Trace element composition of the mount st. Helens plume: stratospheric samples from the 18 may eruption

Atmospheric particulate material collected from the stratosphere in the plume of the 18 May 1980 eruption of the Mount St. Helens volcano was quite similar in composition to that of ash that fell to the ground in western Washington. However, there were small but significant differences in concentrations of some elements with altitude, indicating that the stratospheric material was primarily produced from fresh magma, not fragments of the mountain.     

Stratospheric Aerosol Effects from Soufriere Volcano as Measured by the SAGE Satellite System

During its April 1979 eruption series, Soufriere Volcano produced two major stratospheric plumes that the SAGE (Stratospheric Aerosol and Gas Experiment) satellite system tracked to West Africa and the North Atlantic Ocean. The total mass of these plumes, whose movement and dispersion are in agreement with those deduced from meteorological data and dispersion theory, was less than 0.5 percent of the global stratospheric aerosol burden; no significant temperature or climate perturbation is therefore expected.     

Measurements of the imaginary part of the refractive index between 300 and 700 nanometers for mount st. Helens ash

The absorption properties, expressed as a wavelength-dependent imaginary index of refraction, of the Mount St. Helens ash from the 18 May 1980 eruption were measured between 300 and 700 nanometers by diffuse reflectance techniques. The measurements were made for both surface and stratospheric samples. The stratospheric samples show imaginary index values that decrease from approximately 0.01 to 0.02 at 300 nanometers to about 0.0015 at 700 nanometers. The surface samples show less wavelength variation in imaginary refractive index over this spectral range.     

Airborne lidar measurements of the soufriere eruption of 17 april 1979

At the time of the Soufriere, St. Vincent, volcanic eruption of 17 April 1979, a NASA P-3 aircraft with an uplooking lidar (light detection and ranging) system onboard was airborne 130 kilometers east of the island. Lidar measurements of the fresh volcanic ash were made approximately 2 hours after the eruption, 120 kilometers to the northeast and east. On the evening of 18 April, the airborne lidar, on a southerly flight track, detected significant amounts of stratospheric material in layers at 16, 17, 18, and 19.5 kilometers. These data, and measurements to the north on 19 April, indicate that the volcanic plume penetrated the stratosphere to an altitude of about 20 kilometers and moved south during the first 48 hours after the eruption.     

Magmatic vapor source for sulfur dioxide released during volcanic eruptions: evidence from mount pinatubo

Sulfur dioxide (SO(2)) released by the explosive eruption of Mount Pinatubo on 15 June 1991 had an impact on climate and stratospheric ozone. The total mass of SO(2) released was much greater than the amount dissolved in the magma before the eruption, and thus an additional source for the excess SO(2) is required. Infrared spectroscopic analyses of dissolved water and carbon dioxide in glass inclusions from quartz phenocrysts demonstrate that before eruption the magma contained a separate, SO(2)-bearing vapor phase. Data for gas emissions from other volcanoes in subduction-related arcs suggest that preeruptive magmatic vapor is a major source of the SO(2) that is released during many volcanic eruptions.     

Circumglobal transport of the el chichon volcanic dust cloud

The stratospheric dust cloud from the 4 April 1982 eruption of El Chichón volcano in southern Mexico was observed to travel completely around the world in a 3-week period. Images from satellites operated by the National Oceanic and Atmospheric Administration were used to prepare daily maps of the location of the volcanic dust cloud, which is the largest and longest-lasting one so far observed with satellite imagery.     

Characterization of aerosols from eruptions of mount st. Helens

Measurements of mass concentration and size distribution of aerosols from eruptions of Mount St. Helens as well as morphological and elemental analyses were obtained between 7 April and 7 August 1980. In situ measurements were made in early phreatic and later, minor phreatomagmatic eruption clouds near the vent of the volcano and in plumes injected into the stratosphere from the major eruptions of 18 and 25 May. The phreatic aerosol was characterized by an essentially monomodal size distribution dominated by silicate particles larger than 10 micrometers in diameter. The phreatomagmatic eruption cloud was multimodal; the large size mode consisted of silicate particles and the small size modes were made up of mixtures of sulfuric acid and silicate particles. The stratospheric aerosol from the main eruption exhibited a characteristic narrow single mode with particles less than 1 micrometer in diameter and nearly all of the mass made up of sulfuric acid droplets.     

In situ observations of aerosol and chlorine monoxide after the 1991 eruption of mount pinatubo: effect of reactions on sulfate aerosol

Highly resolved aerosol size distributions measured from high-altitude aircraft can be used to describe the effect of the 1991 eruption of Mount Pinatubo on the stratospheric aerosol. In some air masses, aerosol mass mixing ratios increased by factors exceeding 100 and aerosol surface area concentrations increased by factors of 30 or more. Increases in aerosol surface area concentration were accompanied by increases in chlorine monoxide at mid-latitudes when confounding factors were controlled. This observation supports the assertion that reactions occurring on the aerosol can increase the fraction of stratospheric chlorine that occurs in ozone-destroying forms.     

Ozone and aerosol changes during the 1991-1992 airborne arctic stratospheric expedition

Stratospheric ozone and aerosol distributions were measured across the wintertime Arctic vortex from January to March 1992 with an airborne lidar system as part of the 1992 Airborne Arctic Stratospheric Expedition (AASE II). Aerosols from the Mount Pinatubo eruption were found outside and inside the vortex with distinctly different distributions that clearly identified the dynamics of the vortex. Changes in aerosols inside the vortex indicated advection of air from outside to inside the vortex below 16 kilometers. No polar stratospheric clouds were observed and no evidence was found for frozen volcanic aerosols inside the vortex. Between January and March, ozone depletion was observed inside the vortex from 14 to 20 kilometers with a maximum average loss of about 23 percent near 18 kilometers.     

Stratospheric Chlorine Injection by Volcanic Eruptions: HCI Scavenging and Implications for Ozone

Because the output of volatile chlorine during a major volcanic event can greatly exceed the annual anthropogenic emissions of chlorine to the atmosphere, the fate of volcanic chlorine must be known. Although numerous observations have shown that volcanoes do not significantly contribute to the stratospheric chlorine burden, no quantitative explanation has been published. Hydrogen chloride (HCI) scavenging processes during the early phases of a volcanic eruption are discussed. A plume dynamics and thermodynamics model is used to show that HCI removal in condensed supercooled water can reduce HCI vapor concentrations by up to four orders of magnitude, preventing substantial stratospheric chlorine injection.     

Size distributions and mineralogy of ash particles in the stratosphere from eruptions of mount st. Helens

Samples from the stratosphere obtained by U-2 aircraft after the first three major eruptions of Mount St. Helens contained large globules of liquid acid and ash. Because of their large size, these globules had disappeared from the lower stratosphere by late June 1980, leaving behind only smaller acid droplets. Particle-size distributions and mineralogy of the stratospheric ash grains demonstrate in-homogeneity in the eruption clouds.     

Trajectories of the mount st. Helens eruption plume

The plume of the major eruption of Mount St. Helens on 18 May 1980 penetrated 10 to 11 kilometers into the stratosphere, attaining heights of 22 to 23 kilometers. Wind shears rapidly converted the plume from an expanding vertical cone to a thin, slightly inclined lamina. The lamina was extruded zonally in the stratosphere as the lower part moved eastward at jet stream velocities, while the upper part slowly moved westward in the region of nonsteady transition from the westerlies to the summer stratospheric easterlies. Trajectories computed to position the NASA U-2 aircraft for sampling in the plume are described. Plume volume after 8 hours of strong volcanic emission is estimated at 2 x 10(6) cubic kilometers. Only about 1 percent of this volume is attributed to the volcano; the rest was entrained from the environment.     

Mount agung eruption provides test of a global climatic perturbation

The Mount Agung volcanic eruption in 1963 provides the best-documented global radiative perturbation to the earth's atmosphere currently available. Data on stratospheric aerosols produced by this eruption have been used as input to a model for the atmospheric thermal structure. The computed magnitude, sign, and phase lag of the temperature changes in both the stratosphere and the troposphere are in good agreement with observations, providing evidence that the climatic response to a global radiative perturbation is significant, as well as support for the use of theoretical models to predict climatic effects.     

Increase in the stratospheric background sulfuric Acid aerosol mass in the past 10 years

Data obtained from measurements of the stratospheric aerosol at Laramie, Wyoming (41 degrees N), indicate that the background or nonvolcanic stratospheric sulfuric acid aerosol mass at northern mid-latitudes has increased by about 5 +/- 2 percent per year during the past 10 years. Whether this increase is natural or anthropogenic could not be determined at this time because of inadequate information on sulfur sources, in particular, carbonyl sulfide, which is thought to be the dominant nonvolcanic source of stratospheric sulfuric acid vapor. An increase in stratospheric sulfate levels has important climatic implications as well as heterogeneous chemical effects that may alter the concentration of stratospheric ozone.     

Geochemical precursors to volcanic activity at Mount St. Helens, USA

The importance of the interplay between degassing and crystallization before and after the eruption of Mount St. Helens (Washington, USA) in 1980 is well established. Here, we show that degassing occurred over a period of decades to days before eruptions and that the manner of degassing, as deduced from geochemical signatures within the magma, was characteristic of the eruptive style. Trace element (lithium) and short-lived radioactive isotope (lead-210 and radium-226) data show that ascending magma stalled within the conduit, leading to the accumulation of volatiles and the formation of lead-210 excesses, which signals the presence of degassing magma at depth.     

Thermal structure and dynamics of Saturn's northern springtime disturbance

Saturn's slow seasonal evolution was disrupted in 2010-2011 by the eruption of a bright storm in its northern spring hemisphere. Thermal infrared spectroscopy showed that within a month, the resulting planetary-scale disturbance had generated intense perturbations of atmospheric temperatures, winds, and composition between 20° and 50°N over an entire hemisphere (140,000 kilometers). The tropospheric storm cell produced effects that penetrated hundreds of kilometers into Saturn's stratosphere (to the 1-millibar region). Stratospheric subsidence at the edges of the disturbance produced "beacons" of infrared emission and longitudinal temperature contrasts of 16 kelvin. The disturbance substantially altered atmospheric circulation, transporting material vertically over great distances, modifying stratospheric zonal jets, exciting wave activity and turbulence, and generating a new cold anticyclonic oval in the center of the disturbance at 41°N.     

Superpressure balloon flights in the tropical stratosphere

Seven balloons were launched successfully from Ascension Island in January 1969. The balloons, flown at altitudes of 20 and 24 kilometers, will make possible a detailed analysis of the stratospheric circulation near the equator and will hopefully lead to an understanding of the quasi-biennial stratospheric oscillation in the tropics.     

Atomic Chlorine and the Chlorine Monoxide Radical in the Stratosphere: Three in situ Observations

Three simultaneous observations of atomic chlorine (Cl) and the chlorine monoxide radical (ClO) are reported which encompass the altitude interval between 25 and 45 kilometers. Together, Cl and ClO form a gas-phase catalytic cycle potentially capable of depleting stratospheric ozone. Observed Cl and C1O densities, although variable, imply that chlorine compounds constitute an important part of the stratospheric ozone budget. The results are compared with recent models of stratospheric photochemistry which have been used as a basis for predicting ozone depletion resulting from fluorocarbon release.     

Is there any chlorine monoxide in the stratosphere?

A ground-based search for stratospheric chlorine monoxide was carried out during May and October 1981 with an infrared heterodyne spectrometer in the solar absorption mode. Lines due to stratospheric nitric acid and tropospheric carbonyl sulfide were detected at about 0.2 percent absorptance levels, but the expected 0.1 percent lines of chlorine monoxide in this same region were not seen. Stratospheric chlorine monoxide is less abundant by at least a factor of 7 than is indicated by in situ measurements, and the upper limit for the integrated vertical column density of chlorine monoxide is 2.3 x 10(13) molecules per square centimeter at the 95 percent confidence level. These results imply that the release of chlorofluorocarbons may be significantly less important for the destruction of stratospheric ozone than is currently thought.     

Stable isotope enrichment in stratospheric nitrous oxide

Nitrous oxide is a greenhouse gas that also plays a role in the cycling of stratospheric ozone. Air samples from the lower stratosphere exhibit 15N/14N and 18O/16O enrichment in nitrous oxide, which can be accounted for with a simple model describing an irreversible destruction process. The observed enrichments are quite large and incompatible with those determined for the main stratospheric nitrous oxide loss processes of photolysis and reaction with excited atomic oxygen. Thus, although no stratospheric source needs to be invoked, the data indicate that present understanding of stratospheric nitrous oxide chemistry is incomplete.