钾解吸动力学方程及方程常数的应用

Elovich,parabolic diffusion,power function and exponential equations were used to describe K desorption kinetics of 12 soils in a constant electric field of electro-ultrafiltration(EUF),Results showed that the Elovich,parabolic diffusion and power function equations could describe K desorption kinetics well owing to their high correlation coefficients and low standard errors;but the exponential equation was not suitable to be used in this study due to its relatively low correlation coefficients and relatively high standard errors.This work established successfully the relationships between the constants(slope or intercept)of kinetic equations and the barley responses to K fertilizer in the multiple-site field experiments and K-supplying status of soilsk,the constants of Elovich,parabolic diffusion and power function equations were very significantly or significantly correlated to the soil available K,relative yield of barley and K uptake of barley in NP plot.It was suggested that the kinetic equation constants could be used to estimate K-supplying power of soils.     

土壤钾解吸的动力学方程和大麦反应的关系

本文应用Ｅｌｏｖｉｃｈ、抛物线扩散、权函数和指数方程研究电超滤恒电场下１２种土壤钾解吸的动力学。Ｅｌｏｖｉｃｈ、抛物线扩散和权函数方程具有高的相关系数和小的标准差，可以很好地描述土壤钾解吸的动力学，而指数方程的相关系数低和标准差大而不适宜应用。本文成功地建立了动力学方程与大麦多点田间试验钾肥反应和土壤钾素状况之间的相关关系，Ｅｌｏｖｉｃｈ、抛物线扩散和权函数方程的常数（斜率或截距）与土壤速效钾、大     

Mathematical models to study the kinetics of potassium release from swell-shrink soils of Central India in relation to their mineralogy

Employing four mathematical models (first-order, parabolic-diffusion, Elovich and zero-order), kinetics of potassium desorption from eight soils with and without cropping were studied to evaluate their ability in explaining K release from soils. The decline in the soil test K in cropped soils over original soils was drastic in easily desorbable forms compared to that of strongly held forms like 3 M H₂SO₄ K. Results showed that parabolic diffusion as well as first-order kinetic equation explained the K release data well for both original and K depleted (cropped) soils. Elovich and zero-order equations were not suitable to describe the kinetic data. However, zero-order equation explained K release data better in case of K-depleted soils as compared to original soils. Soils with higher initial K contents registered higher release rate constants. Over the entire period of cropping the range of release rate (b) decreased from 1.26 to 1.53 × 10^?2 to values ranging from 1.12 to 1.30 × 10^?2 h^?1. In contrast, the first-order equation, parabolic diffusion showed higher b values for cropped soils as they represent the diffusion gradient. Mica and its biotite content in both silt and clay fractions showed significant correlation (r) with b values. Similarly with the rate of K release, clay content of soils maintained significant r whereas the silt content did not.     

不同土壤钾素释放动力学及其供钾特征的研究

应用自行研制的连续流动交换仪研究了取自不同类型的19个土壤样品的钾素释放动力学及其供钾特征。不同土壤钾的释放差异很大,钾的释放持续时间变幅为100～600分钟;最大释放速率变幅为0.46～20.55毫克千克-1分-1;平均释放速率变幅为0.009～1.25毫克千克-1分-1;总释放量变幅为40～430毫克千克-1。供试土壤钾的释放过程可以用一级反应方程拟合,表明钾的释放速率主要受交换位上钾离子饱和度的影响。应用一级方程计算出钾的释放速率常数变幅为5.4810-3～65.6210-3分-1。多数土壤的钾释放过程符合单一的一级反应;而以云母类为主,且含有部分绿泥石的土壤的钾释放过程由两个速率不同的一级反应构成,表明不同吸附位上的钾离子可能有不同的释放机制。用供试土壤连续种植玉米幼苗57茬进行土壤钾素耗竭试验,结果表明应用连续流动交换仪研究得出的土壤钾素释放的动力学参数可以较可靠地评价土壤的供钾特征。释钾速率快,持续时间长,总释放量大的土壤(如青海栗钙土),在耗竭试验中显出很强的供钾能力;而释钾速率慢,持续时间短,总释放量小的土壤(如广东砖红壤)在盆栽试验中供植物吸收的钾量很低。有的土壤(如四川紫色土)钾的总释放量不低,但释放速度快,持续时间短,在盆栽试验     

The use of rate equations for a quantitative description of K desorption from soils in an external electric field (electro-ultrafiltration)

Ions can be extracted from soils by applying an external electric field to a soil suspension. When a constant field strength is employed characteristic desorption parameters can be calculated from the results, such as maximum desorbable quantity, halftime, and rate constant. The method consists of a combination of electrodialysis and ultrafiltration and is called electro-ultrafiltration (EUF). It was found that the K transfer from the central compartment A to the cathode compartment B follows a first order rate law, if compartment A contains only the solution of a strong electrolyte such as KCl. If a soil suspension is introduced into compartment A the bulk of K that is transferred to compartment B has first to be desorbed from the soil particles hence the designation as desorption for the transfer from a soil suspension. In this case a second order rate law is followed. The rate equations allow the calculation of the quantity of K involved in the desorption process and the rate with which it is released. It was found that invariably only the exchangeable K takes part in the desorption reaction. The desorption rate differs between soils and depends on clay content and the quantity of exchangeable K present in the soil. It is suggested that the desorption data may provide a means of describing the soil K status by kinetic parameters.     

土壤钾释放速率参数的理论计算及其实践应用

选用二种电场强度研究２０个低丘红壤玉米田试验的钾释放速率特性,用二级动力学方程来表征,并求得土壤释放的速率方程和钾释放的初始速率等参数。     

Time‐dependent zinc desorption in soils

Abstract

Time dependent zinc (Zn) desorption in eight benchmark soils of India was studied in relation to various pH values and ionic strengths. Soil samples were equilibrated in solutions containing 10 μg Zn g^‐1 soil at pH 5.5,6.5, and 7.5 for 48 h at 25±2°C, and adsorbed Zn extracted with calcium chloride (CaCl₂) for various periods of time. Desorption of Zn decreased with increasing pH, and the desorption rate decreased abruptly at pH 7.5. In contrast, an increase in the equilibration period and ionic strength of the background electrolyte increased Zn desorption. Four rival kinetic models were fitted and evaluated for their suitability for describing the Zn desorption process. Reaction rate constant (ß) calculated from the Elovich model for the different soils ranged from 9.99 to 25 (mg Zn kg^‐1)^‐1. The different kinetic models tested indicated that Zn desorption in soils was a diffusion controlled process. The desorption was rapid in the first 4 h, followed by slower phase in the rest of the time at all the pH values indicating a biphasic desorption, characteristic of a diffusion controlled process. The ß value for the Elovich equation showed a strong association with soil clay content and cation exchange capacity (CEC). Further, the best prediction of Zn desorption reaction rate constant could be made using multiple‐regression equation with soil clay content and CEC as variables.     

Potassium fertilization on sandy soils in relation to soil test,crop yield and K-leaching

To study the influence of potassium (K) fertilizer rate on soil test K values, crop yield, and K-leaching in sandy soils, four long-term fertilizer experiments (0–60–120–180 kg K ha^?1 a^?1) were initiated in 1988 in northern Germany on farmers fields. Clay content of the plow layer was about 4%, and organic matter between 2% and 5%. Plant available soil K was estimated with the double lactate (DL) method. Small grain cereals (rye and barley) did not respond to K fertilization in the 7-year period even though the soil test value of the K-0 plots decreased from ca. 90 to ca. 30 mg K_DL kg^?1 within 3 years. This value remained almost constant thereafter. Crop removal (including straw) of 75 kg K ha^?1 a^?1 was therefore apparently supplied from nonexchangeable K fractions. Compared to the optimum, no K application reduced the yield of potato by up to 21%, and that of white sugar yield up to 10%. Maximum potato yield was obtained by annually applying 60 kg K ha^?1 which resulted in a test value of 60 mg K_DL kg^?1 soil. Maximum potato yield was also obtained at 40 mg K_DL kg^?1 soil, however, with a single application of 200 kg K ha^?1. Similar results were obtained with sugar beet. This indicates that for maximum yield, even for K demanding crops, it is not necessary to maintain K_DL values above 40 mg K kg^?1 soil throughout the entire crop rotation. Soil test values increased roughly proportional to the K fertilizer level. About 120 kg fertilizer K ha^?1 a^?1, markedly more than crop K removal, was required to maintain the initial K_DL of 90 mg kg^?1. The K concentration of the soil solution in the top soil measured after harvest was increased exponentially by K fertilizer level and so was K leaching from the plow layer into the rooted subsoil. The leached quantity increased from 22 kg K ha_?1 a_?1 in the plot without K application to 42.79 and 133 kg Kha^?1 a^?1 in plots supplied with 60, 120 and 180 kg K ha^?1 a^?1 respectively. Soil test values around 100 mg K_DL kg^?1 on sandy soils, as often found in the plow layer of farmers fields, lead to K leaching below the root zone that may exceed the critical K concentration of 12 mg K T^?1 for drinking water.     

不同提取方法土壤非交换性钾释放动力学及其速率的研究

采用Ca2+饱和土壤的 0.50molL-1硝酸、0.0 1molL-1草酸和氢质阳离子交换树脂恒温连续提取法 ,利用Elovich和二级动力学模型 ,结合生物吸钾试验 ,研究探讨了描述土壤非交换性钾释放及其速率较为理想的连续提取法及其动力学模型。研究结果表明 ,氢质树脂提取法的Elovich模型描述非交换性钾释放及其速率的效果较为理想 ,拟合方程的相关系数达极显著水平(r =0.982～ 0.996 ) ;不同时间非交换性钾累积释放量的计算值与实测值的标准差最小 (S =1.335～2.480 ) ;通过速率方程计算的不同时间非交换性钾释放速率与黑麦草吸收的非交换性钾数量的相关性也最为密切 (r =0.944～ 0.963) ,故氢质阳离子交换树脂连续提取法结合Elovich模型是描述土壤非交换性钾释放及其速率较为理想的组合方法。以伊利石为主的 2、3和 8号土壤非交换性钾释放速率明显高于其它以高岭石或蒙脱石为主的供试土壤     

Organic and Inorganic Integrated Fertilization Improves Non-exchangeable Potassium Release and Potassium Availability in Soil

ABSTRACT

Potassium (K) plays several key roles in plant metabolism and crop productivity. Non-exchangeable K (NEK) makes K available in soil and to the crops. Impact of integrated use of organic and inorganic fertilizers on NEK release was studied in an ongoing long-term fertilizer experiment (LTFE) under rice-wheat cropping system. The experimental plots in the field were laid out following a randomized complete block design (RCBD) with eight treatments and three replications. Addition of K increased the release of NEK, but integrated use of manure with fertilizers increased K release of NEK from soils than the use of inorganic K alone. The maximum NEK (102 × 10^–2 cmol kg^?1 of soil) was released under 100% NPK with Farm Yard Manure (FYM) treatment and the minimum (93.9 × 10^–2 cmol kg^?1 of soil) under 100% NP-treated soils. Four kinetic models, parabolic diffusion, first order, power function, and Elovich, were tested for characterizing K release data and Elovich model provided the best fit (R² = 0.96–0.97). Available K status in soils, rice yield, and plant K uptake increased significantly with the increase in NEK release rate. Our research outcomes suggest that the addition of K through integrated fertilization is needed to improve plant nutrition and productivity of the intensive rice-wheat cropping systems.     

Evaluation of Adsorption Isotherm Models for Potassium Adsorption under Different Soil Types in Wolaita of Southern Ethiopia

Adsorption isotherm is essential for predicting its mechanisms, which are important for potassium (K) fertilizer application and to recommendation appropriate rates for acidic soils. Thus, the objective of this study was to evaluate K adsorption characteristic of the selected soils by comparing different adsorption models with soil properties of the soil in different districts (Sodo Zurie, Damot Gale, Damot Sore and Boloso Sore) in the Wolaita Zone of Southern Ethiopia. Four adsorption isotherms are: Langmuir, Freundlich, Temkin, and Van Huay were used to describe adsorption processes. Composite surface (0-20 cm) depth soil samples from four districts sites were collected. The results revealed that the K adsorption data coincide with both models with (r² = 0.99). However, Freundlich model was better in describing K adsorption than the other model. The adsorption maxima(ad_(max), distribution coefficient, buffer capacity (BC), and adsorption capacity(a_(capacity) values of soils ranged from -333 to334.5,0.54 to78.7,159.9 to 389.3, and 327 to 417mg Kkg^-1 respectively, these results showed that Sodo Zurie, Bolos Sore and Demote Sore were effective model parameters. Van Huay a_(capacity) 417mg Kkg^-1 while the bonding energy constant Langmuir is -0.075mg Kkg^-1 in Bolos Sore soil compared to other soils, which were found to be more valuable in discriminating between high K adsorption soils. Correlation between some soil properties with ad_(max) were positively a highly correlated with clay, pH, organic carbon (OC) and exchangeable potassium with r² = 0.92**, 0.93**, 0.95** and 0.96 ** respectively, but negatively correlated with bonding energy with r²= -0.79, -0.80,-0.77 and -0.72 respectively, while calcium carbonate (CaCO3) was very highly correlated with ad_(max) r²= 0.99***). The Freundlich constant, Temkin BC, and Van Hauy a_(capacity) were correlated with CaCO3 content soils with r²=0.12,-0.01,and 0.12,respectively, while slope (1/n) was significantly negatively correlated with soil cation exchange capacity (CEC), CaCO₃, clay contents and exchangeable K and Mg²⁺ with r²= 0.04, -0.67, -0.78, -0.69, and –0.69, respectively. These findings reveal the extent of K depletion in the soils of Wolaita providing a baseline for K rates required for crop production and validation of all models through real-time experiments in the field; this is recommended before the models are used on a large scale basis.     

Oxalic Acid Effect on Potassium Release from Typical Rice Soils of Kashmir

Batch experiments were employed to examine the influence of oxalic acid on release kinetics of potassium (K) from soils along with adsorption and desorption of soil K⁺. The soils used were three rice soils from high-, mid-, and low-altitude zones. The results showed that soil K extracted using 0.2 mol L^–1 oxalic acid was similar to that of 1 mol L^–1 boiling nitric acid (HNO₃). The relation between K release (y) and concentrations of oxalic acid (c) could be best described as y = a + b log c, whereas the best-fit kinetic equation of K release was y = a + b √t. The K release for soils was in the order Bonbagh > Ganasthan > Kreeri. An oxalic acid solution with low pH was able to release more K. Oxalic acid decreased soil K⁺ adsorption and increased desorption, the effect of which tended to be greater at lower pH.     

Release Kinetics of Nonexchangeable Potassium by Different Extractants from Soils of Varying Mineralogy and Depth

Abstract

Nonexchangeable potassium (K) release kinetics of six major benchmark soil series of India as affected by mineralogy of clay and silt fractions, soil depth and extraction media was investigated. The cumulative release of nonexchangeable K was greater in smectitic soils (353 mg K kg^?1 at 0‐ to 15‐cm depth and 296 mg K kg^?1 at 15‐ to 30‐cm depth, averaged for 2 soils and 3 extractants) than in illitic (151 mg K kg^?1 at 0‐ to 15‐cm depth and 112 mg K kg^?1 at 15‐ to 30‐cm depth) and kaolinitic (194 mg K kg^?1 at 0‐ to 15‐cm depth and 167 mg K kg^?1 at 15‐ to 30‐cm depth) soils. Surface soils exhibited larger cumulative K release in smectitic and illitic soils, whereas subsurface soils had larger K release in kaolinitic soils. Among the extractants, 0.01 M citric acid extracted a larger amount of nonexchangeable K followed by 0.01 M CaCl₂ and 0.01 M HCl. The efficiency of citric acid extractant was greater in illitic soils than in smectitic and kaolinitic soils. Release kinetics of nonexchangeable K conformed fairly well to parabolic and first‐order kinetic models. The curve pattern of parabolic diffusion model suggested diffusion controlled kinetics in all the soils, with a characteristic initial fast rate up to 7 h followed by a slower rate. Greater nonexchangeable K release rates in smectitic soils, calculated from the first‐order equation (b=91.13×10^?4 h^?1), suggested that the layer edge and wedge zones and swelling nature of clay facilitated the easier exchange. In contrast to smectitic soils, higher release rate constants obtained from parabolic diffusion equation (b=39.23×10^?3 h^?1) in illitic soils revealed that the low amount of exchangeable K on clay surface and larger amount of interlayer K allowed greater diffusion gradients, thus justifying the better fit of first‐order kinetic equation in smectitic soils and parabolic diffusion equation in illitic soils.     

不同培肥措施下土壤CO2释放及其动力学研究

实验室恒温密闭培养法研究了 4种培肥措施连续培肥 23年后农田土壤的CO2释放状况及其动力学特征。结果表明 ,含水量 12%至 24%范围内 ,土壤CO2释放过程完全可以用一级反应动力学方程 y =A0(1-e-kt)进行定量描述 (r2=0.9812～0.995 9,P 0.01) ;土壤CO2释放量和潜在可释放C量A0 随含水量增加呈线性增加 (r2=0.9728～0.9987,P0.01) ,速率常数k则随含水量增加呈线性降低 (r2=0.9356～0.9939,P0.01)。不同培肥措施明显影响土壤CO2释放状况及其动力学特征参数 ;NP化肥和厩肥 +NP化肥 2种培肥措施较不施肥对照明显增加了土壤CO2释放量、潜在可释放C量A0和速率常数k ;秸秆 +NP化肥培肥措施较不施肥对照显著增加了土壤CO2释放量、潜在可释放C量A0,但却显著降低了释放速率常数k ;有机无机肥料配合措施 (秸秆 +NP、厩肥 +NP)与单施NP化肥措施比较 ,明显降低了释放速率常数k。     

Quantity–Intensity Relationships of Potassium in Soils under Some Guava Orchards on Marginal Lands

Quantity–intensity relations of potassium (K) were worked out for guava orchard soils. Equilibrium activity ratio of potassium (AR_e ^k) ranged from 0.46?×?10^?3 to 21.30?×?10^?3 (mol L^?1)^0.5. The majority of the samples had less than 1?×?10^?3 (mol L^?1)^0.5, indicating K depletion in these soils due to continuous K mining. AR_e ^k was significantly and positively correlated with available forms of K, K saturation percentage, labile K (K_L), and specific-site K (K_X) and negatively correlated with free energy of exchange (–ΔG). The potential buffering capacity (PBC₀ ^K) of K varied from 8.8 to 286.2 cmol kg^?1/(mol L^?1)^0.5. PBC₀ ^K was positively and significantly correlated with clay content. Sixty percent of the soils had ΔK⁰ values of less than 0.1 cmol kg^?1. High K_G (Gapon selectivity coefficent) indicated high affinity for K in these soils. Leaf K was positively and significantly correlated with ΔK⁰, K_L, and K_X and negatively correlated with –ΔG.     

Influence of applied zinc and organic matter on zinc desorption kinetics in calcareous soils

Zinc (Zn) desorption from an exchange complex to solution, the release of Zn from organic matter (OM), crystalline minerals and other precipitates into the solution phase, is the process that controls Zn mobility in soils. An experiment was conducted to determine the pattern of Zn desorption and the soil characteristics affecting it. Desorption of Zn in 15 calcareous soils from southern Iran, treated with 10 mg Zn kg soil^?1 as zinc sulfate (ZnSO₄?7H₂O) and 10 g organic matter (OM) kg^?1 as feedlot cattle manure, equilibrated and extracted with diethylenetriamine pentaacetic acid (DTPA), was studied. Eight kinetic models were evaluated to describe the rate of Zn desorption of soil extracted with DTPA. There was a rapid rate of desorption during the first 4 h followed by a slower rate during the next 12 h. Two-constant rate and simple Elovich models were determined as the best models describing Zn desorption kinetics. Zinc desorption increased as Zn was applied, whereas it decreased with applied OM. The constants of the simple Elovich (β_s) and two-constant rate equations (a and b) were closely correlated with cation-exchange capacity (CEC), OM and pH, which affect Zn solubility, sorption–desorption and diffusion in soils.     

Beziehung zwischen dem durch K-Düngung erzielbaren Mehrertrag und dem K-Gehalt der Böden nach Feldversuchen in der Bundesrepublik Deutschland

Relationship between the maximum yield increase from K fertilization and the K content of the soils after field trials in the Federal Republic of Germany Several hundred long term potassium field experiments with crop rotation and with plant residues like straw and sugar beet leaves removed from the fields, on different soils of the FRG were evaluated. The K content in the top soil was determined by the DL and CAL methods (K(lact)), given in mg K₂O/100g soil. No relationship could be found between K(lact) and the maximum possible yield increase for wheat, barley, sugar beets, and potatoes, if K(1act) was >5 mg/100g. It seems unnecessary, therefore, raise the K content of the soils. Occasional significant positive yield response should be less emphazised than average yields. Economical average yield increases on K fertilization were found with sugar beets and potatoes, rarely with barley but never with wheat. In all longterm trials the K amount of fertilizer required for maximum possible yield increase was above the amount of K removed by the crop. 7 to 27year field trials on clayer soils show that the K content of the soil may drop to 5-10mg K20(CAL) without causing increased yield response to K fertilization. The yield responses to K fertilizer are dependent to a high degree on the season (weather conditions), as was shown by high yield increases in exceptionally dry seasons. The large content of plant available Kin the top soils was due to high K fertilization during the past decades and the illitic nature of the soils. From the results of the field trials it may be concluded that an amount of K fertilizer which replaces K removed by the crop is sufficient for all soils with 5-10mg K₂O; for > lOmg K₂O(lact) K fertilization can be less than actual K removal. Because of large variations, the K(lact) figures (chapter 5),are of very limited value for predicting fertilizer requirements. The average K fertilizer consumption used (1981/82) of the FRG was higher than the K removed from soils by 79 kg K₂O/ha (in 1982). Official recommendations of K fertilizer in the FRG as well as the amounts of K actually applied are both in disagreement with the results of fertilizer experiments in the field.     

浙江低丘红壤供钾强度和容量关系及其应用

采用多点玉米田间试验和室内分析相结合的方法,研究了浙江省20个低丘红壤钾素供应的强度和容量关系,并求得相应的参数。供钾强度指标(AR0)变幅为0.0004499～0.006579,平均为0.002001(molL-1)0.5;供钾容量指标(-△K0)变幅为0.3153～4.057,平均为1.578cmolkg-1;钾素供应的缓冲容量(PBC)变幅为442.2～941.2,平均为680.3cmolkg-1(molL-1)0.5。以20个玉米田间试验子粒相对产量、总干物质相对产量、无钾处理玉米吸钾量以及土壤速效钾、酸溶性钾和缓效钾作为参比标准,与AR0、-△K0和PBC作相关分析,结果表明:AR0、-△K0与土壤速效钾、酸溶性钾、玉米子粒相对产量,总干物质相对产量和无钾处理玉米吸钾量之间达极显著相关(P=0.01),与缓效钾呈显著相关(P=0.05)。PBC与玉米子粒和总干物质相对产量之间达极显著相关、与土壤速效钾之间达显著相关。因此,AR0和-△K0能很好地反映土壤供钾能力,PBC在一定程度上也能表征土壤钾肥力。6个参比标准与AR0、-△K0和PBC之间的多元回归分析结果比简单地一元回归分析结果要好,把AR0、-△K0和PBC结合起来综合说明土壤供钾能力和钾素的生物有效性是可行的。     

围海造田长期耕种稻田和旱地土壤氮矿化速率及供氮潜力比较

围海造田是沿海地区拓展土地面积的主要途径。土壤氮矿化参数是揭示围海造田土壤肥力演变和土壤氮供应的重要指标,但是我国沿海造田土壤的相关研究少有报道。本研究以杭州湾南岸海积平原上慈溪市1000年和520年筑塘造田区为对象,选择4个代表性采样点,每个点从低洼稻田采集1个表层混合水稻土,在其相邻高地采集1个表层混合旱地土壤,共8个样品。采用间隙淋洗法研究了土壤样品氮矿化动力学特征。结果如下: 119 d培养试验证实水稻土和旱地土壤有机氮矿化动力学符合一级反应动力学方程Nt=N0(1-e-kt); 水稻土有机氮矿化势（N0）为82.7～161.9 mg/kg（平均114 mg/kg）,占有机氮的7.3%,旱地土壤N0为63.9～104.4 mg/kg（平均83.4 mg/kg）,占有机氮的7.3%; 水稻土有机氮矿化速率（k）为0.033～0.114/d（平均0.064/d）,旱地土壤k为0.007～0.023/d（平均0.020/d）。土壤综合供氮指标（N0k）,水稻土为3.8418.46 mg/(kgd)［平均8.0 mg/(kgd)］,旱地土壤为0.54～2.66 mg/(kgd)［平均1.6 mg/(kgd)］。水稻土总氮含量为1.4～2.0 g/kg （平均1.6 g/kg）,旱地为0.87～2.0 g/kg（平均1.3 g/kg）。可见,水稻土氮库、供氮潜力和速率均大于相邻旱地土壤。因此,从土壤氮肥力来讲,相对于旱地,围海形成的水稻田更具有可持续利用性。     

Soil Potassium‐Release Characteristics and the Correlation of its Parameters with Garlic Plant Indices

Abstract

Potassium (K)‐release characteristics (PRC) of soil play a significant role in supplying available K. Information about PRC in the Hamadan soils is limited. The objective of this research was to study the PRC in nine soils from the Hamadan province by successive extraction with 0.01 M CaCl₂ over a period of 2000 h. The correlation of kinetic equation rate constants with soil properties and garlic indices was also studied. The release of K was initially rapid. More than 60% of the total K released during the first 168 h. The amount of K released after 168 h varied among soils and ranged from 292.8 to 736.8 mg kg^?1. The amount of K released after 2000 h was significantly correlated with K extracted by 1 M HNO₃, 0.01 M CaCl₂, and 0.1 M BaCl₂, whereas it was not significantly correlated with other soil properties. Potassium‐release characteristics were evaluated using five kinetic equations. Statistical analysis showed that the Elovich equation described the K‐release kinetics. A plot of other equations shows a discontinuity in slope at 168 h. Thus, two equations were applied to segments of the total reaction time (2 to 168 and 168 to 2000 h). The release‐rate constants (slope) in segment 1 are higher than in segment 2. The release‐rate constant of the Elovich equation and the zero‐order equation in two segments were significantly correlated with 1 M HNO₃, 0.01 M CaCl₂, and 0.1 M BaCl₂. Rate constants of the other equations were not significantly correlated with soil properties. The release‐rate constants of the Elovich equation and release‐rate constants of the zero‐order equation in two segments were significantly correlated with garlic indices. Rate constants of other equations were not significantly correlated with garlic indices. The results of this research showed that the Elovich and zero‐order equations can be used to describe K‐release characteristics.