再生混凝土抗碳化性能试验研究及理论分析

通过快速碳化试验,以再生骨料掺量、水灰比、水泥用量、原始混凝土强度和矿物掺合料为影响因素,对再生混凝土的碳化性能进行研究。试验结果表明：再生混凝土的碳化深度随水灰比、再生骨料掺量的增加而减小,随原始混凝土强度的增大和水泥用量的增加而增大,适量添加矿物掺和料能降低再生混凝土的碳化深度,提升其抗碳化性能。在已有的普通混凝土碳化模型研究基础上,结合本试验和中国其他学者的试验数据,建立了再生混凝土碳化深度预测模型,模型预测结果与试验值吻合较好。     

Effects of Cement Additives on Properties of CSA Cement from MSWI

Municipal solid waste incineration fly ash (MSWI) was successfully used as raw material in sintering and preparing a calcium sulphoaluminate (CSA) cement clinker in laboratory. The effects of different types and different addition percentages of cement additives on compressive strength and hydration properties were investigated. The results showed that lime (LI) powder / slag (SL) powder was compatible in CSA cement system while the activities of fly ash(FA)/ MSWI was low. Adding these four types of cement additives in CSA cement system respectively, there were negative effects on compressive strengths of hardened cement at early age while LI/SL improved the compressive strength at later age. The performance of combined additives was better, especially, the specimens with 10%LI+10%SL, 10%LI+10%MSWI, and 5%LI+15%SL.     

STUDY ON THE LOW TEMPERATURE CALCINATION AND THE BEHAVIOUR OF STEEL SLAG COLOUR CLINKER CEMENT

The colourcd clinker cement which fired directly from kiln has the advantages of low cost,bright colour and good colour durability.This paper studies the possibility of using calcium flouridc and gypsum combined mineralizer to calcine the col-outed clindcr cement at low temperature.Different methods such as X-ray diffraction ana ysis,scanning electron microscopy,infrared spectra analysis,combined water content chemical asysis,compressive strength test and so on arc used to study the clinder minerals,the colour,the physical and mechanics properties and behaviour of the coloured clinker cement which made both with high quality raw materials and with electric furnace reduced slag additive.     

A Primary Investigation on Concrete Made from Iron and Steel Slags for Building Ecological Artifical Reefs

A method of orthogonal test was used to optimize the strength of the cementitious material for preparing the concrete of high-strength artifical reefs.The results show that with the ratio of iron slag:steel slag=7:1,and when 10% cement clinker and 10% gypsum of Flue Gas Desulfurization Waste (FGDW) was mixed with 80% iron and steel slags powder,the mixed cementitious material had an optimized strength.The optimized specific surface area are 480 m 2/kg and 550 m 2/kg for iron slag and steel slag powder respectively.The ordinary portland cement can be totally substituted by such a mixed cementitious material with iron and steel slags as its major components in preparing the concrete for building high-strength artificial reefs.A concrete with a compressive strengh over 65MPa can be prepared by using such a mixture as a cementitious material and steel slag grains as its fine and coarse aggregats which have been stubilized by a hot-simmering method. Hydration processes of net slurry were analysized by XRD and SEM methods. The results show that the hydration products in the system are mainly AFt and C-S-H gel. The results also show that the pozzolanic reaction of iron slags could be largely promoted by the coordinations of steel slags,clinker and FGDW.     

Technology of Mixing High Property Concrete with Large Dosage Fly Ash

Being the largest mass of man-maded material, concrete demands much to resource and energy as well as affects much to environment. Whether concrete can be the dominating constructive material, the key is whether it can become green material and protect the environment at the same time. The important approach of developing is using industrial castoff largely in concrete. The tests note, that high performance concrete used of large mass of fly ash is doable. By grinding fly ash and adding high-efficient water reducer, when the dosage of cement clinker is only 25% and the dosage of fly ash is 70%, concrete with a good workability that 3 day and 28 day strength are bigger than 20 MPa and 50 MPa respectively can be achieved, which later strength develop very well. The large mass of fly ash concrete can utilize fly ash largely and reduce the dosage of clinker, that is very advantageous to protect environmental.     

Strength-permeability Model of Pervious Cement Concrete

High permeability is an important characteristic of pervious concrete. For the existing permeability testing devices of pervious concrete, the specimen sidewall leakage is serious due to the large numbers of open pores on the surface of specimens. To solve the problem, a new permeability testing method for pervious concrete was developed and a composite sidewall structure with waterproof daub, flexible rubber cushion and rigid sleeve sidewall was proposed. Meanwhile, the strength and permeability of pervious cement concrete are incompatible with a reciprocal relationship. However, limited research has been conducted on the relationship between them. Effects of water-cement ratio (W/C), aggregate-cement ratio and porosity on the properties of pervious concrete, including strength and permeability, were studied. Furthermore, strength-porosity model, permeability-porosity model and strength-permeability model were established. Tests reveal that: a) There is an optimum W/C of pervious concrete, at which strength reaches the maximum; b) The relationship between the strength and W/C shows a downward quadratic curve, and the permeability is proportional to porosity and aggregate-cement ratio; c) The relationship between strength and permeability of pervious cement concrete can be well fitted with the Lorentzian function, and the strength decreases when the permeability increases, but the rate of reduction decreases gradually. The optimum combination of strength and permeability should be determined based on the specific engineering requirements in design.     

A Study on Alkali_Aggregate Reaction of Alkali_Clinker_Slag Cement Concrete

AAR expansion ratios of alkali_clinker_slag(ACS)cement mortars are studied by mortar bar test.The influences of the sort of alkalis and the content of clinker on AAR expansion ratio of ACS cement mortars are analysed.On the basis of above mentioned,the mechanism of AAR in ACS cement system is discussed.     

Fabrication and Formation Mechanism of FoamedIron Slag-Steel Slag Concrete

In order to achieve the comprehensive utilization of iron slag and steel slag, foamed concrete were prepared by adding small amount of gypsum, lime and clinker in steel slag-iron slag system and using aluminum powder as foaming agent,. The three-day, seven-day and twenty-eight-day bulk density and compressive strength of foamed concrete with the different ratio of the main raw materials were researched. Furthermore, in order to research the hydration mechanism and microstructure of foamed concrete, the XRD and SEM images of the three productions of foamed concrete were analyzed. The results showed that the coordination of the dosage of steel slag and iron slag was better when the former was 30% and the latter was 45%, Meanwhile, the compressive strength was 5.1 MPa, the bulk density was 625 kg/m 3; Ettringite and C-S-H gel synergies generated in steel slag-iron slag system. Besides, hydration activity of steel slag was obviously lower than that of iron slag.     

Influence of Fine Recycled Aggregate on Physical and Mechanical Properties of Concrete

Based on a series of recycle process, waste concrete can be made into fine recycled aggregate which can be used completely or partly to compound concrete as a substitute for natural sand. But the special properties of fine recycled aggregate make the performance of concrete with fine recycled aggregate different from normal concrete. Characteristics of fine recycled aggregate and its influence on physical and mechanical properties of concrete are studied. On this basis, the influence of fine recycled aggregate on gas permeation properties, chloride permeability, and carbonation resistance of concrete are also studied. It is found that fine recycled aggregate produces a lot of defects in crushing preparation. And the compressive strength, the chloride permeability and the carbonation resistance of the concrete with fine recycled aggregate as substitution show difference from that of normal concrete.     

土壤固化酶在中国的应用及研究进展

土壤固化酶于二十世纪八十年代逐渐应用于筑路、筑堤、筑坝、垃圾填埋处理、基础加固等领域,中国自1995年将土壤固化酶应用于道路建设以来,取得了一些经验和成效,但也存在一些问题。该文概述了土壤固化酶在中国的应用及研究进展;分析了其所具有的环保价值、可产生经济效益,以及土壤固化酶在中国推广应用过程中出现的一些问题;通过土壤固化酶与石灰、水泥等传统固化材料对土的无侧限抗压强度影响的试验研究,说明土壤固化酶有利于土体稳定的特性;为进一步研究和发展该技术提供依据     

AFLP data suggest a potential role for the low genetic diversity of acid lime (Citrus aurantifolia Swingle) in Oman in the outbreak of witches’ broom disease of lime

Acid lime (Citrus aurantifolia) is the fourth largest fruit crop in terms of cultivated area and production in Oman. However, over half a million lime trees were lost in Oman over the past 35?years due to witches?? broom disease of lime (WBDL) which is caused by Candidatus phytoplasma aurantifolia. This study was conducted to examine genetic diversity of acid lime in Oman. AFLP analysis of 143 acid lime samples from Oman, 2 from Brazil and one from Pakistan using 4 primer pair combinations produced 980 polymorphic loci (100?%) and 146 AFLP genotypes. Despite the long history of acid lime cultivation in Oman, populations of lime from different districts were found to have low levels of genetic diversity (0.0888?C0.2284). AMOVA analysis indicated the existence of high level of genetic differentiation (F _ST?=?0.271) among populations of acid lime from Oman and Brazil, which indicates that both populations have evolved independently for a considerably long period of time. On the other hand, AMOVA analysis showed that only 11?% of the genetic variation exists among populations from the 18 different districts in Oman. This suggests frequent exchange of acid lime planting material across geographical regions in Oman. Findings from this study suggest that the low level of genetic diversity of acid lime in Oman and frequent movement of acid lime planting material across districts are two main factors which contributed to the rapid spread and high susceptibility of acid limes to WBDL in the country.     

Rubber Powder Modified Frost Resistance of Recycled Aggregate Concrete

Utilizing relative dynamic elastic modulus and weight loss of concrete as evaluation indices, the frost resistance of concrete with 0.45 water-cement ratio and different recycled aggregate replacement proportions was studied in the water and 3.5% sodium chloride solution. The mass proportions of recycled aggregate are 25%, 50% and 75%, respectively. Furthermore, the frost resistance of the modified concrete with 5% and 10% rubber powder volume fractions replacing fine aggregates was studied. The results show that: the frost resistance of concrete decreases with the increase of recycled aggregate, when the recycled aggregate mass fractions are 25% and 50%, its influence on the frost resistance of concrete is little, and mixing rubber powders can effectively improve the frost resistance of concrete; when the recycled aggregate mass fraction reaches 75%, its effect on the frost resistance of concrete is significant, and mixing rubber powders has certain improvement effect, but compared with the benchmark group of concrete the maximum freeze-thaw cycles decreases more than 30%. In water frozen test, the weight loss is small and the relative dynamic elastic modulus loss is quite obvious. The frost resistance is better when adding 5% volume fraction of rubber powders. In salt frozen test, the main characteristic is the weight loss exceeds the requirements. The frost resistance is better when adding 10% volume fraction of rubber powders. The improvement effect of rubber powder to the frost resistance of concrete in salt solution is much better than that in water.     

某蓄电池厂铅污染土壤稳定化修复工程药剂筛选研究

依据某蓄电池厂土壤铅污染的基本情况,在修复工程实施前,开展了稳定化固化药剂的筛选试验。在试验过程中采用了石灰、水泥、磷酸二氢钠、磷酸二氢铵、磷酸二氢钙、磷酸氢钙、磷酸三钙、磷酸、磷肥等9 种药剂,分别进行了铅污染土壤稳定化试验。针对低浓度污染土壤,采用10%石灰、20%石灰、10%水泥、20%的水泥、10%的磷酸二氢钙、10%磷酸三钙、20%磷酸三钙、10%磷酸二氢铵、20%磷酸二氢铵和20%的磷酸可以达到修复目标。针对高浓度污染土壤,当添加20%的水泥、20%的磷酸氢钙、10%磷酸三钙、20%磷酸三钙、10%磷酸二氢铵、20%磷酸二氢铵、10%磷酸和20%磷酸可以达到修复目标。从修复成本考虑,建议采用水泥作为稳定化药剂,低浓度污染土壤的添加量为10%,高浓度污染土壤的添加量为20%。     

Strength and Microstructure of Sulphoaluminate Cement Containing Ultra- Fine CaCO3

The existence of ettringite in sulphoaluminate cement hardened paste is mainly in the form of pole-like crystal,which causes unfavorable effect on the cement.In this paper the strength and microstructure of the sulphoaluminate cement containing ultra-fine CaCO_3 weze discussed.Experimet results show that the strength of sulphoaluminate cement was obviously improved by adding 3% of ultra-fine CaCO_3.After curing for 28d,the compressive strength of cement paste and mortar is 100.6MPa and 94.1MPa respectively,and the bending strength of the mortar reached 12.5MPa.SEM study on hardened paste of sulphoaluminate cement containing ultra-fine CaCO_3 showed that its structure was dense and homogeneous,there was hardly any massive crystall detected.     

LITHOLOGICAL CHARACTERS OF CARVED SANDSTONE IN DAZU

The carved sandstone of Dazu county in Sichuan is a stratum under the Pen-laizhen group of late Jurassic. This sandstone is similar to seme typical character of arkcoe in compo-sition and structure of the corrosive cementation. The weathered damage of the carved stone art hasa relation to degenerative after-change process of sandstone.     

Properties of Cemented Copper Tailings Backfill with Steel Slag-Blast Furnace Slag-Fluorgypsum-Based Cementation Material

Cement is a traditional tailings cementation material, which causing the high tailings backfill cost. However, the utilization rate of industrial waste residue, such as steel slag and fluorgypsum, is low. So the steel slag-blast furnace slag-fluorgypsum-based cementation materials preparation with industrial waste residue substitutes for cement. As a result, its cementation tailings performances must be studied. According to mortar fluidity and bleeding quantity of tailing cementation slurry at different time and compressive strength change trend at different hydration ages, the performance of steel slag-blast furnace slag-fluorgypsum-based cementation materials is significantly better than P·O42.5 grade cement and two kinds of commonly used cementation agents in China. After soaking for three days, the pH value of these tailings solidification bodies leaching liquid is less than 9.0, which is much lower than the pH values of three kinds of high alkaline tailings cementation materials mentioned before. Leaching liquid fluorine ion concentration is extremely low. With less impact on environment. SEM analysis also show that these tailings solidification bodies mixing with the steel slag-blast furnace slag-fluorgypsum-based cementation materials have relatively dense microstructure.     

AC Impedance Study of the Interface between Cement Paste and Crushed Stone

The method of AC impedance spectroscopy has been applied to study the properties of interface between cement paste and crushed stone. The effect of interface between cement paste and crushed stone can be determined by comparison of three parameters in AC impedance spectroscopy.     

Regeneration and characterization of somatic hybrid plants of Citrus sinensis (sweet orange) and Citrus micrantha, a progenitor species of lime

Most commercial citrus fruit species and cultivars are inter- and intra-specific hybrids. Conventional hybridization in citrus is largely handicapped by apomixis and long juvenility. As an alternative, somatic hybridization via protoplast fusion has been employed to create novel citrus germplasm. Witches' broom disease of lime (WBDL) emerged in Oman during the 1970s, which has been spreading to the neighboring countries. The disease is extremely destructive. A possible solution to the WBDL problem is to develop resistant hybrids. Resistance is available among the citrus relatives of lime i.e., sweet orange. Somatic hybrids combining sweet orange with lime have been produced but the fruit characteristics are different from lime. Herein, we report the development of somatic hybrids between a progenitor of lime (Citrus micrantha) and sweet orange (Citrus sinensis) in efforts to recreate a lime-like fruit using sweet orange as a donor of disease resistance gene(s). Successful somatic hybridization was verified by ploidy analyses using flow cytometry and RAPD analyses. This is the first report of using a progenitor species in somatic hybridization experiments in efforts to resynthesize an improved lime.     

Micro structure Characteristics of Recycled Fine Aggregate and Its Concrete

The characteristics of recycled fine aggregate (RFA) and its concrete (RFAC) were analyzed by SEM, EDXA, XRD, Micro harness and nitrogen absorption. The results show that RFA is an artificial aggregate with complex compositions, certain hydration activity and high permeability. The mineral compositions of RFA include SiO2, CaCO3 and a small quantity of C2S, which has a certain hydration activity and can form hydration productions. The compaction rate of cement paste in RFAC is low because of pores in it. There is obvious interfacial transition zone (ITZ) between RFAC and cement paste, and its width is bigger than that in ordinary concrete. In addition, the values of micro hardness of the interfacial transition zone on both sides of RFA and cement paste are lower. The porous structure of the recycled fine aggregates and defects of ITZ are main reasons for big pores in RFAC, which has bad effect on impermeability of RFAC.     

The Influence on the Strength of Cement Mortars by Emulsified Epoxy

The influence on the strength of cement mortars by adding emulsified epoxy is studied, and epoxy resin polymer cement mortars with excellent performances are made up through modifying ordinary Portland cement with emulsified epoxy and micro-fine slag. The microstructure of the epoxy resin polymer cement materials are studied and their action and mechanism are discussed by means of modern detection measures such as SEM, XRD. The experimental results indicate cement mortars modifying emulsified epoxy and micro-fine slag have higher compressive strength and flexible strength. The series effects of water-reducing, density, pozzolanicity, filling and solidification cross linking through the action together of epoxy organism and micro-fine slag can endow cement-based materials with perfect mechanic performance. The main hydration products in the system are C-S-H gel and micro-crystal hydrated calcium aluminate. When epoxy resin is solidified, the organism is network. No Ca(OH) 2 has been found.