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以马尾松(Pinus massoniana)为研究对象,分别在 180, 200, 220 ℃条件下对其进行水蒸气
热处理 1, 3, 5 h。借助干燥器法测试不同温度热处理材的甲醛吸附量变化,利用程序升温化学吸附法、
比表面积测试以及表面接触角方法探索不同温度处理的热处理材表面特性的变化规律。结果表明:与未
热处理的素材相比,(1)热处理后的木材甲醛吸附性能得到改善,经 180 ℃、 1 h 处理后的木材甲醛吸附
性能最好,且随处理温度升高、时间延长,甲醛吸附性能降低,总体呈降低趋势;(2)热处理木材对甲
醛的吸附不仅是物理吸附,还存在化学吸附;(3)不同温度处理后,木材的比表面积均减小;(4)经热
处理后,极性的蒸馏水在木材表面的接触角较素材大且热处理的温度越高、表面接触角越大,而非极性
的二碘甲烷在其表面的接触角变化趋势相反。 相似文献
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蒸汽热处理马尾松木材工艺初探 总被引:1,自引:0,他引:1
以浙江本地的马尾松为试材,采用自制的小型热处理木材实验装置进行高温热处理木材工艺实验.通过对热处理前后马尾松木材力学性能和尺寸稳定性的比较,探讨了热处理温度、热处理时间以及升温速度对其性能的影响.研究结果表明:热处理温度对热处理马尾松木材的抗弯强度有显著影响,经热处理后的马尾松木材与未处理材相比,其顺纹抗压强度下降了1.823%~11.084%,抗弯强度下降了0.259%~34.451%,体积干缩湿胀率也有所降低.经综合分析并考虑到热源损耗及尺寸稳定性,得出马尾松木材的热处理最佳工艺为:热处理温度190℃,热处理时间2h,升温速度15℃/h 相似文献
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桉树真空热处理材表面性能分析 总被引:3,自引:0,他引:3
用真空热处理法对粗皮桉木材进行热处理,处理温度分别为160,180,200,220及240℃,处理时间均为4 h.采用接触角测定法,对素材及不同温度条件下热处理材的接触角及表面自由能进行分析;用傅里叶红外光谱分析法,研究木材在热处理过程中的化学(官能团)变化;用热分析仪分析不同温度条件下木材的热解质量损失率.结果表明:素材的表面自由能(50 mN·m-1)<160℃热处理材的表面自由能(46 mN·m-1)<240℃热处理材的表面自由能(32 mN·m-1).热处理后木材中极性的羰基官能团减少,当热处理温度≤180℃时,木材的质量损失率在1%左右;而热处理温度>180 ℃时,每升高20℃,木材的质量损失率约下降2倍. 相似文献
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等离子体处理对6种木材表面润湿性能的影响 总被引:1,自引:0,他引:1
【目的】基于现有大量空气等离子体对人工林木材表面改性的研究,采用不同气体辉光放电等离子体对3种人工林和3种天然林木材进行改性处理,对比研究其对木材表面润湿性能的影响,为常压空气等离子体处理木材表面的工业化生产提供理论支持,为等离子体在不同木材表面改性的应用奠定理论基础。【方法】采用空气(Air)、氧气(O2)、氮气(N2)、氩气(Ar)和氦气(He)5种气体辉光放电低温等离子体分别处理山杨、云杉、蓝桉3种人工林木材和实木制品及木质制品表面饰面常用的红栎、白桦和黑胡桃3种天然林木材,测试计算不同等离子体处理条件下木材的接触角和表面自由能,以及经氮气等离子体不同时间处理后木材的表面水接触角,研究不同气体辉光放电低温等离子体对不同材质木材表面润湿性能的影响。【结果】木材表面经空气、氦气、氩气、氮气和氧气5种气体等离子体处理后,表面与水、二碘甲烷的接触角均明显减小,表面自由能增大,润湿性得到显著改善。试验条件下,氦气等离子体处理对云杉、山杨木材表面润湿性能影响最大,而蓝桉、红栎、白桦和黑胡桃木材均为氩气等离子体处理后的表面接触角降幅最大,表面自由能增大明显。等离子体处理时间对木材表面润湿性影响相对较大,一般人工林木材以3 min为宜,天然木材以4 min为宜。【结论】不同气体等离子体处理木材表面后,木材表面润湿性能均得到改善,且以空气作为等离子体处理气体的润湿效果相对较好。在实际生产应用中,可采用空气等离子体处理提高木材及木基复合材料间的胶合、接枝等性能。 相似文献
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本文以人工林落叶松木材为试材、以生物质燃气为木材热处理介质,采用特定的处理装置和一定的处理条件,对照生物质燃气和氮气两种介质,试验分析处理介质对落叶松热处理木材性能的影响。结果表明:落叶松热处理木材的密度、平衡含水率和尺寸稳定性在两种处理介质中没有显著的变化,说明生物质燃气可以作为热处理木材的介质,并且具有处理成本低、原料来源广泛的特点。 相似文献
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ZHOU Yongdong JIANG Xiaomei LIU Junliang CHAI Yubo WANG Jing WANG Shu Key Lab of Wood Science Technology of State Forestry Administration Research Institute of Wood Industry Chinese Academy of Forestry Beijing P. R. China 《中国林业科技(英文版)》2008,(3):56-60
Plantation poplar is one of the most important resources for wood industry, its utilization field is vast. The wettability of Populus tomentosa with different drying methods was judged by measurement of contact angle using distilled water in this paper. The results showed that the specimens from conventional drying have the biggest contact angle, and the air dried have the smallest contact angle, air dried lumbers have a better wettability than the kiln dried. The changes of contact angle in a period of tim... 相似文献
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Maziar Sedighi Moghaddam Per M. Claesson Magnus E. P. Wålinder Agne Swerin 《Wood Science and Technology》2014,48(1):161-176
The wettability of Scots pine veneers was investigated with different approaches using the Wilhelmy plate method. The probe liquids were water and octane, which differ; in that, water is able to swell the wood sample, whereas octane does not. Novel approaches based on the Wilhelmy plate method to study wettability, liquid penetration, and swelling behavior of wood veneers are introduced. First, immersion to constant depth was performed, and liquid uptake with time was evaluated. Different kinetic regimes, the fastest one associated with contact angle changes and the slowest regime associated with liquid sorption by capillary and diffusion, were observed. Two other approaches, imbibition at constant depth (with initial deeper immersion) and full immersion, were utilized in order to keep the contact angle constant during measurements. Dynamic wettability studies were done by a multi-cycle (10–20 cycles) Wilhelmy method. Based on this, the time-dependent swelling of wood and changes in sample perimeter could be obtained. Generally, water showed higher absorption than octane. In all wettability studies, and for both probe liquids, the penetration process starts with a fast initial sorption, which is followed by swelling in the case of water. 相似文献
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微波等离子体处理对杉木表面性能的影响 总被引:19,自引:1,他引:18
为了解微波等离子体处理对杉木表面性能的影响,使用接触角测定评估表面润湿性,使用扫描电子显微镜观测表面处理前后的差异。结果表明,杉木表面轻微波等离子体处理后,接触角下降为零,即使处理条件十分微弱、处理效果仍然十分明显,这表明微波等离子体处理可显著提高木材表面的润湿性,微波等离子体处理使杉木表面形成粗化面,即表面明显有等离子体蚀刻过的痕迹并留下凹凸不平的坑洼,粗化面的形成可能是导致杉木表面接触角下降, 相似文献
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泡桐木材流体渗透性与扩散性的研究 总被引:11,自引:1,他引:11
本文论述了泡桐木材流体渗透性,扩散性,吸着水与自由水的吸着与吸收动力学特性,密度和干缩性以及电镜观察结果;阐明了泡桐木材具有流体可渗透及可扩散路径,有着输导流体的天然机制,水、热处理难易一般;泡桐材本身并不具有隔潮耐湿性,但由于它密度低,胀缩小,变形和开裂的可能性亦小,用它干燥后制成的箱盒容器的密封性、隔潮耐湿性较好。 相似文献
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Improved water repellency of black spruce wood surfaces after treatment in carbon tetrafluoride plasmas 总被引:1,自引:0,他引:1
Bouddah Poaty Bernard Riedl Pierre Blanchet Vincent Blanchard Luc Stafford 《Wood Science and Technology》2013,47(2):411-422
Plasma treatments for black spruce wood (Picea mariana (Mill.) B.S.P.), a widespread forest species from Canada, were carried out in order to waterproof the exposed surfaces. Experiments were performed using inductively coupled argon plasma with carbon tetrafluoride as the gaseous precursor for plasma-enhanced chemical vapor deposition of functional fluoropolymer coatings on wood. Analysis of the wettability through water contact angle measurements showed water-repellent characteristics, with static contact angles up to 130° depending on plasma exposure time, CF4 concentration in the Ar/CF4 plasma, and plasma source-to-substrate distance. X-ray photoelectron spectroscopy investigations of plasma-treated wood surfaces confirmed the growth of a thin, fluorocarbon layer with fluorine atomic concentrations close to 50 % on highly hydrophobic wood surfaces. Estimation of the thickness of the coatings by stylus profilometry revealed that a minimum layer thickness of about 80 nm is required to obtain water repellant wood surfaces with minimum water uptake. This complete set of data indicates that fluorocarbon-containing plasmas represent a very promising approach for improving the durability of wood products in wet and humid conditions. 相似文献
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Highly hydrophobic bulk wood was successfully prepared by grafting long-chain octadecyl isocyanate (OTI) onto wood cell walls via a urethane linkage. The resulting wood was highly hydrophobic and showed significantly reduced surface free energy. The microstructure and chemical composition of the untreated and treated wood were characterized using the scanning electron microscopy, energy-dispersive X-ray spectrometry, and Fourier transform infrared spectroscopy. The hydrophobic property of the wood was characterized using contact angle measurements. The mechanical and physical properties as well as the chemical durability of the highly hydrophobic wood were evaluated. The results suggested that the resultant OTI-treated wood presented fairly low surface free energy, high hydrophobicity even in the wood core, and excellent stability and durability against chemical corrosion and mechanical abrasion. Furthermore, the physical properties, including self-cleaning, dimensional stability, and water uptake, were significantly improved in the treated wood. 相似文献
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选取丙烯酸酯、聚氨酯、丙烯酸-聚氨酯共聚物3种水性漆为滴液,用接触角测试仪对3种水性漆在杨木表面的接触角进行测试,对比分析其对杨木表面润湿性的影响。结果表明:未进行超纯水稀释的水性漆中,丙烯酸酯、共聚物水性漆在杨木径切面的润湿性优于弦切面,聚氨酯水性漆则反之;共聚物水性漆相比于其他两种漆润湿性更好,聚氨酯次之,丙烯酸酯水性漆的润湿性则相对较差。相比未进行超纯水稀释的水性漆,经稀释处理的3种水性漆在杨木表面的接触角均有不同程度的下降。接触角下降率分析表明:丙烯酸酯水性漆相比其他两种漆在杨木表面的润湿性更好,此外共聚物水性漆在杨木弦切面润湿性优于径切面,而其他两种水性漆则相反。 相似文献