土壤溶质迁移的指数函数模型

边界层方法是描述土壤溶质迁移的简单方法,通过边界层距离与时间的关系可以估计溶质迁移参数。基于边界层方法,研究了土壤溶质迁移的数学模拟及相应参数估计问题。假定土壤溶质浓度剖面为指数函数,得到了描述溶质浓度分布的指数函数模型。各参数对边界层距离的影响分析表明,应选取较小的孔隙水流速度、短历时推求土壤溶质迁移参数;对不同模型预测土壤溶质分布进行比较,结果表明,在短距离处指数型解与精确解的误差比其它都要小。误差分析表明了指数函数模型的有效性和实用性。     

土壤团聚状况对Cl~-运移规律的影响

在室内条件下采用垂直土柱易混置换法,研究土壤团聚体大小对非反应性溶质(Cl-)迁移的影响,并以相同直径的细砂柱作为对照,揭示土壤团聚状况对溶质迁移的影响规律。结果表明:在相同实验条件下,随着土壤团聚体直径的减小,孔隙水流速、溶液流速均减慢,在介质颗粒粒径为0.25～0.5mm时发现优势流的存在;通过分析比较土柱与砂柱的穿透曲线、运移参数,发现穿透曲线与土壤孔隙分布状况密切相关;随着土壤团聚体直径的减小,Cl-在土柱中的溶质出流推后,淋洗结束提前,水动力弥散系数(Dsh)逐渐减小,说明介质的孔隙构造是影响溶质运移的一个重要因素。     

非反应性物质在土壤中的迁移及其参数确定

采用一维对流－水动力弥散方程研究了非反应性化学物质在土壤中的迁移行为。通过实验研究了土壤团聚体大小和孔隙水流速对非反应物质在土壤中迁移的影响。结果表明,对流－水动力弥散方程能较好地预报氚（＾３Ｈ２Ｏ）的穿透英线和迁移行为,随着团聚体由小变大,＾３Ｈ２Ｏ在其土柱中的穿透曲线的溶质出流提前,而淋洗结果推迟,峰值变小,最佳拟合Ｄ值由小变大。流速增加,Ｄ值增大,扩散现象加剧,Ｄ和流速呈正比。这为进一步研究     

利用CT数字图像和网络模型预测近饱和土壤水力学性质

在近饱和状态下,土壤的有效水力学性质主要取决于较大孔隙的结构特征,而这又决定了土壤中的优势流通道以及溶质的运移.基于孔隙形态学特征的网络模型可以很好的表现出较大孔隙的几何形态与拓扑特征对有效水力学性质的影响.本文通过对连续土壤切片CT图像的分析,定量获取了土壤孔隙的大小分布以及连通性参数.在此基础上建立了相关网络模型,在孔隙尺度上模拟了土壤中的水分运动过程并预测了近饱和土壤水力学性质.实验结果表明,虽然随机网络模型对室内填装土样本水力学性质的预测结果要优于相关网络模型,但是结合了实测孔隙形态特征的相关网络模型能够表现出田间原状土样本的双重孔隙度结构,其预测结果更符合实际的土壤结构特征.     

土壤溶质迁移至地表径流过程的室内模拟试验

关于土壤溶质迁移到地表径流,现有研究大多是概念性的认识,对迁移过程中各个部分的定量研究却很少。该文为了量化研究土壤溶质迁移流失过程及其作用机理,通过设计2种水文条件即土壤水分饱和和土壤渗流条件,其中土壤渗流条件设置了2种水头（5 cm,10 cm）,采用人工模拟5组不同地表径流流速,分别研究土壤溶质迁移到地表径流过程中4种途径：土壤侵蚀、伯努利效应、扩散和对流。试验结果表明了伯努利效应导致土壤溶质迁移量增加;特别是在土壤水分饱和条件下,当地表径流流速从55 mL/s升到 200 mL/s时,伯努利效应引起的土壤溶质流失通量占总流失通量的比例从14%升到53%,在土壤水分饱和条件下,混合层深度小于5 mm;但是在土壤渗流条件下,混合层深度随着水头的高低和径流流速的大小而变化。土壤溶质迁移过程同地表径流流速和地下水位高低有着重要关系。     

土壤孔隙结构定量化研究进展

土壤孔隙结构是土壤结构的重要方面,土壤大孔隙引起的优先流和溶质优先迁移与地下水污染、养分流失和灌溉水浪费都有着密切的关系;对土壤孔隙结构的研究具有重要的实践意义和指导作用。本文在综合国内外研究文献的基础上,对前人研究进行系统总结,介绍土壤孔隙结构的获取手段、孔隙结构的表征和模拟方法,并且对今后土壤孔隙结构研究的热点进行了展望,以期为今后进行土壤孔隙结构建模的深入研究提供帮助。     

土壤容重对溶质迁移过程的影响

土壤在径流作用下发生流失、土壤溶质迁移等现象,是一个受径流、土壤性质、下垫面特性、土地利用方式等多种因素综合影响的复杂过程.利用斜坡土槽,采用一定的坡度和实验流量,对不同容重的土样进行了室内放水实验,研究了在土壤饱和条件下,土壤容重对土壤溶质迁移过程的影响.实验结果表明:(1)随径流作用时间的增加,单位时间内土壤溶质迁移量逐渐减少,其关系可用幂函数来描述;(2)土壤溶质发生迁移是受地表径流和壤中流共同作用的结果;(3)土壤容重对土壤溶质迁移过程影响总体表现为土壤容重越大,随径流迁移的土壤溶质量越少;(4)土壤容重增加相同幅度,但同时刻随径流迁移的土壤溶质递减量逐渐减少.     

降雨-径流条件下土壤溶质迁移过程模拟

通过雨滴的打击加速土壤表面溶质迁移至地表径流过程。通过设计3种水文条件即控制排水状态（-5 cm）、土壤水分饱和状态和土壤渗流状态（5 cm）,采用人工模拟3种降雨强度（30、60和90 mm/h）,及同时外加模拟相对于降雨量的0、2、4和10倍径流量,研究土壤溶质迁移到地表径流过程中扩散过程的规律。试验结果表明降雨强度、或地表径流总量、或地表水位线的增加,均加速土壤溶质的扩散过程。渗流作用下,对流-扩散作用存在着一种交互作用,能加速分子扩散过程。土壤溶质迁移过程同降雨强度、地表径流量和地下水位高低有着重要关系。     

利用两区和两流区模型模拟氯离子在黑垆土中的迁移过程

以原状长武黑垆土为研究对象,针对不同输入方式、不同孔隙水流速条件下的氯离子溶质迁移过程,分析原状土壤中大孔隙存在条件下溶质迁移的特征,对两区模型和两流区模型的各拟合参数进行对比和分析。结果表明:大小脉冲输入条件下,氯离子浓度在试验土柱中均随穿透试验的进行呈现先增加而后降低的趋势,其峰值大小及其出现位置随孔隙水流速变化差异显著,且小脉冲输入时溶质穿透曲线较大脉冲时的不对称和拖尾现象更为显著;两流区模型相对于两区模型可较好描述氯离子的穿透曲线;两模型所得模拟参数随孔隙水流速的变化差异性较大。两模型拟合所得弥散度(λ)随孔隙水流速的变化趋势相同,但两流区模型拟合的弥散度大两区模型拟合值2个数量级。两模型拟合所得可动水含量(β)均随孔隙水流速的增加相应增加,而质量交换系数(α)值均极小。     

预测土壤水力性质的形态学网络模型应用研究

土壤水力性质是研究非饱和带中水分和溶质运移的重要参数 ,可以用孔隙网络模型进行预测。通常采用的网络模型中的参数是任意指定的 ,无法真实反映土壤孔隙空间的形态特征。本文采用了一种基于孔隙形态学的网络模型来预测土壤的水力性质 ,即通过图像分析来直接测定孔隙的大小分布及其连通性 ,并将其结合到网络模型中 ,最大程度地再现了三维的土壤孔隙结构。本文根据河南封丘地区采集的砂壤土样本图像分析结果 ,采用形态学网络模型预测了其水力性质 ,同时也进一步评价了这种模型的优缺点及其应用前景。     

Movement of solute through a porous medium under intermittent leaching

Excess salts may be removed from soil by leaching, but ponding water on the soil's surface and allowing infiltration requires large quantities of water. During such leaching water flows preferentially through macropores between aggregates, while the flow within aggregates is much less. Consequently, solute within aggregates is removed much more slowly, thus decreasing overall leaching efficiency. For this reason intermittent ponding can be more efficient because it allows time for solute to diffuse to the surfaces of aggregates during the rest period and subsequently be removed in macropore flow. We explored solute transport in aggregated soils under intermittent leaching in three ways: theoretically, by laboratory experiments on columns of porous ceramic spheres as analogues of aggregates, and by simulation. Solute movement during displacement is described by the mobile-immobile convection-dispersion equation. During the rest period flow ceases, and solute redistributes within the aggregates by diffusion, the key variable being the effective diffusion coefficient, D_e of the solute in the aggregates, and longitudinally by diffusion within macropores (though this was ignored in the simulation). We estimated D_e for our porous spheres from observations of solute outflow into finite volumes of stirred distilled water. The theory was validated against experiments on saturated columns for different aggregate-size distributions, flow velocities, and displacement and rest periods, with most parameters estimated independently. Experiments and simulations showed that water savings of 25% were possible under our laboratory conditions, increasing as aggregate size, flow velocity and duration of rest period increased. The potential of intermittent leaching in the field is considered.     

土壤水流通量对饱水带溶质运移参数的影响

The transport processes of solutes in two soil columns filled with undistrubed soil material collected from an unsaturated sandy aquifer formation in Belgium subjected to a variable upper boundary condition were identified from breakthrough curves measured by means of time domain reflectometry(TDR),Solute breakthrough was measured with 3 TDR probes inserted into each soil column at three different depths at a 10 minutes time interval.In addition,soil water content and pressure head were measured at 3 different depths.Analyteical solute transport models were used to estimate the solute disperison coefficient and average pore-water velocity from the observed breakthrough curves,the results showed that the analytical solutions were suitable in fitting the observed solute transport,The dispersion coefficient was found to be a function of the soil depth and average proe-water velocity,imposed by the soil water flux.the mobile moistrue content on the other hand was not correlated with the average pore-water velocity and the dispersion coefficient.     

Simulation of Water and Chloride Transport in Field Lysimeters

In a lysimeter study in the field with soil samples of a Fluvisol the transport of chloride was monitored under high frequency irrigation. The results of this investigation were used for verification of two computer models of different complexity. One was a transient state water and solute movement model the other a simplified steady state model. It was demonstrated that both models predicted nearly equally well the chloride concentrations in the drainage water. For many practical situations, the simple model may be all that is needed to predict the downward movement of solutes in field soils.     

石砾参数对土壤水流和溶质运移影响研究进展

土壤水流和溶质运移一直是土壤学研究的热点,溶质运移理论主要应用于地下水污染、污染物运移、土壤重金属污染研究等方面。溶质主要通过优先流和基质流进行运移,影响溶质运移因素很多,主要包括土壤结构、质地、水力传导率、体积质量、初始含水量、根系、石砾等。石砾作为土壤质地中的一个分级单位,与溶质运移关系较为复杂。本文综合介绍了石砾基本内涵以及石砾对土壤水流和溶质运移影响研究进展;系统阐述了石砾内部参数(石砾覆盖度、含量、粒径、空间异质性等)和外部参数(根石结构、干湿冻融、耕作等),指出目前研究主要量化土壤表面及土壤表层石砾参数对水文效应、土壤侵蚀、入渗以及径流的影响,然而石砾参数对溶质运移影响研究不够系统,石砾参数与溶质运移关系研究尚处于初步阶段,对土壤深层石砾研究缺乏;归纳了石砾参数研究技术手段及模型;探讨了目前石砾参数对土壤水流和溶质运移影响研究存在的问题以及今后研究趋势。     

田间尺度下污染物在土壤中的迁移: 目前的认识和存在的问题

Agro-chemical transport processes at different scales are discussed and relevant opening question are identified by literature review to make some suggestions concerning the improvement of research methods for filed scale solute transport by aid of evaluation of existing models,and examining transport behaviors of solute in vadose zones on different scales.The results indicate that present research progess and understanding on field scale solute transport have not yet been enough to guarantee the use of our models for the management of field soulte movement.Much more research work needs to be done,particularly,in aspects of high resolution of spatial structures relevant to the hydraulic and transport properties,explicit numerical simulation of actual structure on field scale and field measurement corroborated with model development.     

An analytical solution for advance of solute front in soils

Based on the assumption that solute transport in a semi-infinite soil column or in a field soil profile can be described by the boundary-layer method, an analytical solution is presented for the advance of a solute front with time. The traditional convection-dispersion equation (CDE) subjected to two boundary conditions: 1) at the soil surface (or inlet boundary) and 2) at the solute front, was solved using a Laplace transformation. A comparison of resident concentrations using a boundary-layer method and an exact solution (in a semi-infinite-domain) showed that both were in good agreement within the range between the two boundaries. This led to a new method for estimating solute transport parameters in soils, requiring only observation of advance of the solute front with time. This may be corroborated visually using a tracer solution with marking-dye or measured utilizing time domain reflectometry (TDR). This method is applicable to both laboratory soil columns and field soils. Thus, it could be a step forward for modeling solute transport in field soils and for better understanding of the transport processes in soils.     

The variability of the apparent diffusion coefficient in undisturbed soil columns

In column studies in the laboratory the apparent diffusion coefficients(D)of chloride and TOH for undisturbed and unsaturated soils were determined as a function of the pore water velocity. Parallel the effective diffusion coefficients (D⁺) of Cl^? were measured as a function of water content. It was found that the values of D varied significantly between soil layers and soil types. This findings also held for the low flow velocities studied (0.3 and 1.0 cm/d). The impedance factors to calculate the effective diffusion coefficients (D⁺) from D values in the bulk water, decreased with decreasing bulk densities. In model calculations it was demonstrated that in spite of the differences of D values measured, for many purposes in the field good estimates of the solute distribution in the soils can be obtained by using simple relations between D and v_o.     

地面灌溉技术参数对氮素运移分布影响的研究进展

地面灌溉是应用最广泛的灌水方法，通过优化地面灌溉设计和管理减少水氮淋失，正在成为研究的热点问题，该文对有关成果进行了综述。由于地面灌溉的尺度较大，加之土壤水力参数和溶质运移参数的空间变异，使得地面灌溉施肥条件下溶质(N)运移分布的田间试验研究，无论在技术上还是在投入上都具有一定难度。有关沟灌、畦灌和水平畦田灌溉施肥时水氮分布的田间试验结果指出，肥料(N)分布没有入渗水深分布均匀，且与土壤初始含水率、流量、土壤入渗参数、田面糙率和施肥时机等因素密切相关。在模拟研究方面，文献中报道的模型有纯对流模型、对流-弥散模型、基于活塞流的水平衡模型和传递函数模型等。鉴于地面灌溉条件下水氮运移的复杂性，在水氮运移分布的数学模拟、灌水技术参数和施肥方式对水氮淋失的影响以及灌溉施肥质量评价指标体系等方面尚需要进一步研究。