Escape of hydrogen from venus

Recombination of O(2)(+) represents a source of fast oxygen atoms in Venus' exosphere, and subsequent collisions of oxygen atoms with hydrogen atoms lead to escape of about 10(7) hydrogen atoms per square centimeter per second. Escape of deuterium atoms is negligible, and the ratio of deuterium to hydrogen should increase with time. It is suggested that the mass-2 ion observed by Pioneer Venus is D(+), which implies a ratio of deuterium to hydrogen in the contemporary atmosphere of about 10(-2), an initial ratio of 5 x 10(-5) and an original H(2)O abundance not less than 800 grams per square centimeter.     

Amorphous ice: density and reflectivity

Amorphous ice prepared under a wide range of conditions has a density, determined from its buoyancy in liquid oxygen, of 0.94+/-0.02 gram per cubic centimeter, the same as that of ordinary hexagonal ice, with no indication of the glassy superdense ice (2.32 grams per cubic centimeter) reported recently. The diffuse reflectivity shows a small increase as the ice crystallizes at 153 degrees K. This increase is followed by a much larger increase (probably associated with crystal growth) as the sample warms, and the reflectivity reaches a maximum well below the melting temperature. Although the ice deposits appear translucent, the specular reflectivity is low, thus indicating a dull rather than a glassy surface.     

Superdense water ice

A new allotropic form of water ice with a density of 2.32 +/- 0.15 grams per cubic centimeter has been observed at very low pressures and for temperatures lower than 100 degrees K. It is most likely amorphous.     

Lunar surface material: spacecraft measurements of density and strength

The relation of the density of the lunar surface layer to depth is probably best determined from spacecraft measurements of the bearing capacity as a function of depth. A comparison of these values with laboratory measurements of the bearing capacity of low-cohesion particulate materials as a function of the percentage of solid indicates that the bulk density at the lunar surface is about 1.1 grams per cubic centimeter and that it increases nearly linearly to about 1.6 grams per cubic centimeter at a depth of 5 centimeters.     

Surface oxidation: a major sink for water on Mars

Surface oxidation irreversibly removes both oxygen and hydrogen from the martian atmosphere at a rate of 10(8) to 10(11) per square centimeter per second. This rate corresponds to a net loss of 10(25) to 10(28) per square centimeter (10(2) to 10(5) grams per square centimeter) of H(2)O, if it is assumed that the loss rate is uniform over geologic time. Heretofore, exospheric escape was considered to be the principal irreversible sink for H(2)O, but the loss rate was estimated to be only 10(8) per square centimeter per second. It is possible that surface oxidation may have had a minor effect on the supply of H(2)O in the regolith and polar caps.     

Strength-density relations in particulate silicates of complex shape and their possible lunar significance

Some terrestrial particulate silicate rocks with complex particle shapes have internal friction angles over 45 degrees and cohesion of about 0.1 newton per square centimeter at bulk densities of 0.6 to 0.8 gram per cubic centimeter. Mechanical and other properties of the lunar surface layer, observed with spacecraft, may be consistent with a low bulk density and complex reentrant shapes for the fine particles.     

Apollo 12 lunar samples: trace element analysis of a core and the uniformity of the regolith

Four core and soil samples from Apollo 12 are enriched in a number of trace elements of meteoritic origin to virtually the same degree as Apollo 11 soil. An average meteoritic influx rate of about 4 x 10(-9) gram per square centimeter per year thus seems to be valid for the entire moon. A sample from a light gray, coarse-grained layer in the core resembles lunar basalts in composition, but is enriched by factors of 10(4) to 10(5) in bismuth and cadmium.     

Antarctic ice sheet: preliminary results of first core hole to bedrock

The Antarctic ice sheet at Byrd Station has been core-drilled to bedrock; the vertical thickness of the ice is 2164 meters. Liquid water-indicative of pressure melting-was encountered at the bed. Heat flow through the base of the ice sheet is estimated at 1.8 microcalories per square centimeter per second. The minimum temperature was -28.8 degrees C at 800 meters; maximum ice density, 0.9206 at 1000 meters. Core studies reveal the existence of a chemically pure, structurally stratified sheet comprising bubbly ice to 900 meters that transforms to bubble-free deformed ice, with substantially vertically orientated c-axis structure, below 1200 meters. Below 1800 meters the deformed ice structure gives way to large annealed crystals. Several thin layers of dirt between 1300 and 1700 meters are tentatively identified as volcanic ash, and horizontally banded debris, including fragments of granite, is present in the basal ice.     

Quenchable high-pressure polymorph of zinc selenate

A new quenchable high-pressure form of zinc selenate (ZnSeO(4)) was produced by subjecting the low-pressure modification to 40 kilobars at 400 degrees C for 30 minutes. The new form is orthorhombic, space group D(2h),(17)-Cmcm. The cell constants at 29 degrees C are: a, 5.511 angstroms; b, 8.110 angstroms; and c, 6.585 angstroms. The calculated density is 4.70 grams per cubic centimeter in comparison with 4.61 grams per cubic centimeter for the low-pressure modification. This implies a volume change of 2 percent at the transition.     

Atmospheric particulates: specific surface areas and densities

Suspended particulates in Pittsburgh air were collected on glass-fiber filters. The specific surface areas of particulates brushed from the filter surface varied from 1.55 to 4.51 square meters per gram when measured by the Brunauer-Emmett-Teller (BET) method with nitrogen and krypton, after 8-hour degassing of the samples at 25 degrees C. Specific surfaces of the same samples varied from 4.3 to 8.00 square meters per gram after 4-hour degassing at 200 degrees C. Bulk densities and densities of samples were 0.49 to 0.64 and 2.0 to 2.6 grams per cubic centimeter, respectively. These data provide some basis for explanation of unpredictable responses reported after inhalation of mixtures of pollutant gases and particles by animals and man; they should also assist in interpretation of gas-solid phase reactions in the atmosphere.     

Radio science investigations of the saturn system with voyager 1: preliminary results

Voyager 1 radio occultation measurements of Titan's equatorial atmosphere successfully probed to the surface, which is provisionally placed at a radius of 2570 kilometers. Derived scale heights plus other experimental and theoretical results indicate that molecular nitrogen is the predominant atmospheric constituent. The surface pressure and temperature appear to be about 1.6 bars and 93 K, respectively. The main clouds are probably methane ice, although some condensation of nitrogen cannot be ruled out. Solar abundance arguments suggest and the measurements allow large quantities of surface methane near its triple-point temperature, so that the three phases of methane could play roles in the atmosphere and on the surface of Titan similar to those of water on Earth. Radio occultation measurements of Saturn's atmosphere near 75 degrees south latitude reached a maximum pressure of 1.4 bars, where the temperature is about 156 K. The minimum temperature is about 91 K near the 60-millibar pressure level. The measured part of the polar ionosphere of Saturn has a peak electron concentration of 2.3 x 10(4) per cubic centimeter at an altitude of 2500 kilometers above the 1-bar level in the atmosphere, and a plasma scale height at the top of the ionosphere of 560 kilometers. Attenuation of monochromatic radiation at a wavelength of 3.6 centimeters propagating obliquely through Saturn's rings is consistent with traditional values for the normal optical depth of the rings, but the near-forward scattering of this radiation by the rings indicates effective scattering particles with larger than expected diameters of 10, 8, and 2 meters in the A ring, the outer Cassini division, and the C ring, respectively. Preliminary analysis of the radio tracking data yields new values for the masses of Rhea and Titan of 4.4 +/- 0.3 x 10(-6) and 236.64 +/- 0.08 x 10(-6) times the mass of Saturn. Corresponding values for the mean densities of these objects are 1.33 +/- 0.10 and about 1.89 grams per cubic centimeter. The density of Rhea is consistent with a solar-composition mix of anhydrous rock and volatiles, while Titan is apparently enriched in silicates relative to the solar composition.     

Voyager 2 radio science observations of the uranian system: atmosphere, rings, and satellites

Voyager 2 radio occultation measurements of the Uranian atmosphere were obtained between 2 and 7 degrees south latitude. Initial atmospheric temperature profiles extend from pressures of 10 to 900 millibars over a height range of about 100 kilometers. Comparison of radio and infrared results yields mole fractions near the tropopause of 0.85 and 0.15 +/- 0.05 for molecular hydrogen and helium, respectively, if no other components are present; for this composition the tropopause is at about 52 kelvins and 110 millibars. Distinctive features in the signal intensity measurements for pressures above 900 millibars strongly favor model atmospheres that include a cloud deck of methane ice. Modeling of the intensity measurements for the cloud region and below indicates that the cloud base is near 1,300 millibars and 81 kelvins and yields an initial methane mole fraction of about 0.02 for the deep atmosphere. Scintillations in signal intensity indicate small-scale stucture throughout the stratosphere and upper troposphere. As judged from data obtained during occultation ingress, the ionosphere consists of a multilayer structure that includes two distinct layers at 2,000 and 3,500 kilometers above the 100-millibar level and an extended topside that may reach altitudes of 10,000 kilometers or more. Occultation measurements of the nine previously known rings at wavelengths of 3.6 and 13 centimeters show characteristic values of optical depth between about 0.8 and 8; the maxim value occurs in the outer region of the in ring, near its periapsis. Forward-scattered signals from this ring have properties that differ from those of any of Saturn's rings, and they are inconsistent with a discrete scattering object or local (three-dimensional) assemblies of orbiting objects. These signals suggest a new kdnd of planetary ring feature characterized by highly ordered cylindrical substructures of radial scale on the order of meters and azimuthal scale of kilometers or more. From radio data alone the mass of the Uranian system is GM(sys) = 5,794,547- 60 cubic kilometers per square second; from a combination of radio and optical navigation data the mass of Uranus alone is GM(u) = 5,793,939+/- 60 cubic kilometers per square second. From all available Voyager data, induding imaging radii, the mean uncompressed density of the five major satellites is 1.40+/- 0.07 grams per cubic centimeter; this value is consistent with a solar mix of material and apparently rules out a cometary origin of the satellites.     

Jovian Atmosphere: Structure and Composition between the Turbopause and the Mesopause

The occultation of the star Beta Scorpii by Jupiter was observed at high time resolution in three wavelength channels. The results imply a temperature of 220 degrees K at an altitude in the Jovian atmosphere corresponding to 10(14) molecules per cubic centimeter, and temperature fluctuations of 2 degrees to 10 degrees K over vertical scales of 2 to 10 kilometers. They suggest that the vertical eddy diffusion coefficient near the turbopause has a lower limit of 7 x 10(5)K square centimeters per second, and that the turbopause lies above the altitude where the density is 5 x 10(13) molecules per cubic centimeter. Below the turbopause, the ratio of hydrogen to helium is consistent with cosmic abundances.     

Three-dimensional hydrogen microscopy in diamond

A microprobe of protons with an energy of 17 million electron volts is used to quantitatively image three-dimensional hydrogen distributions at a lateral resolution better than 1 micrometer with high sensitivity. Hydrogen images of a <110>-textured undoped polycrystalline diamond film show that most of the hydrogen is located at grain boundaries. The average amount of hydrogen atoms along the grain boundaries is (8.1 +/- 1.5) x 10(14) per square centimeter, corresponding to about a third of a monolayer. The hydrogen content within the grain is below the experimental sensitivity of 1.4 x 10(16) atoms per cubic centimeter (0.08 atomic parts per million). The data prove a low hydrogen content within chemical vapor deposition-grown diamond and the importance of hydrogen at grain boundaries, for example, with respect to electronic properties of polycrystalline diamond.     

Accretion rate of extraterrestrial matter: iridium deposited 33 to 67 million years ago

Iridium measured in 149 samples of a continuous 9-meter section of Pacific abyssal clay covering the time span 33 to 67 million years ago shows a well-defined peak only at the Cretaceous/Tertiary boundary. In the rest of the section iridium ranges from a minimum concentration near 0.35 nanograms per gram in the Paleocene to a maximum near 1.7 in the Eocene; between 63 and 33 million years ago the mean iridium accumulation rate is approximately 13 nanograms per square centimeter per million years. Correction for terrestrial iridium leads to an extraterrestrial flux of9 +/- 3 nanograms of iridium per square centimeter per million years, and an estimated annual global influx of 78 billion grams of chondritic matter, consistent with recent estimates of the influx of dust, meteorites, and crater-producing bodies with masses ranging from 10(-13) to 10(18 )grams. Combining the recent flux of objects ranging in mass from 10(6) to 10(7) grams with the flux of 10(14) - to 10(15) -gram objects indicates that the number of objects is equal to 0.54 divided by the radius (in kilometers) to the 2.1 power. Periodic comet showers should increase the cometary iridium flux by a factor of 200 to 600 on a time scale of 1 to 3 million years; the predicted iridium maxima (more than 30 times background) are not present in the intervals associated with the Cretaceous/Tertiary boundary or the tektiteproducing late Eocene events.     

Ultraviolet spectrometer observations of uranus

Data from solar and stellar occultations of Uranus indicate a temperature of about 750 kelvins in the upper levels of the atmosphere (composed mostly of atomic and molecular hydrogen) and define the distributions of methane and acetylene in the lower levels. The ultraviolet spectrum of the sunlit hemisphere is dominated by emissions from atomic and molecular hydrogen, which are kmown as electroglow emissions. The energy source for these emissions is unknown, but the spectrum implies excitation by low-energy electrons (modeled with a 3-electron-volt Maxwellian energy distribution). The major energy sink for the electrons is dissociation of molecular hydrogen, producing hydrogen atoms at a rate of 10(29) per second. Approximately half the atoms have energies higher than the escape energy. The high temperature of the atmosphere, the small size of Uranus, and the number density of hydrogen atoms in the thermosphere imply an extensive thermal hydrogen corona that reduces the orbital lifetime of ring particles and biases the size distribution toward larger particles. This corona is augmented by the nonthermal hydrogen atoms associated with the electroglow. An aurora near the magnetic pole in the dark hemisphere arises from excitation of molecular hydrogen at the level where its vertical column abundance is about 10(20) per square centimeter with input power comparable to that of the sunlit electroglow (approximately 2x10(11) watts). An initial estimate of the acetylene volume mixing ratio, as judged from measurements of the far ultraviolet albedo, is about 2 x 10(-7) at a vertical column abundance of molecular hydrogen of 10(23) per square centimeter (pressure, approximately 0.3 millibar). Carbon emissions from the Uranian atmosphere were also detected.     

The Inner Core Translational Triplet and the Density Near Earth's Center

Four long records from superconducting gravimeters yield evidence of the triplet of translational oscillations of the solid inner core about its central position. Calculations of core oscillation modes allow identification of the three translational resonances at periods of 3.5820 +/- 0.0008, 3.7677 +/- 0.0006, and 4.015 +/- 0.001 hours by their rotational splitting. Each resonance is defined by approximately 20 successive spectral estimates. A new Earth model brings the computed periods into agreement with observation. It has a central density of 12.960 grams per cubic centimeter, inner core radius of 1221.1 kilometers, and a density jump at the inner core boundary of 0.407 grams per cubic centimeter.     

Mercury: results on mass, radius, ionosphere, and atmosphere from mariner 10 dual-frequency radio signals

Analysis of the radio-tracking data from Mariner 10 yields 6,023,600 +/- 600 for the ratio of the mass of the sun to that of Mercury, in very good agreement with values determined earlier from radar data alone. Occultation measurements yielded values for the radius of Mercury of 2440 +/- 2 and 2438 +/- 2 kilometers at laditudes of 2 degrees N and 68 degrees N, respectively, again in close agreement with the average equatorial radius of 2439 +/- 1 kilometers determined from radar data. The mean density of 5.44 grams per cubic centimeter deduced for Mercury from Mariner 10 data thus virtually coincides with the prior determination. No evidence of either an ionosphere or an atmosphere was found, with the data yielding upper bounds on the electron density of about 1500 and 4000 electrons per cubic centimeter on the dayside and nightside, respectively, and an inferred upper bound on the surface pressure of 10(-8) millibar.     

Anomalous water: attempts at high-pressure synthesis

The high density, 1.4 grams per cubic centimeter, reported for anomalous water suggests that high pressures should be conducive to the formation of anomalous water. Six attempts at 60 kilobars in which water was cooled from about 600 degrees C in nickel or platinum tubes, with or without the presence of silica, did not produce any detectable amounts of anomalous water.     

Aluminum-26 and beryllium-10 in greenland ice

Activities of beryllium-10 and aluminum-26 dissolved in 200-year-old Greenland ice were found to be 18.4 (+ 8.4, - 4.8) x 10(-6) and 3.2 +/- 0.9 x 10(-7) disintegration per minute per liter, respectively. From these values and the precipitation rate (30 milliliters of water per square centimeter per year), the production rates of these isotopes are calculated to be 3.6 (+ 1.6, - 0.9) x 10(-2) and 1.7 +/- 0.5 x 10(-4) atom per second * square centimeter. These rates agree with the rates calculated for the production of these isotopes by cosmic rays in the atmosphere. Probably all the Al(26) in the ice is accounted for by such atmospheric production; however, an upper limit for the influx of cosmic dust bearing aluminum-26 is calculated at 3.2 x 10(5) tons per year for Earth. Only upper limits could be found for Al(26) and Be(10) in the undissolved particulate matter in the ice; their addition to the activities in the dissolved material leaves our conclusions unchanged.