--N 含量总体呈作物生长前期低、中期高、后期低的趋势; 与上层土壤相比, 100 cm 以下土层NO₃^--N 含量有不同程度的增加。0～200 cm 土体NO₃^--N 平均累积量有机施肥模式比无公害施肥模式低33.8%, 比常规施肥模式低45.9%; 无公害施肥模式比常规施肥模式低18.3%。3 种施肥模式下, NO₃^--N 都有向2 m 以下土体淋洗的趋势。与施用化学肥料相比, 施用有机肥能明显降低土壤剖面NO₃^--N 含量, 控制其累积峰的下移, 但不合理施用有机肥也会产生NO₃^--N 淋洗而污染环境。     

影响土壤镉吸持和解吸的因子

研究了土壤的pH、离子浓度(0.01mol/L、0.05mol/L、0.1mol/L)、阴(阳)离子种类(NO₃^-、Cl^-、OAc^-、SO₄^2-、HPO₄^-及Zn和Pb)及石灰和葡萄糖对土壤镉吸持及其解吸的影响。     

SO42-和Cl-对稻田土壤养分及其吸附解吸特性的影响

利用长期定位试验 ,比较了长期施用含SO₄^2-和Cl^- 化肥 22年后稻田土壤的 pH值、养分状况及其吸附解吸特性。结果表明 ,长期施用含SO₄^2-化肥 ,土壤有机质、速效氮和速效钾的含量较高 ,但全量氮磷钾的含量较低 ;长期施用含Cl^- 化肥 ,土壤全量氮磷钾和速效磷的含量较高 ,但pH值相对较低。长期施用含上述二种阴离子的化肥后 ,土壤对H₂PO₄^-的最大吸附量均较大 ,且在Cl^- 处理下土壤对H₂PO₄^-吸附的结合能较大 ,而SO₄^2-处理下土壤在同等吸附量时对H₂PO₄^-的解吸量相应较多。长期施用含SO₄^2-的化肥亦使土壤对钾素的供应强度较大 (ΔK0的绝对值较大 )、缓冲能力增强 (AR0值较高 ) ,而长期施用含Cl^- 的化肥时则与SO₄^2-相反     

尿素肥斑中氮素形态转化初探

采用特制模拟容器,通过尿素扩散形成营养斑,观察斑内NH₄⁺、NO₂^-和NO₃^-浓度变化及它们之间的相互转化。结果表明,NH₄⁺、NO₂^-和NO₃^-浓度在距离肥斑7～8cm处的微域达到最大,尤以NO₂^-浓度增加较为显著,是一般土壤NO₂^-水平的数千倍。随培养时间增加,NO₂^-和NO₃^-最大浓度峰向施肥点移动,但两者浓度变化趋势不同,NO₂^-浓度在21d前随培养时间增加而增加,之后随培养时间增加而下降,而NO₃^-浓度随培养时间增加一直增加。结果还表明,NO₂^-是尿素营养斑内主要离子形态,从NH₄⁺到NO₂^-的转化比较迅速,而NO₂^-转化为NO₃^-不是短暂的过程,这可能与施肥引起的土壤pH值变化有很大关系。     

3 种挺水植物吸收水体NH4+、NO3-、H2PO4- 的动力学特征比较

本文用动力学试验研究了具有景观价值的3 种挺水植物—— 水生美人蕉(Canna generalis)、细叶莎草(Cyperus papyrus)、紫芋(Colocasia tonoimo)对H₂PO₄^-、NH₄⁺、NO₃^- 的吸收特征及差异。试验结果表明: 3 种挺水植物吸收H₂PO₄^- 时, 美人蕉的吸收速率最快, 且在较低离子浓度条件下也可以吸收该离子, 说明其具有嗜磷特性, 能够适应广范围浓度H₂PO₄^- 环境; 吸收NO₃^- 时, 细叶莎草的速率最快, 但对低浓度NO₃^- 环境的适应能力较差, 美人蕉吸收NO₃^- 的特性与细叶莎草刚好相反; 吸收NH₄⁺ 时, 细叶莎草的吸收速率最快, 且在低浓度NH₄⁺ 环境下仍能吸收该离子, 而美人蕉的吸收速率最慢, 但能在低浓度NH₄⁺ 环境下吸收该离子。说明不同植物对养分的吸收特性存在较大差异, 各自的污染水体修复适用范围也不同。美人蕉可用于各种浓度H₂PO₄^- 污染的水体修复; 而NO₃^- 污染严重的水体最适宜用细叶莎草作先锋植物, 修复到一定程度后再种植美人蕉来维持水质; 细叶莎草在各种浓度NH₄⁺ 污染的水体中均适用, NH₄⁺ 污染较轻的水体也可用美人蕉修复。     

总氮量的测定

众所周知,对于富含NO₃^--N、NO₂^--N的土壤、肥料、污水以及其他样品,用K氏法测得的全氮值不能反映出NO₃^--N、NO₂^--N的含量,因此不能代表总氮量。     

间作及伴随阴离子肥料对油菜吸收积累镉的影响

为提高Cd污染土壤植物修复效率, 采用盆栽方法研究了Cd含量为10.0 mg·kg^-1的土壤中, 伴随阴离子肥料和间作鹰嘴豆对油菜生长与吸收积累Cd的影响。结果表明: 单作下, 不同肥料处理土壤DTPA提取态Cd含量为Cl^->NO₃^->SO₄^2- >无伴随阴离子; 间作鹰嘴豆提高土壤DTPA提取态Cd含量, 且伴随C₁^-、SO₄^2- 或NO₃^- 条件下达显著水平。单作下, 油菜主根长为NO₃^- >C₁^- >SO₄^2- >无伴随阴离子, 根系体积为SO₄^2->NO₃^- >C₁^- >无伴随阴离子, 根系活力NO3 >SO42 >Cl >无伴随阴离子; 间作鹰嘴豆在无肥处理下可显著提高油菜的主根长与根系体积, 在无肥处理、SO₄^2- 、NO₃^- 处理下显著提高根系活力。单作下, 油菜地上部Cd含量表现为C₁^- >SO₄^2- >NO₃^- >无伴随阴离子, 间作鹰嘴豆可显著降低无肥处理地上部Cd含量, 但显著提高施肥处理地上部的Cd含量。单作下, 施肥可显著增加油菜的Cd积累总量, 以伴随C₁^-处理最大, 达470.4 μg·plant^-1; 间作鹰嘴豆也可提高油菜的Cd积累总量, 且伴随C₁^- 处理最大, 达783.7 μg·plant^-1。除伴随C₁^- 处理外, 施肥处理均可显著提高油菜的Cd转移系数, 施肥处理的Cd转移系数均大于1; 间作鹰嘴豆也可提高油菜的Cd转移系数, 且施肥条件下达显著水平。因此, 如果把油菜用作Cd污染土壤植物修复作物, 可选择施用含Cl 肥料和间作鹰嘴豆, 以提高修复效率。     

Chemical Behavior of Chromium in Soils: Ⅲ. Mechanism of Cr(Ⅵ) Adsorption by Soils

An analysis of Cr (Ⅵ)-sorbed surface of the soils by using a scanning electron microscope and an electron probe microscope has proved that aluminium is the chief element affecting Cr (Ⅵ) adsoption. As the ionic strength of the solution increased, the amounts of Cr (Ⅵ) adsorbed by goethite and soils decreased. Cr (Ⅵ) adsorption was greatly depressed in the presence of SO₄^2-, WO₄^2-, MoO₄^2-, HPO₄^2- and H₂PO^4- which competed for anion adsorption sites. The depressing extent of these anions was found to follow the sequence: HPO₄^2-, H₂PO^4->MoO₄^2->WO₄^2->SO₄^2->>Cl^-, NO^3-. The amounts of Cr (Ⅵ) desorption varied with different extractants.     

基于土壤光谱特征的宁夏银北地区盐碱地盐分预测研究

对宁夏回族自治区银北地区盐碱地野外土壤表层光谱反射率和土壤全盐及盐分进行定量分析,筛选出各土壤盐分指标的敏感波段,然后采用全回归和逐步回归的方法建立各盐分的预测模型。结果表明：表层土壤高光谱反射率r,及其平滑去嗓处理后的值R,lg(R)与全盐含量呈极显著正相关关系,1/R,lg(1/R)与全盐呈极显著负相关关系,(R)'和〔lg(1/R)〕'在特定单波段处表现较佳;土壤表层光谱反射率与CO₃^2-的相关性最强,其次是SO₄^2-;土壤光谱反射率与Na⁺的相关性在各种变换方法下均较强,其次为Mg²⁺,与Ca²⁺的相关性最弱。基于R的逐步回归方程为全盐含量预测的最佳模型;基于土壤光谱反射率拟合土壤CO₃^2-的准确度略高于对土壤HCO₃^-;敏感波段估测土壤SO₄^2-含量的决定系数明显高于其他阴离子;采用〔lg(1/R)〕'逐步回归得到的方程拟合土壤Na⁺,K⁺和Mg²⁺含量相对于其他变换方式效果更理想。预测模型中对土壤全盐和Na+的模型精度较高,预测能力强;光谱对土壤SO₄^2-和Mg²⁺的预测能力也较强;对土壤Cl^-和Ca²⁺的预测稳定性、预测能力和精度都较差。     

基于稳定同位素和贝叶斯模型的引黄灌区地下水硝酸盐污染源解析

地下水硝酸盐（NO₃^-）污染已经成为全球严重的水环境问题之一,由于饮用水中高含量NO₃^-会转化成亚硝酸盐而增加各种疾病和癌症风险,其来源的确定对于NO₃^-污染的预防和控制非常重要。本文以黄河下游第二大灌区——潘庄灌区为例,首次采用NO₃^-的氮氧稳定同位素结合贝叶斯模型追溯地下水NO₃^-的来源并量化各种来源的贡献比例。结果表明,地下水NO₃^-含量分布在0.1~197.0 mg·L^-1,平均值为34.2 mg·L^-1。与《生活饮用水卫生标准》中规定的地下水NO₃^-最大含量[20 mg（N）·L^-1,相当于NO₃^-含量90 mg·L^-1]相比,有10%的样品NO₃^-含量超标。井深<30 m、30~60 m和>60 m的地下水NO₃^-平均含量分别为25.9 mg·L^-1、39.7 mg·L^-1和20.1 mg·L^-1。空间上,宁津县、武城县、平原县和禹城市有大片区域地下水NO₃^-含量较高。地下水NO₃^-的δ¹⁵N组成范围为0.72‰~23.93‰,平均值为11.62‰;δ¹⁸O组成范围为0.49‰~22.50‰,平均值为8.46‰。同位素结果表明粪便和污水、农业化肥是地下水中NO₃^-的主要污染来源。这反映了人类活动是引起地下水NO₃^-污染的主要原因。贝叶斯模型结果显示,粪便和污水对潘庄灌区地下水中NO₃^-平均贡献率高达56.2%,化肥的平均贡献率为19.3%,大气降水和土壤的平均贡献率分别为6.2%和12.3%。由于污水、粪便和化肥是地下水中NO₃^-的主要来源,为保护和改善研究区地下水水质,建议加强污水管道建设,强化畜禽粪便的管理以及提高化肥利用效率。     

Variations saisonnieres des composantes de l'alcalinite des eaux dans le haut-estuaire du fleuve Saint-Laurent (Quebec)

Measurements of the total alkalinity and its components have been made on waters collected from the St.` Lawrence River during the year 1980–1981. Analyses of the total inorganic carbon, the borates, the phosphates and the silicates along with the pH and the total alkalinity permitted an evaluation of each component. In all seasons, the carbonate system was the major component (96%) of the total alkalinity. The residual alkalinity accounting for only 2 to 3% and obtained by the difference between the total alkalinity and the sum of the components appears attributable to weak organic acids. The saturation state of calcite coincided with a river saturated by dissolved calcium carbonate during the summer season and only 45% saturated during the winter season.     

Method for estimation of CO2(aq) plus H2CO3°, HCO3− and pH in soil solutions collected under field conditions

A method for the collection of soil solution and the determination of pH, H₂CO₃* (= CO₂(aq) plus H₂CO₃°), HCO₃^? and CO₃^2?, was developed which excluded atmospheric gases during the entire procedure. The soil solution was collected by tension lysimeters without exposure to the atmosphere. Using a closed system, the sample was transferred to a titration beaker for the analysis of pH, H₂CO₃* and HCO₃^?. The analysis of CO₂-acidity was done by titration with 0.0454 N Na₂CO₃ to the end point pH of 8.3. It was immediately followed by an acidimetric titration for the determination of alkalinity using 0.005 N H₂SO₄ under gentle N₂ flow; the equivalence point was determined graphically from the titration curve. In standard solutions, this method gave nearly 100% recovery of H₂CO₃* and HCO₃^?. In soil solutions, the pH markedly increased and H₂CO₃* decreased upon exposure to the atmosphere. The values of the sum of CO₂-acidity and alkalinity in soil solutions at a depth > 5 cm agreed well with the values of total inorganic carbon obtained by CO₂ infrared detection following CO₂ degassing. For solutions obtained from 100 cm and 300 cm depth (limestone) the measured distribution of H₂CO₃* and HCO₃^? was in agreement with the calculated values based on pH-measurement and total inorganic carbon. This comparison was unsatisfactory for the concentration of H₂CO₃* in solutions of the surface (0–15 cm) soil, possibly because the mathematical model as well as the interpretation of the titration curves did not consider any organic compounds in the solution.     

Alkalinity production in epilimnetic sediments: Acidic and non-acidic lakes

Interstitial water profiles in epilimnetic sediments of lakes with varying water column alkalinities were collected to assess the origin and importance of sedimentary alkalinity in freshwater lakes. Release of Ca²⁺ and NH₄ ⁺, and consumption of SO₄ ^? are the most important contributors to alkalinity production m sediments of non-acidic lakes. In acidic lakes, Fe²⁺ and Mn²⁺ replace Ca²⁺ as the dominant cation contributors to alkalinity production. The sedimentary alkalinity flux is an important component of the acid neutralizing capacity of freshwater lakes. However, the presence of large alkalinity gradients in sediment porewaters does not necessarily indicate a large source of alkalinity for the lake, as a significant portion of the alkalinity iu associated with the formation of Fe²⁺, Mn²⁺ and NH₄ ⁺ Oxidation of Fe²⁺ and Mn²⁺ at the anoxic-oxic interface and biological removal of NH₄ ⁺ in the overlying water column results in consumption of the co-diffusing alkalinity.     

Evaluation of a rapid microwave digestion method for determination of total organic carbon in soil

Precise measurement of soil organic carbon (SOC) is essential for constructing regional inventories, developing best agricultural management practices, and modeling purposes. Currently, the automated dry combustion method is considered standard, but the method is both costly and time-consuming. There is a need for a simple, easy to use and cost-effective method of organic C determination in soil. A simple method of total organic carbon (TOC) determination in soil that involved wet digestion of K₂Cr₂O₇-H₂SO₄-soil mixture in a commercial microwave oven followed by spectrophotomteric measurement of Cr (III) was evaluated. The method was compared with automated dry combustion and two other wet digestion methods. The method showed close agreement with dry combustion method (R² = 0.90; root mean square error = 0.70) and the TOC measured with the two methods did not differ for a range of soils drawn from lowland and upland land-uses and varying in pH (6.2–9.3), TOC (2.8–14 g kg^?1), and calcium carbonate content (0–6.7%). The recovery of the added organic C by the microwave method was 98.6 ± 4.2%. The results suggested that microwave-spectrophotometric method could be easily adopted in routine soil analysis as it is not only precise, rapid, and cost-effective but also produced small volume of reagent waste.     

Saline-alkali soils of Russia

Diagnostics, methods of evaluation, and geography of saline-alkali (soda) soils are discussed. The saline-alkali soils include soils of different genetic types with the following chemical properties: the pH of the water suspensions equal to or higher than 8.5; the total alkalinity exceeding 1.4 meq/100 g of soil and the sum of water-soluble calcium and magnesium; and the presence of soluble “alkaline” salts in the soil profiles, the hydrolysis of which results in the alkaline reaction of the soils. The chemical properties of the saline-alkali soils are largely related to the presence of soda (Na₂CO₃, NaHCO₃) in the soils. According to their morphological properties, saline-alkali soils are divided into two groups: alkaline soils with an undiferentiated profile and without a morphologically pronounced solonetzic (natric) horizon, and alkaline soils with a pronounced natric horizon (solonetzes). Solonetzes, in turn, are divided into (a) alkaline solonetzes (with soda or with soda and neutral salts), (b) solonetzes salinized with neutral salts (saline soils) with increased alkalinity in the solonetzic and lower lying horizons, (c) saline solonetzes throughout the profile, and (d) leached solonetzes containing no soluble salts in the profile and almost no exchangeable sodium in the soil exchange complex (SEC) (“dead” solonetzes). The latter two groups of solonetzes cannot be ranked among the alkaline soils. The alkalinity of the saline-alkali soils under study is due to carbonate and bicarbonate ions (carbonate alkalinity), organic acid anions (organic alkalinity), and borate ions (borate alkalinity). The carbonate alkalinity is due to both soda (Na₂CO₃, NaHCO₃) and CaCO₃.     

Growth and Nitrogen Fixation in Dhaincha/Sorghum and Dhaincha/Sunflower Intercropping Systems Using 15Nitrogen and 13Carbon Natural Abundance Techniques

A field experiment on dhaincha, sunflower, and sorghum plants grown in monocropping and intercropping systems was conducted to evaluate growth and nitrogen (N₂) fixation using ¹³carbon (C) and ¹⁵N natural abundance techniques. Intercropping of sesbania/sorghum showed a greater efficiency than monocropping in producing dry matter during the entire growth period, whereas the efficiency of producing dry matter in the sesbania/sunflower intercropping was similar to that in the monocropping system. Moreover, sorghum plants (C4) were more competitive than sesbania (C3) for soil N uptake, whereas sesbania seemed to be more competitive than its associated sunflower (C3). Nitrogen uptake in the mixed stand of sesbania/sorghum was improved as a result of the increase in soil N uptake by the component sorghum and the greater root nodule activity of component sesbania without affecting the amount of N₂ fixed. The Δ ¹³C in plant materials was affected by plant species and the cropping system.     

The stable carbon isotope composition of soil organic carbon and pedogenic carbonates along a bioclimatic gradient in the Palouse region,Washington State,USA

Isotopic signatures of soil components are commonly used to infer past ecologic and climatic shifts in the soil record. The theory behind the fractionation of isotopes that occurs during ecosystem processes is well understood; however, few isotopic studies have explored ecosystem relationships in modern soils. We discuss relationships of stable carbon isotopic signatures in plant tissue, soil organic carbon (SOC), laboratory-respired CO₂, and modern carbonates at 10 sites (seven containing pedogenic carbonates) along a C₃-dominated climatic gradient (mean annual precipitation (MAP) ranging from 200 to 1000 mm) in the Palouse region of eastern Washington state.A horizon soil organic carbon (SOC) δ¹³C values varied from −24.3‰ to −25.9‰ PDB. Values in the arid portion of the gradient (200 to approximately 500 mm MAP) generally decreased and linear regression of SOM ¹³C vs. MAP was significant (r²=0.71, p=0.02). Trends in plant-¹³C of two grass species (Agropyron spicatum and Festuca idahoensis) found throughout this portion of the gradient were similar to that of SOC. Mean pedogenic carbonate δ¹³C values varied from −4.1‰ to −10.8‰ PDB. Linear regression was significant for carbonate ¹³C vs. MAP (r²=0.79, p=0.007), estimated above-ground productivity (r²=0.88, p=0.002) and soil carbon content (r²=0.83, p=0.004). Carbonate δ¹³C values at the most arid site exhibited higher variability than other sites (presumably due to greater spatial variation in plant respiration vs. atmospheric diffusion). Our data suggest that carbon isotopic relationships among ecosystem components may prove useful in determining ecosystem level properties in modern systems, and potentially in ancient systems as well.     

准噶尔盆地温带荒漠土壤碱化分级的初步研究

准噶尔盆地温带荒漠碱化土壤是一种典型的脱盐碱化土壤,它受交换性钠(镁)和能产生水解作用的强碱弱酸盐水解引起的碱度的影响。在多年野外调查和碱化土壤特性研究的基础上,利用综合数值分析法对这些土壤进行了研究。提出了准噶尔盆地温带荒漠土壤碱化分级的具体指标和数据,并确定了水解性碱度为分级的第一重要指标。在推动和简化荒漠土壤分级上起了积极的作用。     

华南红壤的交换性碱和交换性酸

本文提出了一个同时测定土壤的交换性酸和交换性碱的简易方法。将土壤的交换性酸和交换性碱区分为:Na-交换性酸、Ba-交换性酸和SO₄-交换性碱、F-交换性碱。用推荐的方法,在野外对华南地区由不同母质发育的砖红壤、赤红壤、红壤等10个剖面进行了测定。结果表明,红壤类土壤含有相当量的交换性碱,但其数量比交换性酸少。酸性母质发育的土壤的交换性酸和交换性碱量大于由基性岩发育的土壤者。红壤的交换性酸和碱的量随电性盐浓度的增高而增大,浓度大于0.1N后,数量基本不变。     

The nature of alkalinity in virgin and anthropogenically modified solonetzes of northern Kalmykia

The alkalinity of virgin solonetzes and its changes under the impact of 50-year-long afforestation and agricultural loads were investigated. It was found that the maximum alkalinity in both virgin and anthropogenically modified solonetzes is typical of the gypsum-free carbonate horizons containing exchangeable sodium. In these horizons of the virgin (B2, BCca) and anthropogenically modified (BMK, BCca) solonetzes, sodium carbonates (Na₂CO₃ and NaHCO₃) are present because of the in situ ion exchange reaction between sodium in the exchange complex and calcium of calcium carbonates in the solution (the Gedroits reaction). The boundaries of the occurrence of soda in the soil profile are controlled by calcium compounds: the upper boundary of soda formation is specified by the presence of calcium carbonates, whereas the lower boundary is specified by the appearance of calcium sulfates (gypsum). In other horizons, including the solonetzic (B1) horizon, in which calcium carbonates are absent, soda is not formed, and the soil pH and carbonate alkalinity are controlled by the carbonate-calcium equilibria.