Water sorption mechanisms of commercial wood adhesive films

As water moves inside the wood, the gluelines might act as barriers that are potentially leading to local moistening. Even low amounts of water may influence the mechanical performance of glued wood products. Dynamic vapor sorption analysis was performed to assess the sorption processes of six commercial wood adhesives. Vapor sorption isotherms were compared with vapor uptake dynamics. Phenol–resorcinol–formaldehyde showed high moisture uptake of 18 %, while vapor diffusion speed was low. Fish glue showed a water uptake of 45 % at otherwise moderate vapor uptake speed. Melamine–formaldehyde resin gained 22 % water, and polyvinyl acetate absorbed 10 %. The latter was also the fastest vapor absorbing adhesive. Polyurethane only absorbed 3.5 % of moisture at medium uptake speed. Mechanisms of water diffusion seem to be driven by (1) the available free volume in the polymer and (2) the interacting ionic groups of the polymer chain. While the free volume could be linked to the accumulated moisture, the ionic group interaction might determine the measured vapor diffusion dynamics.     

Finger-jointing green softwood: Evaluation of the interaction between polyurethane adhesive and wood

Existing European standards for finger-jointing of load-bearing lumber require the wood to be dried before gluing. This article presents a study on the properties of green-glued finger joints, wet wood being bonded prior to drying. Issues to consider, in comparison to finger-jointing of dry wood, are mechanical performance of the joint, absorption of the polymer by the wood in its natural/wet state, and the chemical reactions of the adhesive on contact with water. Finger-jointed samples were tested in bending, and the glue joints analysed by optical microscopy, scanning electron microscopy and microdensitometry. A patented one-component polyurethane adhesive developed for gluing-green wood which has a moisture content usually higher than 70% was used in the study. The resulting green-glued joints showed improved strength properties in comparison to dry-jointed joints. The results confirm that green-glued joints provide a wide, continuous wood/adhesive interface from one substrate to the other. The adhesive penetrates several cells deep and the density of the wood adjacent to the joint surfaces is increased. The results also indicate that the patented adhesive forms covalent bonds to the wood substrate.     

Finger-jointing green softwood: Evaluation of the interaction between polyurethane adhesive and wood

Abstract

Existing European standards for finger-jointing of load-bearing lumber require the wood to be dried before gluing. This article presents a study on the properties of green-glued finger joints, wet wood being bonded prior to drying. Issues to consider, in comparison to finger-jointing of dry wood, are mechanical performance of the joint, absorption of the polymer by the wood in its natural/wet state, and the chemical reactions of the adhesive on contact with water. Finger-jointed samples were tested in bending, and the glue joints analysed by optical microscopy, scanning electron microscopy and microdensitometry. A patented one-component polyurethane adhesive developed for gluing-green wood which has a moisture content usually higher than 70% was used in the study. The resulting green-glued joints showed improved strength properties in comparison to dry-jointed joints. The results confirm that green-glued joints provide a wide, continuous wood/adhesive interface from one substrate to the other. The adhesive penetrates several cells deep and the density of the wood adjacent to the joint surfaces is increased. The results also indicate that the patented adhesive forms covalent bonds to the wood substrate.     

Gluability of thermally modified beech (Fagus silvatica L.) and birch (Betula pubescens Ehrh.) wood

Abstract

One of the main disadvantages of wood is hygroscopicity resulting from its polar character. The sorption–desorption of water causes unwanted swelling and shrinkage in wood. Thermal modification substantially reduces this inconvenient feature. Unfortunately, the same chemical changes that reduce water sorption alter the polar character of the material and result in poorer wetting of thermally treated wood by waterborne adhesives. Gluability of thermally modified beech (Fagus silvatica L.) and birch (Betula pubescens Ehrh.) wood with two commercial amino resins, melamine–urea–formaldehyde (MUF) and melamine–formaldehyde (MF), and a two-component polyurethane (PUR) adhesive was investigated. Both wood species were modified according to two temperature regimes: 160°C and 190°C. Shear strengths of the joints were then determined according to EN 205:2003 standard. The results showed that thermally modified beech and birch wood can be effectively glued not only with commercially available PUR adhesives, but also with aqueous MF and MUF resins. The resultant shear strengths of the joints were limited by the strength of the thermally modified substrate.     

Improving the thermal stability of one-component polyurethane adhesives by adding filler material

The aim of the current study is to improve the thermal stability of one-component moisture-curing polyurethane adhesives. The approach here tends to add suitable filler materials to the adhesive and to study the resulting effects. The investigation covers mechanical tests to determine the shear strength of the glued wood joints according to EN 302-1 (2004). Furthermore, the distribution of the filler material within the adhesive is shown by means of environmental scanning electron microscopy combined with energy-dispersive X-ray spectroscopy analysis. The thermal stability of the glued wood joints could be significantly improved by adding chalk with a volume fraction of 30% to the adhesive.     

Mechanical behaviour of finger joints at elevated temperatures

Finger joints are commonly used to produce engineered wood products like glued laminated timber beams. Although comprehensive research has been conducted on the structural behaviour of finger joints at ambient temperature, there is very little information about the structural behaviour at elevated temperature. A comprehensive research project on the fire resistance of bonded timber elements is currently ongoing at the ETH Zurich. The aim of the research project is the development of simplified design models for the fire resistance of bonded structural timber elements taking into account the behaviour of the adhesive used at elevated temperature. The paper presents the results of a first series of tensile and bending tests on specimens with finger joints pre-heated in an oven. The tests were carried out with different adhesives that fulfil current approval criteria for the use in load-bearing timber components. The results showed substantial differences in temperature dependant strength reduction and failure between the different adhesives tested. Thus, the structural behaviour of finger joints at elevated temperature is strongly influenced by the behaviour of the adhesive used for bonding and may govern the fire design of engineered wood products like glued laminated timber beams.     

聚氨酯预聚体的合成及其在木材粘接领域的应用

本文研究了聚氨酯预聚体的合成工艺，测试了固化后的聚氨酯胶粘剂胶片的性能，讨论了分子结构对拉伸强度和伸长率的影响，同时进行了聚氨酯粘剂用于含水率木材粘接的试验，结果表明，具有线型结构的，高分子量的胶粘剂延伸性好，但拉伸强度稍低，聚氨酯胶粘剂可以用于高含水率木材的粘接。     

IMPRESSIONS OF FORESTRY IN SOUTHERN EUROPE

The bonding of wood by means of glue has been practised for many centuries.

Adhesion between an adhesive and wood is the result of unbalanced secondary valency forces (Van der Waal's forces) present on the interfaces. It is fundamental to good adhesion that the adhesive must (a) wet the surface it is required to adhere to and (b) penetrate the wood capillaries. The phenomenon of “wetting” is indicated by the contact angle the adhesive forms on the wood surface as well as its ability to penetrate the wood capillaries. Maximum penetration of the capillaries is inhibited in practice due to air becoming trapped in “inkpot” type capillaries caused by the sawblade tearing the wood fibres over in the direction of the cut. Several ways to increase capillary penetration are suggested.

The anisotropic chemical reactivity of wood is theorized in so far that a unit area of wood substance (excluding lumen openings) cut on the cross-sectional plane cannot be as effectively glued as a unit area of wood substance on the radial and tangential plane. This is due to the positioning of the chemically reactive groups on the cellulose chains which are predominantly oriented parallel to the fibre axis.

The engineered design of joints is briefly discussed and mathematical expression given as to how incorrect joint design can be detrimental to the ultimate joint strength.

The general character of the better-known synthetic adhesives is briefly discussed. Little detail is given as excellent hand books exist on this specific subject.     

Technological heterogeneity of adhesive bonds in wood joints

 Gluing of wood is among the most effective methods for the permanent joining of furniture elements or building woodwork manufactured from wood. Technological errors occurring during the preparation process of the glue material may lead to variations in the strength of adhesive/wood joints. The purpose of the described research project was to investigate the effect of the heterogeneity of the glue bond on the distribution of tangential stresses in furniture joints, especially the effect of gas cavities, faulty glue bonds and glue outflows on the distribution of tangential stresses in adhesive bonded overlap, cross and angle wood joints. Using developed numerical models, it was shown that shear stresses in bonds of cross and angle joints reach their maximum values in corners of joints. The torsion center of cross joints is situated in the geometrical center of the bond, while in angle joints – it is found half-way through the length of one of the perpendicular edges of the joint. It was also proven that gas cavities present in the glue bond contribute to increased stresses in the neighbourhood of the source of heterogeneity. This phenomenon initiates a process of de-cohesion and, hence, reduces the overall strength of the joint. Faulty gluing, similar to gas cavities, constitutes a potential source of stress-breaking processes and reduces the strength of joints. On the other hand, glue outflows present in wood bonds increase their strength by expanding the initiation threshold of fractures even in situations where technological heterogeneity of the glue bond occurs. In furniture constructions as well as in large-size building woodwork constructions or, wherever grace and elegance of the finished product is of lesser importance, glue outflows can be treated as a positive and desirable phenomenon. Received 13 March 1999     

Shear fracture characterization of green-glued polyurethane wood adhesive bonds at various moisture and gluing conditions

Abstract

The shear fracture properties of green-glued one-component polyurethane (PUR) wood adhesive bonds subjected to kiln drying were investigated. The local shear strength and fracture energy of the wood adhesive bonds were determined from experimentally recorded complete shear stress versus deformation curves of the bond line. A stable test set-up and small specimens that were anti-symmetrically loaded were used in order to get a uniform and pure state of shear stress. Different moisture contents (MCs) and pressing times were investigated. The fracture properties of conventionally dry-glued wood adhesive bonds and of solid wood were used as reference. The results show that the fracture energy of green-glued bonds with PUR adhesive is dependent on the MC of wood and on the pressing time. The same fracture energy and strength can be obtained by green gluing as by dry gluing, but there seems to exist a maximum MC of sapwood, in the range between 78% and 160%, and a minimum pressing time, in the range between 3 h and 48 h, for which it can be achieved. Both dry- and green-glued polyurethane adhesive bonds were more ductile than solid wood.     

Water vapour diffusion and adsorption characteristics of sugar maple (Acer saccharum,Marsh.) wood polymer composites

Summary Water vapour diffusion characteristics and adsorption isotherms were determined for cell-lumen and cell-wall treated wood polymer composites (WPC). The diffusion coefficients of the cell-lumen WPC were lower than untreated wood and the cell-wall WPC coefficients were lower than cell-lumen. Using the Hailwood and Horrobin sorption model, it was found that the unimolecular layer is formed at lower moisture contents in WPC than in wood. The amount of free dissolved water was reduced only in the cell-wall WPC. The polymer reduces the water vapour accessibility in both types of WPC.     

刨花板厚度方向变形研究Ⅱ.刨花板厚度方向变形模型的建立及释因

本文基于我们以往所做的众多的实验事实 ,从刨花板厚度方向的结构出发 ,全面考虑影响刨花板厚度膨胀率的因素 ,经过论证和筛选 ,建立了刨花板厚度膨胀率的方程模型 :TS(t) =F(t) f(M .C ,t) V(t) ,即刨花板的厚度膨胀率主要取决于人造板内木材的粘弹变形恢复、人造板内木材的吸湿膨胀和胶接点破坏引起的变形 ;当刨花板的含水率存在较大变化时 ,需再加上机械吸附蠕变项A(M .C ,t)     

木材导热系数的研究

本文运用非平衡态热力学线性理论分析了含水率在纤维饱和点以下木材的传热,结果表明木材中的水蒸汽和束缚水参与了传热,木材导热系数由传导导热系数与因水蒸汽和束缚水扩散产生的两个等效导热系数组成。推广Siau关于木材细胞的导热理论,依据水分吸附和扩散的原理,导出了木材弦向和径向导热系数计算公式,与已发表的36种气干材弦向实验值和23种气干材径向实验值符合较好。分析木材径向传热的方法也适用于木材纵向传热。     

Strength performance of mortise and loose-tenon furniture joints under uniaxial bending moment

We determined the effects of adhesive type and loose tenon dimensions （length and thickness） on bending strength of T-shaped mor- tise and loose-tenon joints. Polyvinyl acetate （PVAc） and two-component polyurethane （PU） adhesives were used to construct joint specimens. The bending moment capacity of joints increased significantly with increased length and thickness of the loose tenon. Bending moment capacity of joints constructed with PU adhesive was approximately 13% higher than for joints constructed with PVAc adhesive. We developed a predictive equation as a function of adhesive type and loose tenon dimensions to estimate the strength of the joints constructed of oriental beech （Fagus orientalis L.） under uniaxial bending load.     

A novel method for monitoring real-time curing behaviour

A new method for monitoring real-time curing behaviour of adhesives by means of a rheometer is presented. This method was developed within a study to characterize the curing behaviour of MUF adhesives on beech and ash, both with and without coloured heartwood, as well as on Douglas fir and spruce. During closed assembly time, the decrease in a predefined adhesive layer, caused by the penetration of adhesive and solvents into the wood, can be monitored. Furthermore, the progress of curing can be determined and assessed after predefined closed assembly times. The maximum tensile force and the dissipated energy required for separating assembled adherends allow for characterizing hardening of adhesive systems. First results suggest that this is a promising method contributing to a better understanding of the curing process and how it is influenced by wood species.     

Strength of profile-adhesive joints

The current article presents an attempt to describe the strength of profile-adhesive joints. Its main objective was to develop mathematical models describing phenomena occurring in bent mortise joints prevalent in constructions of skeleton furniture, but also to determine factors influencing the strength of profile-adhesive joints. The presented cases of gluing of a mortise joint reveal that mutual interactions of compressed wood surfaces influence significantly the strength of the developed node. In extreme cases, when a glue bond fails to form on surfaces of elements, the strength of the joint will depend only on the compression strength of wood. That is why, despite the impairment of the adhesive bond, the construction will still be able to carry considerable outside loads. However, the best situation is when well fitted elements of the joint, compressing one another, reduce stresses in the glue bond and increase its strength above the value of outside loads exceeding greatly the shear strength of the glue. Received 1 November 1999     

ACQ防腐处理对马尾松木材胶合强度的影响研究

采用铜氨(胺)季铵盐(ACQ-D)防腐剂处理马尾松木材,以水性高分子异氰酸酯(API)、聚氨酯(PUR)和间苯二酚-苯酚-甲醛树脂(RPF)为胶黏剂制备防腐材胶合试样,研究胶黏剂种类和防腐剂处理浓度对马尾松胶合强度的影响。结果表明:API、PUR、RPF适用于ACQ处理马尾松的胶合,平均剪切强度和木破率均达到GB/T 26899—2011《结构用集成材》要求。胶黏剂种类对防腐材胶合强度有显著影响,表现为PUR和RPF的剪切强度优于API。与未处理材相比,ACQ处理对API胶合有负面影响,对PUR胶合有增强效应,对RPF胶合没有显著影响。在ACQ浓度为0.1%～1.0%范围内,胶合强度没有显著变化。     

Characterising Gluing Properties of Lodgepole Pine Containing Beetle-Transmitted Bluestain

In the article, with the instruments of the Research Institute of Wood Industry, Chinese Academy of Forestry, the experiment method of Forintek Canada Corp. was used to test the laminating of lodgepole pine containing beetle-transmitted bluestain; finally the result was compared with Canada report. The results show that the presence of glue joints of bluestained wood made with either PVA or PRF adhesive makes no difference to the shear strength of the joints, and no difference to durability of the joints using PRF. Also the presence of beetle-transmitted bluestain in wood does not affect the adherence of the interior finishes tested.     

水基聚氨酯胶粘剂在集成材生产中的应用

讨论了水基聚氨酯木材胶粘剂的反应机理和影响其胶接性能的主要因素，进行了ＳＲ－１００木材结构胶制备集成材的应用试验。结果表明：该胶用于针叶材云杉和阔叶材水曲柳、榆木、柞木，所制得集成材的粘接性能达到结构用集成材的指标要求，为生产结构集成材提供技术依据。     

Influence of growth ring angle,adhesive system and viscosity on the shear strength of adhesive bonds

Abstract

To investigate the influence of growth ring angle, adhesive system and viscosity on the bonding properties of adhesive bonds, shear tension tests according to DIN EN 302-1 (2004) were conducted using one-component moisture-curing polyurethane, polyvinylacetate and urea-formaldehyde. Significant differences between the systems could be detected, which were reflected in the predominant failure behaviour for each system. Specimens showing wood failure were influenced mainly by the wood factors, whereas samples which had failed in the adhesive part of the bond differed only in the adhesive properties. The growth ring angle showed the same tendencies as it does in plain wood. Therefore, to gain more information on the adhesive performance in the bond, a loading along the LT plane seems more appropriate for beech wood used in DIN EN 302-1 (2004).