Damping and layer configuration in wood veneer composites

The aim of the present study was to find and describe the relationship between damping properties and both the number of layers and the fiber orientation in wood-veneer-composite specimens. The testing apparatus was a simple torsional pendulum in which the frequencies of the resulting free vibrations were maintained between 13 and 23 Hz. Cross-sectional (30 × 30 mm) specimens with a total length of 250 mm were used. The specimens were cut from manufactured wood-veneer-composite panels (both 0°/90° and 0°/0° oriented) with up to 13 layers. Existing problems such as nonlinearities, which are often responsible for weighting results, were taken into account by using several mathematical approaches. The results led to a consistent picture of the damping properties across the measured range. We found that the damping ratio increased for the 0°/90° orientation with increasing numbers of layers in a cross-sectional specimen of constant outer dimensions. This effect could not be reproduced for specimens oriented 0°/0°.     

On the loss factor of wood during radio frequency heating

 The radial direction loss factor of full-size western hemlock sapwood and heartwood, as well as western red cedar heartwood timbers was measured using the direct calorimetric method with a laboratory-scale radio frequency/vacuum dryer at the frequency of 13.56 MHz, moisture content range between 10 and 80%, temperature range between 25 and 55 °C, and root mean square (rms) electrode voltages of 0.8 and 1.1 kV, respectively. The results indicated that the moisture content, temperature, electric field strength and wood type significantly affected the loss factor. Empirical regression equations were derived based on the experimental data that made possible the calculation of the loss factor and power density within wood during RF heating. Received 18 January 1997     

Dielectric properties of softwood species at microwave frequencies

Summary Dielectric measurements at 3 GHz were made for three softwoods, European pine, spruce and hemlock. The longitudinal, radial and tangential grain directions of the wood were considered as well as moisture contents ranging from 6% to 35%. The positive effect of the moisture content on the loss factor illustrates the selectivity of microwave drying techniques, while the observations also show that the longitudinal dielectric properties are substantially higher than the transverse ones. The specific effect of the wood species on the dielectric behaviour has to be ascribed mainly to those intrinsic characteristics of the species which influence the sorptive capacity of the wood.     

Dielectric properties of hardwood species at microwave frequencies

Dielectric measurements at 9.8GHz and 2.45GHz were made for the three hardwoods Euramerican hybrid poplar, alder, and oriental beech. The method used was based on Von Hippels transmission line method. The measurements were carried out at room temperature of 20°–24°C. The dielectric properties of the wood species were determined for the three principal structural directions at six different moisture conditions, covering the range of 0% to 28% moisture content. Results indicated that the behavior of all wood species studied is quantitatively similar. In general, the dielectric properties increase within the range studied with rising moisture content. The grain direction of the wood also plays a significant role.     

Stress-strain state of wood at kiln drying

Summary A model has been suggested which allows the calculation of stresses arising in kiln drying and humidification of wood, as well as the total residual strain, i.e. set strain _s, consisting of purely residual strain _r and the so-called frozen strain _f. Frozen strains arise under the operating influence of loading when the stiffness is increased because of a decrease in moisture content (or temperature) of the wood. The process of formation of set strains _s has been shown to depend on the history of loading, variations of the moisture content of the wood, as well as cooling of the section before the measurement of _s. The possibility of using set strain as a parameter of the state of stress of wood in kiln drying has been noted.Presented at the VIII. International Symposium on Fundamental Research of Wood. Warsaw, Poland, October 1990     

Torsional-shear stress of wood at various temperatures

Summary The maximum torsional-shear stress of 5 softwoods and 4 hardwoods were tested in the radial and tangential planes. These tests were carried out in glycerin which was preheated to different temperatures between 22°C and 150°C, inclusively. The dense hardwoods possess 2.4 times higher shear stress than softwoods at 22°C. However, at elevated temperatures, the same degree of shear stress reduction (77 %) is obtained for hardwoods and softwoods in both radial and tangential failure. Thus, the reduction in shear stress is independent of physical and structural wood variables.     

A literature-based study on the loss tangent of wood in connection with mechanical pulping

In mechanical pulping, wood is dynamically loaded, which causes large heat losses due to wood viscoelasticity. The heat losses depend on the loss tangent (tan δ) of wood. The loss tangent has a temperature-dependent behaviour, especially in the lignin glass transition region. The glass transition softens wood, and is therefore necessary for gentle mechanical pulping, but at the same time, the loss tangent shows a maximum called the α-peak. The transient peak depends on temperature, loading frequency and moisture content. The temperature where the peak is found can be lowered with chemical treatments, but they also increase the magnitude of the peak. Thermal treatment in the presence of water also increases the magnitude. The loss tangent of wood depends, amongst other things, on the chemical structure of lignin, width of cellulose crystals, microfibril angle, and extractives in the cell wall.     

The viscoelasticity of wood at varying moisture content

Wood is regarded as a viscoelastic material. Creep deformations that arise from variations in the moisture content are described by a theory of hydroviscoelasticity developed by the author. Two different types of behaviour have been apparent: one, arising from a continuously increasing strain with periodic variation in the moisture content, and another with no cumulative effect. The theory has been applied to previously published experimental results concerned with beech, pine, hoop pine, klinki pine, along with birch and spruce plywood. Birch and spruce plywood have been used for experiments concerned with periodically-cycling bending moment and moisture content. The results obtained have been compared with the theory presented. Glue-laminated beams have been subjected to long-term outdoor loading extending for five years. A brief discussion is given of the results obtained.     

Chemical emissions from adhesive-bonded wood products at elevated temperatures

Pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) was employed to examine the chemical emissions from the glued wood samples at elevated temperatures (150, 200, 250, 300, 350, 400, 450, and 500°C). Two wood species, Douglas-fir (Pseudotsuga menziesii) and southern pine (Pinus palustris), one structural adhesive, phenol–resorcinol–formaldehyde (PRF), PRF-bonded Douglas-fir, and PRF-bonded southern pine were evaluated. The volatile compounds with a mass range of 35–300 m/z emitted from the pyrolysis samples were separated by gas chromatography (GC) and identified by mass spectrometry (MS). The results indicated that compared to neat wood and resin film samples, several additional pyrolysis products were observed for the PRF-bonded wood samples including (1) acetaldehyde and butanedial for PRF-bonded Douglas-fir and (2) acetaldehyde, furfural, 2-furanmethanol, butanedial, 2,3-butanedione, cyclopropyl carbinol, 1,2-benzenediol, and 1-(acetyloxy)-2-propanone for PRF-bonded southern pine. These additional compounds were possibly associated with the interaction between wood and PRF resin. The results also indicated that bonded wood products would be less thermally stable than those of neat wood and PRF resin samples.     

Isotropy at the center of a cylindrical wood pole

Summary This paper studies the title problem on the basis of the consideration of the generalized plane deformation of a cylindrically aeolotropic body.

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Zusammenfassung Die vorliegende Studie beschäftigt sich mit der Frage der Isotropie im Zentrum einer geraden zylindrischen Säule aus Holz. Zugrundegelegt ist die Annahme der grundsätzlich ebenen Verformung eines zylindrischen anisotropen Körpers.

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The authors wish to express their sincere appreciation to Dr. E. R. Mark, Department of Forestry, University of Kentucky, Lexington, Kentucky. This problem was encountered in some of his research project under the sponsorship of the McIntire-Stennis Cooperative Research Program of the U.S. Department of Agriculture.     

Measurements of compression creep of wood at humidity changes

Summary Uniaxial compression creep tests of tubular spruce specimens loaded in uniaxial compression are reported. The relative humidity in the interior of the tube is varied in a controlled manner. The results indicate that creep is greatly increased in magnitude by simultaneous humidity changes of either sign.Thanks are due to Dr. John Zahn of Forest Products Laboratory, Madison, Wisconsin, for various helpful advice, as well as for arranging the manufacture of test specimens in his laboratory. Thanks are also due to Forest Products Laboratory of the U.S. Department of Agriculture, Madison, Wisconsin, for funding a large part of this work under subcontract FP-81-0389.     

Determination of optimum borate concentration for alleviating strength loss during heat treatment of wood

Based on the already established mitigating potentials of borate salt on the negative effects of heat treatment on the strength properties of wood (Awoyemi and Westermark 2005), the optimum concentration of the alkali buffer solution required to minimize strength loss was determined. Wood samples were impregnated with 0.1, 0.3 and 0.5 M sodium borate solution and exposed to heat treatment for 4 h at 200°C. The mitigating effect of borate salt on the degree of strength loss during heat treatment increases significantly with increasing concentration from 0.1 to 0.3 M. Increasing the concentration of sodium borate from 0.3 to 0.5 M did not produce significant differences in the degree of strength loss during heat treatment. The increase in the buffering effect observed with increasing concentration of the sodium borate preservative is more pronounced on the modulus of rupture than on the modulus of elasticity. It is evidenced therefore that the buffering effect of borate salt on the modulus of elasticity of wood exposed to heat treatment did not start significantly until the 0.3 M concentration is reached and further increase in concentration beyond this point did not produce any appreciable improvement in strength properties.     

Stress relaxation of wood at several levels of strain

Summary Stress relaxation tests were performed with six tropical American species. Stress relaxation was not found to be a linear function of strain at any level of strain. At qual low levels of strain, stress relaxation in compression was much greater than in tension.A mechanical model consisting of an isolated spring in parallel with a spring and dashpot in series was used as an aid in the derivation of equations describing stress relaxation.An attempt to apply Newtonian viscous theory to the model was unsuccessful in accounting for rate of relaxation. However, when the hyperbolic sine law of viscous flow was applied, mathematically derived curves fitted the data very well.Stress relaxation appears to be related to departure strain which may be obtained readily from static stress strain diagrams.

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Zusammenfassung Versuche über die Spannungsrelaxation wurden mit sechs tropischen Holzarten Amerikas durchgeführt. Es erwies sich, daß die Spannungsrelaxation nicht in jedem Bereich der Dehnung eine lineare Funktion dieser Dehnung ist. In vergleichbar niedrigen Dehnungsbereichen zeigte sich zum Beispiel, daß die Spannungsrelaxation bei Druck größer ist als bei Zugbeanspruchung. Mit Hilfe eines mechanischen Modells, bestehend aus einer einzelnen Feder in Parallelschaltung zu einer Feder mit Dämpfungselement wurden Gleichungen zur Beschreibung der Spannungsrelaxation abgeleitet.Der Versuch die Newtonschen Viskositätsgesetze auf dieses Modell anzuwenden, schlug aufgrund der Relaxationsgeschwíndigkeit fehl. Bei Anwendung des hyperbolischen Sinussatzes für viskoses Fließen stimmten jedoch die ermittelten Werte recht gut mit den mathematisch berechneten Kurvenwerten überein.Die Spannungsrelaxation scheint mit der sogenannten Anfangsdehnung zusammenzuhängen, wie man sie stets bei statischen Spannungs-Dehnungsschaubildern erhält.

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A condensation of a dissertation submitted to the faculty of the Yale School of Forestry as partial fulfillment of the requirements of the D. For. degree.

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This research is part of a comprehensive study being conducted at the Yale School of Forestry in cooperation with the Office of Naval Research, Department of the Navy, under Contract Nonr 609 (13), Project NR 330-001, Properties of Tropical Woods. The author acknowledges the fellowships granted by the Organization of American States, and the Instituto Nacional de la Investigación Científica de México. The author wishes to thank Professor Frederick F. Wangaard for his counsel and assistance, and Professors Robert M. Kellogg and Robert P. Vreeland for encouragement and assistance.     

Constitutive equation of wood at variable humidity and temperature

Summary Theoretical analysis of the effects of variations in moisture content and temperature on the creep of wood is presented. Thermodynamics of the processes of diffusion of water in wood microstructure is discussed and distinction is drawn between macrodiffusion and microdiffusion. The constitutive relation for steady states of moisture content and temperature is formulated on the basis of Maxwell chain model whose viscosity coefficients depend on moisture content and temperature. It is shown that the apparent acceleration of creep due to simultaneous drying (or wetting) as well as heating (or cooling) may be modeled as additional, stress-induced shrinkage (or swelling) and stress-induced thermal expansion (or contraction), described by shrinkage and thermal expansion coefficients that depend on the absolute values of the rates of pore humidity and temperature. Certain other sources of irreversibility of creep are also discussed.Thanks are due to Forest Products Laboratory of the U.S. Department of Agriculture, Madison, Wisconsin, for funding a large part of this work under subcontract FP-81-0389. Thanks are also due to John J. Zahn, research engineer from this laboratory and the subcontract monitor, for his numerous valuable discussions during the progress of the work.     

Changes in wood properties at the boundary of polyporus amarus decay pockets

Summary Incense cedar heartwood infected by the pocket rot fungus Polyporus amarus was subjected to microtensile testing and miscroscopical examination to determine effects of this fungus upon wood substance adjacent to advanced decay pockets. Although springwood of the annual ring nearest the decay pocket in some samples had a slightly lower tensile strength than springwood from the same ring but a distance from the pocket, the difference was not statistically significant. Microscopical examination revealed the presence of small, sparse bore holes and hyphae in approximately the same number inside and outside the advanced decay pockets, and in discolored regions of incipient decay. A few bore holes and hyphae were found in specimens from what was macroscopically considered to be sound wood. Polarized illumination revealed no evidence of diffusion of cellulolytic enzymes from the hyphae in regions other than within advanced decay pockets, but the small numbers of hyphae and bore holes observed in decay pockets indicated that considerable enzyme diffusion might be necessary for decay to procede. The data suggest that possible alteration of physical, mechanical, and chemical properties in wood substance surrounding decay pockets need not be a significant factor for consideration in utilization of pecky incense cedar.

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Zusammenfassung Kernholz von Zeder (Libocedrus decurrens), das von Polyporus amarus befallen worden war, wurde Mikro-Zugfestigkeitsprüfungen und einer mikroskopischen Durchmusterung unterworfen. Es sollten die Auswirkungen dieses Pilzbefalles auf jene Teile der Holzsubstanz geprüft werden, die unmittelbar an die Befallsstellen angrenzen. Das Frühholz eines Jahrringes, das einer Befallsstelle am nächsten lag, zeigte zwar bei einigen Proben eine geringfügig niedrigere Zugfestigkeit als das Frühholz desselben Jahrringes, das aber von der Befallsstelle weiter entfernt lag. Die Unterschiede waren jedoch statistisch nicht signifikant. Die mikroskopische Durchmusterung deckte das Vorhandensein von kleinen, etwas zerstreut liegenden Bohrlöchern und Hyphen auf, in etwa gleichgroßer Anzahl innerhalb und außerhalb der Stellen fortgeschrittenen Befalls und in den verfärbten Bereichen des beginnenden Befalls. Einige wenige Bohrlöcher und Hyphen wurden ferner in Proben festgetsellt, die bei makroskopischer Betrachtung gesund erschienen. Im polarisierten Licht ließ sich keine Diffusion von aus Hyphen stammenden celluloitischen Enzymen außerhalb der Befallsbereiche beobachten. Die wenigen Hyphen und Bohrlöcher, die in den Befallsstellen beobachtet werden konnten, gaben aber einen Hinweis darauf, daß bei der Ausbreitung eine beträchtliche Enzymdiffusion stattfinden muß. Die ermittelten Werte weisen darauf hin, daß die möglicherweise eintretende Änderung der physikalischen, mechanischen und chemischen Eigenschaften des Holzes in unmittelbarer Umgebung der Befallsstellen als wichtige Faktoren bei der Verarbeitung dieses Holzes beachtet werden müssen.

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Presented at the 1968 Forest Products Research Society Annual Meeting.     

Mechanical behaviour of saturated wood under compression Part 2: Behaviour of wood at low rates of strain some effects of compression on wood structure

Summary The mechanical behaviour of three species of hardwoods, soaked in different liquids, had been investigated at high rates of strain using a Hopkinson pressure bar system. In order to determine the influence of the rate of strain, samples from the same species were subjected to compression-tests at low rates of strain. It was noticed that, at low rates of strain, the saturated samples were always less stiff than the dry ones, which is in agreement with the literature, but differs from the behaviour at high rates of strain. This difference is attributed to the behaviour of the liquid present in the large cavities of the material, which must depend on the rate of strain. It was also noticed that the samples could support higher stresses at high rates of strain. Although permanent sets were measured after the tests, the samples were not always visibly damaged, but some typical failures were detected by means of microscopy. The damaged zones presented similar aspects, whatever the rate of strain.     

Pathogenicity of the pine wood nematode at different developmental stages

The ability of the pine wood nematode,Bursaphelenchus xylophilus, a pathogen that causes pine wilt disease, to kill cortical cells of Japanese black pine,Pinus thunbergii, during early development of the disease was conjectured to be a function of nematode developmental stage. A tangential segment of bark was removed from a 2-cm-long current-year stem. The cortex-exposed segments with cut cortical resin canals were designated as + RC-segments and those without them as − RC-segments. When a nematode population containing many older juveniles and adults (NL) was inoculated onto the cut surface, the − RC-segments were still alive 4 d after inoculation, as were non-inoculated control segments. When cortex-exposed segments were inoculated with either a nematode population containing many younger nematodes (NS) or with nematodes isolated from inoculated pine cuttings that also contained many younger juveniles, most tissue cells in − RC-segments died 4 d after inoculation, suggesting that younger juveniles killed pine cells directly, in contrast with older juveniles and adults. When nematodes were inoculated onto + RC-segments in which they could easily enter resin canals, both NL and NS killed the segment tissues. This suggests that NL is pathogenic to pine cells while living in resin canals. Such differences in the pathogenicity of NL and NS to pine parenchymatous cells were also demonstrated in a pathogenicity assay system using bark peelings, which allowed an estimate of direct attack on the cambial cells by nematodes. Based on these results, we hypothesize that younger juveniles are pathogenic to pine parenchymatous cells, while adults and older juveniles are not pathogenic. This work was supported in part by Grants-in-Aid for Scientific Research (No.01440012 and 06454088) and for Young Scientists (to K.I.) from Ministry of Education, Science, Culture, and Sports of Japan, and by a grant from PROBRAIN.     

Influence of inorganic matter on wood pyrolysis at gasification temperature

The influence of inorganic matter on the pyrolysis of Japanese cedar (Cryptomeria japonica) wood was studied at a gasification temperature of 800°C with demineralization through acid washing. Some influences on the formation of char, tar, and low molecular weight products coincided with results reported at temperatures lower than the gasification temperature. However, the carbonization behavior of the volatile products and the yield of polysaccharide fraction were not able to be explained as a sum of the pyrolysis of cellulose, hemicellulose, and lignin even after demineralization. These results suggest some interactions between wood constituent polymers other than the influence of inorganic matter.