Effect of zeolite and saline water application on saturated hydraulic conductivity and infiltration in different soil textures

The effects of zeolite application (0, 4, 8 and16 g kg^?1) and saline water (0.5, 1.5, 3.0 and 5.0 dS m^?1) on saturated hydraulic conductivity (K _s) and sorptivity (S) in different soils were evaluated under laboratory conditions. Results showed that K _s was increased at salinity levels of 0.5‐1.5 dS m^?1 in clay loam and loam with 8 and 4 g zeolite kg^?1 soil, respectively, and at salinity levels of 3.0–5.0 dS m^?1 with 16 g zeolite kg^?1 soil. K _s was decreased by using low and high salinity levels in sandy loam with application of 8 and 16 g zeolite kg^?1, respectively. In clay loam, salinity levels of 0.5–3.0 dS m^?1 with application of 16 g kg^?1 zeolite and 5.0 dS m^?1 with application of 8 g zeolite kg^?1 soil resulted in the lowest values of S. In loam, all salinity levels with application of 16 g zeolite kg^?1 soil increased S compared with other zeolite application rates. In sandy loam, only a salinity level of 0.5 dS m^?1 with application of 4 g zeolite kg^?1 soil increased S. Other zeolite applications decreased S, whereas increasing the zeolite application to 16 g kg^?1 soil resulted in the lowest value of S.     

Zeolite Effects on Immobile Water Content and Mass Exchange Coefficient at Different Soil Textures

The concern for groundwater pollution by agrichemicals through solute movement within the soil is widespread. Zeolite is a type of soil amendment that is utilized to improve physical properties of soil and ameliorate polluted soil. The high negative charge of the zeolite and its open space structure allows adsorption and access of heavy metals and other cations and anions. The objectives of this research were (i) to determine the effects of different application rates of zeolite (0, 2, 4, and 8 g kg^?1) on the immobile water content and mass exchange coefficient in a loam soil and then (ii) to determine the effects of optimum application rate of zeolite on the immobile water content and mass exchange coefficient of sandy loam and clay loam soils in saturated conditions by a mobile and immobile (MIM) model. In a disturbed soil column, a method was proposed for determination of MIM model parameters, that is, immobile water content (θ_im), mass exchange coefficient (α), and hydrodynamic dispersion coefficient (D_h). Breakthrough curves were obtained for different soil textures with different zeolite applications in three replicates, by miscible displacement of chloride (Cl^?1) in disturbed soil column. Cl^?1 breakthrough curves were evaluated in terms of the MIM model. The results showed that the pore water velocity calculated based on the total soil volumetric water content (θ_im+ θ_m) and real pore water velocity calculated based on the mobile water content (θ_m) increased in the loam soil with an increase in zeolite application rate, so that, between these different rates of zeolite application, the maximum value of pore water velocity and real pore water velocity occurred at zeolite application rates of 8.6 and 11.5 g kg^?1, which are indicated as the optimum application rates. However, the comparison between different soils showed that the zeolite application rate of 8 g kg^?1 could increase pore water velocity of sandy loam and loam soils by 31% more than that of clay loam soil. The immobile water content and mass exchange coefficient of loam soil were correlated with the zeolite application rate and reduced with an increase in the rate of applied zeolite. In a comparison between different soils at zeolite application rate of 8 g kg^?1, the immobile water contents of the zeolite-treated soil decreased by 57%, 60%, and 39% on sandy loam, loam, and clay loam soils, respectively, compared with the untreated soil. Furthermore, zeolite application could reduce mass exchange coefficient by 9%, 43%, and 21% on sandy loam, loam, and clay loam soils, respectively. A positive linear relationship was found between θ_im and α. Zeolite application increased real pore water velocity of sandy loam soil by 39% and 46% compared with loam and clay loam soils, respectively. In other studies there was a decrease in ammonium and nitrate leaching due to the zeolite application, and therefore, an increase in real pore water velocity due to zeolite application in sandy loam soil, as compared with the loam and clay loam soils, may not show more rapid movement of solute and agrichemicals to the groundwater.     

Heavy‐Metal Inhibition of Nitrification in Selected Iowa Soils Treated with Stay‐N 2000

Abstract

Heavy‐metal inhibition of nitrification in soils treated with reformulated nitrapyrin was investigated. Clarion and Okoboji soils were treated with ammonium sulfate [(NH₄)₂SO₄] and a nitrification inhibitor. Copper(II) (Cu), Zinc(II) (Zn), Cadmium(II) (Cd), or Lead(II) (Pb) were added to each soil. A first‐order equation was used to calculate the maximum nitrification rate (K _max), duration of lag period (t′), period of maximum nitrification (Δt), and the termination period of nitrification (t _s). In the Clarion soil, the K _max decreased from 12 mg kg^?1 d^?1 without the nitrification inhibitor to 4, 0.25, 0.86, and 0.27 mg kg^?1 d^?1, respectively, when the inhibitor and Cu, Zn, Pb, or Cd were applied. In the Okoboji soil, K _max decreased from 22 mg kg^?1 d^?1 with no inhibitor to 6, 3, 4, and 2 mg kg^?1 d^?1, respectively, when an inhibitor and Cu, Zn, Pb, or Cd were added. The t′ varied from 8 to 25 d in the Clarion soil and from 5 to 25 d in the Okoboji soil, due to addition of Cu, Zn, Pb, or Cd and the inhibitor.     

Potassium fertilization on sandy soils in relation to soil test,crop yield and K-leaching

To study the influence of potassium (K) fertilizer rate on soil test K values, crop yield, and K-leaching in sandy soils, four long-term fertilizer experiments (0–60–120–180 kg K ha^?1 a^?1) were initiated in 1988 in northern Germany on farmers fields. Clay content of the plow layer was about 4%, and organic matter between 2% and 5%. Plant available soil K was estimated with the double lactate (DL) method. Small grain cereals (rye and barley) did not respond to K fertilization in the 7-year period even though the soil test value of the K-0 plots decreased from ca. 90 to ca. 30 mg K_DL kg^?1 within 3 years. This value remained almost constant thereafter. Crop removal (including straw) of 75 kg K ha^?1 a^?1 was therefore apparently supplied from nonexchangeable K fractions. Compared to the optimum, no K application reduced the yield of potato by up to 21%, and that of white sugar yield up to 10%. Maximum potato yield was obtained by annually applying 60 kg K ha^?1 which resulted in a test value of 60 mg K_DL kg^?1 soil. Maximum potato yield was also obtained at 40 mg K_DL kg^?1 soil, however, with a single application of 200 kg K ha^?1. Similar results were obtained with sugar beet. This indicates that for maximum yield, even for K demanding crops, it is not necessary to maintain K_DL values above 40 mg K kg^?1 soil throughout the entire crop rotation. Soil test values increased roughly proportional to the K fertilizer level. About 120 kg fertilizer K ha^?1 a^?1, markedly more than crop K removal, was required to maintain the initial K_DL of 90 mg kg^?1. The K concentration of the soil solution in the top soil measured after harvest was increased exponentially by K fertilizer level and so was K leaching from the plow layer into the rooted subsoil. The leached quantity increased from 22 kg K ha_?1 a_?1 in the plot without K application to 42.79 and 133 kg Kha^?1 a^?1 in plots supplied with 60, 120 and 180 kg K ha^?1 a^?1 respectively. Soil test values around 100 mg K_DL kg^?1 on sandy soils, as often found in the plow layer of farmers fields, lead to K leaching below the root zone that may exceed the critical K concentration of 12 mg K T^?1 for drinking water.     

Coffee‐husk biochar application increased AMF root colonization,P accumulation,N2 fixation,and yield of soybean grown in a tropical Nitisol,southwest Ethiopia

Low soil fertility and soil acidity are among the major bottlenecks that limit agricultural productivity in the humid tropics. Soil management systems that enhance soil fertility and biological cycling of nutrients are crucial to sustain soil productivity. This study was, therefore, conducted to determine the effects of coffee‐husk biochar (0, 2.7, 5.4, and 16.2 g biochar kg^?1 soil), rhizobium inoculation (with and without), and P fertilizer application (0 and 9 mg P kg^?1 soil) on arbuscular mycorrhyzal fungi (AMF) root colonization, yield, P accumulation, and N₂ fixation of soybean [Glycine max (L.) Merrill cv. Clark 63‐K] grown in a tropical Nitisol in Ethiopia. ANOVA showed that integrated application of biochar and P fertilizer significantly improved soil chemical properties, P accumulation, and seed yield. Compared to the seed yield of the control (without inoculation, P, and biochar), inoculation, together with 9 and 16.2 g biochar kg^?1 soil gave more than two‐fold increment of seed yield and the highest total P accumulation (4.5 g plant^?1). However, the highest AMF root colonization (80%) was obtained at 16.2 g biochar kg^?1 soil without P and declined with application of 9 mg P kg^?1 soil. The highest total N content (4.2 g plant^?1) and N₂ fixed (4.6 g plant^?1) were obtained with inoculation, 9 mg P kg^?1, and 16.2 g biochar kg^?1 soil. However, the highest %N derived from the atmosphere (%Ndfa) (> 98%) did not significantly change between 5.4 and 16.2 g kg^?1 soil biochar treatments at each level of inoculation and P addition. The improved soil chemical properties, seed yield, P accumulation and N₂ fixation through combined use of biochar and P fertilizer suggest the importance of integrated use of biochar with P fertilizer to ensure that soybean crops are adequately supplied with P for nodulation and N₂‐fixation in tropical acid soils for sustainable soybean production in the long term.     

Effects of wastewater application on saturated hydraulic conductivity of different soil textures

As metropolitan areas expand, the municipal and industrial uses of freshwater increase. Therefore, water resources for irrigation become limited and wastewater reuse for irrigation becomes a good alternative. For this purpose, the effects of suspended solids in wastewater on the soil physical properties, i.e., saturated hydraulic conductivity, K_s, have to be considered. The objectives of this research were to study the effects of applying freshwater and differently treated wastewater on K_s in the surface and subsurface layers of sandy‐loam, loam, and clay‐loam soils. This effect was studied by investigating the ratio of K_s for wastewater to K_s for fresh water in soil surface as K_r1 and in soil subsurface as K_r2. The results showed that the application of freshwater did not reduce the K_r1 considerably. However, the reduction in K_r1 mainly occurred in soil depth of 0–50 mm due to the application of wastewater. This effect is more pronounced in clay‐loam soil than in loam and sandy‐loam soils. It is concluded that application of wastewater with TSS (total suspended solid) of ≥ 40 mg L^–1 resulted in K_r1 reduction of >50% in different soil textures. However, the K_r2 reduction at soil depth of 100–300 mm is not considerable by application of wastewater for different soil textures. Further, it is concluded that less purified wastewater can be used in light‐texture soils resulting in less reduction in K_r1. Empirical models were developed for predicting the value of K_r1 as a function of amounts of wastewater application and TSS for different soil textures that can be used in management of wastewater application for preventing deterioration of soil hydraulic conductivity.     

Responses of carbon,nitrogen and phosphorus to two consecutive drying–rewetting cycles in soils

Drying and rewetting cycles are known to be important for the dynamics of carbon (C), phosphorus (P), and nitrogen (N) in soils. This study reports the short‐term responses of these nutrients to consecutive drying and rewetting cycles and how varying soil moisture content affects microbial biomass C and P (MBC and MBP), as well as associated carbon dioxide (CO₂) and nitrous oxide (N₂O) emissions. The soil was incubated for 14 d during which two successive drying–rewetting episodes were imposed on the soils. Soils subjected to drying (DRW) were rewetted on the seventh day of each drying period to return them to 60% water holding capacity, whilst continually moist samples (M), with soil maintained at 60% water holding capacity, were used as control samples. During the first seven days, the DRW samples showed significant increases in extractable ammonium, total oxidized nitrogen, and bicarbonate extractable P concentrations. Rewetting after the first drying event produced significant increases only in CO₂ flux (55.4 µg C g^?1 d^?1). The MBC and MBP concentrations fluctuated throughout the incubation in both treatments and only the second drying–rewetting event resulted in a significantly MBC decrease (416.2 and 366.8 mg kg^?1 in M and DRW soils, respectively). The two drying–rewetting events impacted the microbial biomass, but distinguishing the different impacts of microbial versus physical impacts of the perturbation is difficult. However, this study, having a combined approach (C, N, and P), indicates the importance of understanding how soils will react to changing patterns of drying–rewetting under future climate change.     

Bio-extraction of Potassium from Glauconite Nano-particle in an Alfisols of Southern India

ABSTRACT

Glauconite is a potassium (K) bearing mineral, which generally contains 6–10% K₂O and mostly available in various natural deposits in India. Glauconite mineral was converted to nano-particle form by grinding in a high-energy ball mill. The release of K from glauconite nano-particle in soil was studied in a pot culture experiment. Five different treatments viz., 0 mg K₂O kg^?1, 100 mg K₂O kg^?1, 150 mg K₂O kg^?1, 200 mg K₂O kg^?1 used glauconite nano-particle (GNP) as a K source and 100 mg K₂O kg^?1 from muriate of potash (MOP), were applied in soil to grow maize (Zea mays L.) plant. The highest K⁺ concentration was observed in shoot at the application of 200 mg K₂O kg^?1 through GNP and recorded 2 times more K⁺ concentration in shoots as compared to 0 mg K₂O kg^?1 treatment whereas 1.1 times more than the MOP treated soil at 5^th harvesting stage. Selected plant physiological parameters namely electrical conductivity of plant cell, height, leaf area and nitrate reductase activity were also recorded maximum at 200 mg K₂O kg^?1 GNP treated soil. Overall, glauconite nano-particle could supply K throughout the growth period and enhanced biomass yield of maize plant without showing any K deficiency symptom.     

Potassium fertilization and soil diagnostic criteria for forage corn (Zea mays L.) production contributing to lower potassium input in regional fertilizer recommendation

Abstract

Effective soil diagnostic criteria for exchangeable potassium (Ex-K) combined with inorganic potassium (K) application rates were developed to lower K input in forage corn (Zea mays L.) production using experimental fields with different application rates and histories of cattle manure compost. Two corn varieties, ‘Cecilia’ as a low K uptake variety and ‘Yumechikara’ as a high K uptake variety, were selected from among 20 varieties and tested to make diagnostic criteria for K fertilization applicable to varieties with different K uptakes. The K uptakes increased from 96 to 303 kg K ha^?1 for ‘Cecilia’ and from 123 to 411 kg K ha^?1 for ‘Yumechikara’ with increasing Ex-K content on a dry soil basis from 0.11 to 0.92 g kg^?1 with no inorganic K fertilizer application. The K uptake by corn for achieving the target dry matter yield of 18 Mg ha^?1 was estimated to be approximately 200 kg K ha^?1 in common between the two varieties. Yields of both varieties achieved the target yield at an Ex-K content of approximately 0.30 g kg^?1 with no K fertilization, although ‘Yumechikara’ reached the target yield at a lower Ex-K content. At the low Ex-K content of 0.1 g kg^?1, inorganic K fertilizer application at 83 kg K ha^?1 was needed to gain the target yield, and apparent K recovery rate for K fertilizer was calculated to be 70% for both varieties. The K uptakes for gaining the target yield by the K fertilization were lower than that by soil K supply. Based on these results, diagnostic criteria of Ex-K and inorganic K application rates were set up as follows: at an Ex-K content of < 0.15 g kg^?1, inorganic K fertilizer is applied at 83 kg K ha^?1 (100 kg ha^?1 as potassium oxide (K₂O) equivalent); at an Ex-K content of 0.15–0.30 g kg^?1, the application rate is reduced to 33 kg K ha^?1 (40 kg K₂O ha^?1); at an Ex-K content of ≥ 0.30 g kg^?1, inorganic K fertilizer is not applied because of sufficient K in the soil. Additionally, we propose that cattle manure compost be used to supplement soil K fertility.     

GREENHOUSE GAS EMISSIONS FROM AN ALKALINE SALINE SOIL CULTIVATED WITH MAIZE (ZEA MAYS L.) AND AMENDED WITH ANAEROBICALLY DIGESTED COW MANURE: A GREENHOUSE EXPERIMENT

Sludge derived from cow manure anaerobically digested to produce biogas (methane; CH₄) was applied to maize (Zea mays L.) cultivated in a nutrient-low, alkaline, saline soil with electrolytic conductivity 9.4 dS m^?1 and pH 9.3. Carbon dioxide (CO₂) emission increased 3.1 times when sludge was applied to soil, 1.6 times when cultivated with maize and 3.5 times in sludge-amended maize cultivated soil compared to the unamended uncultivated soil (1.51 mg C kg^?1 soil day^?1). Nitrous oxide (N₂O) emission from unamended soil was -0.0004 μg nitrogen (N) kg^?1 soil day^?1 and similar from soil cultivated with maize (0.27 μg N kg^?1 soil day^?1). Application of sludge increased the N₂O emission to 4.59 μg N kg^?1 soil day^?1, but cultivating this soil reduced it to 2.42 μg N kg^?1 soil day^?1. It was found that application of anaerobic digested cow manure stimulated maize development in an alkaline saline soil and increased emissions of CO₂ and N₂O.     

Zinc Uptake by Spinach (Spinacia oleracea L.) as Affected by Zn Application Rate,Zeolite, and Vermicompost

Zinc deficiency in calcareous soils is a serious problem, which may be ameliorated by the application of some soil amendments. A completely randomized factorial experiment was done to investigate the effect of zeolite, vermicompost, zeolite + vermicompost, and Zn application to a calcareous soil on Zn availability, dry weight of spinach (Spinacia oleracea L.), and Zn concen-tration in spinach. Results indicated that zeolite had no effect on soil Zn availability, dry weight, and Zn concentration in spinach. Vermicompost significantly increased dry weight (1.33 g pot^?1) and decreased Zn concentration in spinach (16 mg kg^?1). Application of zeolite + vermicompost significantly increased dry weight (by 2.8 times) and Zn uptake in spinach and it also decreased Zn concentration in spinach less than vermicompost. Zinc application increased Zn concentration in spinach (up to 496 mg kg^?1), but did not affect dry weight except in soils treated with zeolite + vermicompost. Generally, application of zeolite + vermicompost is recommended instead of separate zeolite or vermicompost application for improvement of soil Zn fertility and Zn uptake by spinach.     

Predicting potassium fertilizer requirement using exchange isotherm approach in relation to soil characteristics

Determining potassium (K) fertilizer requirement using sorption isotherms is considered more accurate than conventional soil K tests. A total of 59 surface soil samples were used to establish K exchange isotherm. To evaluate K requirement sorption test, a glasshouse experiment using perennial ryegrass (Lolium perenne, cv. Roper) was carried out on 10 soil samples. The experiment was laid out as a completely randomized design with four replications and four K levels (K₀, K₂₀, K₄₀, K₈₀). Concentrations of K in solution established by adding K in the pots estimated from the sorption curve ranged from 20 to 80 mg K l^?1 including check treatment (no K). Dry matter yield of ryegrass in most soils approached maximum as adjusted K levels were increased to 20 mg K l^?1. The amounts of K required to bring the soils to 20 mg l^?1 in soil solution varied among soils and ranged from 99 to 399 mg kg^?1, on average 205 mg kg^?1 soil. It was found that a useful regression model for the prediction of standard K requirement (K₂₀) included the combination of plant available K extracted by NH₄OAc (Av-K) and clay content: K₂₀ = ?41 ? 0.63 Av-K + 9.0 Clay (R² = 0.61, p < 0.001, n = 59).     

Influence of Lime and Gypsum on Yield and Yield Components of Soybean and Changes in Soil Chemical Properties

Soybean is one of the most important legume crops in the world. Two greenhouse experiments were conducted to determine the influence of liming and gypsum application on yield and yield components of soybean and changes in soil chemical properties of an Oxisol. Lime rates used were 0, 0.71, 1.42, 2.14, 2.85, and 4.28 g kg^?1 soil. Gypsum rates applied were 0, 0.28, 0.57, 1.14, 1.71, and 2.28 g kg^?1 soil. Lime as well as gypsum significantly increased grain yield in a quadratic fashion. Maximum grain yield was achieved with the application of 1.57 g lime per kg soil, whereas the gypsum requirement for maximum grain yield was 1.43 g per kg of soil. Lime significantly improved soil pH, exchangeable soil calcium (Ca) and magnesium (Mg) contents, base saturation, and effective cation exchange capacity (ECEC). However, lime application significantly decreased total acidity [hydrogen (H) + aluminum (Al)], zinc (Zn), and iron (Fe) contents of the soil. The decrease in these soil properties was associated with increase in soil pH. Gypsum application significantly increased exchangeable soil Ca, base saturation, and ECEC. However, gypsum did not change pH and total acidity (H + Al) significantly. Adequate soil acidity indices established for maximum grain yield with the application of lime were pH 5.5, Ca 1.8 cmol_c kg^?1, Mg 0.66 cmol_c kg^?1, base saturation 53%, Ca saturation 35%, and Mg saturation 13%. Soybean plants tolerated acidity (H + Al) up to 2.26 cmol_c kg^?1 soil. In the case of gypsum, maximum grain yield was obtained at exchangeable Ca content of 2.12 cmol_c kg^?1, base saturation of 56%, and Ca saturation of 41%.     

Effects of microbial inoculations on soil chemical,biochemical and microbial biomass carbon of cassava (Manihot esculenta Crantz) growing Vertisols

Cassava is an important subsidiary food in the tropics. In Tamil Nadu, India, microbial cultures were used to eradicate the tuberous root rot of cassava. Hence, an experiment was conducted for two consecutive years to test the effects of coinoculation of microbes on soil properties. The surface soil from the experimental site was analysed for soil available nutrients, soil enzyme activities and microbial biomass carbon. The treatment of Azospirillum with Trichoderma at the 50% recommended N:P₂O₅:K₂O (NPK) rate (50:25:50 kg ha^?1) significantly increased soil available nitrogen (142.81 kg ha^?1) by 72.66% over uninoculated control. There was a significant increase in available phosphorus in soil by the inoculation of AM (arbuscular mycorrhizal) fungi with Trichoderma at the 50% recommended NPK rate (41.04 kg ha^?1) compared to other treatments. The application of Pseudomonas fluorescens with Trichoderma at the 50% recommended NPK rate significantly increased available iron (19.34 µg g^?1) in soil. The treatment of Azospirillum with Trichoderma increased urease enzyme activity at the recommended NPK rate (816.32 μg urea hydrolyzed g^?1 soil h^?1). Soil application of all cultures at the 50% recommended NPK rate significantly increased dehydrogenase activity (88.63 μg TPF g^?1 soil) and β-glucosidase activity (48.82 μg PNP g^?1 soil) in soil. Inoculation of Trichoderma alone at the 50% recommended NPK rate significantly increased microbial biomass carbon (3748.85 μg g^?1 soil). Thus, the microbial inoculations significantly increased soil available nutrient contents, enzyme activities such as urease, dehydrogenase and β-glucosidase activity and microbial biomass carbon by reducing the amount of the required fertilizer.     

The influence of phosphate fertilizer application levels and cultivars on cadmium uptake by Komatsuna (Brassica rapa L. var. perviridis)

Cadmium (Cd) is a common impurity in phosphate fertilizers and application of phosphate fertilizer may contribute to soil Cd accumulation. Changes in Cd burdens to agricultural soils and the potential for plant Cd accumulation resulting from fertilizer input were investigated in this study. A field experiment was conducted on Haplaquept to investigate the influence of calcium superphosphate on extractable and total soil Cd and on growth and Cd uptake of different Komatsuna (Brassica rapa L. var. perviridis) cultivars. Four cultivars of Komatsuna were grown on the soil and harvested after 60 days. The superphosphate application increased total soil Cd from 2.51 to 2.75?mg?kg^?1, 0.1?mol?L^?1 hydrochloric acid (HCl) extractable Cd from 1.48 to 1.55?mg?kg^?1, 0.01?mol?L^?1 HCl extractable Cd from 0.043 to 0.046?mg?kg^?1 and water extractable Cd from 0.0057 to 0.0077?mg?kg^?1. Cd input reached 5.68?g?ha^–1 at a rate of 240?kg?ha^–1 superphosphate fertilizer application. Superphosphate affected dry-matter yield of leaves to different degrees in each cultivar. ‘Nakamachi’ produced the highest yield in 2008 and ‘Hamami No. 2’ in 2009. Compared with the control (no phosphate fertilizer), application of superphosphate at a rate of 240?kg?ha^–1 increased the Cd concentration in dry leaves by 0.14?mg?kg^?1 in ‘Maruha’, 1.03?mg?kg^?1 in ‘Nakamachi’, 0.63?mg?kg^?1 in ‘SC8-007’ in 2008, and by 0.19?mg?kg^?1 in Maruha’, 0.17?mg?kg^?1 in ‘Hamami No. 2’, while it decreased by 0.27?mg?kg^?1 in ‘Nakamachi’ in 2009. Field experiments in two years demonstrated that applications of different levels of calcium superphosphate did not influence Cd concentration in soil and Komatsuna significantly. However, there was a significant difference in Cd concentration of fresh and dry Komatsuna leaves among four cultivars in 2008 and 2009. The highest Cd concentration was found in the ‘Nakamachi’ cultivar (2.14?mg?kg^?1 in 2008 and 1.91?mg?kg^?1 in 2009). The lowest Cd concentration was observed in the ‘Maruha’ cultivar (1.51?mg?kg^?1?dry weight (DW)) in 2008 and in the ‘Hamami No. 2’ cultivar (1.56?mg?kg^?1?DW) in 2009. A decreasing trend in Cd concentration was found in ‘Nakamachi’, followed by ‘SC8-007’, ‘Hamami No. 2’ and ‘Maruha’ successively. It is necessary to consider a low-uptake cultivar for growing in a Cd polluted soil. In these two years’ results, ‘Maruha’ cultivar was the lowest Cd uptake cultivar compared to the others.     

Experimental Study on the Effects of Natural Zeolite on Lead Toxicity,Growth, Nodulation,and Chemical Composition of Soybean

Lead (Pb) is one of the most dangerous contaminants that has been released into the environment over many years by anthropogenic activities. In the present study, the effect of zeolite on the Pb toxicity, growth, nodulation, and chemical composition of soybean (Glycine max L. var. Williams) was evaluated. Treatments consisted of factorial combination of three levels of zeolite (0, 2, and 5 g kg^?1) and three levels of Pb (0, 10, and 25 mg kg^?1) with three replicates in a completely randomized design. Lead application decreased shoot and root dry weights. Without any use of Pb, addition of zeolite increased shoot dry weight, iron (Fe), manganese (Mn), zinc (Zn), and copper (Cu) concentrations and the number and dry weight of root nodules. Moreover, the greatest value for these parameters was obtained by greatest level of zeolite application (5 g zeolite kg^?1 soil). It is suggested that zeolite has positive effects on growth and chemical composition of soybean and reduces Pb toxicity in plant parts.     

Increase in the fracture toughness and bond energy of clay by a root exudate

Root exudates help drive the formation of the rhizosphere by binding soil particles, but the underlying physical mechanisms have not been quantified. This was addressed by measuring the impact of a major component of root exudates, polygalacturonic acid (PGA), on the interparticle bond energy and fracture toughness of clay. Pure kaolinite was mixed with 0, 1.2, 2.4, 4.9 or 12.2 g PGA kg^?1 to form test specimens. Half of the specimens were washed repeatedly to remove unbound PGA and evaluate the persistence of the effects, similar to weathering in natural soils. Fracture toughness, K_IC, increased exponentially with added PGA, with washing increasing this trend. In unwashed specimens K_IC ranged from 54.3 ± 2.5 kPa m^?1/2 for 0 g PGA kg^?1 to 86.9 ± 4.7 kPa m^?1/2 for 12.2 g PGA kg^?1. Washing increased K_IC to 61.3 ± 1.2 kPa m^?1/2 for 0 g PGA kg^?1 and 132.1 ± 4.9 kPa m^?1/2 for 12.2 g PGA kg^?1. The apparent bond energy, γ, of the fracture surface increased from 5.9 ± 0.6 J m^?2 for 0 g kg^?1 to 12.0 ± 1.1 J m^?2 for 12.2 g kg^?1 PGA in the unwashed specimens. The washed specimens had γ of 13.0 ± 1.9 J m^?2 for 0 g kg^?1 and 21.3 ± 2.6 J m^?2 for 12.2 g PGA kg^?1. Thus PGA, a major component of root exudates, has a large impact on the fracture toughness and bond energy of clay, and is likely to be a major determinant in the formation of the rhizosphere. This quantification of the thermodynamics of fracture will be useful for modelling rhizosphere formation and stability.     

Evaluating the effect of biochar on salt leaching and nutrient retention of Yellow River Delta soil

Biochar has the potential to decrease salinity and nutrient loss of saline soil. We investigated the effects of biochar amendment (0–10 g kg⁻¹) on salinity of saline soil (2.8‰ salt) in NaCl leaching and nutrient retention by conducting column leaching experiments. The biochar was produced in situ from Salix fragilis L. via a fire-water coupled process. The soil columns irrigated with 15 cm of water showed that biochar amendment (4 g kg⁻¹) decreased the concentration Na⁺ by 25.55% in the first irrigation and to 60.30% for the second irrigation in sandy loam layer over the corresponding control (CK). Meanwhile, the sodium adsorption ratio (SAR) of soil after the first and second irrigation was 1.62 and 0.54, respectively, which were 15.2% and 49.5% lower than CK. The marked increase in saturated hydraulic conductivity (Ks) from 0.15 × 10^–5 cm s⁻¹ for CK to 0.39 × 10^–5 cm s⁻¹, following 4 g kg⁻¹ of biochar addition, was conducive to salt leaching. Besides, biochar use (4 g kg⁻¹) increased NH₄⁺-N and Olsen-P by 63.63% and 62.50% over the CK, but accelerated NO₃^–-N leaching. Since 15 cm hydrostatic pressure would result in salt accumulation of root zone, we would recommend using 4 g kg⁻¹ of biochar, 30 cm of water to ease the problem of salt leaching from the surface horizon to the subsoil. This study would provide a guidance to remediate the saline soil in the Yellow River Delta by judicious application of biochar and irrigation.     

Quantifying soil respiration in response to short-term tillage practices: a case study in southern Turkey

Abstract

The study aimed at quantifying the rates of soil CO₂ efflux under the influence of common tillage systems of moldboard plow (PT), chisel plow (CT), rotary tiller (RT), heavy disc harrow (DT), and no-tillage (NT) for 46 days in October and November in a field left fallow after wheat harvest located in southern Turkey. The NT and DT plots produced the lowest soil CO₂ effluxes of 0.3 and 0.7 g m^?2 h^?1, respectively, relative to the other plots (P < 0.001). Following the highest rainfall amount of 87 mm on the tenth day after the tillage, soil CO₂ efflux rates of all the plots peaked on the 12th day, with less influence on soil CO₂ efflux in the NT plot than in the conventional tillage plots. Soil evaporation in NT (64 mmol m^?2 s^?1) was significantly lower than in the PT (85 mmol m^?2 s^?1) and RT (89 mmol m^?2 s^?1) tillage treatments (P < 0.01). The best multiple-regression model selected explained 46% of variation in soil respiration rates as a function of the tillage treatments, soil temperature, and soil evaporation (P < 0.001). The tillage systems of RT, PT, and CT led, on average, to 0.23, 0.22, and 0.18 g m^?2 h^?1 more soil CO₂ efflux than the baseline of NT, respectively (P≤0.001).     

Effect of Raw and NH4+-enriched Zeolite on Nitrogen Uptake by Wheat and Nitrogen Leaching in Soils with Different Textures

Leaching of nutrients in soil can change the surface and groundwater quality. The present study aimed at investigating the effects of raw and ammonium (NH₄⁺)-enriched zeolite on nitrogen leaching and wheat yields in sandy loam and clay loam soils. The treatments were one level of nitrogen; Z₀: (100 kg (N) ha^?1) as urea, two levels of raw zeolite; Z₁:(0.5 g kg^?1 + 100 kg ha^?1) and Z_2: (1 g kg^?1 + 100 kg ha^?1), and two levels of NH₄⁺-enriched zeolite; Z₃: (0.5 g kg^?1 + 80 kg ha^?1) and Z₄: (1 g kg^?1 + 60 kg ha^?1). Wheat grains were sown in pots and, after each irrigation event, the leachates were collected and their nitrate (NO₃^?) and NH₄⁺ contents were determined. The grain yield and the total N in plants were measured after four months of wheat growth. The results indicated that the amounts of NH₄⁺ and NO₃^? leached from the sandy loam soil were more than those from the clay loam soil in all irrigation events. The maximum and minimum concentrations of nitrogen in the drainage water for both soils were observed at control and NH₄⁺-zeolite treatments, respectively. Total N in the plants grown in the sandy loam was higher compared to plants grown in clay loam soil. Also, nitrogen uptake by plants in control and NH₄⁺-zeolite was higher than that of raw-zeolite treatments. The decrease in the amount of N leaching in the presence of NH₄⁺-zeolite caused more N availability for plants and increased the efficiency of nitrogen fertilizers and the plants yield.