Hydrolytic enzyme activities in agricultural and forest soils. Some implications for their use as indicators of soil quality

Although a great deal of information exists about the effect of land use on soil enzyme activities, much of this is contradictory and brings into question the suitability of soil enzyme activities as indicators of how land use affects soil quality. The purpose of this study was to investigate the effect of land use on different soil biochemical properties, especially hydrolytic enzyme activities, with the aim of providing knowledge about the problems related to the use of enzymes as indicators of soil quality. The data presented derive from various studies in which a large number of soils under different types of forest or agricultural management were analysed by the same methods. All of the soil samples were characterized in terms of their main physical and chemical properties, the activity of several hydrolases, microbial biomass C and soil basal respiration. The results indicate that soil use causes a large reduction in organic matter content and that the effect on enzyme activity varies depending on the type of land use or management and the type of enzyme. Furthermore, the enzyme activities per carbon unit (specific activities) in soils affected by land use are almost always higher than in maximum quality soils (climax soils under oak vegetation or oak soils), and land use also generates greater increases in the specific activity as the C content decreases. The mechanism responsible for these increases probably involves loss of the most labile organic matter. Enzyme enrichment is not always produced to the same degree, as it varies as a function of the enzyme and the type of land use under consideration. It is concluded that the complexity of the behaviour of the soil enzymes raises doubts about the use of enzyme activities as indicators of soil degradation brought about by land use.     

Estimation of nitrogen and phosphorus losses to surface water and groundwater through the implementation of the SWAT model for Norwegian soils

Scope and Background

It is acknowledged that diffuse sources cause the most important nitrogen (N) and phosphorus (P) losses to the river system and substantially enrich the groundwater in nitrates. These losses arise primary from agricultural activities mainly fertilizer applications, and they are determined by soil attributes. In cold climates, winter conditions and freezing of soils may influence the infiltration capacity of the soil and thereby can have a serious effect on the partitioning of excess precipitation and subsequently on the soil and nutrient transportation. The purpose of this article is to investigate the behaviour of six widespread and different textured soil types, on nutrient (N, P) losses under cold climate conditions. The investigation was conducted in the Norwegian Vansjø-Hobølv catchment through the application of a physical model named Soil and Water Assessment Tool (SWAT), taking into consideration the additional aspect of freezing soils during winter, which distinguishes Scandinavian from other European soils.

Methods

SWAT is a physical river basin model that was developed for the U.S.D.A. Agricultural Research Service, by the Blackland Research Center in Texas. In the current modeling approach the catchment was divided into 43 Hydrologic Response Units (HRUs) which consist of different combinations of the existed landcover and soil types. Nitrogen and phosphorus losses arising from these HRUs were estimated for the period 1990–2001 through the simultaneous simulation of water and sediment processes that are closely linked to the nutrient processes. The model took into account soil temperature in order to quantify water and nutrient transport to deeper layers, considering negligible downward movement when the soil temperature was under 0°C. It also simulated the aboveground development of the snowpack and the snowmelt processes on a daily basis. The six different soil types were distinguished in two groups according to their similarity in texture and other physical properties, one group of fine-textured soils and a group of coarse soils. The results were evaluated for different crop cultivations (barley, oats and wheat) of the aforementioned soils. Finally, the model was calibrated and validated by comparing predicted results with measured data.

Results and Discussion

Fine-textured soils caused significant runoff, sediment, total nitrogen (TN) and total phosphorus (TP) yields to the river system while coarser soils were characterized by high water drainage and nitrates leaching. The first soil group caused a mean of 517 mm of runoff in annual basis, 200 mm higher than this arising from coarse soils. Moreover, 3 tonnes of sediments per hectare, 24.6 kgN/ha and 0.54 kgP/ha were lost annually to surface water from fine soils while the average respective losses originating from coarse soils were only 1.3 tn of sediments/ha, 13.6kgN/ha and 0.17kgP/ha. The sensitivity ranking of the soil types to TN and TP losses was silty-clay-loam>silty-loam>clay>loamy>sandy-loam>sandy. An average of 277 mm of water was percolated annually under the bottom of the soil profile in coarse soils causing the additional leaching of 5.6 kgN-NO₃/ha whereas the losses originating from fine-textured soils were 153 mm and 2.5 kg/ha respectively. According to their sensitivity in nitrates leaching, the six soil types were ranked in the following order: sandy>loamy>sandy-loam>silty-loam>silty-clay-loam>clay.

Conclusions and Perspectives

The results showed that even though under cold climate conditions, with monthly periods of average air-temperatures below zero, the overall amounts of annual TN and TP losses to surface waters as well as nitrates leaching to groundwater were considerable. This demonstrates that the cold climate conditions did not affect the long-term behavior of the six widespread Norwegian soils, which on an annual basis responded similarly to the respective European soils. According to the model’s estimations, infiltration with N and P transport still occur in wintertime, and comparing to other studies that reported similar results, different possible explanations were considered. The results demonstrate the need of considering the soil differentiation in Scandinavian countries similarly to the rest of Europe in order to apply mitigation measures against nitrogen and phosphorus losses to surface and groundwater.

     

Influence of biomineralization on the physico-mechanical profile of a tropical soil affected by erosive processes

Most of the soils of tropical countries are affected by erosion processes. As a result, much attention has been dedicated to the use of microorganisms to improve the geotechnical properties and stability of soils in the context of “bioengineering”. This work was carried out to analyze the effects of the use of a CaCO₃ precipitating nutrient on native microbiota with the aim of mitigating the erosion processes in a tropical soil profile. We observed that the use of nutrient B4 enabled native bacteria present in the soil to precipitate calcium carbonate, resulting in improvements in the physical, chemical, mineralogical and mechanical properties of the soil, which allowed the mitigation of the erosion processes that characterize the soil profile studied.     

Relationships between rock fragment cover and soil hydrological response in a Mediterranean environment

Rock fragments are a key factor for determining erosion rates, particularly in arid and semiarid environments where vegetation cover is very low. However, the effect of rock fragments in non-cultivated bare soils is still not well understood. Currently, there is a need for quantitative information on the effects of rock fragments on hydrological soil processes, in order to improve soil erosion models. The main objective of the present research was to study the influence of rock fragment cover on run-off and interrill soil erosion under simulated rainfall in Mediterranean bare soils in south-western Spain. Thirty-six rainfall simulation experiments were carried out at an intensity of 26.8 mm h⁻¹ over 60 min under three different classes of rock fragment cover (<50%, 50–60% and >60%). Ponding and run-off flow were delayed in soils with high rock fragment cover. In addition, sediment yield and soil erosion rates were higher in soils with a low rock fragment cover. The relationship between soil loss rate and rock fragment cover was described by an exponential function. After this first set of experiments, rock fragments were removed from sites with the highest cover (>60%) and the rainfall simulation experiments were repeated. The steady-state run-off rate and soil loss increased significantly, showing that run-off and soil erosion were partly conditioned by rock fragment cover. These results have significant implications for erosion modelling and soil conservation practices in areas with the same climate and soil characteristics.     

Validating the effectiveness and sensitivity of two soil quality indices based on natural forest soils under Mediterranean conditions

Soils from natural ecosystems have specific physical, chemical and biochemical properties determined by the conditions in which these soils have developed. These soils that develop without external disturbance reach a balance amongst their properties. Thus, the creation of a model that represents the established balance of different soil properties from stable ecosystems can be used as a soil quality index, thus any perturbation must lead to modifications in this natural balance. Two regression models with soils from undisturbed forest regions in eastern Spain were previously developed, representing the balance between organic carbon and some physical, chemical and biochemical properties. For undisturbed forest soils, the prediction of soil organic carbon (SOCc) with the calibrated models should be similar to the actual value of this variable (SOCa) (SOCc ≈ SOCa). Consequently, the residuals (SOCc − SOCa) should be around 0. On the contrary, disturbance practices cause a disruption in the balance defined between the different properties and SOC. As a consequence, residuals must be < or >0. Furthermore, the more the degree of degradation increases, the more the values of SOCc must differ from the values of SOCa. According to this, two soil quality indices (SQI) were defined, one for each model, by the calculation of the model residuals (SQI = SOCc − SOCa). The SQIs have been applied to different undisturbed forest soils to evaluate their validity. In addition, they have also been applied to severely altered soils, like agricultural soils, and abandoned agricultural fields, to assess the sensibility of this index to perturbations. After applying the soil quality indices to eleven undisturbed forest soils, it has been verified that a balance exists between organic matter content and different physical, chemical and biochemical properties in forest soils from SE Spain, and the proposed calibrated models are capable of reflecting that balance (SQI ≈ 0). Our results confirm that our models are sensitive to soil perturbation, because agricultural and abandoned agricultural soils have shown an imbalance between organic carbon content and the physical, chemical and biochemical properties (SQI > 0). Moreover, soils from abandoned fields showed lower deviation in the natural equilibrium, indicating a recovery of soil quality.     

A method for predicting soil susceptibility to the compaction of surface layers as a function of water content and bulk density

Identifying the vulnerability of soils to compaction damage is becoming an increasingly important issue when planning and performing farming operations. Soil compaction models are efficient tools for predicting soil compaction due to agricultural field traffic. Most of these models require knowledge of the stress/strain relationship and of mechanical parameters and their variations as a function of different physical properties. Since soil compaction depends on the soil's water content, bulk density and texture, good understanding of the relations between them is essential to define suitable farming strategies according to climatic changes. In this work we propose a new pedotransfer function for 10 representative French soils collected from cultivated fields, a vineyard and forests. We investigate the relationship between soil mechanical properties, easily measurable soil properties, water content and bulk density. Confined compression tests were performed on remoulded soils of a large range of textures at different initial bulk densities and water contents. The use of remolded samples allowed us to examine a wide range of initial conditions with low measurement variability. Good linear regression was obtained between soil precompression stress, the compression index, initial water content, initial bulk density and soil texture. The higher the clay content, the higher the soil's capacity to bear greater stresses at higher initial water contents without severe compaction. Initial water content plays an important role in clayey and loamy soils. In contrast, for sandy soils, mechanical parameters were less dependent on initial water content but more related to initial bulk density. These pedotransfer functions are expected to hold for the soils of tilled surface layers, but further measurements on intact samples are needed to test their validity.     

基于离散元的西北旱区农田土壤颗粒接触模型和参数标定

为了解决利用离散元法模拟土壤作业过程在预测农具阻力和土壤动态运动时存在失真等问题,整合延迟弹性模型(hysteretic spring contact model,HSCM)和线性内聚力模型(liner cohesion model,LCM)优势建立西北旱区农田土壤模型,以不同参数(静摩擦系数、动摩擦系数和内聚强度)组合下仿真得到的土壤仿真堆积角为响应值,基于Box-Behnken试验法建立回归模型,并根据该回归模型进行了参数预测并验证,对17组土壤仿真堆积角方差分析表明:静摩擦系数、动摩擦系数、动摩擦系数和抗剪强度的交互项、动摩擦系数的二次项对仿真堆积角的影响极显著;静摩擦系数和动摩擦系数的交互项、静摩擦系数的二次项对仿真堆积角的影响显著。使用预测的参数进行6种不同含水率土壤直接剪切仿真和试验对比可知,当含水率为1%~20%时,仿真与试验间的抗剪强度相对误差为1.18%~9.31%,仿真与试验间的内摩擦角相对误差为0.55%~4.07%。对仿真和试验鸭嘴插入阻力数据进行分析可知,仿真与试验曲线在入土距离处于0~50 mm期间时,但仿真入土阻力曲线波动较大,仿真和试验阻力走势基本一致,玉米直插穴播最深处50 mm处的仿真和试验入土阻力相对误差为0.928%,可利用此时的入土阻力分析直插鸭嘴结构对强度的影响。     

基于VG-PENG收缩特征曲线与收缩各向异性的裂隙率估算模型

为量化农田裂隙发育程度,考虑脱湿过程中土壤孔隙在基质域、沉降域和裂隙域间转化,该研究提出基于土壤收缩特征和收缩各向异性的裂隙体积比率(裂隙率)关于含水率的预测模型。该模型包括3个子模型:改进VG型式的基质域收缩特征VG-PENG模型,描述收缩各向异性的几何因子Logistic模型,基于上述VG-PENG收缩特征模型和几何因子模型的裂隙率预测模型。通过土壤收缩试验和裂隙演化监测试验,采用图像处理技术提取裂隙数据,评价了该模型的优度及适用性。结果表明,VG-PENG收缩模型具有较好的连续性和明确的物理意义,可精确描述土壤收缩特征(R~20.98);该研究引入Logistic曲线描述土壤收缩几何因子,揭示了收缩过程中土壤横向开裂和纵向沉降的各向异性机理,提出了脱湿初期纵向沉降(几何因子趋近1)、中期主沉降-副开裂(几何因子处于1～3之间)、后期趋于稳定3个阶段,Logistic模型可精确描述收缩几何因子随含水率变化;基于VG-PENG收缩模型和Logistic几何因子模型,构建了裂隙率关于含水率的演化模型,该模型呈"S"型曲线,取决于土壤收缩属性及其各向异性特征,裂隙率模拟值和实测值吻合较好,呈显著水平(R~20.90,P0.001)。该研究裂隙率预测模型修正了土壤收缩各向异性在裂隙率估算中造成的误差,并突破性地将VG-PENG收缩特征曲线进一步推演并应用于裂隙率模拟,可方便、快捷地通过土壤收缩数据预测农田裂隙率随含水率演化规律,为膨缩土裂隙流研究提供理论依据和参数基础。     

侵蚀引起的苏南坡地土壤退化

Soil erosion accelerates soil degradation. Some natural soils and cultivated soils on sloping land in southern Jiangsu Province, China were chosen to study soil degradation associated with erosion. Soil erosion intensity was investigated using the ¹³⁷Cs tracer method. Soil particle-size distribution, soil organic matter (OM), total nitrogen (TN) and total phosphorus (TP) were measured, and the effects of erosion on soil physical and chemical properties were analyzed statistically using SYSTAT8.0. Results indicated that erosion intensity of cultivated soils was greater than that of the natural soils, suggesting that cultivation increased soil loss. Erosion also led to an increase of coarser soil particle proportion, especially in natural soils. In addition, silt was the primary soil particle lost due to erosion. However, in cultivated fields, coarser soil particles over time were attributed not only to soil erosion but also to mechanical eluviation as a result of farming activities. Moreover, erosion caused a decrease in soil OM, TN and TP as well as thinning of the soil layer.     

Isolating the effect of soil properties on agricultural soil greenhouse gas emissions under controlled conditions

Agricultural soils are important sources of greenhouse gases (GHGs). Soil properties and environmental factors have complex interactions which influence the dynamics of these GHG fluxes. Four arable and five grassland soils which represent the range of soil textures and climatic conditions of the main agricultural areas in the UK were incubated at two different moisture contents (50 or 80% water holding capacity) and with or without inorganic fertiliser application (70 kg N ha⁻¹ ammonium nitrate) over 22 days. Emissions of N₂O, CO₂ and CH₄ were measured twice per week by headspace gas sampling, and cumulative fluxes were calculated. Multiple regression modelling was carried out to determine which factors (soil mineral N, organic carbon and total nitrogen contents, C:N ratios, clay contents and pH) that best explained the variation in GHG fluxes. Clay, mineral N and soil C contents were found to be the most important explanatory variables controlling GHG fluxes in this study. However, none of the measured variables explained a significant amount of variation in CO₂ fluxes from the arable soils. The results were generally consistent with previously published work. However, N₂O emissions from the two Scottish soils were substantially more sensitive to inorganic N fertiliser application at 80% water holding capacity than the other soils, with the N₂O emissions being up to 107 times higher than the other studied soils.     

Biochars improve aggregate stability,water retention,and pore‐space properties of clayey soil

The influence of biochar amendments on the physical quality of a clayey soil (Vertisol) was evaluated by aggregate‐size distribution and stability, water retention, and pore‐space structure of biochar‐amended soils. Clayey soil was treated with three kinds of biochars (straw biochar, woodchips biochar, and wastewater‐sludge biochar) at the rate of 0, 20, 40, and 60 g biochar (kg soil)^–1 and incubated for 180 d in glasshouse. The application of straw biochar (SB) and wastewater‐sludge biochar (WSB) significantly enhanced the formation of 5–2 and 0.25–0.5 mm macroaggregates in the clayey soil relative to the control treatment, while the < 0.25‐cm microaggregate decreased with biochar additions. However, woodchips biochar (WCB) had no obvious effect on the formation of macroaggregate. The application of SB and WSB increased the mean weight diameter (MWD) and geometric mean diameter (GMD) of clayey soil, implying that biochar increased the aggregate stability. They improved the aggregate stability through an enhanced resistance to slaking and increased interparticular cohesion. The SB‐amended soils exhibited significant increases in the available water contents of soils. The application of SB significantly increased pore volume in the macropore (> 75 μm) and mesopore (30–75 μm) ranges, which may be the result of the reorganization of pore‐size distribution and aggregation processes induced by the addition of biochar. Results indicated that biochar had the potential to improve the physical quality and pore‐space status of clayey soil. It is suggested that biochar may be considered as a soil amendment for improving poor physical characteristics of clayey soil.     

Predicting unsaturated hydraulic conductivity of soil based on some basic soil properties

Soil hydraulic conductivity is a crucial parameter in modeling flow process in soils and deciding water management. In this study, by combining the non-similar media concept (NSMC) to the one-parameter model of Brooks and Corey, a new NSMC-based model for estimating unsaturated hydraulic conductivity of various soils was presented. The main inputs are soil bulk density, particle-size distribution, soil water retention characteristic and saturated hydraulic conductivity of soil. The results indicated that the NSMC-based model could generally more accurately predict unsaturated hydraulic conductivity of soils, as compared to four one-parameter models and van Genuchten–Mualem model. This study, by introducing NSMC, provided a new way to incorporate soil physical heterogeneity into soil hydraulic simulation, and hence NSMC-based approach is expected to improve efficiency of the existing models in the simulation of soil water flow.     

基于CT分析露天煤矿复垦年限对土壤有效孔隙数量和孔隙度的影响

露天煤矿排土场由于排土过程中大型机械压实等作用会对土壤的孔隙结构产生影响,重构适合于植被生长的土壤孔隙结构是排土场土地复垦的重要工作。为对排土场重构土壤孔隙结构进行定量分析,该文采用高精度无损计算机断层扫描技术(CT)对山西平朔矿区安太堡露天煤矿排土场平台全黄土母质覆盖的不同复垦年限(0、20、23 a)以及原地貌的土壤进行分层扫描成像,并利用Photoshop和Arcgis软件对扫描图像进行处理和统计分析,探讨了排土和复垦对土壤孔隙数量和孔隙度的影响,分析了排土场重构土壤大、中和小孔隙的变化。结果表明:原地貌土壤孔隙数量和孔隙度最大,其次是复垦23和20 a的土壤,排土后未复垦土壤孔隙数量和孔隙度最小。采矿和排土等活动由于大型机械压实作用降低了土壤孔隙数量和孔隙度,尤其是大孔隙数量和大孔隙度;土地复垦对增加土壤孔隙数量和孔隙度有一定的作用,但是过程比较缓慢。采矿和排土等活动对表层土壤孔隙数量和孔隙度的影响要高于底层土壤。该研究可为黄土区大型露天煤矿排土场重构土壤结构的优化与土地复垦措施选择提供依据。     

Causal processes of soil salinization in Tunisia,Spain and Hungary

Soil salinization arises due to the build up of soluble salts at or near the soil surface. Salts accumulate by primary and secondary processes that alter the soils physicochemical properties and lead to direct and indirect soil degradation. Results are presented here from the study of three contrasting salt‐affected landscapes. The Chott el Fedjadj, Tunisia, is a naturally salt‐affected basin containing saline sediments deposited during a marine incursion. The endoreic conditions lead to salt recirculation, concentration and reprecipitation. In the Guadalentin Valley, Spain, increased irrigated agriculture has led to aquifer overexploitation releasing gas and salts. Irrigating with the resultant contaminated groundwater has induced soil salinization. The salt accumulation and translocation is dictated predominantly by irrigation method, water quality and quantity. Hungary has the largest expanse of naturally salt‐affected soil in Europe, with the dominant soil type being solonetz. In Hungary the type of salt‐affected soil development is related to the salts present, hydraulic properties of the soil and depth and quality of the watertable. In Tunisia a catenary relationship of increased water and soil salinity towards the centre of the chott is found, whereas in Spain the highest salinities were found under flood irrigation with the valley displaying a complex spatial distribution of soil salinity. The sediment distribution in Hungary dictates that solonchak soils are found mostly in the Danube–Tisza interfluve and solonetz soils in the Tisza floodplain, with localized variations in soil type related to watertable characteristics. Copyright © 2001 John Wiley & Sons, Ltd.     

A soil quality index based on the equilibrium between soil organic matter and biochemical properties of undisturbed coniferous forest soils of the Pacific Northwest

Recent studies have suggested that the organic matter contents of undisturbed soils (under natural vegetation) are in equilibrium with biological and biochemical properties. Accordingly, we hypothesised that such equilibria should be disrupted when soils are subjected to disturbance or stress, and that measurement of this disruption can be expressed mathematically and used as a soil quality index. In this study, we evaluated these hypotheses in soils from the H.J. Andrews Experimental Forest in Oregon. Both O and A horizons were sampled from nine sites in Spring 2005 and Fall 2006. Soil samples were analyzed for enzyme activities (phosphatase, β-glucosidase, laccase, N-acetyl-glucosaminidase, protease and urease), and other biological and chemical properties including N-mineralization, respiration, microbial biomass C (MBC), soil organic carbon (SOC) and total nitrogen content. In addition, soil samples from one old-growth site were manipulated in the laboratory to either simulate chemical stresses (Cu addition or pH alteration) or physical disturbances (wet-dry or freeze-thaw cycles). The results showed variation in biological and biochemical soil properties that were closely correlated with SOC. Multiple regression analysis of SOC levels against all soil properties showed that a model containing only MBC and phosphatase activity could account for 97% of the SOC variation among the sites. The model fit was independent of spatial and temporal variations because covariates such as site, stand age, sampling date, and soil horizon were found to be not statistically significant. Although the application of stress/disturbance treatments inconsistently affected most of the individual biochemical properties, in contrast, the ratio of soil C predicted by the model (C_p), and soil C measured (C_m) was consistently reduced in soils submitted to at least one level of stress and disturbance treatments. In addition, C_p/C_m was more affected in soils submitted to wet-dry cycles and Cu contamination than to freeze-thaw cycles or shifts in soil pH. Our results confirm previous evidence of a biochemical balance in high quality undisturbed soils, and that this balance is disrupted when the soil is submitted to disturbances or placed under stress conditions. The C_p/C_m ratio provides a simple reference value against which the degrading effects of pollutants or management practices on soil quality can be assessed.     

Porosity and soil water properties of Caribbean volcanic ash soils

Abstract. Volcanic ash soils are generally recognized as soils with excellent and stable physical properties. Here we characterized the porosity and water properties of volcanic ash Andosols and Nitisols from Guadeloupe in contrasting banana systems: (1) perennial crop without mechanization, (2) mechanized and regularly replanted crop. Desiccation from 1 kPa to 1550 kPa moisture tension leads to significant shrinkage in the Andosol, representing a 50% reduction of the void space. The clayey Nitisol exhibited limited shrinkage. Soil clods from the mechanized plots had a significantly smaller macroporosity than that from perennial plots. The soil hydraulic conductivity was also drastically reduced in the compacted layers of the mechanized plots. However, Nitisols appeared to be less affected than Andosols. Laboratory compression tests showed that both soils were susceptible to compaction at soil moisture close to field capacity. The shrinkage properties of the Andosol were due to microaggregation of non-crystalline components upon drying. The relative stability of the macroporosity in the Nitisol was probably related to the presence of stable microaggregates made of halloysite and iron oxide. Two major processes promote soil structure degradation in the Andosol under mechanized banana cropping, surface desiccation and soil compaction. They are both induced by repeated tillage after clearing.     

Loss of yield caused by soil erosion on sandy soils in the UK

Abstract. Soil productivity, the intrinsic ability of land to yield useful products, can be affected by soil erosion. While much research has been carried out on the processes, there is as yet little information on the impact of soil erosion on in situ productivity of agricultural land in the British Isles. This paper reports the results of a de-surfacing experiment on deep sandy soils in East Anglia. Grain yields of fertilized barley planted immediately after de-surfacing were at least 15 and 45% less on 15 and 25 cm de-surfaced plots than on non-desurfaced soils. There was strong evidence pointing to an acceleration of soil erosion itself on the de-surfaced plots. Both the amount of water stored in the topsoil and water use by the crop decreased with increasing severity of simulated erosion. We observed a drop in organic matter and readily available nitrogen with erosion. Nitrogen mineralization and leaching losses were also affected by simulated soil erosion. The experiment showed that sudden severe erosion may induce substantial barley production losses on deep sandy soils. The size and effect of de-surfacing depends on a number of factors such as soil depth, subsoil type, precipitation and crop type.     

Weathered pumice influence on selected alluvial soil properties in west Nayarit, Mexico

Parent material and pumiceous alluvial soils, located in a tropical region of Mexico, were studied to supply information on soil suitability for agricultural production in the context of sustainable agriculture. In recent alluvial soils, an understanding of how soil characteristics vary with parent material and topography provides a basis for determining land utilization type, land suitability as well as land quality. The main objective of this study was to establish the relationship of soil properties to parent material in west Nayarit, Mexico. Field studies were initiated in 1993 by a request for technical assistance from the Comision Federal de Electricidad. The studied soils were derived from pumice that has been reworked and mixed with detrital material from other sources. We found that such soils have unique physical, chemical and mineralogical characteristics that are rarely found in soils derived from other parent materials. Data for two selected alluvial soil profiles are presented. These soils were developed on Holocene volcanogenic pumiceous alluvial river terraces and river floodplains, under current udic-isohyperthermic soil-climate conditions. The agronomic properties, tillage influences and fertilizer requirements of these soils have been studied extensively. To maximize their productivity and minimize deterioration, proper management must be based on an understanding of the unique physical, chemical and mineralogical properties. Results indicate that such soils have physical properties that provide a good environment for deep rooting and can supply the water necessary for vigorous plant growth. In both soils, water retention at 33 and 1500 kPa, particle surface area, calculated clay, cation exchange capacity, Al exchangeable percentage and P retention, and the occurrence of isotropic coatings on rock fragments and peds tend to increase in the presence of the large amounts of hydrolyzed pumice that are found in the 0.02–2.0 mm fraction. Scanning electron microscope–energy dispersive X-ray analyses demonstrate that the coatings dominantly consist of noncrystalline material, probably allophanic-like material as suggested by the Si/Al molar ratio of 1.0. Selective dissolution analysis reveals that these abundant noncrystalline materials consist of ferrihydrite and allophane with an atomic ratio (Al_o−Al_p)/Si_o of approximately 1.4. Both ferrihydrite and allophane have very large specific surface area and absorptive capacity that make a significant contribution to the overall properties of these soils. X-ray diffraction analysis and transmission electron microscope observation show that the major group of crystalline clay minerals in the upper section of studied soils are tubular and spheroidal halloysite. These soils were classified as Vitrandic Udifluvents according to Soil Taxonomy.     

土壤中水溶性铜对西红柿的毒害影响因素及预测模型

该文选取17种具有代表性的中国土壤,研究了土壤孔隙水以及0.01mol/LCaCl2浸提态Cu对西红柿生长的毒害,结果发现对于土壤孔隙水中Cu对西红柿生物量10%抑制的毒性阈值(EC10)和50%抑制的毒性阈值(EC50),在17个非淋洗土壤中变化范围分别为0.06～1.47和0.17～3.42mg/L,淋洗土壤变化范围分别为0.05～2.24和0.13～4.37mg/L,最大值与最小值相差为23～41倍;0.01mol/LCaCl2提取态Cu的EC10和EC50,在非淋洗土壤变化范围分别为0.18～2.64和0.57～6.14mg/kg,淋洗土壤变化范围分别为0.18～1.28和0.61～7.11mg/kg,相差从6.9～14.4倍,表明土壤溶液性质影响水溶性Cu对西红柿的毒性阈值。同时,发现土壤孔隙水中Ca2+、溶解性有机碳是影响孔隙水中Cu对西红柿生长毒性的主要因子。当进一步考虑土壤溶液的重要因子(溶解性有机碳、土壤溶液pH值、电导率、全硫含量、Ca2+、Mg2+、K+、Na+),发现基于水溶性Cu的毒性阈值和土壤溶液性质的多元回归系数变化范围为0.75～0.99,说明利用土壤溶液性质能较好的预测土壤中水溶性Cu对西红柿的毒性阈值。该研究可为土壤水溶性Cu的风险评估提供参考。