Effectiveness and geomorphological impacts of check dams for soil erosion control in a semiarid Mediterranean catchment: El Cárcavo (Murcia, Spain)

The construction of transverse structures (check dams) is a widely used method in Spanish Mediterranean areas to stabilise gullies and ephemeral streams, to reduce channel incision and to prevent sediment deposition downstream. The effectiveness of check dams and their effects on the morphology of ephemeral channels (ramblas) were investigated in a semiarid, highly degraded catchment. In the study area, 36 dams were surveyed, of which 29 were filled up with sediments, 2 had been destroyed and only 5 had still not completely filled with sediments. The streams above the dams held sediments, which resulted in a decrease in the longitudinal gradient. Field observations of changes in the cross-sectional shape of the stream channel, the composition of channel bed material, and bankfull stage measurements indicated that the dams cause erosion downstream. The amount of sediments stored by the dams was found to be higher than the amount of eroded material in the downstream reaches of the dam.     

The sediment budget of a large river regulated by dams (The lower River Ebro, NE Spain)

Purpose

The aim of this work was to develop a comprehensive fluvial suspended sediment budget for a large regulated river, the lower River Ebro (NE Spain).

Materials and methods

The sediment loads of the Ebro mainstem and its main tributaries were estimated from continuous records of water discharge and turbidity (appropriately transformed to suspended sediment concentrations). Records were obtained at ten monitoring sections during the relatively dry 2008–2011 period.

Results and discussion

The sediment load estimated for the River Ebro upstream of the Mequinenza Reservoir is remarkable (i.e. mean suspended load of 0.6?×?10⁶?t?year^?1), despite the fact that the site is already affected by a sediment deficit due to upstream reservoirs. Further downstream, and owing to their humid characteristics, the contribution of the Pyrenean tributaries (Segre and Cinca Rivers) is much larger compared with their Iberian Massif counterparts (Matarranya and Algars Rivers), with sediment loads of 0.49?×?10⁶ and 2,260 t, respectively. The suspended sediment load trapped in the Mequinenza-Ribarroja-Flix Dam Complex for the study period was estimated at 2.3?×?10⁶?t. Below the dams, the sediment load was reduced by 95 % but increased gradually in a downstream direction due to the erosion processes that clear water (i.e. very low sediment concentrations) flood flows exert on the river bed and banks and the episodic contribution from ephemeral tributaries.

Conclusions

Reservoirs have reduced the overall sediment load and the natural variability of flow and sediment transport in the River Ebro. In addition, the sediment budget revealed that floods were not the only drivers of the sediment dynamics in the lower Ebro. For instance, the particular location of the monitoring sections showed that episodic contributions from small tributaries alter the general sediment load of the river during certain torrential events.     

Differential weathering of granitic stocks and landscape effects in a Mediterranean climate,Southern Iberian Massif (Spain)

Mineralogical and structural features control the weathering processes and landform development of two different crystalline stocks in the Iberian Massif, Spain (the Santa Elena and Linares stocks). The Santa Elena stock shows irregular saprolite profiles and boulder landforms whereas the Linares stock develops broad and plain landscapes with uniform saprolites and less boulder forms. The Santa Elena stock is more closely jointed and fractured than the Linares body. The main secondary minerals are kaolinite, and illite; illite/smectite interstratification was only observed in deep samples from the Linares profile. The Linares profile is feldspar-enriched whereas in Santa Elena plagioclase is almost absent and clay mineral content, especially kaolinite, is higher. Feldspars show dissolution channels developed along cleavage planes filled by clay minerals. Biotite–kaolinite intergrowths have fanned-out textures of epitaxial disposition. Weathered materials are enriched in Al and H₂O and Fe, and depleted in Ca, Na, Mg, Ti, P. The Santa Elena weathered materials are richer in H₂O than those from Linares and have lower Si/Al ratios. Mineralogical and geochemical evidence indicate the Santa Elena materials are more intensely weathered. High fracturation and high Ca-richer plagioclase contents are key factors producing the pervasive Santa Elena stock weathering. Fluvial erosion removed the alteration products in incised tectonically controlled streams resulting in boulder accumulation.     

2000-year environmental history of a karstic lake in the Mediterranean Pre-Pyrenees: the Estanya lakes (Spain)

The sediment record of the Estanya lakes (Pre-Pyrenees, Spain) indicates that this region was intensely affected by land use during the Middle and Modern ages, which contrasts with the present-day poor socioeconomic development of the region. The correlation between sediment and biotic data and well-known historical events suggests a reliable history of environmental changes in this area during the last 2000 years. Changes in lake level were mainly controlled by climatic factors, whereas properties such as lithology, organic carbon, ostracods and pollen content are mainly associated with lake management and land use. Major sedimentological changes resulted from the use of the lake for hemp retting at the start of the XIVth century. Subsequent depopulation of the area in the XXth century led to the progressive recovery of the lacustrine ecosystem.     

Soil Erosion and the Efficiency of the Conservation Measures in Mediterranean Hillslope Farming (SE Spain)

Eurasian Soil Science - The rainfed mountain plantations in semiarid areas of the Mediterranean region with conventional practices register soil erosion values much higher than soil formation...     

Cyclic influences on the heavy metal chronology in a Central Mediterranean area (Palermo Gulf,Italy)

Purpose  

The evaluation of long-term heavy metal concentrations in the Gulf of Palermo (Italy) has been carried out in order to investigate how changes of pollution levels in the last 50 years can be reflected in marine sediments. Measurements of Cr, Cu, Hg, Pb, and Zn concentrations were performed on dated fractions of a sediment core. Time series analysis has allowed to obtain information on the chronology of the heavy metal pollution of the area and to identify seasonal components and trends.     

Dry Deposition to the Forest Canopy and Surrogate Surfaces in Two Mediterranean Holm Oak Forests in Montseny (NE Spain)

The fluxes recovered from washing branches and surrogatesurfaces were compared for two holm oak (Quercus ilex L.)forests in the Montseny mountains (NE Spain) differentiallyexposed to pollution. For 5 periods in May and June 1996 afterexposures ranging between 68–189 hr, 6 metacrylate plates and 8branches were extracted with distilled water. Also, a sequentialwashing of branches was undertaken, with 5 min separationsbetween the 3 initial washes, one hour between the 3rd and the4th, and 6 hr between the 4th and the last one. The compositionwas analysed for PO₄ ^3-, SO₄ ^2-,NO₃ ^-, Cl, F, NH₄ ⁺,Ca²⁺, Mg²⁺, Na⁺, K⁺, Cu, Pb, Mn, Co, Ni and Zn. The applied techniques were consistent in that dry deposition would accountfor the throughfall fluxes of NO₃ ^-, Cl^-,Cu and Zn. Potassium and Mn would derive mostly from leaching and their fluxes were strongly related with the holm oak flower growth. ForMg²⁺ and SO₄ ^2- either leaching or impaction of small particles or gases (for SO₄ ^2-) could account forthe recovered fluxes. Also for Na⁺ and Ca²⁺ the experiments did not produce conclusive results. Ammonium, F, Pb,Co, and Na were under the detection limit of analyticaltechniques in the plate-wash. The exposed site presented higherleaf-wash and plate-wash fluxes for all elements. This wasattributed to its higher exposure to pollutants, and forleaching-derived elements, to its higher site fertility.     

Assessment of biogeochemical trends in soil organic matter sequestration in Mediterranean calcimorphic mountain soils (Almería, Southern Spain)

Total soil organic matter levels and humic acid formation processes in mountain calcimorphic soils from Sierra María-Los Vélez Natural Park (Almería, Southern Spain) were found to differ depending on soil use (pine and oak forests, and cleared areas either cultivated or affected by bush encroachment). Biogeochemical indicators such as the concentration of exchangeable cations, or the concentration of the different types of humic substances were neither influenced by the type of vegetation nor soil use. In fact, multidimensional scaling and multiple correlations suggest that soil carbon sequestration processes are controlled by small-scale topographical features and their impact on water holding capacity. From a qualitative viewpoint, there were two more or less defined sets of soils: one set consisted of soils with humic acids with marked aliphatic character, displayed intense 2920 cm⁻¹ infrared band, and had low optical density. The resolution-enhanced infrared spectra suggested typical lignin patterns and well-defined amide bands, which point to a selective preservation of comparatively young organic matter. This situation contrasts with that in other set of soils with low C levels (<20 g kg⁻¹) where humic acids with featureless infrared spectra showed high aromaticity and were associated with perylenequinonic chromophors of fungal origin: this is considered the consequence of overlapping biogeochemical mechanisms involving both microbial synthesis and condensation processes. The results from visible and infrared derivative spectroscopies suggest that the reliability of statistically assessing the biogeochemical performance of the different uses on the site studied in terms of the intensity of the prevailing humic acid formation mechanisms, i.e., accumulation of inherited macromolecular substances in the former set, vs. microbial synthesis including the condensation of precursors of low molecular weight substances in the latter.     

The effects of soil moisture variability on the vegetation pattern in Mediterranean abandoned fields (Southern Spain)

The demographic pressure decrease in Southern Spanish Mediterranean mountainous areas in the mid twentieth century led to the abandonment of agriculture and rupture in the geo-ecosystem balance which had existed until then. Since then, different phases of recovery have been put into action to return the landscape to its earlier natural condition according to climate and soil degradation state after the abandon. In Mediterranean climatic conditions (between subhumid and semi-arid regimes), degraded soil recovery has followed different tendencies rendering the landscape in heterogenic and complex one. This heterogeneity has manifested in the vegetation pattern of abandoned fields. In this paper, we analyze the state of three abandoned fields situated under different Mediterranean climatic conditions from the recovery point of view by means of monitoring the effects of spatial and temporal variability of soil moisture in the vegetation pattern over a period of two years sampling (Nov. 2002–Nov. 2004). The results showed that: i) more annual rainfall volume did not guarantee success in the biological recovery of the system due to the influence of other factors such as the degradation state of the soil post-abandonment or the steep slope gradient; ii) soil moisture variability tended to play a more important role in affecting vegetal cover in semi-arid conditions; and iii) in dry climatic conditions the system demonstrated greater signs of recovery (greater biodiversity).     

Frequency–magnitude relationships for precipitation,stream flow and sediment load events in a small Mediterranean basin (Vallcebre basin,Eastern Pyrenees)

Precipitation, discharge and suspended sediment concentrations were continuously measured during 10 years (1995–2004), at the Ca l'Isard sub-basin (1.32 km²) of the Vallcebre experimental catchments. Daily precipitation record is 22 years long. When the ranks of the events obtained with the diverse variables considered (precipitation depth, peak discharge, runoff depth, suspended sediment concentration and sediment load) were compared, the results confirmed the complexity of the response of the catchment and demonstrated that precipitation is an irregular criterion for ranking the main sediment transporting events. When the partial duration series corresponding to the 10% major events were analysed, daily precipitation, peak discharge and sediment concentration series showed good fits with log-normal distributions, but event precipitation, runoff and sediment load series needed bi-modal log-normal distributions. This behaviour may be attributed to the fact that event mass magnitudes depend not only on event intensity but also on its duration.     

Fluxes and storage of fine-grained sediment and associated contaminants in the Na Borges River (Mallorca,Spain)

Samples of suspended and fine channel bed sediment were used to examine the spatial and temporal variability in the amount of fine-grained sediment and associated contaminants temporarily stored in the Na Borges River (319 km²) in Mallorca and the relationship of such channel storage to the fluxes of fine sediment and associated contaminant through the system. This Mediterranean groundwater-dominated river drains a predominantly agricultural catchment, although urbanisation during the twentieth century has changed the catchment hydrology. A re-suspension technique was used to obtain estimates of channel storage at monthly intervals during the 2004–2005 hydrological year at eight locations along the main stem of the stream (i.e. 26 km). The estimates of fine sediment storage ranged between 0 and 13,000 g m^− 2, with a mean value of 2400 g m^− 2. Only Cu exceeded the critical threshold (36 μg g^− 1), established by existing guidelines for the contaminant content of fluvial sediment. The results demonstrated significant spatial and temporal variability, in response to the influence of urban point sources, agricultural practises, seasonal groundwater interactions and the first-flush effect. The amount of fine sediment entering storage during the study period was 515.2 t, representing the net increase in storage over the study period. As a result, the mean specific storage was 21 t km^− 1. Suspended-sediment load and temporary fine sediment storage are the two basic components of the channel sediment budget that interact to determine sediment transport through a channel system, and they can therefore be used to compute the total input of sediment and associated contaminants to the system. Accordingly, storage values were compared with estimates of suspended sediment load and associated contaminant load values at three measuring stations along the river. During the study period, storage in the main channel system represented 87% of the sediment input and 68% of the contaminant input, indicating that deposition was more important than transport. The low gradient of the main channel and the low return period (i.e. 0–2.5 years) of the flood events that occurred during the study period meant that remobilised bed sediment and associated contaminants were redeposited downstream rather than being flushed to the catchment outlet as suspended sediment. Furthermore, the river bed is dry during the summer months, allowing sealing and crusting processes to stabilise the sediment deposited during the wet season and thereby reduce its availability for remobilisation at the beginning of the next wet season. Together, these factors promote sediment deposition and storage, with the result that sediment progressively accumulate over several hydrological years until a major flood event (i.e. return period ≈ 5 years) evacuates the stored sediment.     

The fate of arsenic in soils adjacent to an old mine site (Bustarviejo,Spain): mobility and transfer to native flora

Background, aim, and scope  

The mobility of arsenic in soils and its transfer to other environmental components present significant environmental risks. The management of polluted land is determined by the availability, mobility, and transfer of inorganic pollutants to different ecosystem compartments. In this paper, the fate of arsenic at this mining site has been evaluated to determine future management practises to minimise such risk.     

Development of a soil degradation assessment tool for organic olive groves in southern Spain

Forty-six organic olive orchards under different soil management systems were evaluated in the province of Córdoba (southern Spain) to assess the state of their soil properties and the degree of degradation of their topsoil, and the possibilities for monitoring any soil degradation risk. Our study indicated that 55% of the olive farms sampled (OF) presented a low soil degradation, in which most of their deficiencies were a low content in some soil nutrients such as P, which may be partly due to the moderate fertility of some soils in the area. This result could be explained by the low or moderate intensity of the farming systems used in a large part of the study area. Seven percent of the sampled OFs had a large number of physical, chemical and biological soil properties, that could be considered as being degraded, and these olive orchards were classified as seriously degraded. The remaining OFs were in an intermediate state. The degree of soil degradation was not correlated with any specific soil management method or with predicted soil erosion rates, suggesting that it was the result of specific and varied on-farm conditions difficult to detect without a field evaluation. Three soil degradation indexes were obtained through a principal component analysis of the soil properties analyzed. These indexes were able to distinguish between OFs with low soil degradation and those in a serious state of degradation. Two of the indexes are basically integrative ones that can be used in relatively large surveys considering a large number of soil properties. The third index developed used only three soil properties, organic C, water stable macroaggregates, and extractable P, and has the potential to be used as a relatively easy and inexpensive screening test of soil degradation for organic olive farms in the area.     

Conservation of isolated Atlantic heathlands in the Mediterranean region: effects of land-use changes in the Montseny biosphere reserve (Spain)

In the Mediterranean region, cycles of controlled burning combined with continuous grazing appear to have been an effective tool for maintaining isolated Calluna vulgaris heathlands in the form in which they occur in many places in the Atlantic region. Changes in land use and management of the mosaic of extensively exploited heathland and associated grassland over recent decades, such as bringing land into cultivation followed by its abandonment and the prohibition of fires has resulted in a process of transformation into new shrub communities with lower biodiversity. In the Mediterranean region, these changes are similar to those described in the Atlantic area, but encroachment occurs faster and could lead ultimately to afforestation by Mediterranean woodland.In a study area of 300 ha of heathland in the Spanish Mediterranean basin (specifically, in the Montseny Natural Park and Biosphere Reserve), comparison of present and former vegetation showed that shrub cover increased from 15% in 1967 to 32% in 2000. Broom (Cytisus scoparius) was the main invasive species in abandoned crop fields, whereas Mediterranean holm oak forest (Quercus ilex) increased by 18%. The surface area of fernlands doubled and C. vulgaris heathlands decreased from 35% to just 9% during the same period. Intermixed grasslands also decreased moderately and progressively from 4% to 3%.It seems probable that cycles of fires are more important in terms of shrub control and biodiversity conservation than continuous grazing alone, even at a high rate of stocking (four small ruminants per hectare per year). This encroachment process throws into relief the role that isolated habitats can play as a monitor of land use changes.     

Conflicting outcomes of an integrated approach to sediment quality assessment in a Sardinian coastal area subjected to mining activities

Journal of Soils and Sediments - Multidisciplinary research was carried out to verify the best approach for a reliable assessment of sediment quality in marine areas affected by strong metal...     

Pedological and geomorphological cycles in a catena of Galicia (NW Spain)

A catena developed on gabbro in Galicia, N.W. Spain, was studied. The methods utilized, consisting of macro- and microscopic mineralogical and morphological observation, allowed the identification of different features produced by the action of pedological and geomorphological processes. The application of Butler's K cycle concept allows a relative sequence of events to be established in which pedogenetic processes are integrated within the general framework of the evolutionary history of the slope. Five K cycles could be recognized, beginning with a phase of deep weathering and ending with the present phase of incipient soil formation. In between feature a.o. phases of solifluxion, the formation of an argillic horizon and the development of a stoneline.     

Mineralogical variability in weathering microsystems of a granitic outcrop of Galicia (Spain)

Several products of weathering have been studied in a granitic outcrop in Galicia (N.W. Spain). Alteration took place under a humid temperate climate. The various materials and the microsystems in which they occur are: (1) fissures containing gibbsite and/or 1:1 sheet silicates of varying degrees of crystallinity, (2) fissures containing 2:1 sheet silicates of beidellite type, (3) encrustations of siliceous material showing varying degrees of structural order, with or without organic matter, and (4) encrustations of non-crystalline matter composed chiefly of Al, P and Si.The results demonstrate the importance of considering the different microsystems which contribute to the formation of secondary products in a given weathering system.     

Soils of a dune coastal salt marsh system in relation to groundwater level,micro-topography and vegetation under a semiarid Mediterranean climate in SE Spain

Twenty-one soil profiles were described, analysed and classified in a salt marsh dune system in SE Spain. Sites for sampling were selected according to micro-topographical positions and vegetation types. The pedons showed an A–C type profile. Most of the profiles at summit positions had a microbiotical crust in the upper centimetres, formed by fungal mycelia that contribute to agglutination of sand particles. In two soils, a buried Ab horizon could be identified. Soils at inter-dune depressions showed redoximorphic features with diffuse boundaries, therefore indicating the actual activity of the oxidation–reduction processes. The presence of remains of Posidonia oceanica buried in many of the profiles indicates both a progressive regression of the shoreline and the accretion of the dune system. Sand grains were the most abundant size fraction (generally higher than 65%). Salinity strongly increased at the depressions, with Cl⁻, SO₄²⁻, Na⁺ and Mg²⁺ being the most abundant ions. The microtopographical position at the dune had more influence on the vegetation cover and the soil type than did the distance to the shoreline. Most of the profiles at summit sites were colonised by trees (Pinus halepensis and Juniperus phoenicea subsp. turbinata), shrubs (Pistacea lentiscus, Rhamnus lycioides), thyme-brushwoods (Crucianella maritima, Teucrium dunense) or grasses (Ammophila arenaria), and they were classified as Arenosols or Torripsammens. The slopes of the depressions were dominated by Schoenus nigricans, living on Gleysols or Halaquepts and Aquisalids, or Limonium cossonianum, living on Solonchaks or Aquisalids. Juncus maritimus occupied footslope or bottom positions of the depressions, growing on Solonchaks or Aquisalids and Gleysols or Halaquepts. The succulent halophytes Arthrocnemum macrostachyum and Sarcocornia fruticosa were typical species at bottom positions, living on Solonchaks and Fluvisols or Aquisalids. In two of the profiles at interdune depressions a petrocalcic horizon appeared.     

Road-deposited sediment, soil and precipitation (RDS) in Bratislava, Slovakia: compositional and spatial assessment of contamination

Background, aim and scope  The urban environment in Bratislava is, in association with rapid urbanisation and industrialisation, significantly influenced by several potential sources of pollution, including automobile exhaust and industry emmissions. Urban road-deposited sediments contain many potentially toxic elements such as Pb, Cr, Cu, Zn and also Fe at concentrations much higher than in soil. In this study, the chemical composition and spatial variability of road-deposited sediments in urban area of Bratislava were assessed for the elements As, Cd, Cr, Cu, Hg, Ni, Pb, Fe and Mn. Additional evaluation of archive data for soil, snow and atmospheric dust was undertaken to provide an integrated view on urban environment contamination. Materials and methods  Urban road-deposited sediments (RDS) were collected during summer 2003 and 2004 mainly from major city crossroads. RDS samples were analysed for total metal content, pseudo-total metal content (HNO₃ digestion) and by a sequential extraction method, grain fraction composition and mineralogical composition (X-ray analysis). Metal concentrations in soil and snow samples from urban and non urban city area were compared. Results and discussion  The highest concentrations for all metals were found in the finest RDS fraction (<0.125 mm). Whilst in the fraction <1 mm mean concentrations of Cr, Cu and Pb reached 55.2, 143.8 and 34.4 mg kg⁻¹, respectively, for the fraction <0.125 mm, markedly higher contents of these elements were documented at the level of 86.8, 218.4 and 63.1 mg kg⁻¹, respectively. The soil contents of potentially toxic risk elements in the urban area including As, Cr, Cu, Fe, Hg, Mn, Ni, Pb and Zn were higher than in the non-urban area (except for Cd with similar contents). This distribution pattern of evaluated chemicals in urban and non-urban area is more evident in the case of winter precipitation (snow). The snow concentrations of As, Cr, Cu, Fe, Mn, Pb and Zn in the urban area were two tot five times higher than in non-urban area. Conclusions and recommendations  Monitoring of road-deposited sediments, dust, soil and precipitation has confirmed the significant contamination of the urban environment in Bratislava with potentially toxic elements that can pose a threat for the health of its residents. Future works should be based on analyses of temporal variability of RDS and analyses of organic matter content.     

Leaching and efficiency of six organic zinc fertilizers applied to navy bean crop grown in a weakly acidic soil of Spain

Zinc contamination of groundwater from fertilizers applied to pulse crops is a potential problem, but the use of different types of organic chelates can minimize the contamination potential while still adequately feeding the crops. The objective of this study was to compare the leaching, distribution in fractions and availability, and relative effectiveness of Zn from six organic Zn fertilizers (zinc-ethylenediaminetetraacetate- N-2-hydroxyethylethylenediaminetriacetate (Zn-EDTA-HEDTA), Zn-HEDTA, zinc- S, S'-ethylenediaminedisuccinate (Zn- S, S-EDDS), zinc-polyhydroxyphenylcarboxylate, Zn-EDTA, and zinc-ethylenediaminedi(2-hydroxy-5-sulfophenylacetate) (Zn-EDDHSA)) applied to a navy bean ( Phaseolus vulgaris, L.) crop cultivated by applying different Zn levels, in a weakly acidic soil under greenhouse conditions. Zinc soil behavior was evaluated by diethylenetriaminepentaacetic acid-triethanolamine (DTPA-TEA), DTPA-ammonium bicarbonate (DTPA-AB), Mehlich-3, and BaCl 2 extractions and sequential fractionation. In all the fertilizer treatments, the percentage of labile Zn that remained in the soil was high with respect to the quantity of Zn applied, with values respectively ranging from 42 to 80% for Zn-EDDHSA and Zn-EDTA sources. A positive correlation with a high level of significance existed between the micronutrient concentration in the navy bean crop (total and soluble) and labile Zn fractions, available Zn, and easily leachable Zn ( r ranged from 0.89 to 0.95, P < 0.0001). The relatively high quantity of total Zn leached by applying Zn-EDTA and Zn-S,S-EDDS sources (11.9 and 6.0%, respectively, for the rate 10 mg of Zn kg(-1) of soil) poses a potential pollution risk for neighboring waters. It would seem recommendable to apply Zn-HEDTA or Zn-EDDHSA sources, even applied at the low rate (5 mg of Zn kg(-1) of soil), because they produced available Zn concentrations in the soil that were above the critical concentration and also produced high Zn concentrations in plants (139 and 106 mg of Zn kg(-1) of dry matter, respectively).