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1.
The synthesis of poly(norbornene ester)s by using a (η 3-substituted allyl) palladium (N-heterocyclic carbene (NHC)) complex as catalyst was performed and the relationship between chemical structure and glass transition temperature or refractive index of poly(norbornene ester)s was investigated. Norbornene ester monomers were synthesized via esterification of 5-norbornene-2-methyl alcohol and aromatic carboxylic acids. The polymerization catalyst, (η 3-substituted allyl) palladium (NHC) complex, was synthesized according to a published procedure. 1H-NMR spectroscopy was performed to determine chemical structure of monomers and polymers. The molecular weight of the polymers was measured via gel permeation chromatography and the thermal properties were analyzed via thermogravimetric analysis and dynamic mechanical analysis. Refractive indices of polymer films were measured using a prism coupler. Polymers with the highest M n (between 100 kg/mol and 300 kg/mol) were synthesized when the ratio of monomer to catalyst was 2000:1. The glass transition temperature of synthesized polymers was about 100 °C lower than that of conventional norbornene polymers. Among the six polymers of different chemical structures, four polymers exhibited a refractive index of 1.6 or more at a wavelength in the visible light region.  相似文献   

2.
The effect of chemical treatment i.e. bleaching, alkalization and graft copolymerization on the morphology changes of okra bast fiber has been investigated by means of infrared spectroscopy (IR), scanning electron microscopy (SEM), water absorption and tensile properties measurements. The graft copolymerization reaction of bleached fiber with acrylonitrile monomer (AN) has been carried out under the catalytic influence of K2S2O8 and FeSO4 redox system. The maximum graft yield (11.43 %) has been found at 70°C temperature, 3×10−2 mol/l acrylonitrile, 5×10−3 mol/l K2S2O8, 5×10−3 mol/l FeSO4 and for 90 min. On the contrary, the fiber has been treated with 10 % NaOH solution, which is much effective to remove the impurities. Based on findings of water absorption, tensile properties and SEM micrograph, the AN-grafted fiber has been showed better properties than bleached and alkali treated fibers. The degree of modification of okra bast fiber by chemical treatment has been evaluated by IR measurement.  相似文献   

3.
Polypropylene (PP) fibers with a sorbital derivative nucleating agent (SDN) and rare earth aluminates (SrAl2O4:Eu2+,Dy3+) were prepared via melt compounding and melt-spinning. Non-isothermal crystallization kinetics and luminescence properties of PP and luminous PP fibers were studied by differential scanning calorimetry (DSC), polarized optical microscopy (POM), and decay of the afterglow test. The crystallization temperature determined by DSC increased with the addition of the nucleating agent during the cooling process from 200 °C. The Jeziorny model successfully described the non-isothermal crystallization behavior of the luminous PP with various SDN contents. The crystal grain size and morphology of the sample with the SDN was different from that without nucleating agent. The luminous PP fabric having high initial brightness intensity, approximately 461 mcd g-1m-2, can be prepared with addition of 10 wt% of rare earth aluminates and 0.5 % of SDN.  相似文献   

4.
We describe an experiment where cattle urine was applied at a rate of 420 kg N ha−1, equivalent to 10 L m−2, to mesocosm swards of a high lipid genetically modified perennial ryegrass line (HME) and its wild type (WT). We measured N pools and fluxes in the plant and soil, soil microbial populations and N2O production. HME plants produced 21% greater biomass than WT (p = .02), resulting in greater N uptake (27% higher in HME, p = .05). Urine N recovery in total plant biomass during the experiment in HME and WT swards were 54.7% and 33.9% respectively. The nitrification potential of soil was significantly lower (p = .01) in HME than WT. Partial least square-discriminant analysis using microbial gene abundance data indicated that HME and WT plant growth induced distinct microbial populations in the soil. These differences in plant soil microbial interactions between HME and WT swards resulted in significantly lower N2O emissions from the HME sward. Total N2O emissions over the 4 weeks after urine application was 38% lower (p < .03) in HME swards than in WT swards. The next step in this work is to identify the specific changes in HME traits that drive the reduction in N2O.  相似文献   

5.
Effluent lagoons on dairy farms can overflow and potentially pollute adjacent land and associated water bodies. An alternative solution to effluent disposal is needed by dairy operators in island environments. An attractive win‐win alternative is to recycle nutrients from this resource through effluent irrigation for forage grass production that minimizes environmental pollution. This study assessed biomass production and nutrient removal by, and high application rates to, tropical grasses that were subsurface drip‐irrigated with dairy effluent. Four grass species – Banagrass (Pennisetum purpureum K. Schumach.), California grass (Brachiaria mutica (Forssk.) Stapf.), Stargrass (Cynodon nlemfuensis Vanderyst) and Suerte grass (Paspalum atratum Swallen) – were subsurface (20–25 cm) drip‐irrigated with effluent at two rates based on potential evapotranspiration (ETp) at the site (Waianae, Hawaii) ?2·0 ETp (16 mm d?1 in winter; 23 mm d?1 in summer) and 0·5 ETp (5 mm d?1 in winter; 6 mm d?1 in summer). Treatments were arranged in an augmented completely randomized design. Brachiaria mutica and P. purpureum had the highest dry‐matter yield (43–57 t ha?1 year?1) and nutrient uptake especially with the 2·0 ETp irrigation rate (1083–1405 kg ha?1 year?1 N, 154–164 kg ha?1 year?1 P, 1992–2141 kg ha?1 year?1 K). Average removal of nutrients by the grasses was 25–94% of the applied nitrogen, 11–82% of phosphorus and 2–13% of the potassium. Average values of crude protein (90–160 g kg?1), neutral detergent fibre (570–620 g kg?1) and acid detergent fibre (320–360 g kg?1) were at levels acceptable for feeding to lactating cattle. Results suggest that P. purpureum and B. mutica irrigated with effluent effectively recycled nutrients in the milk production system.  相似文献   

6.
Graft copolymerization of granular allyl starch with carboxyl-containing vinyl monomers using H2O2/Fe2+ initiator in aqueous dispersion was investigated for enhancing grafting efficiency of the copolymerization. The graft copolymerization was evaluated in terms of grafting efficiency, grafting ratio, and conversion of monomer to polymer. Influences of both allyl etherification of starch and structures of vinyl monomers used on the copolymerization were revealed. Variables such as molar ratio of Fe2+ to H2O2, initiator concentration, monomer concentration, polymerization temperature, and time of the graft copolymerization were also studied. It was found that allyl etherification of starch enhanced the grafting efficiency and grafting ratio evidently. Acrylic acid exhibited the greatest grafting efficiency and ratio for the copolymerization after starch was allyl-etherified. The copolymerization should be carried out under the protection of nitrogen gas at 30–35 °C for 3 h by using H2O2/Fe(NH4)2(SO4)2 as initiator. Preferred molar ratio of H2O2/Fe(NH4)2(SO4)2/anhydroglucose was in a range of 20/1/1000 to 60/3/2000.  相似文献   

7.
以33个不同玉米基因型为材料,在低磷和高磷两个供磷水平下,分析玉米基因型磷效率与多个相对根系性状的关系,建立最优回归方程。结果表明,相对总根重和相对须根数对磷效率的回归系数显著,建立磷效率与相对总根重和相对须根数二者的最优回归模型为Y=-0.224-0.576X2+1.780X3,R2=0.880(p<0.05);相对表层根重对磷效率的回归系数显著,建立磷效率与相对表层根重的最优回归模型为Y=-0.235+1.136X1,R2=0.653(p<0.05);相对须根数和相对表层根重可以作为培育高磷效率玉米基因型的改良目标性状。  相似文献   

8.
《Plant Production Science》2013,16(4):352-364
Abstract

In this study, a deterministic algorithm named Ensemble Square Root Filter (EnSRF), an algorithm significantly improved from the Ensemble Kalman Filter (EnKF), was used to integrate remotely sensed information (ASD spectral data, HJ-1 A/B CCD and Landsat-5 TM data) with a wheat (Triticum aestivum L.) growth model (WheatGrow). The analyzed values of model variables, leaf area index (LAI) and leaf nitrogen accumulation (LNA), were calculated based on EnSRF without perturbed measurements. Independent datasets were used to test EnSRF and the root mean square error (RMSE) values were 0.81 and 0.82 g m-2, with relative error (RE) values of 0.15 and 0.13, for LAI and LNA, respectively. RMSE values for LAI and LNA were 1.39 and 1.70 g m-2, respectively (RE, 0.28 and 0.34) based on EnKF, 1.17 and 1.80 g m-2 (RE, 0.24 and 0.35), respectively, based on the WheatGrow model alone, and 0.97 and 1.25 g m-2 (RE, 0.21 and 0.24), respectively, based on the remote sensing models. These results indicated that the LAI and LNA values based on EnSRF matched the measured values well compared with the EnKF, WheatGrow and remote sensing models. In addition, the predicted results are consistent with the temporal and spatial distribution of winter wheat growth status and grain yields in the study area, with RE values of less than 0.2 and 0.1 for LAI and LNA, respectively. These results provide an important approach for simulating winter wheat growth status based on combining remote sensing and crop growth models.  相似文献   

9.
The ability of inherently conducting polymer (ICP) coated textiles to recover gold metal from aqueous solutions containing [AuCl4] was investigated. Nylon-lycra, nylon, acrylic, polyester and cotton were coated with a layer of polypyrrole (PPy) doped with 1,5-naphthalenedisulfonic acid (NDSA), 2-anthraquinonesulfonic acid (AQSA) orp-toluenesulfonic acid (pTS). Textiles coated with polyaniline (PAn) doped with chloride were also used. The highest gold capacity was displayed by PPy/NDSA/nylon-lycra, which exhibited a capacity of 115 mg Au/g coated textile, or 9700 mg Au/g polymer. Varying the underlying textile substrate or the ICP coating had a major effect on the gold capacity of the composites. Several ICP coated textiles recovered more than 90% of the gold initially present in solutions containing 10 ppm [AuCl4] and 0.1 M HCl in less than 1 min. Both PPy/NDSA/nylon-lycra and PAn/Cl/nylon-lycra recovered approximately 60% of the gold and none of the iron present in a solution containing 1 ppm [AuCl4], 1000 ppm Fe3+ and 0.1 M HCl. The spontaneous and sustained recovery of gold metal from aqueous solutions containing [AuCl4] using ICP coated textiles has good prospects as a potential future technology.  相似文献   

10.
Plantain chips were produced from unripe plantain fruits.The chips were packed in polyethylene bags and stored at30 ± 2 °C for 1, 2 and 3 months, respectively.The storage stability of the chips was evaluated by analyzing periodically for changes in the physicochemical,microbiological and sensory characteristics. Protein andash contents of the chips did not change (p > 0.05) overtime. Fat decreased slightly (p > 0.05) over time. VitaminC decreased and was negatively correlated with storagetime (r = –95; p < 0.05). Peroxide value and microbialcount increased with storage (p < 0.05). Sensory scoresfor chips did not change (p > 0.05) at 2 months storage,but, thereafter, decreased (p < 0.05).  相似文献   

11.
Low molecular weight copolymers of maleic anhydride and vinyl acetate were prepared to develop formaldehyde free cross-linking agents. Since lower molecular weight is favorable for efficient penetration of the finishing agent into the cotton fibers in the padding process, the concentration of the initiator, chain transfer agent and the monomer ratios were varied to obtain copolymers of low molecular weights. The prepared polymers were characterized by GPC,1H-NMR, FTIR, DSC and TGA. Copolymers of molecular weights of 2 000 to 10 000 were obtained and it was found that the most efficient method of controlling the molecular weight was by varying the monomer ratios. Poly(maleic anhydride-co-vinyl acetate) did not dissolve in water, but the maleic anhydride residue hydrolyzed within a few minutes to form poly(maleic acid-co-vinyl acetate) and dissolved in water. However, the maleic acid units undergo dehydration to form anhydride groups on heating above 160 °C to some extent even in the absence of catalysts. The possibility of using the copolymers as durable press finishing agent for cotton fabric was investigated. Lower molecular weight poly(maleic anhydride-co-vinyl acetate) copolymers were more efficient in introducing crease resistance, which appears to be due to the more efficient penetration of the crosslinking agent into cotton fabrics. The wrinkle recovery angles of cotton fabrics treated with poly(maleic anhydride-co-vinyl acetate) copolymers were slightly lower than those treated with DMDHEU and were higher when higher curing temperatures or higher concentrations of copolymer were used, and when catalyst, NaH2PO2, was added. The strength retention of the poly(maleic anhydride-co-vinyl acetate) treated cotton fabrics was excellent.  相似文献   

12.
Seabuckthorn (Hippophae rhamnoides L.) is uniquely capable of growing well under various extreme environmental conditions, such as water deficit, salt stress, low temperature, and high altitude. It is of economic value and its berries are used in cosmetics and pharmaceutical products. In this study, we compared the effects of salt stresses (9:1 molar ratio of NaCl to Na2SO4, pH 6.48–6.65) and alkali stresses (9:1 molar ratio of NaHCO3 to Na2CO3, pH 8.70–8.88) on the levels of inorganic ions and organic acids in H. rhamnoides L. to elucidate the physiological mechanism by which it tolerates salt or alkali stress (high pH). The results showed that, in leaves and stems under alkali stress, the Na+ content increased to a much greater extent than under salt stress. Neither salt nor alkali stress decreased the K+ content in leaves and stems; however, in roots, the K+ content decreased sharply with increasing alkali stress, whereas it remained relatively unchanged with increasing salt stress. This revealed a specific mechanism of absorption or transport for Na+ and K+ that was affected strongly by alkali stress. The results indicated that accumulation of organic acid (OA) was a central adaptive mechanism by which H. rhamnoides maintained intracellular ionic balance under alkali stress. OA may play different roles in different organs during adaptation to alkali stress, and its percentage contribution to total negative charge was higher in leaf than in stem. H. rhamnoides accumulated mainly malate, oxalate, and citrate in leaves and stems; however, in roots, less malate and citrate was accumulated, and acetate accumulation was enhanced significantly, which indicated that roots and shoots use different mechanisms to modulate OA metabolism.  相似文献   

13.
Hail affects yield and quality of maize crops, and consequences also depend on the growth stage at which the injury occurred. Whole‐plant maize (WPM) silage is often used within the same farm for cattle feeding and biogas production. The present study aimed to verify the effects of hail damage, simulated by artificial defoliation, on yield and chemical and nutritional features, as well as on biochemical methane potential (BMP) of maize forage. In a randomized block design with three replicates, four defoliation levels (0%, 33%, 66% and 100% of leaf area removal respectively) have been applied at either the V12 (12th leaf), R1 (silking) or R3 (milk) stages for two consecutive years. WPM yield, chemical and nutritional features, and BMP were measured. Dry‐matter (DM) yield per hectare was progressively reduced (p < 0.001) with increasing levels of defoliation and with application at V12 in comparison with R1 or R3 (1.26 vs. 1.39 and 1.46 kg ha?1 for V12 vs. R1 and R3; p < 0.003). Nutritive value and BMP per unit of product were less altered than dry‐matter yield per hectare by defoliation. Anticipating defoliation reduced net energy for lactation (5.26 vs. 5.46 MJ kg?1 DM for V12 and R3 respectively; p = 0.02). Total defoliation resulted in an accumulation of nitrates (NO3) compared to the other treatments (3.98 vs. 1.53 g NO3 kg?1 DM; p < 0.001). BMP was mainly reduced by early and complete defoliation. Equations were developed to estimate the effects of defoliation on yield, composition, and nutritive and energetic values of WPM.  相似文献   

14.
Adequate seed production is essential for cultivar success in perennial ryegrass turf and forage industries, but improvement is limited by the complexity of yield components and low-rank correlations between selection and production environments. This study examined seed yield components among 20 perennial ryegrass entries in both spaced plantings (selection environment) and swards (production environment) at two locations in Minnesota. Competitive (23 plants/m2) and non-competitive (3 plants/m2) spaced-plant nurseries were tested. Competitive spaced-plant total yield was highly correlated with sward yield (rs = 0.64 and 0.66, p < 0.01) at both locations, whereas the non-competitive environment showed no correlation. Structural equation modelling (SEM) was used to explore the indirect and direct relationship of fall vegetative growth, winterkill, and yield components on total seed yield in all environments. Fertile tiller number (spikes plant−1/m−2) exhibited both strong direct and indirect influence on total seed yield in all environments. However, the importance of fertile tiller number in the SEM was reduced with increased plant competition. The SEM showed that both weight per spike and seed yield per spike influenced total yield in spaced plants; however, neither consistently predicted total sward yield. The ratio of these two traits (g seed spike−1/g spike−1) gave an index of fertility that was easy to measure and had a superior correlation with sward yield at two locations (rs = 0.81 and 0.54, p < 0.05) when spaced plants were under competition. Results suggest that increasing competition in spaced plantings and selecting for spike fertility may more accurately identify superior plant material compared to lower competition environments.  相似文献   

15.
As the challenges toward increasing water for irrigation become more prevalent, knowledge of crop yield response to water can facilitate the development of irrigation strategies for improving agricultural productivity. Experiments were conducted to quantify maize yield response to soil moisture deficits, and assess the effects of deficit irrigation (DI) on water productivity (water and irrigation water use efficiency, WUE and IWUE). Five irrigation treatments were investigated: a full irrigation (I1) with a water application of 60 mm and four deficit treatments with application depths of 50 (I2), 40 (I3), 30 (I4), and 20 mm (I5). On average, the highest grain yield observed was 1008.41 g m?2 in I1, and water deficits resulted in significant (p < .05) reduction within range of 6 and 33%. This reduction was significantly correlated with a decline in grain number per ear, 1000-grain weight, ear number per plant, and number of grain per row. The highest correlation was found between grain yield and grain number per ear. The WUE and IWUE were within range of 1.52–2.25 kg m?3 and 1.64–4.53 kg m?3, respectively. High water productivity without significant reduction in yield (<13%) for I2 and I3 compared to the yield in I1 indicates that these water depths are viable practices to promote sustainable water development. Also, for assessing the benefits of irrigation practices in the region crop water production functions were established. Maize yield response to water stress was estimated as .92, suggesting the environmental conditions are conducive for implementing DI strategies.  相似文献   

16.
The free radical solution polymerization of acrylonitrile (AN) with itaconic acid (IA) or methyl acrylate (MA) was carried out in dimethylsulfoxide (DMSO) using 2 2'-azobisisobutyronitrile (AIBN) as the initiator. Based on the monomer conversion versus time data, the copolymerization rate was retarded by IA but promoted by MA. The monomer sequence distribution was characterized by 13C NMR to explain the significant difference in the copolymerization kinetics of the ANIA and AN-MA copolymers. The results of the copolymer composition curves and 13C NMR spectral analysis illustrated that the penultimate model was suitable for describing the copolymerization behavior of AN-IA, and the terminal and penultimate models were adequate for AN-MA. The penultimate reactivity ratios, r MA , were ~2 times higher than r IA , indicating that the reactivity of AN-terminated radical having MA as the preceding group was higher than that with IA. Then, the corresponding content of triads sequence AN-AN-AN (AAA) in the AN-MA copolymers was higher than those in the AN-IA copolymers. The appearance of new resonance signals of the quaternary and methyl carbon indicated a higher content of IA in copolymers. The higher IA concentrations the lower viscosity-average molecular weight of the polymers. The decrease in the molecular weight was correlated to the formation of the oligomers.  相似文献   

17.
CO2浓度升高对玉米叶片光合生理特性的影响   总被引:3,自引:0,他引:3  
以沈糯3号为研究材料,利用开顶式气室(OTCs)法研究了二氧化碳(CO2)浓度升高处理下,玉米叶片叶绿素含量、光合生理特性及其子粒产量的变化,揭示CO2浓度升高对玉米光合生理特性及子粒产量的影响机理。结果表明,在整个生育期内,与对照相比,高浓度CO2处理下,玉米叶片叶绿素a、叶绿素b及叶绿素(a+b)的含量增加,而叶绿素a/b的值则先升高后降低;在整个处理期间,净光合速率均高于对照(p>0.05),升高幅度为12.6%~71.1%,气孔导度低于对照(p>0.05),其降低幅度为2.9%~18.8%。处理至抽雄期和灌浆期,胞间CO2浓度分别增加152%和161%,均极显著高于对照(p<0.01);蒸腾速率的变化较小。高浓度CO2处理下,玉米穗粒数和穗粒重均明显高于对照(p<0.05)。CO2浓度升高在一定程度上促进了玉米的光合作用,从而使玉米子粒产量增加。  相似文献   

18.
Maize was harvested at one‐third milk line (297 g kg?1 DM) stage. All inoculants were applied at 1 × 106 cfu g?1 of fresh forage. After treatment, the chopped forages were ensiled in 1·5‐L anaerobic jars. Three jars per treatment were sampled on days 2, 4, 7, 12 and 90 after ensiling, for chemical and microbiological analysis. Homofermentative LAB‐inoculated silages had lower pH and higher lactate:acetate ratio (except for Lactobacillus plantarum/Pediococcus cerevisiae and L. plantarum/Propionibacterium acidipropionici) than the control and both heterofermentative LAB‐inoculated silages. Both L. buchneri inhibited yeast growth and CO2 production during exposure of silage to air. The L. plantarum/P. cerevisiae, L. plantarum (Ecosyl) and L. plantarum/Enterococcus faecium‐inoculated silages had higher dry‐matter digestibility than the control and L. buchneri‐inoculated silages. Inoculants did not affect digestibility of neutral detergent fibre, except for L. buchneri (Biotal), organic matter nor ME content of silages. The LAB silage inoculants generally had a positive effect on maize silage characteristics in terms of lower pH and shifting fermentation toward lactate with homofermentative LAB or toward acetate with L. buchneri. The use of L. buchneri can improve the aerobic stability of maize silages by the inhibition of yeast activity.  相似文献   

19.
The effects of shredding forages on the density and fermentation quality of the resulting silages were studied. Lucerne (Medicago sativa L.), red clover (Trifolium pratense L.), perennial ryegrass (Lolium perenne L.) and a grass–clover mixture were harvested and wilted indoors for 1–2 days. The dry‐matter content of the forages after wilting was 192 g/kg, 192 g/kg, 237 g/kg and 214 g/kg respectively. The forages were then either unprocessed or shredded once (1×) or four (4×) times using a novel laboratory shredder and were ensiled in laboratory‐scale silos. Fermentation was terminated after either 50 or 113 days of ensiling. Density and the fermentation weight losses of the silages were recorded. Initial density of the silages was considerably increased with increased intensity of shredding (p < 0.01). The initial density (DM basis) of the 4× shredded silages ranged from 177 to 236 kg DM/m3 whereas it was 124–163 kg DM/m3 in non‐shredded silages. The 4× shredded silages had the greatest fermentation weight loss at day 1 of ensiling (p < 0.01). Overall fermentation weight loss after 113 days of ensiling was reduced in the 4× shredded silages (p < 0.01). Shredding increased L‐lactate concentration and reduced pH of the silages (p < 0.01). The NH3 concentrations were reduced by 25%–46% in 4× shredded silages and butyrate concentrations were reduced by 76%–97% in shredded silages in comparison to non‐shredded silages (p < 0.01). Shredding improved initial density and fermentation quality of silages while reducing overall fermentation weight losses.  相似文献   

20.
A database containing 140 articles published in journals (731 treatment means evaluated) was used to examine the effect of different lactic acid bacteria (LAB) on fermentation, chemical composition and aerobic stability of maize (corn) silage. Compared with the control, dry matter (DM) loss increased by 8% and 50% (p < .01) due to inoculation of maize silage with either homolactic LAB (hoLAB) or heterolactic LAB (heLAB). In vitro DM digestibility of maize silage increased only with hoLAB inoculation (+2.22%; p < .01). The heLAB inoculation increased (p < .01) the aerobic stability of maize silage by 71.3 hr. To investigate the effect of silage inoculation on livestock production, a second database comprising 35 articles [99 treatment means evaluated based on results from 648 cattle (429 beef cattle and 219 dairy cows) and 298 sheep] was used. Inoculation of maize silage with either hoLAB or heLAB did not affect milk yield (p > .05), but their combination (mixLAB) depressed milk yield (–2.5 kg/day; p < .01). Inoculation with hoLAB increased DM intake in sheep (+0.15 kg/day; p = .02), but decreased it in beef cattle (–0.26 kg/day; p = .01) without affecting average daily gain for both sheep and beef cattle (p ≥ .06). In conclusion, fermentative loss increased regardless of the bacterial inoculant used, while aerobic stability increased mainly by using heLAB. Benefits from hoLAB inoculation on animal performance were noted only for feed intake in sheep, while productive performances of dairy cows and beef cattle were not improved.  相似文献   

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