Gas diffusivity in soils compared to ideal isotropic porous media

Evidence of anisotropy is reported for advective air and water permeabilities in soils. Thus, anisotropy is likely to exist also for diffusive gas fluxes. Information about direction‐dependent soil gas diffusivity is scarce and most modeling approaches assume isotropy. At hundreds of closely lying positions in a compacted and adjacent undisturbed forest soil, gas diffusivity (D_s/D₀) was measured either in vertical or horizontal direction. The volume‐independent diffusion efficiency (i.e., diffusivity divided by air‐filled porosity) was fitted by a generalized additive model (GAM). Significant regressors were air‐filled porosity (?), soil depth, and the discrete diffusion direction. The model yields in all cases higher vertical diffusion efficiencies. The compaction factor did not yield a significant regressor of its own, i.e., the reduction of diffusivity in the compacted soil was the same as in low‐porosity samples of the undisturbed profile. To elucidate the role of sharing vertically and horizontally orientated pore space and a potential competition between diffusivity in different spatial directions, simple geometric models consisting of 3‐dimensionally crossed pores have been parameterized. These models provided a good explanation of the typical nonlinear D_s/D₀(?) relationship. By simple one‐parameter correction (linear or power function), this mechanistic model could be fitted to the data. The one‐parameter correction of the geometric model could be a straightforward approach to consider direction dependence of measured diffusivities. However, by applying this approach to the observations the anisotropy effect was not clearly evident, which could be attributed to a changing D_s/D₀(?) relationship with depth. As a reason for the preference of the vertical gas diffusion the dominance of vertical stresses and the activity of anecic earthworms are discussed. Direction dependency of gas diffusivity seems to be a basic feature of natural pore systems and has to be considered for modeling gas fluxes in soils. Generally, a preferential vertical diffusion direction reduces horizontal balancing and increases the heterogeneity of gas concentrations in the soil air.     

Vulnerability of Bavarian silty loam soil to compaction under heavy wheel traffic: impacts of tillage method and soil water content

Soil compaction caused by traffic of heavy vehicles and machinery has become a problem of world-wide concern. The aims of this study were to evaluate and compare the changes in bulk density, soil strength, porosity, saturated hydraulic conductivity and air permeability during sugar beet (Beta vulgaris L.) harvesting on a typical Bavarian soil (Regosol) as well as to assess the most appropriate variable factors that fit with the effective controlling of subsequent compaction. The field experiments, measurements and laboratory testing were carried out in Freising, Germany. Two tillage systems (conventional plough tillage and reduced chisel tillage) were used in the experiments. The soil water contents were adjusted to 0.17 g g⁻¹ (w₁), 0.27 g g⁻¹ (w₂) and 0.35 g g⁻¹ (w₃).Taking the increase in bulk density, the decrease in air permeability and reduction of wide coarse pore size porosity (−6 kPa) into account, it seems that CT (ploughing to a depth of 0.25 m followed by two passes of rotary harrow to a depth 0.05 m) of plots were compacted to a depth of at least 0.25 m and at most 0.40 m in high soil water (w₃) conditions. The trends were similar for “CT w₁” (low soil water content) plots. However, it seems that “CT w₁” plots were less affected than “CT w₃” plots with regard to bulk density increases under partial load. In contrast, diminishments of wide coarse pores (−6 kPa) and narrow (tight) coarse pores (−30 kPa) were significantly higher in “CT w₁” plots down to 0.4 m. Among CT plots, the best physical properties were obtained at medium soil water (w₂) content. No significant increase in bulk density and no significant decrease in coarse pore size porosity and total porosity below 0.2 m were observed at medium soil water content. The soil water content seemed to be the most decisive factor.It is likely that, CS (chiselling to a depth of 0.13 m followed by two passes of rotary harrow to a depth 0.05 m) plots were less affected by traffic treatments than CT plots. Considering the proportion of coarse pore size porosity (structural porosity) and total porosity, no compaction effects below 0.3 m were found. Medium soil water content (w₂) provides better soil conditions after traffic with regard to wide coarse pore size porosity (−6 kPa), air permeability (at 6 and 30 kPa water suction), total porosity and bulk density. Proportion of wide coarse pores, air permeability and bulk density seems to be suitable parameters to detect soil compaction under the conditions tested.     

ROTHAMSTED STUDIES OF SOIL STRUCTURE IV.

Porosity and gas diffusion have been measured within dry crumbs sieved from the horizons of one soil from each of the Hanslope, Ragdale, Evesham, Denchworth, Flint and Salop series. Crumb porosities, ?c, ranged from 0.19 to 0.33, dimensionless gas diffusivities, D_c/D₀, from 0.015 to 0.098, and the effectiveness of unit pore space for diffusion, given by α_c= (D_c/D₀)/?_c, from 0.06 to 0.29. Values of ?_c and D_c/D₀ were used to calculate complexity factors k_c for the crumb pores. The results are discussed in terms of soil texture, pore size, ease of soil management, and the frequency and intensity of wetting and drying of the soil in each horizon. None of the results suggests why the soils of the Ragdale, Denchworth and Salop series should be more difficult to manage than the others.     

Evaluation of gas diffusivity models for no-tilled and tilled volcanic ash soils

Accurate quantification of soil gas diffusion is essential to understand the gas transport mechanism in soils, especially for soil greenhouse gas emissions. To date, the performance of soil gas diffusivity (D_p/D₀, where D_p is the soil gas diffusion coefficient and D₀ is the diffusion coefficient in free air) models has seldom been evaluated for no-tilled and tilled volcanic ash soils. In the present study, six commonly used models were evaluated for volcanic ash soils under two treatments by comparing the predicted and measured soil gas diffusivities at water potentials of pF 1.3–3. The Buckingham-Burdine-Campbell (BBC), soil-water-characteristic-dependent (SWC-dependent), and two-region extended Archie’s Law (2EAL) models showed better performance for both no-tilled and tilled volcanic ash soils, which is likely because porosity and pore size parameters of bimodal soils were taken into consideration in these models. Since the BBC model showed better accuracy than the SWC-dependent and 2EAL models and required fewer, more easily measurable parameters, this study recommends the BBC model for predicting soil gas diffusivity of volcanic ash soil under different tillage managements. In future studies, the BBC model should be further tested at water potentials of pF > 3, and may be improved by including the parameters of pore continuity and saturation.     

Compaction effects on CO2 and N2O production during drying and rewetting of soil

The effects of compaction on soil porosity and soil water relations are likely to influence substrate availability and microbial activity under fluctuating soil moisture conditions. We conducted a short laboratory incubation to investigate the effects of soil compaction on substrate availability and biogenic gas (CO₂ and N₂O) production during the drying and rewetting of a fine-loamy soil. Prior to initiating the drying and wetting treatments, CO₂ production (−10 kPa soil water content) from uncompacted soil was 2.3 times that of compacted soil and corresponded with higher concentrations of microbial biomass C (MBC) and dissolved organic C (DOC). In contrast, N₂O production was 67 times higher in compacted than uncompacted soil at field capacity. Soil aeration rather than substrate availability (e.g. NO₃⁻ and DOC) appeared to be the most important factor affecting N₂O production during this phase. The drying of compacted soil resulted in an initial increase in CO₂ production and a nearly two-fold higher average rate of C mineralization at maximum dryness (owing to a higher water-filled pore space [WFPS]) compared to uncompacted soil. During the drying phase, N₂O production was markedly reduced (by 93-96%) in both soils, though total N₂O production remained slightly higher in compacted than uncompacted soil. The increase in CO₂ production during the first 24 h following rewetting of dry soil was about 2.5 times higher in uncompacted soil and corresponded with a much greater release of DOC than in compacted soil. MBC appeared to be the source of the DOC released from uncompacted soil but not from compacted soil. The production of N₂O during the first 24 h following rewetting of dry soil was nearly 20 times higher in compacted than uncompacted soil. Our results suggest that N₂O production from compacted soil was primarily the result of denitrification, which was limited by substrates (especially NO₃⁻) made available during drying and rewetting and occurred rapidly after the onset of anoxic conditions during the rewetting phase. In contrast, N₂O production from uncompacted soil appeared to be primarily the product of nitrification that was largely associated with an accumulation of NO₃⁻ following rewetting of dry soil. Irrespective of compaction, the response to drying and rewetting was greater for N₂O production than for CO₂ production.     

Compaction and tillage depth combinations for water management and rice production in low-retentive permeable soils

Excessive percolation loss and low water retention adversely affect the production of rice in coarse-textured lateritic soils. A tillage scheme has been developed from long-term field experimentation during 1973–1978 to measurably reduce the percolation losses and enhance the productivity of rice in this soil under both lowland and upland conditions. Artificially compacted surface and subsurface layers were induced in soil by suitably combining level of compaction as obtained by one (D₁), two (D₂), four (D₃) or six (D₄) passes of a 800 kg iron roller at a load intensity of 0.21 kg cm⁻² and post-compaction tillage or puddling depth of o cm (T₀), 5 cm (T₁), 10 cm (T₂) or 15 cm (T₃). An additional no-compaction treatment (D₀) was included in lowland experiments. where the effect of either the depht or intensity of puddling was also studied. The utility of this tillage scheme in increasing the efficiency of nitrogen fertilizer use was characterized by a separate upland experiment in 1976 with a lower rate (60 kg N ha⁻¹) of N application than that (100 kg N ha⁻¹) applied in all other experiments.Rice yield was significantly increased on upland by artificially compacting the soil to D₂. However, with further compaction to D₃ and D₄, the yield decreased. When postcompaction tillage was adopted, the grain yield decreased at low compaction level (D₁, D₂) but increased at high compaction level (D₃, D₄) with increase in tillage depth from 0 to 15 cm. The maximum grain yield occurred at D₃T₁.Higher grain yield at D₃T₁, D₂T₀ and D₄T₂ is attributable to a more favourable soil bulk density profile, a lower infiltration rate and higher surface retention of water. The efficiency of applied nitrogen fertilizer was apparently increased at these compaction—tillage depth combinations, where the upland rice yield experienced insignificant reduction with decrease in nitrogen application rate from 100 to 60 kg ha⁻¹.Similar trends of yield response to compaction—tillage combinations were also observed under lowland conditions. When the soil was puddled (following high compaction) with a wedge plough or a power tiller, rice yields were increased by 48 and 56%, respectively, over yields using conventional puddling (without compaction). The yield increased further with the increase in intensity of puddling using a power tiller.     

Effects of pre-sowing compaction on soil physical properties, soil atmosphere and growth of oats on a clay soil

The effects on a number of soil physical and aeration parameters of compaction during spring pre-sowing operations were measured on a clay soil (49% clay). A soil-tyre contact stress of 200 kPa was applied by tractor tyres.
Yield of an oat crop was reduced by 30% as a result of compaction. Total porosity of the soil was reduced by 6% v/v owing to loss of pores > 60 μm, and water retention was increased. The resultant decrease in air-filled porosity greatly reduced gas diffusion and air permeability coefficients of the soil, and, for a time, O₂ content of the soil atmosphere was significantly lowered in the compacted treatment. Penetrometer resistance after sowing was 3.5 MPa in the control and 4.5 MPa in the compacted treatment; in the latter, root growth was inhibited until the soil dried and cracked. By the end of June, canopy temperature measurements indicated water stress in the oat crop on compacted soil but not in that on the control.
The results obtained indicated that air permeability, measured in the field, of 1 mm s⁻¹ provides a satisfactory single value below which crop growth is likely to be reduced.     

Effects of compaction on soil surface water repellency

Water repellency can reduce the infiltration capacity of soils over timescales similar to those of precipitation events. Compaction can also reduce infiltration capacity by decreasing soil hydraulic conductivity, but the effect of compaction on soil water repellency is unknown. This study explores the effect of compaction on the wettability of water repellent soil. Three air‐dry (water content ～4 g 100 g^?1) silt loam samples of contrasting wettability (non‐repellent, strongly and severely water repellent) were homogenized and subjected to various pressures in the range 0–1570 kPa in an odeometer for 24 h. Following removal, sample surface water repellency was reassessed using the water drop penetration time method and surface roughness using white light interferometry. An increase in compaction pressure caused a significant reduction in soil surface water repellency, which in turn increases the soil's initial infiltration capacity. The difference in surface roughness of soils compacted at the lowest and highest pressures was significant (at P > 0.2) suggesting an increase in the contact area between sessile water drops and soil surfaces was providing increased opportunities for surface wetting mechanisms to proceed. This suggests that compaction of a water repellent soil may lead to an increased rate of surface wetting, which is a precursor to successful infiltration of water into bulk soil. Although there may be a reduction in soil conductivity upon compaction, the more rapid initiation of infiltration may, in some circumstances, lead to an overall increase in the proportion of rain or irrigation water infiltrating water repellent soil, rather than contributing to surface run‐off or evaporation.     

Estimation of the diffusion coefficients of adsorbed and non-adsorbed solutes in soil

A method is proposed which follows Darrah's experimental procedure and takes advantage of a mathematical solution provided by Carslaw & Jaeger to estimate the diffusion coefficients of adsorbed and non-adsorbed solutes in soil. The method requires only the values of the concentration of the solute at the input face of a uniform column of soil, C^s, and of the total amount, Q_t, that has entered the soil after a specified time during which the surface of the block is in contact with a thin porous pad containing a known initial amount of solute, Q₀, at concentration C₀, expressed in the same units as C^s. In the C^s/C₀ vs. Q_t/Q₀ space there is a unique relationship between the effective diffusion coefficient, D_e, of the solute in the soil and the contact conductance for this solute, h, between the pad and the soil surface. The proposed procedure is firstly to determine D_e, and h for a non-adsorbed solute in the experimental soil using the experimental values of C^s/C₀ and Q/_Q for that solute. This value of D_e, gives the diffusion impedance factor for the solute in the soil, f, which is assumed also to apply to adsorbed solutes. A first estimate of the effective diffusion coefficient of an adsorbed solute, ¹D_ea, is then made using f and the diffusion coefficient of the free solute in water, D_L, obtained from the literature (i.e. ¹D_ea= D_Lf). Only if the solute is weakly adsorbed will the values of C^s/C₀, and Q_t/Q₀ lie in C^s/C₀, vs. Q_t/Q₀, space as defined by ¹D_ea and the contact conductance, h. Instead a second space relating C^s/C₀ and Q_t/Q₀, is now constructed from nominated values of h and D_e, where D_e, is defined in terms of ¹D_ea, the adsorption coefficient, F , and the volumetric moisture content of the soil, θ. The position of the experimental values of C^s/C₀, and Q_t/Q₀ within this new space defines h and the actual D_e, and F of the solute as it diffuses and is adsorbed in the soil. The advantages and limitations of the method are discussed. In particular, the method assumes that the adsorption process is linear and reversible.     

A LABORATORY METHOD TO MEASURE GAS DIFFUSION AND FLOW IN SOIL AND OTHER POROUS MATERIALS

An apparatus was constructed to measure diffusivity of krypton-85 and gas permeability in an enclosed core of soil of field structure or in other porous material. Sample enclosure decreased water loss by evaporation, reduced mass flow caused by changes in ambient temperature and pressure during diffusion measurement, and allowed subsequent measurement of gas permeability without further sample disturbance. When a bundle of tubes was used as a test sample to calibrate the apparatus, the resistances to diffusion and viscous flow agreed approximately with those calculated from the tube size and number. Gas movement was measured in dry sieved soil and in undisturbed cores of silty loam soil to illustrate the practical value of the method. In the dry cores, diffusivity relative to free air (D_A/D_o) was greater in ploughed soil, 0.18, than in direct drilled soil, 0.14, nearly in proportion to the greater air porosity in the ploughed soil, but air permeability in ploughed soil was four times greater than in direct drilled soil and was about 1 000 times greater than in compacted sieved soil.     

Assessment of earthworm contribution to soil hydrology: a laboratory method to measure water diffusion through burrow walls

The capacity for water diffusion in burrow walls (i.e. the coefficient of sorptivity) either burrowed by Lumbricus terrestris (T-Worm) or artificially created (T-Artificial) was studied through an experimental design in a 2D terrarium. In addition, the soil density of earthworm casts, burrow walls (0–3 mm around the burrow) and the surrounding soil (>3 mm) were measured using the method of petroleum immersion. This study demonstrated that the quantity of water which transits through burrows of L. terrestris in the soil matrix was lower than that transited through soil fractures, due to a reduction of soil porosity in burrow walls (compaction: cast > worms burrow walls > surrounding soil > artificial burrow walls). Earthworm behaviour, in particular burrow reuse with associated cast pressing on walls, could explain the larger burrow wall compaction in earthworm burrows. If water diffusion was lower through the compacted burrows, burrow reuse by the worms makes them more stable (worms would maintain the structure over years) than unused burrows. The present experimental design could be used to test and measure the specific differences between earthworm species in their contributions to water diffusion. Probably, these contributions depend on the presumed related-species behaviours which would determine the degree of burrow wall compaction.     

PORE CHARACTERISTICS OF SOILS FROM TWO CULTIVATION EXPERIMENTS AS SHOWN BY GAS DIFFUSIVITIES AND PERMEABILITIES AND AIR-FILLED POROSITIES

Gas diffusivity and permeability, and air-filled porosity, were measured in undisturbed soil cores at six water potentials between -2 kPa and oven dryness. All increased as water potential fell. In silt loam at 30 to 80 mm depth, relative diffusivity and air permeability at -2 kPa were 0.0013 and 5 × 10^?8cm² after direct drilling, and were 6 and 15 times greater respectively after ploughing, presumably because of the larger volume of air-filled large pores in the ploughed soil. These pores may also have been more continuous or less tortuous than in the direct drilled soil. However, at equal air-filled porosities up to 0.18 v/v, the pores were apparently more continuous and less tortuous in the direct drilled than in the ploughed soil. In the direct drilled silt loam at any given matric potential, air-filled porosity, gas diffusivity and permeability within and below the previously ploughed layer were isotropic. In clay loam at 30 to 80 mm depth gas diffusivity and permeability at -2 kPa were greater than in the silt loam irrespective of tillage but increased less on oven drying.     

Shrinkage behaviour of transiently- and constantly-loaded soils and its consequences for soil moisture release

Soils under loaded conditions may have different shrinkage behaviour from that of load‐free soils. In this study, we applied two kinds of mechanical stress (σ) on repacked homogeneous soil samples: transient and constant stresses, simulating the traffic load during tillage and the overburden pressure, respectively. Three transient stresses were applied on the soil surface with 150, 400 and 1400 kPa, while the constant stresses ranged from 1.8, 3.8, 5.5, to 7.3 kPa. We hypothesized that the two stresses play different roles in soil shrinkage behaviour as depicted by void ratio (e) and moisture ratio (?), as compared with load‐free soil. Thus, our aim was to build up the relationship between e, ? and σ. For a swelling soil, total pores can be divided into rigid and non‐rigid components according to their swelling and shrinkage capacity relative to soil moisture. The non‐rigid pores compacted by the transient stress can be regained in the subsequent wetting at load‐free conditions, whereas the compacted rigid pores do not recover. The reduction in rigid pores does not alter the soil pore shrinkage capacity. The shrinkage curves of transiently‐loaded soils are therefore parallel to each other with an identical coefficient of linear extensibility (COLE) and the same shrinkage slope, although their structural shrinkage phase narrows with an increase of stress. However, the constant stress compresses non‐rigid pores readily through suppressing their swelling capacity during wetting as well as compacting rigid pores. If the change of rigid pores is negligible, the shrinkage curves of constantly‐loaded soils converge at the zero shrinkage or the dry‐end point with the load‐free soil shrinkage. If the reductions of rigid and non‐rigid pores are both considered, the soil shrinkage combines the part of parallel shrinkage derived from the reduced rigid pores and the intersected shrinkage resulted from the altered non‐rigid pores. On the basis of different shrinkage behaviours resulting from the two mechanical stresses, we propose numerical formulae to illustrate a series of curves for the e‐?‐σ relationship. The different changes in rigid and non‐rigid pores cause soil water release differently.     

Effect of compaction on pore functions of soils in a Saalean moraine landscape in North Germany

Soil compaction and related changes of soil physical parameters are of growing importance in agricultural production. Different stresses (70, 230, 500, and 1000 kPa) were applied to undisturbed soil core samples of eight typical soils of a Saalean moraine landscape in N Germany by means of a confined compression device to determine the effect on (1) total porosity/pore‐size distribution, (2) saturated hydraulic conductivity, and (3) air conductivity to assess the susceptibility towards compaction. Different deformation behaviors after exceeding the mechanical strength particularly resulted from a combination of soil characteristics like texture and initial bulk density. The saturated hydraulic conductivity, as an indicator for pore continuity, was largely affected by the volume of coarse pores (r² = 0.82), whereas there was no relationship between bulk density and saturated hydraulic conductivity. Since coarsely textured soils primarily possess a higher coarse‐pore fraction compared to more finely textured soils, which remains at a high level even after compaction, only minor decreases of saturated hydraulic conductivity were evident. The declines in air conductivity exceeded those in hydraulic conductivity, as gas exchange in soils is, besides the connectivity of coarse pores, a function of water content, which increases after loading in dependence of susceptibility to compaction. A soil‐protection strategy should be focused on more finely textured soils, as stresses of 70 kPa may already lead to a harmful compaction regarding critical values of pore functions such as saturated hydraulic conductivity or air capacity.     

Compaction influences N2O and N2 emissions from 15N-labeled synthetic urine in wet soils during successive saturation/drainage cycles

Nitrous oxide emitted from urine patches is a key source of agricultural greenhouse gas emissions. A better understanding of the complex soil environmental and biochemical regulation of urine-N transformations in wet soils is needed to predict N₂O emissions from grazing and also to develop targeted mitigation technologies. Soil aeration, gas diffusion and drainage are key factors regulating N transformations and are affected by compaction during grazing. To understand how soil compaction from animal treading influences N transformations of urine in wet soils, we applied pressures of 0, 220 and 400 kPa to repacked soil cores, followed by ¹⁵N-labeled synthetic urine, and then subjected the cores to three successive saturation–drainage cycles on tension tables from 0 to 10 kPa.Compaction had a relatively small effect on soil bulk density (increasing from 0.81 to 0.88 Mg m⁻³), but strongly affected the pore size distribution. Compaction reduced both total soil porosity and macroporosity. It also affected the pore size distribution, principally by decreasing the proportion of 30–60 μm and 60–100 μm pores and increasing the proportion of micropores (<30 μm).Rates of urine-N transformations, emissions of N₂ and N₂O, and the N₂O to N₂ ratio were affected by the saturation/drainage cycles and degree of compaction. During the first saturation–drainage cycle, production of both N₂O and N₂ was low (<0.4 mg N m⁻² h⁻¹), probably because of anaerobic conditions inhibiting nitrification. In the second saturation/drainage cycle, the predominant product was N₂ at all compaction rates. By the third cycle, with increasing availability of mineral-N substrates, N₂O was the dominant product in the uncompacted (max = 4.70 mg N m⁻² h⁻¹) and 220 kPa compacted soils (max = 7.65 mg N m⁻² h⁻¹) with lower amounts of N₂ produced, while N₂ was produced in similar quantities to N₂O (max = 3.11 mg N m⁻² h⁻¹) in the 400 kPa compacted soil. Reduced macroporosity in the most compacted soil contributed to more sustained N₂ and N₂O production as the soils drained. In addition, compaction affected the rate of change of soil pH and DOC, both of which affected the N₂O to N₂ ratio.Denitrification during drainage and re-saturation may make a large contribution to soil N₂O emissions. Improving soil drainage and adopting grazing management practices that avoid soil compaction while increasing macroporosity will reduce total N₂O and N₂ emissions.     

Gas diffusion in structured materials: the effect of tri-modal pore size distribution

Coefficients of gas diffusion (hydrogen through air) were measured on packings of Portland stone chips over a range of water contents. The chips were obtained by crushing blocks of Portland stone on which similar gas diffusion measurements had been previously made. The packings had a tri-modal pore-size distribution: pores between the stone chips; pores within the chips but between ooliths; pores within the chips and within ooliths. As the water content of the packings was progressively decreased, the diffusion coefficient for the packings increased in three steps corresponding to successive drainage of the three pore modes. The previous results for the blocks were used to give good theoretical prediction of the three steps obtained by measurement. These results support earlier speculation that a similar stepwise increase in diffusion coefficient in soils might have been caused by micro-pedal structure within soil crumbs.     

Emission of N2O, N2 and CO2 from soil fertilized with nitrate: effect of compaction, soil moisture and rewetting

Soil compaction and soil moisture are important factors influencing denitrification and N₂O emission from fertilized soils. We analyzed the combined effects of these factors on the emission of N₂O, N₂ and CO₂ from undisturbed soil cores fertilized with (150 kg N ha⁻¹) in a laboratory experiment. The soil cores were collected from differently compacted areas in a potato field, i.e. the ridges (ρ_D=1.03 g cm⁻³), the interrow area (ρ_D=1.24 g cm⁻³), and the tractor compacted interrow area (ρ_D=1.64 g cm⁻³), and adjusted to constant soil moisture levels between 40 and 98% water-filled pore space (WFPS).High N₂O emissions were a result of denitrification and occurred at a WFPS≥70% in all compaction treatments. N₂ production occurred only at the highest soil moisture level (≥90% WFPS) but it was considerably smaller than the N₂O-N emission in most cases. There was no soil moisture effect on CO₂ emission from the differently compacted soils with the exception of the highest soil moisture level (98% WFPS) of the tractor-compacted soil in which soil respiration was significantly reduced. The maximum N₂O emission rates from all treatments occurred after rewetting of dry soil. This rewetting effect increased with the amount of water added. The results show the importance of increased carbon availability and associated respiratory O₂ consumption induced by soil drying and rewetting for the emissions of N₂O.     

Estimation of CO2 diffusion coefficient at 0–10 cm depth in undisturbed and tilled soils

Diffusion coefficients (D) of CO₂ at 0–10 cm layers in undisturbed and tilled soil conditions were estimated using the Penman (Penman HL. 1940. Gas and vapor movement in soil, 1. The diffusion of vapours through porous solids. J Agric Sci. 30:437–463), Millington–Quirk (Millington RJ, Quirk JP. 1960. Transport in porous media. In: Van Baren FA, editor. Transactions of the 7th International Congress of Soil Science. Vol. 1. Amsterdam: Elsevier. p. 97–106), Ridgwell et al. (Ridgwell AJ, Marshall SJ, Gregson K. 1999. Consumption of atmospheric methane by soils: A process-based model. Global Biogeochem Cy. 13:59–70), Troeh et al. (Troeh FR, Jabro JD, Kirkham D. 1982. Gaseous diffusion equations for porous materials. Geoderma. 27:239–258) and Moldrup et al. (Moldrup P, Kruse CW, Rolston DE, Yamaguchi T. 1996. Modeling diffusion and reaction in soils: III. Predicting gas diffusivity from the Campbell soil–water retention model. Soil Sci. 161:366–375) models. Soil bulk density and volumetric soil water content (θ_v) at 0–10 cm were measured on 14 April, 2 June and 12 July 2005 at 0–10 cm depth in no-till (NT) and conventional till (CT) malt barley and undisturbed soil grass–alfalfa (UGA) systems. Air-filled porosity (ε) was calculated from total soil porosity and θ_v measurements. Both soil air porosity and estimated CO₂ diffusivity at the 0–10 cm depth were significantly affected by tillage. Results of CO₂ diffusion coefficients in the soil followed trends similar to those for soil ε data. The CT tended to have significantly greater estimated soil CO₂ diffusion coefficients than the NT and UGA treatments. The relationship between D/D ₀, and air-filled porosity was well described by a power (R ² = 0.985) function. The model is useful for predicting CO₂ gas-diffusion coefficients in undisturbed and tilled soils at various ranges of ε where actual gas D measurements are time-consuming, costly and infeasible.     

Short-range spatial variation of nitrous oxide fluxes in relation to compaction and straw residues

The spatial heterogeneity of N₂O flux at short distances (0.1–2 m) was characterized in relation to various soil physical and chemical properties and the location of incorporated crop residues in arable soils. Plots were prepared with uniform compaction (either zero or compacted by a laden two‐wheel‐drive tractor) in two field experiments, one under winter barley (Hordeum vulgare), the other under oil‐seed rape (Brassica napus). Flux measurements were made of N₂O using small chambers (7.3 cm diameter) placed at intervals of approximately 10 cm along a transect (c. 2 m long) across the direction of application of the treatments of compaction and residue incorporation. The flux of N₂O and many other measurements showed large variation over short distances, particularly when fluxes were small. The spatial variation of the flux was not closely related to the soil properties. Correlations showed that cone resistance, air permeability and closeness to incorporated residues were as important as soil NO₃, NH₄ and soluble C in determining flux of N₂O from non‐compacted soils. Most properties of compacted soils did not correlate with N₂O flux. Correlation and multiple regression analysis failed to establish consistent relations between soil environmental variables and N₂O flux, but principal component regression indicated that, overall, N₂O flux increased with decreasing distance from straw residues and air permeability, and with increasing cone resistance and wet bulk density.     

Effects of agricultural machinery with high axle load on soil properties of normally managed fields

In a field study, conducted on 10 conventionally managed field sites in Germany, the effects of high axle loads (15–25 Mg) on soil physical properties were investigated. Soil texture classes ranged from loamy sand to silty clay loam. All sites were annually ploughed, and one site was additionally subsoiled to 40 cm depth. In the context of common field operations wheeling was performed either by a sugar beet harvester (45 Mg total mass, 113 kPa average ground contact pressure) or a slurry spreader (30 Mg total mass, 77 kPa average ground contact pressure). Soil moisture conditions varied from 3.2 to 32 kPa water tension during this pass. Penetration resistance was measured before the pass. Soil cores were collected in a grid scheme at each site before and after the machine passed. Bulk density, aggregate density, air-filled porosity and air permeability at seven distinct soil water tensions ranging from 0.1 to 32 kPa were determined in these cores taken from three layers (topsoil, plough pan and subsoil).At most sites, a pass by the sugar beet harvester or slurry spreader strongly affected topsoil properties. Bulk density and aggregate density increased while air-filled porosity and air permeability decreased. The plough pan was already severely compacted before wheeling: therefore changes were small. The subsoil showed no changes or only minor signs of compaction. Only at one site, which was subsoiled the year before, significant signs of compaction (i.e. changes in bulk density, air-filled porosity and air permeability) were detected in subsoil layers.The results show that using present-day heavy agricultural equipment does not necessarily lead to severe subsoil compaction in soils where a compacted plough pan already exists. However, fields which were subsoiled leading to an unstable soil structure are in serious danger of becoming severely compacted.