甘肃主要农业土壤中Cu、Zn、Mn、Fe的形态及有效性研究

本文对甘肃省主要农业土壤中Ｃｕ、Ｚｎ、Ｍｎ、Ｆｅ的形态及其有效性进行了研究。结果表明，供试土壤的全Ｃｕ含量范围为２２－２４ｍｇ／ｋｇ，全Ｍｎ为５４２－７７２ｍｇ／ｋｇ，全Ｆｅ为３５６８５－３８３５５ｍｇ／ｋｇ。四种元素均以灌漠土的含量最低，褐土最高。土壤中Ｃｕ、Ｚｎ、Ｍｎ、Ｆｅ的大部分以残留矿物态和氧化铁结合态存在。生物试验和统计分析表明，Ｃｕ、Ｚｎ、Ｍｎ、Ｆｅ的交换态和松结有机态对植物最为有效，     

我国北亚热带白浆化土壤矿物学特性的研究

本文对北亚热带地区七个白浆化土壤的原生矿物和次生矿物的特性进行了研究。重，轻矿物含量表明土壤继承了母质的特性，粘淀层与漂白层的母质沉积是间断的，前者风化强度大于后者。石英颗粒表现特征显示漂白层物来来源于黄土物质再堆积，粘土矿物以水云母为主，其结晶度较差，氧化铁类型以针铁矿和赤铁矿为主，也有非晶质氧化铁和硅酸盐中的Ｆｅ＾２＋，其形成条件与现代化成土条件一致。     

塔里木盆地冲积新成土土壤质地对土壤性状的影响

通过塔克拉玛干沙漠腹地两个大剖面土壤质地的变化，分析了冲积新成土土壤质地对土壤性状的影响。分析结果表明，受土壤颗粒吸收的影响，细土层土壤有机质和全盐含量高于砂土层。在大量的微量元素中，细土层Ｆｅ２Ｏ３，Ａｌ２Ｏ３，Ｐ２Ｏ５，ＣａＯ，ＭｇＯ，ＭｎＯ，ＴｉＯ２，Ｖ，Ｃｒ，Ｎｉ，Ｃｕ，Ｚｎ，Ｓｒ，Ｙ，Ｎｂ，Ｔｂ和Ｐｂ的含量高于砂土层，而ＳｉＯ２，Ｎａ２Ｏ和Ｂａ５的含量低于细土层。     

北亚热带江淮地区白浆土铁锰结核的研究

研究江淮地区白浆土铁锰核的重量分布，颜色及其地球化学特征。结果表明，在白浆层中结核含量最高且多具有同心圆结构，结构颜色和形状决定于颗粒的大小，在结核中发生了Ｓｉ，Ｆｅ，Ａｌ和Ｍｎ的富集，其它元素则与土壤相近，可以判定，铁锰结核是在白浆化过程中就地形成并累积的。     

新疆南天山乌什谷地灌淤土及其在土壤系统分类中的地位

乌什谷地水旱轮作中的水耕作用是引起灌淤土成土过程和成土特征变异的主要动力，形成的人为土具有灌淤表层的全部诊断条件，其变异主要表现在：活性Ｆｅ２Ｏ３增多，耕层至心土层达４克／千克以上，占土壤全Ｆｅ２Ｏ３的１０％以上，心土层下呈减少趋势，铁的晶胶率耕层低，而心，底土中显著增高，Ｋｈ值（层段晶化度／表层晶化度）１．３－４．５之间，多数剖面有锈斑；耕下均有鳞片状结构，不具有双重熟化和双重淋淀层段，本文中将     

鼎湖山土壤有机质深度分布的剖面演化机制

根据鼎湖山森林植被带(SL)、灌丛—草甸过渡带土壤剖面(GC)有机质含量,有机质Δ14C、δ13C值,土壤粘粒含量及孢粉分析结果,研究华南亚热带山地土壤有机质深度分布特征的成因机制。结果表明土壤有机质的深度分布特征与土壤剖面的发育过程密切相关,随深度增大,有机质的来源数量不断减少,而成土时间增加,分解作用导致的有机质含量降低幅度增大,有机质含量不断减少。土壤有机质14C表观年龄随深度增加,土壤有机质δ13C值与有机质含量的深度变化具有明显对应关系,这些都是土壤剖面发育过程中有机质不同更新周期组分呈规律性分解的结果。粘粒的深度分布反映土壤剖面淋滤淀积的特点,表明土壤剖面经受了长期成土风化。土壤剖面的上述特征均为剖面发育过程中不断沉积、不断成土的结果,表明土壤剖面成土演化对于有机质深度分布具有显著制约。     

安徽凤阳石英岩发育土壤的磁学性质及环境磁学意义

通过对安徽凤阳石英岩发育土壤典型剖面的磁学参数测量,结果表明,A层和B层中的磁性矿物含量明显高于C层,且A层和B层中磁性矿物的粒度明显比C层细.C层的磁学性质由磁铁矿主导,A层和B层的磁学性质由磁赤铁矿主导.磁赤铁矿是石英岩在成土过程中形成的次生矿物.土壤中磁赤铁矿的出现及含量的变化指示成土作用的强弱.石英岩的磁性对土壤的磁性影响甚小,而成土作用和生物作用对土壤磁性增强起到了主要作用.     

Fe^2＋和Mn^2＋对水稻锌吸收与运转的影响

水培试验结果表明，Ｆｅ＾２＋、Ｍｎ＾２＋对水稻锌的吸收和运转有明显的影响。高浓度Ｆｅ＾２＋或Ｍｎ＾２＋（５μｇ／ｇ）显著降低水稻吸锌量、抑制锌由根向茎、叶的运转。稻株生物量与叶片Ｆｅ／Ｚｎ比值或Ｍｎ／Ｚｎ比值有明显折负相关关系，在叶片Ｆｅ／Ｚｎ〉８或Ｍｎ／Ｚｎ〉２６时，水稻生物量明显降低。造成水稻缺锌的主要原因是土壤有效锌含量低，而高浓度Ｆｅ＾２＋和Ｍｎ＾２＋是诱发和加重水稻缺锌的重要条件。因此在     

中国白浆土研究Ⅱ.无定形铁、锰、铝氧化物特性及其元素地球化学分异

本文主要研究了白浆土中无定形态铁、锰、铝氧化物特性及其元素的地球化学特征。结果表明：（１）游离态、活性态及络合态的铁、锰、铝氧化物都向着粘粒中富集。其中游离态及活性态中，Ａｌ２Ｏ３富集最强烈，Ｆｅ２ｏ３次之，ＭｎＯ最弱。（２）铁、锰、铝氧化物的活性是ＭｎＯ高于Ｆｅ２Ｏ３，而Ａｌ２Ｏ３主要取决于ＰＨ值，同时也受其它因素的影响。ＭｎＯ和Ｆｅ２Ｏ３在活性上的差异，不仅取决于两者在标准氧化还原电位的差异上     

土壤中有机金属络合物的性质和组成

本文综述了应用一系列物理化学方法对土壤有机金属络合物的组成与性质的研究状况，其中包括应用放射性同位素和激光莹光法测定田间定位试验，模拟试验中土壤有机配位体与Ｆｅ，Ｍｎ，Ｃａ形成的络合物的组成与性质。     

Podzol formation in sandy soils of Finland

Podzolization occurs quickly in acidic parent materials with addition of acidic litter from coniferous trees. This study was conducted to evaluate Podzol formation and estimate lengths of time required to meet morphological and chemical criteria of podzolic B horizon and spodic horizon in Finland. Soil color, organic C, ODOE, and extractable Al and Fe were measured in a seven-pedon chronosequence (230–1800 years) and four older pedons (8300–11,300 years). The bulk mineralogical composition of the BC and C horizons was uniform with quartz, plagioclase and K-feldspar as main components and amphibole, illite and chlorite as minor components. The fine (<5 μm) fraction of selected samples was primarily amorphous allophone-like material with some mixed-layered illite–vermiculite. All pedons in the study met the criteria for albic horizons according to the FAO–Unesco, World Reference Base (WRB) and Soil Taxonomy systems. According to the FAO–Unesco system, all pedons had spodic B horizons and were classified as Podzols. According to the WRB system, none of pedons of the chronosequence had spodic horizons, whereas the older pedons met the criteria for a spodic horizon. About 4780 years were required to form a spodic horizon according to the WRB system. The oldest pedon of the chronosequence and the older pedons had spodic horizons according to Soil Taxonomy, but the younger pedons failed to meet the spodic horizon criteria. About 1520 years were required to form a spodic horizon that met the color and organic C criteria of Soil Taxonomy, whereas it took about 4780 years to meet the required accumulation of Fe and Al. This study points out the discrepancy between the color criteria and the criteria reflecting the accumulation of Al, Fe and organic matter in the B horizon.     

悬着水位对铝硅酸盐的稳定性及土壤发生的影响

The mineral stability and solute activities of soil solution extracted from selected horizons of seven studied pedons of Alfisols in Kentucky, USA, and the relationship between distribution of iron-manganese concretions and the restrictive layers were investigated. The results showed that the genesis and development of these soils and mineral weathering trends were strongly influenced by the depth of bedrock and the presence of perched water tables at lithic (limestone) interfaces due to the dissolution and buffering effect of limestone bedrock. The extractable Mg/Ca ratio as depth function and soil depth above bedrock could be used as indices of weathering and degree of soil development. Maximum iron-manganese concretion accumulation was found to occur in the horizon overlying clay horizon (>40% clay) with a sharp increase in clay content (>10%), which suggested that zones of Fe-Mn concretion accumulation in soils of the Inner Bluegrass Region appeared to be a sensitive genetic indicator of argillic horizons with restrictive permeability.     

Geochemical characterization of placic horizons in subtropical montane forest soils,northeastern Taiwan

Well‐developed placic horizons have been found in subalpine forest soils with large clay contents in Taiwan. We investigated their formation processes in five profiles in a subalpine ecosystem of northeastern Taiwan, using scanning electron microscopy (SEM), energy‐dispersive spectrometry (EDS), electron probe microanalysis (EPMA), differential X‐ray diffraction (DXRD) and chemical extractions. The placic horizons, ranging from 3‐ to 17‐mm thick, always occurred above argillic horizons with abrupt changes in pH and texture between the two horizons. When fully developed, the placic horizons were clearly differentiated between upper and lower sub‐horizons. EDS and chemical extractions revealed that the cementing materials in both were predominantly inorganic Fe oxides. However, contents of aluminosilicates and organically complexed Fe and Al were greater in the lower than in the upper placic sub‐horizon. Results of EPMA indicated that interstitial fine materials in the upper placic sub‐horizon were composed mainly of Fe oxides, whereas Fe oxides were codominant with illuvial clay in the lower sub‐horizon. These analyses identified the migration of Fe and clay as major formation processes in both sub‐horizons. We hypothesize that there is a pedogenic sequence that starts with clay illuviation, followed by podzolization. The resultant textural and permeability differentiation reinforces the tendency to profile episaturation that is already inherent from the heavy rainfall and clayey surface soils. Topsoil Fe is therefore reduced and mobilized, and then illuviated with clay and organically complexed Fe/Al to initiate the lower placic sub‐horizon. The poor permeability of this layer reinforces the moisture conditions in the surface soils, and the further reduction, illuviation and deposition of inorganic Fe to form the upper placic sub‐horizon.     

Parent material influence on soil distribution and genesis in a Paleudult and Kandiudult complex,southeastern USA

Parent materials greatly influence soil development and the distribution of soils on the southeastern US Coastal Plain. We examined the physical, chemical, and mineralogical properties of 11 pedons in a 1-ha plot on the Upper Coastal Plain of Georgia, USA. Uniformity of parent materials was assessed by sand grain size characteristics. The soils have sandy epipedons of variable thickness and argillic horizons of variable texture. Six of the pedons also have kandic horizons. They are classified (US Soil Taxonomy) in Psammentic, Grossarenic, Arenic, and Typic subgroups of Paleudults and Kandiudults. Loamy pedons possess argillic horizons with two distinct increases in clay and greater differences between eluvial and illuvial horizons than sandy pedons. The upper boundary of the argillic horizon is approximately parallel to the present geomorphic surface, suggesting that it is associated with the contemporary surface. Discontinuities, identified by changes in sand grain size ratios and plots of the third (skewness) and fourth (kurtosis) moments of sand grain distribution, roughly correspond to the bottom of the solum. Our data suggest that there are both eolian and fluvial components in the solum, whereas subjacent horizons are completely derived from fluvial deposits. Sandier pedons have greater gibbsite/kaolinite ratios, possibly because greater permeability has enhanced leaching and Si loss. Our data suggest parent materials largely control soil distribution over this plot.     

Characterization of Andosols in Yakushima Island

We examined soils derived from volcanic ash of Kikai-Akahoya tephra on Yakushima Island, Japan, and classified them according to the Unified Soil Classification System of Japan, 2nd Approximation (USCSJ 2nd) and the World Reference Base for Soil Resources (WRB). Five pedons with horizons showing high (>20%) volcanic glass content were investigated. Soils developed under evergreen broad-leaved forests had high acid oxalate-extractable aluminum (Alo) and acid oxalate-extractable silicon (Sio) concentrations, and low acid oxalate-extractable iron (Fe)/dithionite-citrate-extractable Fe ratio. This indicates a warmer climate and less severe leaching conditions compared with soils developed under coniferous forests dominated by Cryptomeria japonica and grasslands dominated by Pseudosasa owatarii. All soils contained considerable amount of hydroxyl-Al-interlayered 2:1 clay minerals. The surface horizons of the pedons developed under the cool-temperate C. japonica forests contained smectite as a result of podzolization. However, the surface horizon of the pedon developed under cool-temperate P. owatarii grasslands did not contain smectite. All pedons belonged to the Kuroboku soils great group (USCSJ 2nd) and Andosols (WRB). Pedons in mountainous areas did not contain horizons with more than 6?g?kg^?1 of Sio and hence were classified as non-allophanic Andosols. In mountainous areas, it was observed that allophane formation was inhibited by Al leaching due to intense rainfall (>10,000?mm year^?1); Al consumption due to the formation of the Al-humus complex; and Al incorporation into the interlayers of vermiculite. The low soil water pH [pH(H₂O)] and leaching of silicon (Si) in mountainous areas would support these anti-allophanic effects.     

太湖地区水耕人为土中漂白层的成因探讨

采集太湖地区4个具有漂白层的水耕人为土剖面(E-A1、E-A2、E-A3、E-A4)及1个发育于相同母质上的一般水耕人为土剖面作为参照(Ref),描述了土壤剖面的形态特征,分析了土壤颗粒组成、黏粒矿物组成、铁氧化物以及大量和微量元素等,并探讨了漂白层成因。5个剖面土壤颗粒组成以粉粒为主,在60%~75%之间,且剖面中各层次变异系数较小,小于10%;大量元素和微量元素在剖面各层次间变异系数也小于10%,指示漂白层与上覆和下伏土层发育在相似物质来源的土壤母质上;而E-A1剖面漂白层中较高的粉粒含量(75.04%)、较大的中细粉粒和中细粉粒/粗粉粒比值的变异系数(38.05%、61.85%)表明该剖面母质具有不均一性。说明E-A2、E-A3、E-A4、Ref剖面土壤性质的变化主要是由于成土作用形成的,而E-A1剖面土壤的性质变化除受成土作用影响外,还受沉积环境的影响。E-A2、E-A3、E-A4剖面的漂白层中蒙脱石和蛭石、粉粒和粗粉粒、SiO2、CaO、Zr等含量高于上下土层,而水云母和绿泥石、游离铁、Al2O3、Rb、Li、Ba、稀土元素(Rare earth element,REE)等则相反;同时,参照剖面亦有与E-A2、E-A3、E-A4剖面类似的特点,只是漂白作用出现在耕作层,不能定义为漂白层;而E-A1剖面的部分性质则显示出空间上的不一致性,其粉粒含量并非漂白层最高,而是随剖面土层深度向下越来越大。这些变异表明,太湖地区水耕人为土漂白层的形成,可以由黄土性泻湖相沉积物经过水耕过程中水分的周期性淹水和排干,通过机械淋洗和活性铁的淋溶而形成(剖面E-A2、E-A3、E-A4),也可以是母质沉积的过程中受湖水水面升降,导致机械淋溶,然后水耕过程叠加活性铁的淋溶而形成(剖面E-A1)。     

Podzolization as a deferralitization process: a study of an Acrisol–Podzol sequence derived from Palaeozoic sandstones in the northern upper Amazon Basin

Morphological, geochemical and mineralogical studies were carried out in a representative soil catena of the low‐elevation plateaux of the upper Amazon Basin to interpret the steps and mechanisms involved in the podzolization of low‐activity clay soils. The soils are derived from Palaeozoic sandstones. They consist of Hydromorphic Podzols under tree savannah in the depressions of the plateaux and predominantly of Acrisols covered by evergreen forest elsewhere. Incipient podzolization in the uppermost Acrisols is related to the formation of organic‐rich A and Bhs horizons slightly depleted in fine‐size particles by both mechanical particle transfer and weathering. Weathering of secondary minerals by organic acids and formation of organo‐metallic complexes act simultaneously over short distances. Their vertical transfer is limited. Selective dissolution of aluminous goethite, then gibbsite and finally kaolinite favour the preferential cheluviation of first Fe and secondly Al. The relatively small amount of organo‐metallic complexes produced is related to the quartzitic parent materials, and the predominance of Al over Fe in the spodic horizons is due to the importance of gibbsite in these low‐activity clay soils. Morphologically well‐expressed podzols occur in strongly iron‐depleted topsoils of the depression. Mechanical transfer and weathering of gibbsite and kaolinite by organic acids is enhanced and leads to residual accumulation of sands. Organo‐metallic complexes are translocated in strongly permeable sandy horizons and impregnate at depth the macro‐voids of embedded soil and saprolite materials to form the spodic Bs and 2BCs horizons. Mechanical transfer of black particulate organic compounds devoid of metals has occurred later within the sandy horizons of the podzols. Their vertical transfer has formed well‐differentiated A and Bh horizons. Their lateral removal by groundwater favours the development of an albic E horizon. In an open and waterlogged environment, the general trend is therefore towards the removal of all the metals that have initially accumulated as a response to the ferralitization process and have temporarily been sequestrated in organic complexes in previous stages of soil podzolization.     

A comparison of hydroxylamine and ammonium oxalate solutions as extractants for Al, Fe and Si from Spodosols and Spodosol-like soils in Canada

The suitability of acid hydroxylamine as an extractant for Al, Fe and Si hydrous oxides was evaluated by comparing its effectiveness with that of ammonium oxalate in pedogenic studies of Spodosols in Canada. Al, Fe and Si were extracted by acid hydroxylamine and acid ammonium oxalate solutions from samples of three major horizons of nine pedons of Spodosols and two pedons of Spodosol-like soils. Relative to oxalate, hydroxylamine extracted only slightly less Al and Fe but considerably more Si from all horizons of the selected pedons. Oxalate appears to be slightly more effective in extracting pedogenic amorphous material whereas hydroxylamine is more effective in extracting amorphous material formed by mechanical grinding. On the whole, the hydroxylamine method gives a good approximation of oxalate-extractable Al and Fe in all major horizons studied and should be used for soils containing magnetite. The hydroxylamine method, however, does not give a good approximation of oxalate-extractable Si.