共查询到20条相似文献,搜索用时 109 毫秒
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蕃麻皂素即海柯吉宁,是一种具开发潜力合成生产地塞米松药物的原料,在论述国内外利用海柯吉宁研究及生产地塞米松现状的基础上,指出了国内合成生产存在的问题,针对国内用海柯吉宁合成生产地塞米松收率低的问题,提出把优化工艺作为合成生产的研究重点,且从3个方面进行研究,可将其收率从现在的6.03%提高到10%以上。 相似文献
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木材浸渍用低分子量低色度酚醛树脂 总被引:6,自引:0,他引:6
为了探讨低分子量酚醛树脂处理木材导致材色加深的因素,采用紫外(UV)和红外(UV)吸收光谱分析低分子量酚醛树脂在合成和固化过程中主要产物的光吸收作用,确定了采用低分子量酚醛树脂改性木材化学药剂的合理配制和处理条件,并测定了处理后大青杨木材材色。结果表明:低分子量酚醛树脂生木材材色的色差变化较小,长时间放置材色稳定。 相似文献
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新型浸渍酚醛树脂的研制 总被引:4,自引:0,他引:4
本文介绍了一种新型浸渍酚醛树脂,通过调整合成工艺及更换添加剂等措施,使该树脂具有良好的水溶性及低量的了酚,用该树脂浸渍的胶膜纸生产的浸渍纸贴面混凝土板板,其耐磨、耐酸碱,耐干裂,耐水蒸气等各项指标都能满足使用要求。 相似文献
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Improvement of physical and biological properties of particleboards by impregnation with phenolic resin 总被引:3,自引:1,他引:3
Summary Particleboards were treated with a low molecular-weight phenol-formaldehyde resin and their properties were evaluated. Particles were dipped into aqueous solutions of resin or sprayed with resin solutions before spraying the conventional phenol-formaldehyde resin adhesive, or sprayed with a mixture of low molecular-weight resin and the adhesive resin in a single step. Though mechanical properties and dimensional stability of the phenolic-resin-treated boards were affected considerably by the incorporated resin loading (IRL), the methods of treatment did not produce significantly different results. After boiling for 2-hours, the boards treated at 10% IRL retained 80% of their strength values in the dry condition. The internal bond strength increased with increasing IRL values, and the boards with 20% IRL showed twice the value of untreated controls at the same level of board density. Treated particleboards showed a dramatic reduction in the rate of swelling even at low resin loading. Results obtained from accelerated laboratory tests of biodegradation suggested that incorporated resin-solids worked well to enhance decay and termite resistance of particleboards. For a brown-rot fungus, the weight loss was substantially reduced at 15% IRL, whereas attack was suppressed almost entirely even at low resin loadings for the white-rot fungus. 相似文献
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为确定高产脂云南松的早期选择指标,采用石蜡切片法对不同海拔、不同产脂量云南松的针叶、树干韧皮部和木质部的组成性树脂道特征进行解剖观察,结果表明:高产脂与低产脂云南松的针叶树脂道个数、树干木质部树脂道密度、韧皮部树脂道大小及单位长度树脂道数量存在极显著差异(P<0.01),但不同海拔之间无显著差异;高、低海拔高产脂云南松针叶树脂道数量分别比低产脂的高38.89%、30.34%,树干木质部树脂道密度分别高58.06%、48.48%,韧皮部树脂道大小分别高32.20%、29.73%,韧皮部单位长度树脂道数量分别高21.95%、38.51%.说明针叶树脂道数量、树干木质部树脂道密度及韧皮部树脂道大小3项指标,也可作为云南松产脂力评价的部分指标. 相似文献
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低温低pH尿素与甲醛反应工艺的研究 总被引:2,自引:0,他引:2
本文研究了低温低pH尿素与甲醛反应的新方法。研究表明尿素与甲醛反应有着不同的历程,反应过程明显缩短。树脂具有化学改进的骨架结构,当固化时树脂含有亚甲基比亚甲基醚键多得多,树脂的耐水解性更稳定,释放甲醛较少。同时作者提出了低温低pH下尿素与甲醛反应的生成物作为一种基本树脂,以解决脲醛树脂胶粘剂贮存期不长,在贮存与运输中因气温的变化造成树脂变质的难题。 相似文献
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松树增脂剂应用效果分析 总被引:3,自引:0,他引:3
松树增脂剂在福建省马尾松主产区推广应用结果表明:施用增脂剂具有明显的增产效果,增产幅度达13 3%~36 1%,增脂剂对于低产马尾松树脂增产效果更为明显。增脂剂增产后效作用明显,施用增脂剂后,全年可增加30d采脂时间,并可延长采割年限2~3a,节约和保护采脂资源,提高采脂效率。 相似文献
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本文研制的螺旋板式脂液澄清槽,脂液扰动小,基本无“死角”现象,应用于松香生产的脂液澄清过程中,与钟罩式和折流板式澄清槽比较,具有沉降时间短、脂液含水率低、所得松香特级品率高的优点,且设备体积小,加工制作方便。 相似文献
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To enhance dimensional stability and biological properties, low molecular weight phenolic resins of a conventional alkaline type and neutralized type were impregnated into Japanese cedar wood (Cryptomeria japonica D. Don) and heat-cured. The treatment with the neutralized type resin retained the original wood color, whereas the alkaline treatment changed the color of wood to red-brown. The concentrations of the resin solutions and the weight gains due to the resin loading of wood after treatment were highly correlated, and the target resin loading could be assessed from the solution concentration. A high dimensional stability of 60% antiswelling efficiency was attained when both types of resins were impregnated at about 30% resin loading and no significant difference was recognized between the two. To suppress decay attack from brown-rot and white-rot fungi, 15% and 10% resin loading due to treatment was required for the neutralized and alkaline types of phenolic resins, respectively. The penetration of resin into wood cell walls was investigated by means of light microscopy, Scanning Electron Microscopy (SEM), and Electron Probe X-ray Microanalysis (EPMA). A m-Bromophenol-formaldehyde resin of three levels of an average molecular weight was used to detect the presence of resin by bromine signals. The phenolic resins with low and medium molecular weights (290 and 470) were shown to penetrate into the cell walls the furthest, thereby contributing to the enhancement of dimensional stability and decay resistance in the resin-impregnated wood. Also, for phenolic resin with a high molecular weight (820), only the resin components of low molecular weight appeared to be present in the walls, making very little contribution to the dimensional stability. 相似文献
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介绍新平县松脂资源及松脂生产现状,分析认为松脂产量上不去的主要因素是采脂资源的产权关系不明晰.阐述集体林权制度改革的理论、政策法律依据及改革的目标.结合集体林权制度改革,探讨新平县采脂区处理好采脂资源最佳利用的对策措施. 相似文献
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The effects of molecular weight of PF resin on the deformation behaviour of NaClO2 treated resin-impregnated wood during compression were investigated. Blocks of Japanese cedar were subjected to 2% NaClO2 aqueous solution. This was repeated up to four times resulting in a weight loss of 28%. Treated and untreated samples were
impregnated with PF resin having different molecular weight. With increasing molecular weight, weight gain and volume gain
decreased for untreated PF resin-impregnated wood, while NaClO2 treated wood impregnated with high molecular weight PF resin showed almost double the weight gain compared to untreated condition.
NaClO2 treatment has shown considerable potential for high compression of PF resin-impregnated wood at lower pressing pressure regardless
of the molecular weight of the resin. Low to high molecular weight resin was shown to penetrate into NaClO2 treated wood as estimated by weight gain contributing to the plasticization of cell wall considerably and thus resulting
in cell wall collapse at low pressing pressure. The density of NaClO2 treated wood impregnated with high molecular weight resin attained a value of over 0.8 g/cm3 which is close to the density of untreated wood impregnated with low molecular weight resin. Such compressed wood exhibited
high dimensional stability after boiling for 3 h. Thus, the penetration of resin into wood contributes to highly compressed
dimensional stable resin-impregnated wood at low pressing pressure. 相似文献