Biomass and respiration activity of soil microorganisms in anthropogenically transformed ecosystems (Moscow region)

In the forest, meadow, arable, and urban ecosystems (recreational, residential, and industrial zones) of Sergiev Posad, Shatura, Serpukhov, and Serebryanye Prudy districts of Moscow region, spatially separated sites (3–5 points per site) have been randomly selected and soil samples have been taken from the 0–10 (plant litter excluded) and 10- to 150-cm layers (a total of 201 samples have been taken). In the samples, the microbial biomass carbon (C_mic), the rate of the basal (microbial) respiration (BR), and the physical parameters (the particle size distribution (PSD), organic carbon (C_org), pH, heavy metals, and nutrients (NPK)) have been determined. High spatial variability has been revealed for C_mic and BR in all the ecosystems and the functional zones of the studied districts, and a clear tendency of a decrease in these parameters has been shown in the arable soils (by 1.4–3.2 times) and the industrial zone (by 1.7–3.3 times) compared to the natural analogues and other corresponding functional zones. It has been shown that the spatial distribution of the microbiological parameters is significantly (p ≤ 0.05) affected by the physicochemical properties of the soil (C_mic by the PSD and PSD × C_org; BR by the pH and pH × NPK; contributions of 40 and 63%, respectively), as well as by the type of ecosystem and the region of study (the contribution of the sum of these factors to the C_mic and BR was 56 and 67%, respectively). A tendency toward the deterioration of the functioning of the microbial community under the anthropogenic transformation of the soil has been shown. The contribution of the urban soils as a potential source of CO₂ emission to the atmosphere has been calculated and discussed.     

长期施肥下红壤旱地的固碳效率

红壤旱地的有机碳含量普遍较低,通过外源添加有机肥是增加土壤有机碳含量的重要手段。本研究以红壤旱地长期肥料试验为基础,研究了不同施肥处理的土壤有机碳含量和储量的变化规律,并进一步探讨碳投入与玉米产量及土壤碳储量的量化关系。结果表明:施用有机肥可以大幅提升红壤旱地的有机碳含量,氮磷钾+有机肥(NPKM)和有机肥(OM)处理在27年间的增加速率分别为0.08 g/(kg·a)和0.06 g/(kg·a),有机碳储量的增加速率分别为0.24t/(hm~2·a)和0.16 t/(hm~2·a);与不施肥(CK)处理相比,NPKM和OM处理的土壤有机碳含量分别增加了51.5%和42.0%,有机碳储量则分别增加57.1%和45.7%。进一步分析表明,有机碳投入量与土壤有机碳储量变化速率之间存在显著的正相关关系(R~2=0.971 5,P0.001),且线性拟合方程(y=–0.158+0.086x)表明,双季玉米种植下红壤旱地的固碳效率为8.6%,当有机碳投入量为1.84 t/(hm~2·a)时,红壤旱地的有机碳储量保持平衡。因此,施用有机肥是提高红壤旱地有机碳储量的有效途径,固碳效率和土壤有机碳平衡点则可以有效指导红壤旱地有机肥的管理措施。     

An experience in regional estimates of changes in soil carbon pools of the southern taiga and forest-steppe during the historical period

Regional estimates of changes in soil organic carbon (SOC) pools during the historical period were obtained according to a unified approach for Kostroma (southern taiga) and Kursk (forest-steppe) oblasts. The potential pools of soil carbon were calculated with due account for the classification position of particular soils, their texture, and the character of natural vegetation. In the estimates of actual SOC pools, land use patterns and the age structure of forest stands were taken into account. It was shown that modern pools of organic carbon in the soils of Kostroma oblast are only 1–2% smaller than the potential pools; for the soils of Kursk oblast, this difference reaches 23–27%. Mean weighted values of the actual SOC contents in these oblasts decreased by 0.1–0.2 and 6.5–7.6 kg C/m² in comparison with the potential SOC contents, respectively, which is related to their environmental specificity and to different types of land use at present and in the historical past.     

Priming effect and its regulating factors for fast and slow soil organic carbon pools: A meta-analysis

The priming effect (PE) plays a critical role in the control of soil carbon (C) cycling and influences the alteration of soil organic C (SOC) decomposition by fresh C input.However,drivers of PE for the fast and slow SOC pools remain unclear because of the varying results from individual studies.Using meta-analysis in combination with boosted regression tree (BRT) analysis,we evaluated the relative contribution of multiple drivers of PE with substrate and their patterns across each driver gradient.The results showed that the variability of PE was larger for the fast SOC pool than for the slow SOC pool.Based on the BRT analysis,67%and 34%of the variation in PE were explained for the fast and slow SOC pools,respectively.There were seven determinants of PE for the fast SOC pool,with soil total nitrogen (N) content being the most important,followed by,in a descending order,substrate C:N ratio,soil moisture,soil clay content,soil pH,substrate addition rate,and SOC content.The directions of PE were negative when soil total N content and substrate C:N ratio were below 2 g kg~(-1)and 20,respectively,but the directions changed from negative to positive with increasing levels of this two factors.Soils with optimal water content (50%–70%of the water-holding capacity) or moderately low pH (5–6) were prone to producing a greater PE.For the slow SOC pool,soil p H and soil total N content substantially explained the variation in PE.The magnitude of PE was likely to decrease with increasing soil pH for the slow SOC pool.In addition,the magnitude of PE slightly fluctuated with soil N content for the slow SOC pool.Overall,this meta-analysis provided new insights into the distinctive PEs for different SOC pools and indicated knowledge gaps between PE and its regulating factors for the slow SOC pool.     

The relative impact of land use and soil properties on sizes and turnover rates of soil organic carbon pools in Subtropical China

The dynamics of soil organic carbon (SOC) pools determine potential carbon sequestration and soil nutrient improvement. This study investigated the characteristics of SOC pools in five types of cultivated topsoils (0–15 cm) in subtropical China using laboratory incubation experiments under aerobic conditions. The sizes and turnover rates of the active, slow and resistant C pools were simulated using a first‐order kinetic model. The relative influence of soil environmental properties on the dynamics of different SOC pools was evaluated by applying principal component analysis (PCA) and aggregated boosted trees (ABTs) analysis. The results show that there were significantly greater sizes of different SOC pools and lower turnover rates of slow C pool in two types of paddy soils than in upland soils. Land use exerted the most significant influence on the sizes of all SOC pools, followed by clay content and soil pH. The soil C/N ratio and pH were the major determinants for turnover rates of the active and slow C pools, followed by clay content which had more impact on the turnover rates of the active C pool than the slow C pool. It is concluded that soil type exerts a significant impact on the dynamics of SOC.     

Impact of tillage intensity on carbon and nitrogen pools in surface and sub‐surface soils of three long‐term field experiments

Management options such as the intensity of tillage are known to influence the turnover dynamics of soil organic matter. However, less information is available about the influence of the tillage intensity on individual soil organic matter pools with different turnover dynamics in surface as compared with sub‐surface soils. This study aimed to analyse the impact of no tillage (NT), reduced tillage (RT) and conventional tillage (CT) on labile, intermediate and stable carbon (C) and nitrogen (N) pools in surface and sub‐surface soils. We took surface and sub‐surface soil samples from the three tillage systems in three long‐term field experiments in Germany. The labile, intermediate and stable C and N pool sizes were determined by using the combined application of a decomposition experiment and a physical‐chemical separation procedure. For the surface soils, we found larger stocks of the labile C and N pool under NT and RT (C, 1.7 and 1.3 t ha^?1; N, 180 and 160 kg ha^?1) than with CT (C, 0.5 t ha^?1; N, 60 kg ha^?1). In contrast, we found significantly larger stocks of the labile C pool under CT (2.7 t ha^?1) than with NT and RT (2 t ha^?1) for the sub‐surface soils. The intermediate pool accounted for 75–84% of the soil organic C and total N stocks. However, the stocks of the intermediate N and C pools were only distinctly larger for NT than for CT in the surface soils. The stocks of the stable C and N pools were not affected by the tillage intensity but were positively correlated with the stocks of the clay‐size fraction and oxalate soluble aluminum, indicating a strong influence of site‐specific mineral characteristics on the size of these pools. Our results indicate soil depth‐specific variations in the response of organic matter pools to tillage of different intensity. This means that the potential benefits of decreasing tillage intensity with respect to soil functions that are closely related to organic matter dynamics have to be evaluated separately for surface and sub‐surface soils.     

Repeated monitoring of organic carbon stocks after eight years reveals carbon losses from intensively managed agricultural soils in Western Germany

Past land‐use changes, intensive cropping with large proportions of root crops, and preferred use of mineral fertilizer have been made responsible for proceeding losses of soil organic C (SOC) in the plough layer. We hypothesized that in intensive agriculturally managed regions changes in SOC stocks would be detectable within a decade. To test this hypothesis, we tracked the temporal development of the concentrations and stocks of SOC in 268 arable sites, sampled by horizon down to 60 cm in the Cologne‐Bonn region, W Germany, in 2005 and in 2013. We then related these changes to soil management data and humus balances obtained from farmers' surveys. As we expected that changes in SOC concentrations might at least in part be minor, we fractionated soils from 38 representative sites according to particle size in order to obtain C pools of different stability. We found that SOC concentrations had increased significantly in the topsoil (from 9.4 g kg^?1 in 2005 to 9.8 g kg^?1 in 2013), but had decreased significantly in the subsoil (from 4.1 g kg^?1 in 2005 to 3.5 g kg^?­1 in 2013). Intriguingly, these changes were due to changes in mineral‐bound SOC rather than to changes in sand‐sized organic matter pools. As bulk density decreased, the overall SOC stocks in the upper 60 cm exhibited a SOC loss of nearly 0.6 t C (ha · y)^?1 after correction by the equivalent soil mass method. This loss was most pronounced for sandy soils [?0.73 t SOC (ha · y)^?1], and less pronounced for loamy soils [?0.64 t SOC (ha · y)^?1]; silty soils revealed the smallest reduction in SOC [?0.3 t SOC (ha · y)^?1]. Losses of SOC occurred even with the overall humus balances having increased positively from about 20 kg C (ha · y)^?1 (2003–2005) to about 133 kg C (ha · y)^?1 (2005–2013) due to an improved organic fertilization and intercropping. We conclude that current management may fail to raise overall SOC stocks. In our study area SOC stocks even continued to decline, despite humus conservation practice, likely because past land use conversions (before 2005) still affect SOC dynamics.     

The role of soils in the regional carbon budget of pine forests in Karelia

The carbon pool and its fluxes were studied in Karelian pine forests of automorphic sites for the characterization of the regional carbon cycle. On the permanent sample plots arranged in pine stands (dominant forest types) of the middle and northern taiga, the structure and dynamics of the phytomass, as well as the composition of the soil organic matter, were investigated. The contribution of different components of the forest ecosystems to the regional carbon budget was studied. The carbon pools in the soils of the middle and northern taiga subzones were 330–440 × 10² and 440–550 × 10² kg/ha, respectively. The share of soil carbon in the total carbon pool of the forest biogeocenoses studied amounted to 46–35 and 33–24%, respectively. The period of considerable carbon fixation in the pine ecosystem (nearly 20 × 10² kg/ha/yr) turned out to be limited to the middle-aged stands. In the mature and overmature pine forests, only 4 × 10² kg of C/ha/yr were fixed. The main part of carbon in the soil (65–75%) was contained in the illuvial horizons, although its content there was less that 1% as compared to 30–50% in the forest litters. On industrial harvesting of wood, the main reserves of soil carbon are not spent; only the fund of mobile carbon in organic horizons of poor soils is exhausted or carbon accumulates intensely due to the development of continuous plant cover on fertile soils.     

Dynamics of labile and recalcitrant soil carbon pools in a sorghum free-air CO2 enrichment (FACE) agroecosystem

Experimentation with dynamics of soil carbon pools as affected by elevated CO₂ can better define the ability of terrestrial ecosystems to sequester global carbon. In the present study, 6 N HCl hydrolysis and stable-carbon isotopic analysis (δ¹³C) were used to investigate labile and recalcitrant soil carbon pools and the translocation among these pools of sorghum residues isotopically labeled in the 1998-1999 Arizona Maricopa free air CO₂ enrichment (FACE) experiment, in which elevated CO₂ (FACE: 560 μmol mol⁻¹) and ambient CO₂ (Control: 360 μmol mol⁻¹) interact with water-adequate (wet) and water-deficient (dry) treatments. We found that on average 53% of the final soil organic carbon (SOC) in the FACE plot was in the recalcitrant carbon pool and 47% in the labile pool, whereas in the Control plot 46% and 54% of carbon were in recalcitrant and labile pools, respectively, indicating that elevated CO₂ transferred more SOC into the slow-decay carbon pool. Also, isotopic mixing models revealed that increased new sorghum residue input to the recalcitrant pool mainly accounts for this change, especially for the upper soil horizon (0-30 cm) where new carbon in recalcitrant soil pools of FACE wet and dry treatments was 1.7 and 2.8 times as large as that in respective Control recalcitrant pools. Similarly, old C in the recalcitrant pool under elevated CO₂ was higher than that under ambient CO₂, indicating that elevated CO₂ reduces the decay of the old C in recalcitrant pool. Mean residence time (MRT) of bulk soil carbon at the depth of 0-30 cm was significantly longer in FACE plot than Control plot by the averages of 12 and 13 yr under the dry and wet conditions, respectively. The MRT was positively correlated to the ratio of carbon content in the recalcitrant pool to total SOC and negatively correlated to the ratio of carbon content in the labile pool to total SOC. Influence of water alone on the bulk SOC or the labile and recalcitrant pools was not significant. However, water stress interacting with CO₂ enhanced the shift of the carbon from labile pool to recalcitrant pool. Our results imply that terrestrial agroecosystems may play a critical role in sequestrating atmospheric CO₂ and mitigating harmful CO₂ under future atmospheric conditions.     

Biological carbon assimilation and dynamics in a flooded rice – Soil system

Information on the input, distribution and fate of photosynthesized carbon (C) in plant–soil systems is essential for understanding their nutrient and C dynamics. Our objectives were to: 1) quantify the input to, and distribution of, photosynthesized C by rice into selected soil C pools by using a C¹⁴ continuous labelling technique and 2) determine the influence of the photosynthesized C input on the decomposition of native soil organic carbon (SOC) under laboratory conditions. The amounts of C¹⁴ in soil organic C (SOC¹⁴) were soil dependent, and ranged from 114.3 to 348.2 mg C kg⁻¹, accounting for 0.73%–1.99% of total SOC after continuous labelling for 80 days. However, the mean SOC¹⁴ concentrations in unplanted soils (31.9–64.6 mg kg⁻¹) were accounted for 21.5% of the rice-planted soils. The amounts of C¹⁴ in the dissolved organic C (DOC¹⁴) and in the microbial biomass C (MBC¹⁴), as percentages of SOC¹⁴, were 2.21%–3.54% and 9.72%–17.97%, respectively. The DOC¹⁴ and MBC¹⁴ were 6.72%–14.64% and 1.70%–7.67% of total DOC and MBC respectively after 80-d of rice growth. At 80-d of labelling, the SOC¹⁴ concentration was positively correlated with the MBC¹⁴ concentration and rice root biomass. Rice growth promotes more photosynthesized (newly-derived) C into soil C pools compared to unplanted soils, reflecting the release of root exudates from rice roots. Laboratory incubation of photosynthesized (plant-derived) C in soil decreased the decomposition of native SOC (i.e. a negative priming effect), in some, but not all cases. If this negative priming effect of the new C on native SOC also occurs in the field in the longer term, paddy soils will probably sequester more C from the atmosphere if more photosynthesized C enters them.     

Changes in carbon stocks of Danish agricultural mineral soils between 1986 and 2009

To establish a national inventory of soil organic carbon (SOC) stocks and their change over time, soil was sampled in 1986, 1997 and 2009 in a Danish nation‐wide 7‐km grid and analysed for SOC content. The average SOC stock in 0–100‐cm depth soil was 142 t C ha^?1, with 63, 41 and 38 t C ha^?1 in the 0–25, 25–50 and 50–100 cm depths, respectively. Changes at 0–25 cm were small. During 1986–97, SOC in the 25–50‐cm layer increased in sandy soils while SOC decreased in loam soils. In the subsequent period (1997–2009), most soils showed significant losses of SOC. From 1986 to 2009, SOC at 0–100 cm decreased in loam soils and tended to increase in sandy soils. This trend is ascribed to dairy farms with grass leys being abundant on sandy soils while cereal cropping dominates on loamy soils. A statistical model including soil type, land use and management was applied separately to 0–25, 25–50 and 50–100 cm depths to pinpoint drivers for SOC change. In the 0–25 cm layer, grass leys added 0.95 t C ha^?1 year^?1 and autumn‐sown crops with straw incorporation added 0.40 t C ha^?1 year^?1. Cattle manure added 0.21 t C ha^?1 year^?1. Most interestingly, grass leys contributed 0.58 t C ha^?1 year^?1 at 25–50 cm, confirming that inventories based only on top‐soils are incomplete. We found no significant effects in 50–100 cm. Our study indicates a small annual loss of 0.2 t C ha^?1 from the 0–100 cm soil layer between 1986 and 2009.     

Polycyclic aromatic hydrocarbons in atmospheric particulate depositions and urban soils of Moscow,Russia

Purpose

The study was conducted to quantify the polycyclic aromatic hydrocarbons (PAHs) accumulation in urban soils from different functional areas via atmospheric inputs with particulate matter.

Materials and methods

PAH concentration and pattern were measured in the particulate matter of snow depositions, in the upper layers of artificial soils from densely built-up areas and in the undisturbed natural soils (Umbric Retisols) from green park area. Samples were collected in 2011–2013 at 58 sites with different traffic activities located at the territory of the Eastern Administrative Okrug of Moscow. The soil samples and filters with particulate matter were extracted by pressurized liquid extraction using Dionex ASE200. Clean-up analyses were performed on SPE cartridges filled with silica gel. Concentrations of PAHs were determined by high-performance liquid chromatography using an Agilent 1100 System equipped with fluorescent detector.

Results and discussion

Mean values of PAH input with snow particles were 45–57 μg/m² for recreational and residential zones, and 140–264 μg/m² for traffic zones. The samples of depositions from different functional areas showed a similar PAH pattern and consisted primarily of 3–4-ring PAHs. Total PAH concentrations in upper layers of artificial soils showed similar mean values of 1.43–2.21 μg/g for all functional zones. The PAH content in soils from the park area was twofold lower than that from the built-up area (0.34–0.63 μg/g), despite equal levels of atmosphere contamination on these territories. The upper layers of natural soils from recreational and traffic zones showed slight differences in PAH content, though PAH input with snow was fivefold higher in the traffic zone. Compared with airborne depositions, soils contained significant amounts of 5–6-ring PAHs.

Conclusions

A high level of soil PAH contamination in urban areas of Moscow, several orders of magnitude higher than the current PAH input to them from the atmosphere, indicates a lack of direct connection of the PAH pool in soils with this source. The high PAH content in the upper layer of constructed soils can be the result of repeated use of materials subjected to a constant technogenic impact for the production of artificial soils.

     

云南省土壤有机碳储量估算及空间分布

根据云南省第二次土壤普查资料,采用土壤类型法估算了云南省主要土壤类型的有机碳(SOC)密度和储量,并对云南省土壤有机碳密度的空间分布差异和影响土壤有机碳储量的主要因子进行了分析。结果表明,云南省0-20 cm土层平均SOC密度为59.77 t/hm²,SOC储量为2.30×10⁹ t;0-100 cm土层平均SOC密度为159.95 t/hm²,SOC储量为6.15×10⁹ t,占全国储量的7.28%,占全球陆地生态系统SOC储量的0.41%;其中SOC储量占前4位的土壤类型为红壤、黄棕壤、赤红壤、棕壤,不同深度下4者之和约占云南省总储量的60%。在土壤有机碳密度空间分布上,SOC密度分布最高的区域为云南省西北部和东北部地区,其次是西部的横断山脉和东部的云南高原地区,而以紫色土为主的中北部地区SOC密度则最低。由于降雨量、温度、海拔和土地利用类型的共同影响,导致了区域内的SOC密度分布不均,其中降雨量、温度和海拔等自然因素是影响SOC密度分布的主要因子。     

USING THE 137Cs TECHNIQUE TO STUDY THE EFFECT OF SOIL REDISTRIBUTION ON SOIL ORGANIC CARBON AND TOTAL NITROGEN STOCKS IN AN AGRICULTURAL CATCHMENT OF NORTHEAST CHINA

Soil organic carbon (SOC) and total nitrogen (TN) stocks can be affected by soil erosion and this is of great significance in relation to global environmental concern about environmental change. This study investigated the spatial patterns of ¹³⁷Cs, SOC and TN as well as their relationships for an agricultural catchment and presents a budget analysis of the redistributions of SOC and TN for the period 1954–2010. ¹³⁷Cs, SOC and TN inventories were found to be significantly correlated, and the application of the¹³⁷Cs technique proved to be useful for evaluating SOC and TN dynamics in the Luvic Phaeozem soil typical of the Chinese black soil region. Spatial patterns of soil, SOC and TN were greatly influenced by shelterbelts/windbreaks within the study catchment. Higher ¹³⁷Cs, SOC and TN stocks were generally found upwind of the shelterbelts and at the study catchment outlet, whereas lower stocks of ¹³⁷Cs, SOC and TN occurred behind the shelterbelts (i.e. in the lee). The total net losses of SOC and TN over the past 56 years were approximately 152 and 11 t respectively, with 47 and 38 per cent of the eroded SOC and TN in soils redeposited within the study catchment, respectively. Based on the relationships of soil, SOC and TN in the investigated catchment, erosion‐induced SOC and TN losses per year are around 1·2 × 10⁶ and 0·1 × 10⁶ t for the typical black soil region of Northeast China. Copyright © 2012 John Wiley & Sons, Ltd.     

Soil Organic Carbon and Inorganic Carbon Accumulation Along a 30‐year Grassland Restoration Chronosequence in Semi‐arid Regions (China)

Carbon accumulation is an important research topic for grassland restoration. It is requisite to determine the dynamics of the soil carbon pools [soil organic carbon (SOC) and soil inorganic carbon (SIC)] for understanding regional carbon budgets. In this study, we chose a grassland restoration chronosequence (cropland, 0 years; grasslands restored for 5, 15 and 30 years, i.e. RG5, RG15 and RG30, respectively) to compare the SOC and SIC pools in different soil profiles. Our results showed that SOC stock in the 0‐ to 100‐cm soil layer showed an initial decrease in RG5 and then an increase to net C gains in RG15 and RG30. Because of a decrease in the SIC stock, the percentage of SOC stock in the total soil C pool increased across the chronosequence. The SIC stock decreased at a rate of 0·75 Mg hm⁻² y⁻¹. The change of SOC was higher in the surface (0–10 cm, 0·40 Mg hm⁻² y⁻¹) than in the deeper soil (10–100 cm, 0·33 Mg hm⁻² y⁻¹) in RG5. The accumulation of C commenced >5 years after cropland conversion. Although the SIC content decreased, the SIC stock still represented a larger percentage of the soil C pool. Moreover, the soil total carbon showed an increasing trend during grassland restoration. Our results indicated that the soil C sequestration featured an increase in SOC, offsetting the decrease in SIC at the depth of 0–100 cm in the restored grasslands. Therefore, we suggest that both SOC and SIC should be considered during grassland restoration in semi‐arid regions. Copyright © 2016 John Wiley & Sons, Ltd.     

Effect of Graded Levels of Surface Crop Residue Application Under Minimum Tillage on Carbon Pools and Carbon Lability Index in Sorghum (Sorghum bicolor (L.) Moench)-Cowpea (Vigna unguiculata) System in Rainfed Alfisols

A long term experiment (2005–2012) was conducted in rainfed semi-arid tropical Alfisol at Hayathnagar Research Farm of Central Research Institute for Dryland Agriculture, Hyderabad, India. The aim of this experiment was to study the long-term impacts of graded levels of surface crop residue application on carbon (C) pools, aggregate associated C, C lability index and their relationship with crop yield. The experiment was conducted in a randomized block design (RBD) with minimum tillage (MT). Experimental treatments comprised of four levels of surface application of sorghum crop residues (@ 0, 2, 4 and 6 t ha^?1). The test crops, sorghum and cowpea, were grown in rotation yearly. Based on the pooled analysis of long term data (2005–2012), the study revealed that the surface application of sorghum residue @ 6 t ha^?1 and 4 t ha^?1 recorded 21% and 16% higher sorghum grain yields, respectively over control (no residue) whereas, the corresponding increase in the cowpea yield was 50% and 60%, respectively. Besides, the concentrations of soil organic carbon (SOC), inorganic carbon (IC), total carbon (TC), particulate organic carbon (POC) in the top surface soil (upper layer, 0–5cm depth) were found significantly higher than the sub-surface soil (lower layers, 5–15 cm depth) in all the treatments. Storage of soil C was assessed in soil aggregates fractions, and it was found that the smaller size aggregate fractions (0.053mm) contained significantly (p = 0.05) higher content of SOC compared to the large sized fractions (2 mm). The amount of very labile fraction of C extracted with 12 N H₂SO₄ was significantly higher (1.04 g kg^?1) with the application of sorghum stover @ 6t ha-¹ compared to other residue level treatments, in the 0-5 cm soil layer. The Lability Index (LI) increased with the increase in the amount of residues applied and was significantly higher in the surface soils compared to subsurface soil. The results of this study will be highly relevant and of significant value from the view point of managing SOC and its different pools in soil under abiotically stressed semiarid tropical Alfisols soils.     

Degradation of [carboxyl-14C] 2,4-D and [ring-U-14C] 2,4-D in 114 agricultural soils as affected by soil organic carbon content

This study compared the degradation of [carboxyl-¹⁴C] 2,4-dichlorophenoxyacetic acid (2,4-D) (C2,4-D) and [ring-U-¹⁴C] 2,4-D (R2,4-D) in 114 agricultural soils (0–15 cm) as affected by 2,4-D sorption and soil properties (organic carbon content, pH, clay content, carbonate content, cation exchange capacity, total microbial activity). The sample area was confined to Alberta, Canada, located 49–60° north longitude and 110–120° west latitude and soils were grouped by soil organic carbon content (SOC) (0–0.99%, 1–1.99%, 2–2.99%, 3–3.99% and >4% SOC). Degradation rates of C2,4-D and R2,4-D followed first-order kinetics in all soils. Although total microbial activity increased with increasing SOC, degradation rates and total degradation of C2,4-D and R2,4-D decreased with increasing SOC because of increased sorption of 2,4-D by soil and reduced bioavailability of 2,4-D and its metabolites. Rates of R2,4-D degradation were more limited by sorption than rates of C2,4-D degradation, possibly because of greater sorption and formation of bound residues of 2,4-D metabolites relative to the 2,4-D parent molecule. Based on the sorption and degradation parameters quantified, there were two distinct groups of soils, those with less than 1% SOC and those with greater than 1% SOC. Specifically, soils with less than 1% SOC had, on average, 2.4 times smaller soil organic carbon sorption coefficients and 1.4 times smaller 2,4-D half-lives than soils with more than 1% SOC. In regional scale model simulations of pesticide leaching to groundwater, covering many soils, input parameters for each pesticide include a single soil organic carbon sorption coefficient and single half-life value. Our results imply, however, that the approach to these regional scale assessments could be improved by adjusting the values of these two input parameters according to SOC. Specifically, this study indicates that for 2,4-D and Alberta soils containing less than 1% SOC, the 2,4-D pesticide parameters obtained from generic databases should be divided by 2.5 (soil organic carbon sorption coefficient) and 1.5 (half-life value).     

Organic carbon and total nitrogen variability in permafrost-affected soils in a forest tundra ecotone

Soils of the high latitudes are expected to respond sensitively to climate change, but still little is known about carbon and nitrogen variability in them. We investigated the 0.44‐km² Little Grawijka Creek catchment of the forest tundra ecotone (northern Krasnoyarsk Krai, Russian Federation) in order (i) to relate the active‐layer thickness to controlling environmental factors, (ii) to quantify soil organic carbon (SOC) and total nitrogen (NT) stocks, and (iii) to assess their variability with respect to different landscape units. The catchment was mapped on a 50 × 50 m grid for topography, dominant tree and ground vegetation, organic‐layer and moss‐layer thickness, and active‐layer thickness. At each grid point, bulk density, and SOC and NT concentrations were determined for depth increments. At three selected plots, 2‐m deep soil cores were taken and analysed for SOC, NT and ¹⁴C. A shallow active layer was found in intact raised bogs at plateaux situations and in mineral soils of north‐northeast (NNE) aspect. Good drainage and greater solar insolation on the south‐southwest (SSW) slopes are reflected in deeper active layers or lack of permafrost. Organic carbon stocks to a soil depth of 90 cm varied between 5 and 95 kg m^–2. The greatest stocks were found in the intact raised bogs and on the NNE slopes. Canonical correspondence analysis indicates the dominant role of active‐layer thickness for SOC and NT storage. The 2‐m soil cores suggest that permafrost soils store about the same amount of SOC from 90 to 200 cm as in the upper 90 cm. Most of this deep SOC pool was formed in the mid‐Holocene (organic soils) and the late Pleistocene (mineral soils). Our results showed that even within a small catchment of the forest tundra, active‐layer thickness and, hence, SOC and NT storage vary greatly within the landscape mosaic. This has to be taken into account when using upscaling methods such as remote sensing for assessing SOC and NT storage and cycling at a regional to continental level.     

Soils of the northern part of the Subpolar Urals: Morphology, physicochemical properties, and carbon and nitrogen pools

The morphology and physicochemical properties of mountain-tundra and mountain-forest soils of the Subpolar Urals are analyzed. Gleyic humus-illuvial podburs, in combination with humus-illuvial podburs and raw-humus gleyzems, predominate in the mountain-tundra zone; permafrost-affected gleyzems and peat gleyzems with a shallow (30–50 cm) permafrost table are developed on colluvial fans at the foots-lopes. Iron-illuvial podzols, iron-illuvial svetlozems, eluviated burozems, texture-differentiated podzolic soils with a microprofile of a podzol, and gleyed peat-podzolic soils occur in the mountain-forest zone. The organic carbon and nitrogen pools in the soils considerably vary depending on the soil type and local landscape conditions. The organic carbon pool stored in the upper 50 cm of the soil profile varies from 7.7 to 39.3 kg/m² in the mountain-tundra soils and from 6.5 to 11.8 kg/m² in the mountain-forest soils. The corresponding values for the nitrogen pool are 0.4–2.4 and 0.4–0.8 kg/m², respectively.     

Carbon sequestration in dryland ecosystems of West Asia and North Africa

The West Asia–North Africa (WANA) region has a land area of 1.7 billion ha, and a population of 600 million. Desertification and soil degradation are severe problems in the region. The problem of drought stress is exacerbated by low and erratic rainfall and soils of limited available water holding capacity and soil organic carbon (SOC) content of less than 0.5 per cent. The SOC pool of most soils has been depleted by soil degradation and widespread use of subsistence and exploitative farming systems. The historic loss of a SOC pool for the soils of the WANA region may be 6–12 Pg compared with the global loss of 66–90 Pg. Assuming that 60 per cent of the historic loss can be resequestered, the total soil‐C sink capacity of the WANA region may be 3–7 Pg. This potential may be realized through adoption of measures to control desertification, restore degraded soils and ecosystems, and improve soil and crop management techniques that can enhance the SOC pool and improve soil quality. The strategies of soil‐C sequestration include integrated nutrient management (INM) and recycling, controlled grazing, and growing improved fodder species on rangeland. Improved technologies for cropland include use of INM and biofertilizers, appropriate tillage methods and residue management techniques, crop rotations and cover crops, and water and nutrient recycling technologies. Through adoption of such measures, the potential of soil‐C sequestration in the WANA region is 0.2–0.4 Pg C yr⁻¹. Copyright © 2002 John Wiley & Sons, Ltd.