A study of metal oxide on antimicrobial effect of plasma pre-treated cotton fabric

Cotton, a natural fibre that consists of cellulose, is highly popular because it is sweat-absorbing and comfortable to wear. However, cotton fabrics provide an excellent environment for microorganisms to grow, owing to their ability to retain moisture. Therefore, numerous chemicals have been used to enhance anti-microbial activity of cotton textiles. This paper reports results of use of silver oxide (Ag₂O) or zinc oxide (ZnO) as a catalyst in the antimicrobial formulation (halogenated phenoxy compound (Microfresh, MF)) and a binder (Microban, MB) for improved treatment of cotton fabrics and minimisation of side effects of the treatment. In addition, from the morphological study, plasma technology was employed to roughen the surface of the materials to improve loading of metal oxides on the surface. Moreover, the characteristic infra-red bands related to plasma-treated cotton produced results different from untreated fabric, implying plasma treatment can improve hydrophilicity of the fabric. Mechanical strength of the specimens was also increased by plasma treatment. Meanwhile, the research showed that the control fabric slightly inhibited the growth of S. aureus because of the bleach residues on fabric surface. On the other hand, anti-bacterial activity of MF-MB-treated specimen, especially in the presence of metal oxide catalyst, was enhanced, providing a slightly larger zone of inhibition. Moreover, plasma gas contains reactive oxygen species that can enter the cell, eventually causing its death. The hydrophilic nature of carbonyl groups present in oxygen plasma pre-treated specimens also increased the anti-microbial activity after treatment with MF-MB.     

Relationship between curing temperature and low stress mechanical properties of titanium dioxide catalyzed flame retardant finished cotton fabric

N-methylol dimethylphosphonopropionamide is a flame-retardant agent commonly combined with melamine resin and phosphoric acid catalyst to impart flame-retardant property to cotton fabrics. A co-catalyst titanium dioxide (TiO₂) is added into the formulation in order to improve the flame-retardant performance by enhancing the crosslinking reaction and physically attaching on to cotton fabrics. The fabrics cured at temperature of 150 °C and 170 °C have a better flame-retardant ability and can withstand multiple times of home laundering compared with those cured at temperature of 110 °C and 130 °C. The flame-retardant ability is further enhanced by treating the fabrics in the presence of TiO₂. In addition, the low stress mechanical properties measured by Kawabata Evaluation System for Fabric (KES-F) are altered after flame-retardant treatment. These changes are contributed by the formation of crosslinks after treatment, acid-catalyzed depolymerization in a strong acidic medium and the presence of co-catalyst TiO₂. In addition, the properties of cotton fabrics depend greatly on the choice of curing temperature. High curing temperature usually caused poor hand properties of the fabrics due to the extensive crosslinks formation. Lastly, the existence of TiO₂ in the treatment not only improves the reaction efficiency but also has positive enhancement with respect to compressional recovery ability and tensile properties.     

Fabric objective measurement of the plasma-treated cotton fabric subjected to wrinkle-resistant finishing with BTCA and TiO<Subscript>2</Subscript> system

Handle is an important factor when designing the end-uses of fabric as it is also a critical factor for purchasing decision. In the present study, the Kawabata Evaluation System for Fabrics (KES-F) was used for measuring the fabric handle of BTCA-TiO₂ treated cotton fabric with or without plasma pre-treatment. The results revealed that the BTCA-TiO₂ treated cotton fabrics without plasma pre-treatment had a negative effect on tensile, shearing, compressional, and surface properties while the bending properties were improved. On the other hand, the plasma pre-treatment improved the tensile and compressional properties, but not the bending, shearing, and surface properties.     

Superhydrophobic and Antibacterial Properties of Cotton Fabrics Treated with PVDF and nano-ZnO through Phase Inversion Process

Cotton fabrics exhibiting superhydrophobic and antibacterial properties were prepared through a non-solvent induced phase separation method using hydrophobic poly(vinylidene fluoride) (PVDF) and its hybrids with photocatalytic zinc oxide nanoparticles (nano-ZnO) as surface modifying agents for cotton fabric. The effects of coagulating medium and temperature on microstructural morphology and surface hydrophobictity of the cotton fabrics were investigated by FE-SEM observation and contact angle measurement. Superhydrophobic cotton fabrics exhibiting water contact angle higher than 150 ° could be obtained by coating the fabrics with solutions of PVDF and nano-ZnO followed by coagulation in ethanol as non-solvent. This phenomenon is considered to be originated from both chemically hydrophobic PVDF layer and physical micro- and nano-bumps formed on the surface of cotton fabric, which are essential requirements for Lotus effect. Moreover, antibacterial properties could be synergistically obtained by utilizing photocatalytic effect of nano-ZnO.     

Cotton fabric mechanical properties affected by post-finishing processes

Following the work done previously [1]. In this paper, the effect of various post-finishing agents on the low stress mechanical and surface properties of dyed cotton fabrics, as well as their handle value have been studied. The mechanical properties of the treated cotton fabrics were measured by the famous KES-FB system. It has been found that cotton fabric mechanical properties and fabric handle can be modified by not only the external finishing agents but also the internal finishing agents which are used for correcting the inherent defect of the fabrics. The results in this report will inform the textile industry in engineering required fabric properties with appropriate finishing processes.     

Mechanical properties of denim fabric reinforced poly(lactic acid)

Denim, a twilled cotton fabric, was used to enhance the mechanical and thermal properties of poly(lactic acid) (PLA). The denim fabric reinforced composites with different numbers of denim layers were fabricated by using a hand layup method. The impact, tensile, and dynamic mechanical properties of the composites were observed with increasing denim layers to examine the reinforcing effect of denim fabrics. Numerical analysis was carried out to model the elastic modulus of the composite by using a commercial software. Three-dimensional geometry of the denim fabric reinforced PLA composite was generated through a CAD program, and the elastic modulus was calculated by applying uniform deformation on one surface. The impact strength, tensile strength, and thermal properties of the composites were improved by piling denim fabrics. The denim fabric reinforced composites exhibited outstanding impact strength due to the retarded crack propagation as well as large energy dissipation. The 3 layer denim reinforced composite showed best results among all specimens, and its impact strength, tensile strength, and tensile modulus were measured to be 82 J/m, 75.76 MPa, and 4.65 GPa, respectively. The PLA/denim composites have good mechanical properties and can substitute traditional composites such as glass fiber or carbon fiber reinforced composites.     

The influence of corona discharge treatment on the properties of cotton and polyester-cotton knitted fabrics

In this study, the effect of corona discharge treatment on the physical and mechanical properties of bleached cotton and polyester-cotton fabrics were investigated. For this purpose, the samples were treated by corona discharge at two levels of voltage 5 and 10 kV, and at various duration times of plasma, ca. 1.4, 2.1 and 3.5 min. The corona discharge treatment was applied on the fabric samples before and after bleaching treatment. The results show that the corona influences on the surface morphology, breaking strength, air permeability, abrasion resistance, and pilling of cotton and polyester-cotton fabrics. Moreover, the levels of voltage and duration of plasma have a different effect on the properties of fabrics.     

Comparative study of cellulase treatment on low stress mechanical properties of cotton denim fabric made by torque-free ring spun yarn

Cellulase is useful for bio-polishing cotton fabrics which enhances their aesthetic performance instead of stonewashing process. Torque-free ring spun process is a widely used technique to produce newly low-twist and balanced torque yarns with soft hand. In this paper, denim fabrics woven with torque-free ring spun yarn and conventional ring spun yarn respectively were treated with cellulase under the same condition and their fabric handle, expressed as low stress mechanical properties, such as tensile strength, bending, shearing, compression and surface performance were investigated by Kawabata Evaluation System for Fabric (KES-F). After cellulase treatment, both denim fabrics revealed better flexibility, elasticity recovery, raised shearing stiffness, fluffier and improved smoothness. While torque-free ring spun yarn made denim fabric showed a better fabric handle than conventional ring spun yarn made denim fabric.     

Assessment of the surface roughness of cotton fabrics through different yarn and fabric structural properties

The effects of some yarn properties (i.e. type, count, twist level, ply number, unevenness and crimp) and fabric constructional properties (i.e. cover, thickness and balance) on surface roughness values of cotton woven fabrics were investigated. A general overview of the results showed that surface roughness values of fabrics were affected from yarn and fabric properties and the effects were related to fabric balance, fabric cover (not cover factor), fabric thickness and crimp values of yarns in fabric structures. Surface roughness values of fabrics decreased as yarn fineness and yarn twist levels increased but as yarn ply number decreased. Also, surface roughness values gradually decreased from open-end yarn constituting fabrics to combed yarn constituting fabrics. Results showed that different properties of yarns caused changes in yarn crimps in fabric structure and also governed the changes in fabric balance, as well as changes in roughness of fabric surfaces. The changing properties of yarns and impact of these properties on fabric construction affected the formation of cotton fabric surfaces from smooth to coarse.     

Effect of Silver Particle size on color and Antibacterial properties of silk and cotton Fabrics

In this study silver nanoparticles with different particle sizes and hence colors were synthesized on silk and cotton fabrics through reduction of silver nitrate. Particle sizes of the silver colloids were measured by dynamic light scattering (DLS). The structure and properties of the treated fabrics were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and UV-Vis reflectance spectroscopy. Various characteristics of the treated fabrics including antibacterial activities against a Gram positive (Staphylococcus aureus) and a Gram negative (Escherichia coli) bacteria, color effect, wash and light fastness, water absorption, fabric rigidity, and UV blocking properties were also assessed. The results indicated that the treated fabrics displayed different colors in the presence of silver nanoparticles with different particle sizes and exhibited good and durable fastness properties. Also, the size of the silver particles had a tangible effect on antibacterial activity of treated fabrics and its antibacterial performance was improved by decreasing the size of particles. Moreover, this process imparted significantly UV blocking activity to fabric samples.     

Polyester modification through synthesis of copper nanoparticles in presence of triethanolamine optimized with response surface methodology

In this paper, polyester fabric was modified through synthesis and fabrication of Cu/Cu₂O nanoparticles using a facile and cost-effective method at boil by chemical reduction through exhaustion route. Triethanolamine (TEA) was used for aminolysis of polyester fabric and pH adjusting, copper sulfate (CuSO₄) as metal salt, sodium hypophosphite (SHP) as reducing agent and polyvinylpyrrolidone (PVP) as stabilizer. A response surface methodology was also employed to optimize the reaction conditions and study the effects of SHP, PVP and TEA concentrations in the processing. The images of field-emission scanning electron microscopy (FESEM), the patterns of energy-dispersive spectroscopy (EDX) and X-ray diffraction (XRD) patterns confirmed successfully synthesis of Cu and Cu₂O nanoparticles on the polyester fabric. Further, the thermal behavior of the untreated and treated fabrics was studied by using thermogravimetric analysis (TGA) and differential scanning colorimetry (DSC). The treated fabrics indicated good properties regarding wettability and flame-retardant along with high tensile strength.     

The effect of biodegradable organic acids on the improvement of cotton ink-jet printing and antibacterial activity

In this study, various biodegradable organic acids with varying numbers of carboxylic acid groups were incorporated into the ink formulation both in the presence and absence of sodium hypophosphite (SHP) to investigate the colour yield and antibacterial properties. Ink-jet prints on cotton fabric, which were either pretreated (industry standard practice) or non-pretreated, were analyzed to determine if there is a significant difference in their properties. Antibacterial activities and dye fixation of printed cotton fabrics were also tested. The results indicated that at optimum pH, the non-pre-treated samples printed with ink formulations containing more carboxylic acid groups in their structure (BTCA) in the absence of SHP, demonstrated higher levels of reactive dye fixation and antibacterial properties than pre-treated samples containing no biodegradable organic acid in the ink formulation. The printed cotton fabrics with ink formulation that contained BTCA without dye were characterized by ATR-FTIR and thermogravimetric analysis (TGA) and their morphology was investigated through the use of SEM to determine if cross-linking had taken place.     

The effect of fabric balance and fabric cover on surface roughness of polyester fabrics

The effects of fabric balance and fabric cover on surface roughness values of textured polyester woven fabrics with different constructional parameters were investigated. The warp yarn properties (type, count and warp density) were kept constant while the effect of variation in weft yarn density and weave pattern were studied. Measurements were conducted on pre-treated white fabric samples and the results assessed in relation to their constructional properties. A general overview of the results showed that surface roughness values of polyester fabrics affected by fabric balance and fabric cover and the effects were related to fabric thickness, yarn densities, yarn crimp, positioning of yarns in fabric structure. A change in weave pattern from sateen to plain increased the fabric balance and fabric cover, but decreased the surface roughness. Similarly, an increase in weft density increased the fabric balance and fabric cover, but decreased surface roughness. In order to produce fabrics with smooth surface properties yarn density should be increased, yarn float lengths decreased, cover of fabrics increased and fabric balance improved.     

Preparation of electroconductive,magnetic, antibacterial,and ultraviolet-blocking cotton fabric using reduced graphene oxide nanosheets and magnetite nanoparticles

The main goal of present study was the fabrication of cotton fabric with special functions, including electrical conductivity, magnetic, antibacterial, and ultraviolet (UV) blocking. In this regard, the cotton fabric was primarily coated with graphene oxide and then reduction of graphene oxide and synthesis of magnetite nanoparticles accomplished in one step. The alkaline hydrolysis of magnetite precursors and reduction of graphene oxide was simultaneously performed using sodium hydroxide to produce reduced graphene oxide/Fe₃O₄ nanocomposite on the fabric surface. The prepared cotton fabrics were characterized with field emission scanning electron microscope (FE-SEM), X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS). The treated fabrics with reduced graphene oxide/Fe₃O₄ nanocomposite displayed a low electrical resistivity i.e. 80 kΩ/sq. Furthermore, the coated fabrics showed reasonable magnetic properties due to the presence of magnetite nanoparticles on the surface of cotton fabrics. Moreover, this process imparted proper antibacterial properties and UV blocking activity to cotton samples.     

A study of physical modification on grey cotton by laser irradiation

The surface morphology of the CO₂ laser treated grey cotton fabrics was studied which showed a characteristics sponge-like structure on cotton fibres after treating with CO₂ laser irradiation. The laser treatment parameters ranging from 100 to 150 pixel time and 40 to 70 dot per inch (dpi) were irradiated on the grey cotton fabrics directly and the degree of physical modifications, such as surface morphology, wettability and fabric strength, were changed accordingly with various laser treatment parameters. The surface morphology, wettability and tensile strength of cotton fibre treating with laser were evaluated using different instruments, such as Scanning Electron Microscope (SEM), contact angle meter and tensile strength machine. In spite of creating a sponge-like structure on fibre surface after treating with laser, the wettability of the samples was highly improved but the tensile strength was decreased.     

A comparative study of finer conventional and modified cotton yarns and their resultant woven fabrics

A modified ring spinning technique has been recently developed by incorporating false twisting devices into the conventional ring frame. Its application on the coarser yarn counts (7–32 Ne) showed notable advantages in modified yarn and fabric performance. More recently, it was noted that this technique can also be applied for producing finer cotton yarns. Thus this paper aims to carry out a systematic study of the physical properties of the finer modified yarns (80 Ne) and woven fabrics with respect to the conventional ones. Physical properties of conventional and modified single yarns were evaluated and compared. These two types of single yarn were used for the production of woven fabrics. Moreover, the above two types of single yarn were also plied and used for the production of woven fabrics under a commercial condition. All woven fabrics were assessed in terms of fabric tensile strength, tearing strength, abrasion resistance, fabric weight, and air-permeability as well as other fabric performance measured by the Kawabata Evaluation System (KES). Experimental results showed that finer modified yarns and fabrics exhibit higher strength, lower hairiness, and improved abrasion resistance, slightly better compression property, and smoother surface with relatively larger thickness.     

黄麻／棉织物服用性能探讨

本文通过试验测定了黄麻／棉织物的服用性能，并与苎麻／棉，涤／棉，纯棉等织物的服用性能进行比较，结论表明黄麻／棉织物作为服用织物是可行的。     

Influence of oxygen plasma pre-treatment on the water repellency of cotton fibers coated with perfluoroalkyl-functionalized polysilsesquioxane

Oxygen plasma pre-treatment was applied to cotton fabric with the aim of improving the water repellency performance of an inorganic-organic hybrid sol-gel perfluoroalkyl-functionalized polysilsesquioxane coating. Cotton fabric was pre-treated with low-pressure oxygen plasma for different treatment times and operating powers. Afterward, 1H,1H,2H,2H-perfluorooctyltriethoxysilane (SiF) was applied to the cotton fabric samples using the pad-dry-cure method. The surfaces of the untreated and modified cotton fibers were characterised using Fourier transform infrared spectroscopy, Xray photoelectron spectroscopy, scanning electron microscopy, and atomic force microscopy. The water repellency of the SiF-coated fabric samples was evaluated using static and sliding contact angle measurements with water. The results show that the plasma treatment with the shortest treatment time (10 s) and the lowest operating current (0.3 A) increased the atomic oxygen/carbon ratio of the cotton fiber surface from 0.6 to 0.8 and induced the formation of a nano-sized grainy surface. Increasing the plasma treatment time and/or operating current did not intensify the surface changes of the cotton fibers. Such saturation effects were explained by the large influence of reactive oxygen atoms during the plasma treatment. The measured static water contact angles on the surface of the untreated and plasma pre-treated and SiF-coated cotton fabrics showed that the oxygen plasma pre-treatment enabled the increase of the water contact angle from 135° to ≈150°, regardless of the applied plasma treatment time and discharge power. This improvement in the hydrophobicity of the SiF coating was followed by a decrease in the sliding angle of water droplets by more than 10° compared to the plasma untreated and SiF-coated sample characterized by a water sliding angle of 45°. Additionally, measurements of the water sliding angle revealed that the increase of the static contact angle from 149° to 150° corresponded to a drop of the water sliding angle from 33 to 24°, which suggests that the plasma pre-treatment of 20 s at an operating current of 0.3 A produced the best water-repellent performance of the SiF-coated cotton fabric.     

Flame-Retardant and Wear Comfort Properties of Modacrylic/FR-Rayon/Anti-static PET Blend Yarns and Their Woven Fabrics for Clothing

This study examined the flame retardant, anti-static, and wear comfort properties of woven fabrics from two types of yarns composed of modacrylic, FR-rayon, cotton, and anti-static PET fibers. The FR-rayon-blended modacrylic fabric mixed with anti-static PET fibers exhibited better flame-retardant and anti-static properties than those of the cotton-blended modacrylic fabric. In addition, the absorption and drying properties of the FR-rayon-blended modacrylic fabric were superior to those of the cotton-blended modacrylic fabric. The thermal conductivity of the FR-rayon-blended fabric was lower than that of the cotton-blended one, whereas the water vapor permeability was slightly higher than that of the cotton-blended one. These wear comfort properties of the FR-rayon-blended fabric were attributed to the micro-pores and longer fiber length of the FR-rayon fibers, as well as their yarn and fabric structural parameters. This study suggests that FR-rayon-blended modacrylic fabric has better flame-retardant and anti-static properties in both twill and rip weaves with good warmth keepability, and higher water and vapor transmission properties than cotton-blended one. In addition, the FR-rayon-blended modacrylic clothing exhibited a better wear comfort feel than the cotton-blended one due to the lower microclimate humidity. This means that FR-rayon-blended modacrylic fabric makes it more comfortable to wear than cotton-blended one.     

Self-decontaminating cotton fabrics based on photo-induced macromolecular radicals

Photoactive blend films consisting of sulfonated polyether ether ketone and polyvinyl alcohol were incorporated onto cotton fibers to prepare self-decontaminating cotton fabrics. Electron paramagnetic resonance (EPR) spectroscopy was used to confirm the free-radical nature of the photoactive film and the cotton fabric. Several physical and mechanical properties of the fabrics, such as surface morphology, tensile strength, softness, whiteness, and water vapor permeability, were investigated, and it was found that the treated cottons basically maintained the original performance. Moreover, favorable photo-induced self-decontaminating capabilities of the treated fabrics were demonstrated against three kinds of pollutants, including decomposition of 80.2 % diuron under UVA light irradiation for 3 hours, inactivation of 93.33 % of E.coli and 86.67 % of S.aureus, and degradation of 64.1 % methyl orange under the light irradiation for 1 hour.