Amelioration of saline–sodic soil with gypsum can increase yield and nitrogen use efficiency in rice–wheat cropping system

A 2-year field experiment was conducted to determine crop yield and N use efficiency (NUE) from a saline–sodic soil (clay loam) with and without application of gypsum. Treatments included two N application rates (15% and 30%) higher than the recommended one to the normal soil, and gypsum added at 50% and 100% of soil gypsum requirement (SGR) to the saline–sodic soil, both cultivated with rice and wheat during 2011–2013. Results revealed a decrease in pH of saturated soil paste (pH_s), electrical conductivity of saturation extract (EC_e), sodium adsorption ratio (SAR) and exchangeable sodium percentage with N fertilizer along with gypsum application in saline–sodic soil. However, the effect was most prominent when gypsum was added at 50% of SGR. Crop yield and NUE remained significantly lower (p < 0.05) in saline–sodic-soils as compared to normal soil. However, gypsum application reduced this difference from 47% to 17% since both yield and NUE increased considerably. Crop yield and NUE remained higher for wheat than for rice. During first year, higher doses of N with gypsum application at 50% SGR proved most effective, whereas, in subsequent year, recommended N along with gypsum at 50% SGR became more profitable. All these results lead us to conclude that gypsum application can ameliorate saline–sodic soil thereby increasing crop yield and NUE.     

Predicted trends of soil erosion and sediment yield from future land use and climate change scenarios in the Lancang–Mekong River by using the modified RUSLE model

Soil erosion and sediments in the Lancang-Mekong River Basin as a result of climate change and changes in land use pose a threat to the existence of the riparian people, biodiversity and ecosystems. This study seeks to assess the annual soil erosion in terms of spatial distribution and the trends of sediment yield with the climate and land changes in future scenarios in 2030 and 2040 through the modified RUSLE model. Future lands were simulated by using the MLP artificial neural network and the Markov chain analysis. The future climate was examined by using the Max Planck Institute model, which showed a corrected bias and downscaled grid size under the Representative Concentration Pathways (RCPs). The simulated land use indicated that the forest areas were converted mostly to agricultural lands and urban areas. In the future, the average rainfall under all RCP scenarios is higher than that from the historical period. The R and C factors changed constantly, thereby affecting the soil erosion rate and sediment yield. The maximum erosion was estimated at approximately 21,000 and 21,725 t/km²/y under RCP8.5 in both years. Meanwhile, the results of sediment yield in 2030 and 2040 under RCP scenarios were much higher when compared to historical sediment data around 66.3% and 71.2%, respectively. Thailand's plateau, some parts of Cambodia and Laos PDR and the Mekong Delta are vulnerable to increase soil erosion and sediment yield. Measures to address these issues need to be planned to prepare and mitigate the possible effects, especially the loss of storage capacity in dams.     

Determination of total cadmium in calcareous soils by extraction using aliquat‐336 and 3‐heptan‐one after aqua regia digestion

Abstract

Measurement of total soil cadmium (Cd) is difficult due to calcium (Ca) and other chemicals which cause high background absorbance when trace levels of Cd are to be determined. When soil Cd is low, even use of deuterium background correction with flame atomic absorption spectroscopy (AAS) cannot provide accurate Cd results. Use of furnace atomic absorption with method of standard additions can circumvent these interferences, but the cost and time required are substantial. We desired a more rapid, convenient, and reliable alternative to extraction using dithizone and back‐extraction into acid, or to ammonium pyrollidinedithiocarbamate (APDC) which does not require close pH adjustment nor have many sources of potantial contamination. We evaluated analysis of these complex soil extracts with the method of Viets (1978) which extracts metals from 1N acid solutions using Aliquat‐336 in methylisobutyl‐ketone (MIBK). We tested the use of the less toxic and less water soluble 3‐heptanone as an organic solvent alternative to MIBK which can be directly analyzed by flame atomic absorption. A series of extraction experiments were conducted to determine if Cd was extracted from standard solutions and from total metal digests of calcareous soils into an Aliquat‐336/3‐heptanone solution, and under what conditions extraction was optimum. In the optimum method, Cd was extracted from aqua regia soil digests by 10% Aliquat‐336 in 3‐heptanone without addition of ascorbic acid or potassium iodide (KI) used by Viets. Excellent recovery of Cd was obtained for both standard reference soils and low Cd highly calcareous soils from North Dakota and Minnesota. Addition of ascorbic acid and KI did not increase the efficiency of extraction indicating that the extraction system used was free of ferric‐iron [Fe(III)] interference. The ion‐association complex of Cd remained stable for at least 24 hr after extraction, providing a very convenient method to analyze low levels of total Cd in soils and other geologic materials.     

Habitat prediction mapping using BioClim model for prioritizing germplasm collection and conservation of an aquatic cash crop ‘makhana’ (Euryale ferox Salisb.) in India

An aquatic cash crop, ‘makhana’ (Euryale ferox Salisb.) was studied for predicted habitat suitability through ‘BioClim’ model for the year 1950–2000 and projected climate data for 2050 and 2070 for the Indian region based on primary data from survey and exploration for germplasm collection by ICAR-National Bureau of Plant Genetic Resources (ICAR-NBPGR), New Delhi, India. A total of 362 diverse ‘makhana’ or foxnut germplasm accessions were augmented mainly from different districts of Indian state of Bihar and conserved at the National Genebank (NGB) at ICAR-NBPGR, New Delhi. Predicted habitat suitability map of climate for the period 1950–2000 showed that the current locations of the highly suitable areas of cultivation of ‘makhana’ in Bihar were extended to other states namely- Jharkhand, Uttar Pradesh and West Bengal in eastern India. Out of the total highly suitable estimated areas, maximum were located in Bihar (65.0 per cent) followed by Uttar Pradesh (12.3 per cent), Jharkhand (12.2 per cent) and West Bengal (10.5 per cent). Based on future predicted climate data for the year 2050 the habitat suitability map indicated that out of the total high suitable areas, Bihar had maximum area as compared to the other three states. Predicted climate data using ‘BioClim’ variables showed that high suitable areas shifted from major part in Jharkhand, Uttar Pradesh and West Bengal and negligible areas bordering Katihar district of Bihar. While predicted climate data for the year 2050 and 2070 showed high suitable areas in West Bengal, especially Malda and Dakschin Dinajpur districts completely shrank due to temperature rise; while Uttar Dinajpur (Goal Pokhar-I, Goal Pokhar-II and Islampur districts) appeared as new areas. In Uttar Pradesh, new districts viz. Balrampur and Shravasti were identified as high suitable areas for ‘makhana’ cultivation. As ‘makhana’ is a popular cash crop of eastern part of the country, and has not been cultivated widely in other regions, hence the knowledge on its botany, distribution, cultivation practices and uses are provided.

     

Identification of the effects of long-term application of nitrogen fertilizer on the availability of 11 elements in soils and their supply to ‘Jonathan’ apple trees by using simultaneous multi-element analysis

Abstract

The objective of this study was to investigate the effects of long-term application of ammoniacal N fertilizer for 43?years on the availability of 10 essential elements (B, N, Mg, K, Ca, Mn, Fe, Ni, Cu, and Zn) and Al in root-zone soils and their supply to ‘Jonathan’ apple trees. To achieve this objective, we used simultaneous multi-element analysis. To estimate the soil depth from which the apple trees took up these elements, we calculated the ratios of their concentrations in the N fertilized plot (N plot) to those in the no N plot (0?N plot) (N/0N ratio). Long-term N fertilization significantly increased the fruit and leaf N/0N ratios of N and Mn and significantly decreased that of K. These ratios in the fruits and leaves were similar to those in the 20–90?cm soil layer. This result suggests that N, K, and Mn in the fruits and leaves were supplied from the 20–90?cm soil layer. The N/0N ratios of all 11 elements in the fruits and leaves were significantly positively correlated with those in the 20–90?cm soil layer, but not in the 0–20?cm soil layer. Our findings indicate that long-term N fertilization altered the tree nutrition of not only N, but also K and Mn. These changes in the tree nutrition were ascribed to the fertilizer-induced changes in the availability of elements in the subsoils.     

Semiquantitative determination of imogolite and Al-rich allophane (Si / Al ≃ 1 : 2) in some volcanic ash soils in San'in region by a combination of thermogravimetry-differential thermal analysis and trimethylsilylation analysis of soil clays

Abstract

A method to determine the contents of imogolite and Al-rich allophane (Sil Al ? 1 : 2) in volcanic ash soils was presented. The method is based on the (1) assessment of the presence of Al-rich allophane in clays by successsive extraction with dithionite-citrate and oxalate-oxalic acid, (2) trimethylsilylation of soil clay with a mixture of hexamethyldisiloxane, HCl, and isopropyl alcohol, and determination of the content of monomeric Si based on the trimethylsilyl derivative of monomeric orthosilicate anion by gas / liquid chromatography, (3) determination of the total content of imogolite and Al-rich allophane based on the content of monomeric Si from imogolite, (4) determination of the imogolite content by Thermogravimetry (TG )-Differential Thermal Analysis (DTA) based on the weight loss due to endothermic dehydroxylation with maximum values at ca. 386°C, (5) calculation of the Al-rich allophane content by subtracting the imogolite content from the total content of these minerals, and (6) evaluation of the imogolite and Al-rich allophane content of soil by multiplying clay content of soil and the two mineral content of clay. The trimethylsilylation analysis was found to be reproducible, and the estimated total amounts of two minerals in clays by this method were adequately approximated to those evaluated from the amount of Si (= Si_o) extracted with oxalate-oxalic acid after extraction with dithionite-citrate. The variation in the abmldance of two minerals in the soil horizons of volcanic ash soils from the San'in region indicated that this method is suitable for the profile-study of volcanic ash soils.