Nitrate leaching and pasture yields following the application of dairy shed effluent or ammonium fertilizer under spray or flood irrigation: results of a lysimeter study

Abstract. Nitrate leaching and pasture ( Lolium perenne / Trifolium repens ) yields were measured on monolith lysimeters (80 cm diam. × 120 cm depth) of a Templeton sandy loam soil (Udic Ustochrept), following repeated applications of dairy shed effluent (DSE) or ammonium fertilizer (NH₄Cl), under spray (50 mm/month) or flood (100 mm/month) irrigation. Applications of DSE at 400 kg N/ha per annum resulted in significantly less nitrate leaching (8–25 kg N/ha per yr) compared with NH₄Cl (28–48kg N/ha per yr) ( P < 0.01). Over the two year period, the total mineral N (predominantly nitrate) leached was equivalent to 2.5–3.7% of the total N applied in the DSE and 8.7–9.8% of the N applied in the NH₄Cl. There was a trend of slightly less nitrate leaching under the flood irrigation than under the spray irrigation, probably because of the greater potential for denitrification under the wetter conditions. Average nitrate concentrations in the leachate were generally below the drinking water standard except in the NH₄Cl treatment under spray irrigation where it averaged 10 mg NO₃-N/l over the two year period. DSE was equally as effective as NH₄Cl in stimulating pasture dry matter production. Annual nitrogen uptakes were similar for the DSE (343 kg N/ha) and NH₄Cl (332–344kg N/ha) treatments in the first year but were higher in the DSE (361–412 kg N/ha) than in the NH₄Cl (324–340 kg N/ha) treatments in the second year. Pasture uptakes of phosphorus and sulphur were also higher in the DSE than in the NH₄Cl treatments in the second year. The results emphasize the need to set different regulatory limits for land application of organic wastes of various types and for N fertilizers.     

The spatial variability of soil nitrates in arable and pasture landscapes: implications for the development of geographical information system models of nitrate leaching

Abstract. In response to the European Community Nitrate Directive (91/676) a catchment scale Geographical Information System (GIS) model of nitrate leaching has been developed to map nitrate vulnerability and predict average weekly fluxes of nitrate from agricultural land units to surface water. This paper presents a pilot study which investigated the spatial variability of soil nitrates in order to: (1) define an appropriate pixel size for modelling N leaching; (2) quantify the within-unit variability of soil nitrate concentrations for pasture and arable fields; and (3) assist in the design of an efficient sampling strategy for estimating mean nitrate concentrations. Soil samples, taken from two 800 m transects in early September 1994, were analysed for water soluble nitrate. The arable soils had a mean nitrate-nitrogen concentration of 0.693 μg/g (S.E. 0.054 μg/g) and the pasture soils had a higher mean nitrate-nitrogen concentration of 0.86 μg/g (S.E. 0.085 μg/g). Spatial variability was investigated using variograms. The pasture data had a weak spatial relationship, whereas the arable data exhibited a strong spatial relationship which fitted a spherical variogram model (r² 0.87), with a range of 40 m. A pixel size of 40 m is suggested for nitrate modelling within the GIS based on the arable variogram and an improved sampling strategy for model validation is suggested, involving bulking sub-samples over a 40 m grid for estimating mean nitrate concentrations in combined land use and soil units.     

Nitrate leaching losses under Miscanthus grass planted on a silty clay loam soil

Abstract. Nitrate leaching under newly planted Miscanthus grass was measured for three years. The crop received either no fertilizer-N or an annual spring application of 60 kg or 120 kg N ha^-1. During three winters soil water was collected from porous cup probes installed 90 cm deep. Nitrate leaching was calculated from the mean drain flow recorded in two drain gauges multiplied by the mean nitrate-N concentration in the soil water solutions collected. In the first year soil water nitrate concentrations were high on all treatments and N losses were 154, 187 and 228 kg ha^-1 respectively on the unfertilized treatment and those that received 60 or 120 kg N ha^-1. Leaching losses in the second and third years were, in turn, 8, 24 and 87 kg ha^-1 and 3, 11 and 30 kg ha^-1 for the unfertilized treatment and for the 60 and 120 kg N ha^-1 treatments respectively. Leaching losses were closer to those recorded under extensively managed grassland than arable land. The large losses in the first year were probably due to the previous agricultural management at the site and excessive inputs of N on the fertilized plots. In the second and third year, lower drainage volumes may also have influenced losses. The results show that Miscanthus , once established, can lead to low levels of nitrate leaching and improved groundwater quality compared with growing arable crops.     

Nitrate leaching from a small catchment in central England

Abstract. Flow and nitrate concentrations were measured weekly for four years at twelve stream-water monitoring sites in a catchment in the English Midlands designated as a Nitrate Advisory Area. Farm surveys and satellite images have provided soil and land use information. Measurements show the nitrate load to be dominated by discharge, with large variability due to differing weather conditions from year to year. Within-year variability in nitrate concentrations is also related to weather conditions, with high concentrations when field capacity is reached if this occurs late in the year. There is also clear evidence of dilution of nitrate during intense storms. The effect of changing weather conditions makes it impossible to identify catchment-scale changes in leaching due to changes in agricultural practice over a period as short as four years. Measurements from a major spring in the catchment show an increasing trend in nitrate concentrations through the period. There is some evidence that the greatest N leaching to streams in the catchment is associated with intensive grassland on soils which are naturally poorly drained.     

Progress in studies of nitrate leaching from grassland soils

Abstract. The large input of research effort on aspects of nitrate leaching over the last two decades has produced many innovative scientific and practical results. The MAFF Nitrate Programme has enabled considerable progress to be made in unravelling much of the complexity of the grassland nitrogen (N) cycle, and identifying gaps as essential first stages in providing improved managements for N in grassland systems. From a practical standpoint, there have been key outputs which have allowed the identification of options for policy, and which should allow grassland farmers to increase the efficiency of N use throughout their farming system and thereby improve the sustainability of their enterprises. As well as quantifying N transformations, transfers and losses, other important outcomes have been the development of user-friendly models of N cycling (NCYCLE and variants) and an easy to use field kit to determine mineral N in pasture soils. The use of modelling to produce fertilizer recommendations with a Decision Support System and of new approaches developed within the Programme, in particular system synthesis desk studies, and 'farmlet' investigations to determine the consequences of modifying N flows and losses, have allowed us to produce solutions to satisfy the dual aims of meeting environmental and economic production targets.     

Nitrate leaching from the Broadbalk Wheat Experiment, Rothamsted, UK, as influenced by fertilizer and manure inputs and the weather

Abstract. Nitrate leaching was measured over the eight drainage seasons spanning the nine years from 1990–1998 on the 157‐year old Broadbalk Experiment at Rothamsted, UK. The weather pattern of two dry, three wet and three dry years was the dominant factor controlling nitrogen (N) loss. Both the concentration of nitrate in the drainage waters and the amount of N leached increased with the amount of N applied, mostly because of long‐term, differential increases in soil organic matter and mineralization. On average, losses of N by leaching were 30 kg ha^?1yr^?1 when no more than the optimum N application was applied and were typical of amounts leached from arable land in the UK. Losses increased significantly in both amounts and as the percentage of N applied for supra‐optimal applications of N and from autumn‐applied farmyard manure (FYM). Extra spring‐applied fertilizer was very effective at increasing yields on plots given FYM in the autumn but at the expense of leaching losses three times those from optimum fertilizer N applications. Losses increased after potatoes because they left significant amounts of mineral N in the soil, and decreased after forage maize because it used applied N more effectively. Losses measured 120 years ago from identical treatments were 74% greater than current losses because of today's larger yields and more efficient varieties and management practices. Average concentrations of nitrate in drainage waters did not exceed the EU limit of 11.3 mg NO₃‐N l^?1 until supra‐optimal amounts of N fertilizer (>150–200 kg ha^?1yr^?1) were applied in spring or FYM was applied in autumn. However some drainage waters from all plots, even those that have not received fertilizer for >150 years, exceeded the limit when rain followed a dry summer and autumn. Nitrate leaching into waters will remain a problem for profitable arable farming in the drier parts of Eastern England and Europe despite increased N use efficiency.     

Nitrate leaching from short-rotation coppice

In the UK, short‐rotation coppice (SRC) is expected to become a significant source of ‘bio‐energy’ over the next few years. Thus, it is important to establish how nitrate leaching losses compare with conventional arable cropping, especially if SRC is grown in Nitrate Vulnerable Zones. Nitrate leaching was measured using porous ceramic cups in each of the three phases in the lifespan of SRC, establishment, harvest and removal and was compared with conventional arable cropping. Nitrogen concentrations were increased in drainage water as soon as the crop cover was destroyed to plant the SRC (peak 70 mg L^?1 nitrate‐N) and increased further (peak 134 mg L^?1 nitrate‐N) on cultivation. Once the coppice crop was established, concentrations returned to a smaller level (average 18 mg L^?1 nitrate‐N). Concentrations were not affected by the harvesting operation, and annual applications of nitrogen (40, 60 and 100 kg ha^?1 N in the first, second and third years, respectively) had little effect. By contrast, concentrations in the arable rotation showed a regular pattern of increase in the autumn, and the average peak value over the 4 years was 54 mg L^?1 nitrate‐N. When the SRC was ‘grubbed up’ and roots removed, the soil disturbance resulted in a flush of mineralization which, combined with a lack of crop cover, led to increased nitrate‐N in leachate (peak 67 mg L^?1 nitrate‐N). In a normal life‐span of SRC (15–30 years), the relatively large nitrate losses on establishment and at final grubbing up would be offset by small losses during the productive harvest phase, especially when compared with results under the arable rotation.     

Nitrate leaching loss following application of organic manures to sandy soils in arable cropping.

Abstract. Experiments were set up at two sites to measure nitrogen (N) leaching loss from applications of separated pig/cattle slurry and cattle farmyard manure(FYM), during winters 1990/91–1993/94 (site A) and from broiler litter and FYM, during winters 1990/91–1992/93 (site B). The manures were applied at a target rate of 200 kg ha^-1 total N during the autumn and winter to overwinter fallow or top dressed onto winter rye. The total N in leachate was calculated from leachate N concentrations, in samples collected using ceramic cups buried at 90 cm, and an estimate of drainage volume. Nitrogen losses were greatest following manure applications in September, October and November but losses following applications in December or January were not significantly elevated above those from untreated controls. Losses were consistently lower from FYM than from broiler litter or separated slurry. The presence of a cover crop (winter rye) significantly reduced overall N leaching compared with the fallow, but only reduced the manure N leaching losses at one site during one winter when a high proportion of drainage occurred late. The incorporation of a nitrification inhibitor (DCD) with manures applied in October did not significantly reduce the manure N leaching.     

Nitrate leaching in an organic dairy/crop rotationas affected by organic manure type, livestock densityand crop

Abstract. In dairy farming systems the risk of nitrate leaching is increased by mixed rotations (pasture/arable) and the use of organic manure. We investigated the effect of four organic farming systems with different livestock densities and different types of organic manure on crop yields, nitrate leaching and N balance in an organic dairy/crop rotation (barley–grass-clover–grass-clover–barley/pea–winter wheat–fodder beet) from 1994 to 1998. Nitrate concentrations in soil water extracted by ceramic suction cups ranged from below 1 mg NO₃-N l^?1 in 1^st year grass-clover to 20–50 mg NO₃-N l^?1 in the winter following barley/pea and winter wheat. Peaks of high nitrate concentrations were observed in 2^nd year grass-clover, probably due to urination by grazing cattle. Nitrate leaching was affected by climatic conditions (drainage volume), livestock density and time since ploughing in of grass-clover. No difference in nitrate leaching was observed between the use of slurry alone and farmyard manure from deep litter housing in combination with slurry. Increasing the total-N input to the rotation by 40 kg N ha^?1 year^?1 (from 0.9 to 1.4 livestock units ha^?1) only increased leaching by 6 kg NO₃-N ha^?1. Nitrate leaching was highest in the second winter (after winter wheat) following ploughing in of the grass-clover (61 kg NO₃-N ha^?1). Leaching losses were lowest in 1^st year grass-clover (20 kg NO₃-N ha^?1). Averaged over the four years, nitrate concentration in drainage water was 57 mg l^?1. Minimizing leaching losses requires improved utilization of organic N accumulated in grazed grass-clover pastures. The N balance for the crop rotation as a whole indicated that accumulation of N in soil organic matter in the fields of these systems was small.     

Nitrate leaching from organic farms and conventional farms following best practice

Abstract. This paper compares nitrate leaching losses from organic farms, which depended on legumes for their nitrogen inputs (66 site years) with those from conventional farms using fertilizers under similar cropping and climatic conditions (188 site years). The conventional farms were within Nitrate Sensitive Areas in England, but sites following special practices associated with that scheme were excluded. Nitrate losses during the organic ley phase (including the winter of ploughing out) were similar (45 kg N ha^–1) to those from conventional long-term grass receiving fertilizer N inputs of less than 200 kg N ha^–1 (44 kg N ha^–1) and from the grass phase of conventional ley-arable rotations (50 kg N ha^–1). Losses from conventional grass receiving higher N inputs were greater than from organic or less intensive grass. Nitrate losses following arable crops averaged 47 and 58 kg N ha^–1 for the organic and conventional systems respectively, with part of the difference being due to the greater proportion of non-cereal break crops in the latter. Thus under similar cropping, losses from organic systems are similar to or slightly smaller than those from conventional farms following best practice.     

Investigating preferential flow in a large intact soil block under pasture

Abstract. A large soil block was constructed to determine the importance of preferential flow routes compared with matric flow pathways at a pasture site in mid-Devon. The sandy loam soil was well structured and uniform. The soil block measured 5 m×3 m×1 m and was instrumented with an array of 54 tensiometers, TDR wave guides and suction samplers connected to an in situ chloride analysis system. Four steady state irrigation experiments were conducted with a range of rainfall intensities. During each experiment chloride and nitrate tracers were applied and the patterns of movement were observed. Although the application of tracer was uniform and the soil was relatively homogeneous, there was large variability across the block in terms of time taken to reach the peak concentration (TPC) and the peak concentration itself. About 44 samplers operated at the greatest intensities (10–2 mm h⁻¹) and only 35 at the smallest (1 mm h⁻¹). No relationship was found between TPC and depth. The fastest TPC and largest concentrations were associated with the greatest rainfall intensities. Relative importance of the individual water pathways was a function of soil heterogeneity: parts of the soil block were highly active with several pathways having short TPCs and conductivities in excess of 4 m day⁻¹ whereas other areas had longer TPCs and conductivities of 1–2 m day⁻¹. The pattern was also dynamic, with conductivities of the pathways changing through time, though most of the faster pathways maintained their greater conductivities for more than one year.     

Comparison of type and depth of lysimeter for measuring the leaching losses of nitrogen under urine patches

Abstract. A study of the leaching losses of nitrate under urine patches in irrigated and non-irrigated dairy pastures in the South East of South Australia was undertaken with repacked and monolith lysimeters 1 m deep, and with monolith lysimeters 150, 300 and 450 mm deep. The aim was to quantify differences in measurements of drainage and nitrogen fluxes for these different lysimeters. Drainage of water and N flux were found to vary significantly between types and depths of lysimeters. Drainage volumes in repacked lysimeters were 78% and 33% more than in monolith lysimeters in irrigated and non-irrigated paddocks, and N fluxes were 5 and 3 times higher in repacked lysimeters respectively. The results indicate that lysimeter estimates of recharge rates and N fluxes to water tables are best determined by leaching studies which are longer term, and use deep monolith lysimeters. Shorter term studies and the use of shallow or repacked lysimeters have potential to distort conclusions.     

Effects of the 1995–1997 drought on nitrate leaching in lowland England

Abstract. The effect of drought between summer 1995 and 1997 on stream and river nitrate concentrations was investigated using sites close to the long-running meteorological station in Oxford, UK. Nitrate concentrations in the River Windrush were relatively low during the drought, but after it had ended reached the highest level since records began in 1973. The low concentrations during the drought probably reflect a reduced contribution from agricultural runoff. High nitrate concentrations were found in a field drain at Wytham Environmental Change Network site during and after the drought, but discharge was greatly reduced. A woodland stream at Wytham had much lower nitrate concentrations than the field drain but these similarly increased during and after the drought. There was evidence that both a concentrating effect of low water volumes and enhanced soil nitrogen mineralization and nitrification rates were causing concentrations to rise. The effects of mineralization and nitrification were more important in woodland than agricultural land. Nitrate load over the course of a year was determined largely by discharge, but steeper gradients for the relationship between cumulative load and cumulative discharge were seen during and after the drought than before, reflecting the higher concentrations.     

The effectiveness of cover crops during eight years of a UK sandland rotation

Abstract. Growing cover crops during the winter before spring-planted crops is often suggested as an effective method to decrease nitrate leaching. A four-course crop rotation (potatoes-cereal-sugarbeet-cereal) was followed through two rotations on a sandy soil in the English Midlands. Three management systems were imposed on the rotation to test their effects on nitrate loss. The effects of cover crops on nitrate leaching and crop yields were compared with the more conventional practice of over-winter bare fallow before potatoes and sugarbeet.
Cover crop N uptake was variable between years, averaging 25 kg ha⁻¹, which is typical of their performance on sandy soils in the UK. The cover crops usually decreased nitrate leaching but their effectiveness depended on good establishment before the start of drainage. Over 7 years, cover crops decreased the average N concentration in the drainage from 24 to 11 mg l⁻¹. Potato yield and tuber N offtake increased after cover crops. Ware tuber yield increased by an average of c . 8%; this was unlikely to be due to additional N mineralization from the cover crop because the potatoes received 220–250 kg fertilizer N ha⁻¹, and non-N effects are therefore implicated. Sugar yield was not increased following a cover crop.
After 8 years of nitrate-retentive practices, there were no measurable differences in soil organic matter. However, plots that had received only half of the N fertilizer each year contained, on average, 0.14% less organic matter at the end of the experiment.     

夏季休闲期不同年限日光温室土壤硝态氮淋溶状况

连续2 a（2006和2007年）研究了夏季休闲前后陕西杨凌示范区13个日光温室0～200 cm土壤剖面氮素的动态变化,以评价夏季休闲期间日光温室栽培下土壤累积硝态氮的淋溶情况。结果表明：日光温室蔬菜收获后不同年限温室0～200 cm土壤剖面累积了大量的硝态氮,2006和2007年不同年限日光温室土壤剖面硝态氮的平均残留量分别为 667.6和781.8 kg/hm2。休闲近2个月后,休闲期间降雨量低的2006年（65 mm）不同温室土壤硝态氮含量及电导率与休闲前相比明显增加;而降雨量高的2007年（214 mm）,土壤剖面残留的硝态氮及电导率显著降低,说明发生硝态氮的淋溶,13个日光温室0～200 cm 土壤剖面硝态氮较夏季休闲前降低量在223.8～658.0 kg/hm2之间,平均为298.5 kg/hm2。不同年限日光温室0～200 cm 土壤剖面硝态氮降低量相比,1998年温室＞2004年温室＞2002年温室,其中1998年的温室土壤剖面硝态氮降低量平均达355.1 kg/hm2。可见,夏季休闲期间的降雨量是影响日光温室栽培土壤累积大量硝态氮发生淋溶损失的主要因素。     

Effect of nitrogen inputs to cereals on nitrate leaching from sandy soils

Abstract. The effect of nitrogen fertilizer inputs to cereal crops on nitrate leaching after harvest was tested on 21 experiments on sandy soils in England. At small nitrogen fertilizer rates leaching increased very little with increasing inputs, while at high rates more than half of any additional nitrogen could be accounted for as increase in nitrate leached. In many cases the response fitted two straight lines. Nitrogen offtake in grain also fitted two straight lines, with a form which complemented the leaching response. The gradient averaged 0.52 kg N in grain for every additional 1kg N applied below the break point, but only 0.05 kg/kg above. The break points were generally close to or above the economic optimum N input. The effect of inputs on leaching could he quantitatively related to nitrogen offtake in grain, assuming a constant ratio of nitrogen in grain to total nitrogen uptake. The results show that fields receiving N inputs in excess of the economic optimum cause a disproportionately large nitrate loss. However because of uncertainty in predicting the break point in advance, modest further reduction in leaching will occur by reducing inputs to somewhat below the expected economic optimum.     

Control of nitrate leaching from a Nitrate Vulnerable Zone using paper mill waste

Abstract. The effects on nitrate leaching of incorporation of paper mill waste at three cultivation depths in fields previously cropped to iceberg lettuce and calabrese are reported. In the lettuce experiment, incorporation of 40 t DM paper mill waste/ha resulted in a decrease in N leaching (measured with suction cups) from 177 to 94 kg/ha (S.E._d= 23). Deep ploughing with and without paper waste increased N leaching from 105 kg/ha (normal ploughing or surface incorporation) to 172 kg/ha (S. E. _d= 27). Measurements of nitrate leaching using deep soil cores showed a less clear cut effect. Nitrous oxide (N₂O) emissions were very high immediately after paper waste was ploughed in to a depth of 35 cm. Non–significant increases in biomass N content were measured in the spring following paper waste application. There was no significant reduction in plant N uptake in subsequent crops. Removal of above–ground crop residues did not have a significant effect on nitrate leaching or N₂O losses. In the calabrese experiment, application of 40 t DM paper mill waste/ha followed by summer cropping with iceberg lettuce caused a decrease in N leaching (measured using deep soil cores) from 227 to 152 kg/ha (S. E._d= 22, mean of all cultivation treatments).     

Nitrate leaching and adsorption in a Kenyan Nitisol

Abstract. ¹⁵N labelled NH₄NO₃ (fertilizer N) was applied at a rate of 50 kg N ha^–1 to an Ando-Humic Nitisol and two maize crops grown on it. About 20 months later, soil cores were taken to a depth of 2.5 m. Leached fertilizer N was found between 1.4 m and 1.8 m deep and was delayed relative to net drainage by between 4.2 and 4.9 pore volumes. Anion exchange capacity (AEC) increased ten-fold down the profile, up to 2.9 cmol_ckg^–1. The delay to fertilizer N leaching was predicted to be between 4.1 and 5.3 pore volumes when calculated from the AEC and from an equation relating delay due to AEC in laboratory columns of repacked soil obtained by Wong et al. (1990b). It was concluded that the nitrate leaching delay equation was also valid in undisturbed field profiles. Two concentration maxima for mineral N were found, which did not usually coincide with the fertilizer N and were thought to result from mineralization of soil organic matter and plant residues at the end of each season. The delay equation overestimated their leaching delay but the results were considered close enough to support the hypothesis for their formation.     

华北平原水浇玉米-小麦轮作农田硝态氮的淋失

Soil water deep drainage and nitrate (NO3^-) leaching losses below the root zone were investigated in a 1 ha wheatmaize rotation field under traditional agricultural management that local farmers generally follow in the North China Plain, using the soil water balance method and NO3-N concentration in suction samples. Water drainage, and NO3-N distribution and leaching losses exhibited pronounced spatial and temporal variability. Soil water deep drainage and NO3- N leaching loss mostly occurred during the summer maize growing season (rainy season), which coincided with irrigations and significant rainfall. On average, soil water deep drainage was 39 and 90 mm in the 1998/1999 and 1999/2000 cropping years, correspondingly, accounting for 10% and 19% of the total irrigation plus rainfall, respectively. The NO3-N leaching loss from soil and fertilizer N below the root zone ranged from 6 to 17 (averaging 12) and 30 to 84 (averaging 61) kg N ha^-1 in 1998/1999 and 1999/2000, correspondingly, equivalent to 1.4%-4.1% and 7.3%-20.3% of N fertilizer applied,respectively. The results indicated that water and fertilizer inputs could be greatly reduced, thus improving water and nutrient use efficiency in this region.