Enhancing phosphorus availability,soil organic carbon,maize productivity and farm profitability through biochar and organic–inorganic fertilizers in an irrigated maize agroecosystem under semi‐arid climate

Biochar amendments offer promising potential to improve soil fertility, soil organic carbon (SOC) and crop yields; however, a limited research has explored these benefits of biochar in the arid and semi‐arid regions. This two‐year field study investigated the effects of Acacia tree biomass‐derived biochar, applied at 0 and 10 t ha^?1 rates with farmyard manure (FYM) or poultry manure (PM) and mineral phosphorus (P) fertilizer combinations (100 kg P ha^‐1), on maize (Zea mays L.) productivity, P use efficiency (PUE) and farm profitability. The application of biochar with organic–inorganic P fertilizers significantly increased soil P and SOC contents than the sole organic or inorganic P fertilizers. Addition of biochar and PM as 100% P source resulted in the highest soil P (104% increase over control) and SOC contents (203% higher than control). However, maize productivity and PUE were significantly higher under balanced P fertilizer (50% organic + 50% mineral fertilizer) with biochar and the increase was 110%, 94% and 170% than 100%‐FYM, 100%‐PM and 100% mineral fertilizer, respectively. Maize productivity and yield correlated significantly positively with soil P and SOC contents These positive effects were possibly due to the ability of biochar to improve soil properties, P availability from organic–inorganic fertilizers and SOC which resulted in higher PUE and maize productivity. Despite the significant positive relationship of PUE with net economic returns, biochar incorporation with PM and mineral fertilizer combination was economically profitable, whereas FYM along biochar was not profitable due to short duration of the field experiments.     

Critical carbon inputs to maintain soil organic carbon stocks under long‐term finger‐millet (Eleusine coracana [L.] Gaertn.) cropping on Alfisols in semiarid tropical India

Enrichment of soil organic carbon (SOC) stocks through sequestration of atmospheric CO₂ in agricultural soils is important because of its impacts on adaptation to and mitigation of climate change while also improving crop productivity and sustainability. In a long‐term fertility experiment carried out over 27 y under semiarid climatic condition, we evaluated the impact of crop‐residue C inputs through rainfed fingermillet (Eleusine coracana [L.] Gaertn.) cropping, fertilization, and manuring on crop yield sustainability and SOC sequestration in a Alfisol soil profile up to a depth of 1 m and also derived the critical value of C inputs for maintenance of SOC. Five treatments, viz., control, farmyard manure (FYM) 10 Mg ha^–1, recommended dose of NPK (50 : 50 : 25 kg N, P₂O₅, K₂O ha^–1), FYM 10 Mg ha^–1 + 50% recommended dose of NPK, and FYM 10 Mg ha^–1 + 100% recommended dose of NPK imposed in a randomized block design replicated four times. Application of FYM alone or together with mineral fertilizer resulted in a higher C input and consequently built up a higher C stock. After 27 y, higher profile SOC stock (85.7 Mg ha^–1), C build up (35.0%), and C sequestration (15.4 Mg C ha^–1) was observed with the application of 10 Mg FYM ha^–1 along with recommended dose of mineral fertilizer and these were positively correlated with cumulative C input and well reflected in sustainable yield index (SYI). For sustenance of SOC level (zero change due to cropping) a minimum quantity of 1.13 Mg C is required to be added per hectare per annum as inputs. While the control lost C, the application of mineral fertilizer served to maintain the priori C stock. Thus, the application of FYM increased the C stock, an effect which was even enhanced by additional amendment of mineral fertilizer. We conclude that organic amendments contribute to C sequestration counteracting climate change and at the same time improve soil fertility in the semiarid regions of India resulting in higher and more stable yields.     

Effects of cattle manure on selected soil physical properties of smallholder farms on two soils of Murewa,Zimbabwe

The effects of cattle manure and inorganic N‐fertilizer application on soil organic carbon (SOC), bulk density, macro‐aggregate stability and aggregate protected carbon were determined on clay and sandy soils of the Murewa smallholder farming area, Zimbabwe. Maize was grown in four fields termed homefields (HFs) and outfields (OFs) because of spatial variability induced by management practices and with the following fertility treatments: control (no fertility amelioration), 5, 15 and 25 t/ha cattle manure + 100 kg/ha N applied annually for seven consecutive years. The addition of cattle manure resulted in significant (P < 0.01) increases in SOC, macro‐aggregate stability and aggregate protected carbon in clay soils from at least the 5 t/ha cattle manure rate and was comparable between HFs and OFs on clay soils. Aggregate protected carbon in clay soils was significantly higher from the 15 and 25 t/ha cattle manure rates compared to the 5 t/ha cattle manure treatment. In contrast, only SOC was significantly (P < 0.05) increased with the addition of cattle manure on the sandy soils, while bulk density, macro‐aggregate stability and aggregate protected carbon were not significantly changed. Bulk density was also not significantly (P > 0.05) different on the clay soils. A significant and positive linear relationship (r² = 0.85) was found between SOC and macro‐aggregate stability, while an r² value of 0.82 was obtained between SOC and aggregate protected carbon on the clay soils. However, no regressions were performed on data from the sandy soils because of the lack of significant changes in soil physical properties. Application of cattle manure and inorganic N‐fertilizer significantly increased (P < 0.05) maize grain yield on both soil types. Results show that inorganic N‐fertilizer combined with cattle manure at 5–15 t/ha per yr is necessary to increase maize yields and SOC on sandy soils in Murewa, while at least 15 t/ha per yr cattle manure is required on the clay soils to improve physical properties in addition to maize yields and SOC.     

Seasonal differences in tillage draught on a sandy loam soil with long‐term additions of animal manure and mineral fertilizers

Energy requirements for soil tillage are closely linked to soil properties, such as clay, water and soil organic carbon (SOC) contents. Long‐term application of inorganic fertilizer and organic amendments affects SOC content but little is known about seasonal differences in tillage draught requirements of soils subject to contrasting nutrient management regimes. We assessed autumn and spring tillage draught following harvest of early‐sown and timely sown winter wheat grown on a sandy loam in the Askov Long‐Term Experiment on Animal Manure and Mineral Fertilizers. Draught force was related to soil texture, soil water and SOC content, shear strength and bulk density, nutrient management, and yield of the preceding winter wheat. Contents of clay and SOC ranged from 8.9 to 10.6% and from 0.98 to 1.36%, respectively. In the autumn and spring, SOC normalized by clay content explained 38 and 5% of the variation in specific draught, respectively. Specific draught did not differ significantly among individual fertilization treatments. SOC was closely correlated with clay and water contents and bulk density, and with yield of the preceding wheat. Draught force was significantly smaller in the spring than in the autumn. In the autumn when soils were drier (?700 hPa), tillage draught was correlated with several soil characteristics, whereas water content was the dominating parameter in the spring when soils were wetter (?100 hPa). The range of SOC contents observed in this study aligns with that observed in Danish sandy loams under intensive cultivation, and within this range, SOC per se had little effect on draught requirements.     

Long‐term effects of fertilization on some soil properties under rainfed soybean‐wheat cropping in the Indian Himalayas

This study aims to examine the effects of long‐term fertilization and cropping on some chemical and microbiological properties of the soil in a 32 y old long‐term fertility experiment at Almora (Himalayan region, India) under rainfed soybean‐wheat rotation. Continuous annual application of recommended doses of chemical fertilizer and 10 Mg ha^–1 FYM on fresh‐weight basis (NPK + FYM) to soybean (Glycine max L.) sustained not only higher productivity of soybean and residual wheat (Triticum aestivum L.) crop, but also resulted in build‐up of total soil organic C (SOC), total soil N, P, and K. Concentration of SOC increased by 40% and 70% in the NPK + FYM–treated plots as compared to NPK (43.1 Mg C ha^–1) and unfertilized control plots (35.5 Mg C ha^–1), respectively. Average annual contribution of C input from soybean was 29% and that from wheat was 24% of the harvestable aboveground biomass yield. Annual gross C input and annual rate of total SOC enrichment from initial soil in the 0–15 cm layer were 4362 and 333 kg C ha^–1, respectively, for the plots under NPK + FYM. It was observed that the soils under the unfertilized control, NK and N + FYM treatments, suffered a net annual loss of 5.1, 5.2, and 15.8 kg P ha^–1, respectively, whereas the soils under NP, NPK, and NPK + FYM had net annual gains of 25.3, 18.8, and 16.4 kg P ha^–1, respectively. There was net negative K balance in all the treatments ranging from 6.9 kg ha^–1 y^–1 in NK to 82.4 kg ha^–1 y^–1 in N + FYM–treated plots. The application of NPK + FYM also recorded the highest levels of soil microbial‐biomass C, soil microbial‐biomass N, populations of viable and culturable soil microbes.     

Long‐term fertilization impacts on corn yields and soil organic matter on a clay‐loam soil in Northeast China

A long‐term fertilization experiment with monoculture corn (Zea mays L.) was established in 1980 on a clay‐loam soil (Black Soil in Chinese Soil Classification and Typic Halpudoll in USDA Soil Taxonomy) at Gongzhuling, Jilin Province, China. The experiment aimed to study the sustainability of grain‐corn production on this soil type with eight different nitrogen (N)‐, phosphorus (P)‐, and potassium (K)–mineral fertilizer combinations and three levels (0, 30, and 60 Mg ha^–1 y^–1) of farmyard manure (FYM). On average, FYM additions produced higher grain yields (7.78 and 8.03 Mg ha^–1) compared to the FYM0 (no farmyard application) treatments (5.67 Mg ha^–1). The application of N fertilizer (solely or in various combinations with P and K) in the FYM0 treatment resulted in substantial grain‐yield increases compared to the FYM0 control treatment (3.56 Mg ha^–1). However, the use of NP or NK did not yield in any significant additional effect on the corn yield compared to the use of N alone. The treatments involving P, K, and PK fertilizers resulted in an average 24% increase in yield over the FYM0 control. Over all FYM treatments, the effect of fertilization on corn yield was NPK > NP = NK = N > PK = P > K = control. Farmyard‐manure additions for 25 y increased soil organic‐matter (SOM) content by 3.8 g kg^–1 (13.6%) in the FYM1 treatments and by 7.8 g kg^–1 (27.8%) in the FYM2 treatments, compared to a 3.2 g kg^–1 decrease (11.4%) in the FYM0 treatments. Overall, the results suggest that mineral fertilizers can maintain high yields, but a combination of mineral fertilizers plus farmyard manure are needed to enhance soil organic‐matter levels in this soil type.     

Effect of addition of organic residues,farmyard manure and fertilizer nitrogen on soil fertility in rice‐wheat cropping system

A field experiment was conducted for 3 crop years (July‐June) at the Indian Agricultural Research Institute, New Delhi to study the effects of Sesbania and cowpea green manuring (GM) and incorporation of mungbean residues after harvesting grain, Leucaena loppings, FYM and wheat straw incorporation before planting rice and application of 0,40,80 and 120 kg N ha^?1 to rice on the soil organic carbon (SOC), alkaline permanganate oxidizable N (APO‐N), 0.5 M sodium bicarbonate extractable P (SBC‐P) and 1N ammonium acetate exchangeable K (AAE‐K) in surface 0–15 cm soil after the harvest of rice and wheat grown in sequence. Green manuring and addition of organic residues prevented the decline in SOC. On the other hand addition of N fertilizer tended to decrease SOC after rice harvest. On the contrary application of green manures, organic residues, FYM and fertilizer N increased APO‐N, which indicates the benefit of these treatments to a more labile soil organic N pool. Also application of green manures, organic residues, FYM and fertilizer N increased SBC‐P. Not much change was observed in AAE‐K by the treatments applied.     

Effects of humus content,farmyard manuring,and mineral‐N fertilization on yields and soil properties in a long‐term trial

Investigations carried out at Field F3 of the Halle long‐term fertilization trials using data from 1974 to 1983 showed that with adequate supply of mineral N‐fertilizer soil organic matter (SOM) had no significant effects of yield. Similarly enhanced SOM did not justify a reduction of mineral N (Stumpe et al., 2000). The studies presented here examine the effects of the SOM differences existing after the termination of those trials in 1986 up until 1997 (then mainly differences of hardly decomposable SOM) in comparison to farmyard manuring with enhanced mineral N application (3‐factor‐experiment). As with total SOM, hardly decomposable SOM did not directly affect yields. The effects of FYM treatment observed at lower mineral‐N levels were compensated for by enhanced mineral‐N supply. The direct effect of FYM (40 t ha^—1) corresponded to a mineral‐N supply of about 60 kg ha^—1 and the residual effect to about 20 kg ha^—1. The differences of the C‐content in the soil at the beginning of the present studies continued throughout the experimental period of 12 years. In addition, significant differentiation has been caused by FYM and N fertilization in comparison to unfertilized treatments. The major finding is that differences in SOM content do not lead to yield differences on physically good soils (chernozem‐like soils) if appropriate compensation by mineral‐N fertilization takes place.     

Sulfur mineralization in two soils amended with organic manures,crop residues,and green manures

The mineralization of sulfur (S) was investigated in a Vertisol and an Inceptisol amended with organic manures, green manures, and crop residues. Field‐moist soils amended with 10 g kg^—1 of organic materials were mixed with glass beads, placed in pyrex leaching tubes, leached with 0.01 M CaCl₂ to remove the mineral S and incubated at 30 °C. The leachates were collected every fortnight for 16 weeks and analyzed for SO₄‐S. The amount of S mineralized in control and in manure‐amended soils was highest in the first week and decreased steadily thereafter. The total S mineralized in amended soils varied considerably depending on the type of organic materials incorporated and soil used. The cumulative amounts of S mineralized in amended soils ranged from 6.98 mg S (kg soil)^—1 in Inceptisol amended with wheat straw to 34.38 mg S (kg soil)^—1 in Vertisol amended with farmyard manure (FYM). Expressed as a percentage of the S added to soils, the S mineralized was higher in FYM treated soils (63.5 to 67.3 %) as compared to poultry manure amended soils (60.5 to 62.3 %). Similarly the percentage of S mineralization from subabul (Leucaena leucocephala) loppings was higher (53.6 to 55.5 %) than that from gliricidia (Gliricidia sepium) loppings (50.3 to 51.1 %). Regression analysis clearly indicated the dependence of S mineralization on the C : S ratio of the organic materials added to soil. The addition of organic amendments resulted in net immobilization of S when the C : S ratio was above 290:1 in Vertisol and 349:1 in Inceptisol. The mineralizable S pool (S_o) and first‐order rate constant (k) varied considerably among the different types of organic materials added and soil. The S_o values of FYM treated soils were higher than in subabul, gliricidia, and poultry manure treated soils.     

Impact of mineral and organic fertilization on yield,C content in the soil,as well as on C,N and energy balances in a long-term field experiment

Data from a 49-year-long organic–mineral fertilization field experiment with a potato–maize–maize–wheat–wheat crop rotation were used to analyse the impact of different fertilizer variations on yield ability, soil organic carbon content (SOC), N and C balances, as well as on some characteristic energy balance parameters. Among the treatments, the fertilization variant with 87 kg ha^?1 year^?1 N proved to be economically optimal (94% of the maximum). Approximately 40 years after initiation of the experiment, supposed steady-state SOC content has been reached, with a value of 0.81% in the upper soil layer of the unfertilized control plot. Farmyard manure (FYM) treatments resulted in 10% higher SOC content compared with equivalent NPK fertilizer doses. The best C balances were obtained with exclusive mineral fertilization variants (?3.8 and ?3.7 t ha^?1 year^?1, respectively). N uptake in the unfertilized control plot suggested an airborne N input of 48 kg ha^?1 year^?1. The optimum fertilizer variant (70 t ha^?1 FYM-equivalent NPK) proved favourable with a view to energy. The energy gain by exclusive FYM treatments was lower than with sole NPK fertilization. Best energy intensity values were obtained with lower mineral fertilization and FYM variants. The order of energy conversion according to the different crops was maize, wheat and potato.     

Effects of long-term compost and fertilizer application on stability of aggregate-associated organic carbon in an intensively cultivated sandy loam soil

The study examined the influence of compost and mineral fertilizer application on the content and stability of soil organic carbon (SOC). Soil samples collected from a long-term field experiment were separated into macroaggregate, microaggregate, and silt + clay fractions by wet-sieving. The experiment involved seven treatments: compost, half-compost N plus half-fertilizer N, fertilizer NPK, fertilizer NP, fertilizer NK, fertilizer PK, and control. The 18-year application of compost increased SOC by 70.7–121.7%, and mineral fertilizer increased by 5.4–25.5%, with no significant difference between control soil and initial soil. The C mineralization rate (rate per unit dry mass) in microaggregates was 1.52–2.87 mg C kg⁻¹ day⁻¹, significantly lower than in macroaggregate and silt + clay fractions (P < 0.05). Specific C mineralization rate (rate per unit SOC) in silt + clay fraction amounted to 0.48–0.87 mg C g⁻¹ SOC day⁻¹ and was higher than in macroaggregates and microaggregates. Our data indicate that SOC in microaggregates is more stable than in macroaggregate and silt + clay fractions. Compost and mineral fertilizer application increased C mineralization rate in all aggregates compared with control. However, compost application significantly decreased specific C mineralization rate in microaggregate and silt + clay fractions by 2.6–28.2% and 21.9–25.0%, respectively (P < 0.05). By contrast, fertilizer NPK application did not affect specific C mineralization rate in microaggregates but significantly increased that in silt + clay fractions. Carbon sequestration in compost-amended soil was therefore due to improving SOC stability in microaggregate and silt + clay fractions. In contrast, fertilizer NPK application enhanced SOC with low stability in macroaggregate and silt + clay fractions.     

A simple soil organic carbon level metric beyond the organic carbon-to-clay ratio

Soil is a precious and non-renewable resource that is under increasing pressure and the development of indicators to monitor its state is pivotal. Soil organic carbon (SOC) is important for key physical, chemical and biological soil properties and thus a central indicator of soil quality and soil health. The content of SOC is driven by many abiotic factors, such as texture and climate, and is therefore strongly site-specific, which complicates, for example, the search for appropriate threshold values to differentiate healthy from less healthy soils. The SOC:clay ratio has been introduced as a normalized SOC level metric to indicate soils' structural condition, with classes ranging from degraded (<1:13) to very good (>1:8). This study applied the ratio to 2958 topsoils (0–30 cm) in the German Agricultural Soil Inventory and showed that it is not a suitable SOC level metric since strongly biased, misleading and partly insensitive to SOC changes. The proportion of soils with SOC levels classified as degraded increased exponentially with clay content, indicating the indicator's overly strong clay dependence. Thus, 94% of all Chernozems, which are known to have elevated SOC contents and a favourable soil structure, were found to have either degraded (61%) or moderate (33%) normalized SOC levels. The ratio between actual and expected SOC (SOC:SOC_exp) is proposed as an easy-to-use alternative where expected SOC is derived from a regression between SOC and clay content. This ratio allows a simple but unbiased estimate of the clay-normalized SOC level. The quartiles of this ratio were used to derive threshold values to divide the dataset into the classes degraded, moderate, good and very good. These classes were clearly linked to bulk volume (inverse of bulk density) as an important structural parameter, which was not the case for classes based on the SOC:clay ratio. Therefore, SOC:SOC_exp and its temporal dynamic are proposed for limited areas such as regions, states or pedoclimatic zones, for example, in a soil health monitoring context; further testing is, however, recommended.     

Changes in the microbial community of an arable soil caused by long-term metal contamination

The effects of past applications of farmyard manure (FYM, applied from 1942 to 1967), metal‐contaminated sewage sludge (applied from 1942 to 1961) and mineral fertilizer (NPK, applied from 1942 until now) on the microbial biomass and community structure in a sandy loam, arable soil from the Woburn Market Garden Experiment, UK, were investigated in 1998. Concentrations of Cu, Ni and Zn in soils which previously received sewage sludge were less than current European Union (EU) limits, but the soil Cd concentration was more than twice the permitted limit. Organic‐C concentration in the FYM‐treated soil and contaminated soils was about twice that of NPK‐treated soil. The initial microbial biomass‐C and estimates of total bacterial numbers by acridine orange direct count were significantly (P < 0.05) greater in the FYM‐treated soil compared with the NPK‐treated and the most contaminated soils. Total phospholipid fatty acid (PLFA) concentration (another measure of biomass) was significantly greater in the FYM‐treated soil compared with either the low or high metal‐contaminated soils, both of which contained similar PLFA concentrations. In the metal‐contaminated soils, in contrast, fluorescent Pseudomonas counts, as a percentage of total plate counts, were at least 1.5 times greater than in the uncontaminated soils. The concentrations of these microbial parameters were significantly (P < 0.05) less in the NPK soil than in all the other treatments. Biomass‐C as a percentage of organic‐C was also significantly (P < 0.05) greater in the uncontaminated soils compared with the metal‐contaminated soils. Biomass specific respiration rates in the metal‐contaminated soils were c. 1.5 times those in the FYM‐treated soil. In the metal‐contaminated soils, the concentration of mono‐unsaturated and hydroxy‐fatty acids (derived from phospholipids), and lipopolysaccharide hydroxy‐fatty acids (all indicative of Gram‐negative bacteria) were significantly (P < 0.05) greater than branched fatty acids (indicative of Gram‐positive bacteria). Furthermore, Gram‐negative counts were 62–68% greater than Gram‐positive counts in the metal‐contaminated soils. Branched fatty acid concentration was significantly (P < 0.05) greater in the FYM‐treated soil than in the metal‐contaminated soils. Gram‐positive counts were also 63% greater than Gram‐negative counts in the FYM‐treated soil. We found that effects of the relatively small heavy metal concentration caused measurable decreases in soil microbial biomass‐C concentrations, acridine orange direct counts and Gram‐positive counts. There were also increases in biomass specific respiration rates, and the microbial community had changed substantially, nearly 40 years after the metal inputs ceased. We conclude that, at the very least, the current EU permitted limits for heavy metals in agricultural soils should not be relaxed.     

不同施肥方式下滩涂围垦农田土壤有机碳及团聚体有机碳的分布

通过在苏北滩涂地区开展田间试验,研究了不同施肥处理(不施肥、施农家肥、商品有机肥、无机肥)对滩涂地区围垦农田土壤有机碳及团聚体有机碳的影响。结果表明,与对照相比,不同施肥处理均能明显增加0~30 cm土层土壤有机碳含量和有机碳密度,施农家肥增加幅度最高,增加值分别为0.66 g kg-1和0.07 kg m-2。试验地区水稳性团聚体以5 mm和0.25~0.5 mm为主,含量分别为37%~57%和13%~20%;随着土层深度增加,5 mm团聚体含量降低,0.25~0.5 mm团聚体则增加;农家肥能显著增加5 mm团聚体含量,同时降低0.25~5 mm团聚体含量。团聚体中有机碳含量表现为,除0.25~0.5 mm团聚体外,5 mm至0.5~1 mm团聚体之间,粒径越小,有机碳含量越高,其中0.5~1 mm团聚体有机碳含量最高,为6.83 g kg-1;与其他处理相比,农家肥的施用能明显增加各粒级团聚体中有机碳含量。试验地区土壤有机碳含量与5 mm团聚体及其有机碳含量极显著正相关(p0.01),而与0.25~5 mm团聚体负相关(p0.01或p0.05)。     

Co-application of sugarcane bagasse biochar,farmyard manure and mineral nitrogen improved growth indices of corn grown in alkaline calcareous soil

Abstract

Soil quality and crop productivity can be improved by the combined soil application of organic amendments and synthetic fertilizers. We evaluated the sole and combined effects of sugarcane-bagasse biochar (SBB), farmyard manure (FYM) and nitrogen (N) fertilizer on soil properties and corn yield traits. Three N fertilizer rates (0, 50 and 100% of recommended) were used with or without the organic amendments. We observed significant increases in soil nitrate-N (at vegetative and reproductive phases), ammonical-N and microbial-biomass-N contents in responses to a co-application of 0.5% SBB, 0.5% FYM and 100% N fertilizer (p?≤?0.05). While the same co-application also resulted in the most significant soil organic carbon value, the maximum soil microbial biomass carbon was observed when 0.5% SBB and 0.5% FYM combination was applied along with 50% N fertilizer (p?≤?0.05). Plant growth indices—shoot length and, fresh and dry weights of shoot and root were also recorded to be the highest where the same organic amendments were applied in addition to a 50% or 100% mineral N fertilizer (p?≤?0.05). Combined application of the organic amendments effectively improved soil CEC compared to those in responses to individual applications of SBB and FYM (p?≤?0.05). Conclusively, for increasing the corn yield and improving the soil quality, the co-application of 0.5% SBB and 0.5% FYM was more effective than any of the individual 1% applications; Additions of 50% and 100% mineral N to the organic combination were equally useful for increasing the grain yield.     

Quantification of N2 fixation and annual N benefit from N2 fixation in soybean accrued to the soil under soybean‐wheat continuous rotation

A computational exercise was undertaken to quantify the percent N derived from atmosphere %Ndfa) in soybean and consequent N benefit from biological N₂‐fixation process annually accrued to the soil by the soybean crop using average annual N‐input/‐output balance sheet from a 7 yr old soybean‐wheat continuous rotational experiment on a Typic Haplustert. The experiment was conducted with 16 treatments comprised of combinations of four annual rates of farmyard manure (FYM ? 0, 4, 8, and 16 t ha^–1) and four annual rates of fertilizer N (? 0, 72.5, 145, and 230 kg N ha^–1) applications. The estimated N contributed through residual biomass of soybean (RBN_S) consisting of leaf fall, root, nodules, and rhizodeposition varied in the ranges of 7.02–16.94, 11.65–28.83, 3.31–8.91, and 11.3–23.8 kg N ha^–1 yr^–1, respectively. A linear relationship was observed between RBN_S and harvested biomass N (HBN_S) of soybean in the form of RBN_S = 0.461 × HBN_S – 20.67 (r = 0.989, P < 0.01), indicating that for each 100 kg N assimilated by the harvested biomass of soybean, 25.4 kg N was added to the soil through residual biomass. The Ndfa values ranged between 13% and 81% depending upon the annual rates of application of fertilizer N and FYM. As per the main effects, the %Ndfa declined from 76.4 to 26.0 with the increase in annual fertilizer‐N application from 0 to 230 kg N ha^–1, whereas %Ndfa increased from 40.8 to 65.8 with the increase in FYM rates from 0 to 16 t ha^–1, respectively. The N benefit from biological N₂ fixation accrued to the soil through residual biomass of soybean ranged from 7.6 to 53.7 kg N ha^–1 yr^–1. The treatments having %Ndfa values higher than 78 showed considerable annual contribution of N from N₂ fixation to the soil which were sufficient enough to offset the quantity of N removed from the soil (i.e., native soil N / FYM‐N / fertilizer‐N) with harvested biomass of soybean.     

Soil Carbon Sequestration in Long-Term Fertilization Under Jute-Rice-Wheat Agro-Ecosystem

Soil organic carbon (SOC) sequestration in response to long-term fertilizer management practices under jute-rice-wheat agro-ecosystem in alluvial soils was studied using a modeling approach. Fertilizer management practices included nitrogen (N), phosphorus (P) and potassium (K) fertilization, manure application, and root-stubble retention of all three crops. Soil carbon (C) model RothC was used to simulate the critical C input rates needed to maintain initial soil C level in long timescale (44 years). SOC change was significantly influenced by the long-term fertilizer management practices and the edaphic variable of initial SOC content. The effects of fertilizer combination “100%NPK+FYM” on SOC changes were most significant over “100%NPK” fertilization. If the 100% NPK fertilizer along with manure applied with stubble and roots retention of all crops, alluvial soils of such agro-ecosystem would act as a net C sink, and the average SOC density kept increasing from 18.18 Mg ha^?1 during 1972 to the current average of ～22 Mg ha^?1 during 2065 s. On an average, the critical C input was estimated to be 5.30 Mg C ha^?1 yr^?1, depending on local soil and climatic conditions. The critical C input could be effectively estimated using a summary model driven by current SOC level, mean annual temperature, precipitation, and soil clay content. Such information will provide a baseline for assessing soil C dynamics under potential changes in fertilizer and crop residues management practices, and thus enable development of management strategies for effectively mitigating climate change through soil C sequestration.     

Effect of water and nitrogen management on aggregate size and carbon enrichment of soil in rice‐wheat cropping system

A study was carried out on a silty clay loam soil (Typic Haplustept) to evaluate the effect of farmyard manure (FYM) vis‐à‐vis fertilizer and irrigation application on the soil organic C content and soil structure. The fertilizer treatments comprised of eight different combinations of N and FYM and three water regimes. The results indicated that the application of FYM and increasing N rate increased soil organic carbon (SOC) content. Addition of FYM also increased the percentage of large sized water stable aggregates (> 5 mm) and reduced the percentage of smaller size aggregates. This was reflected in an increase in the mean weight diameter (MWD) and improved soil structure. The organic carbon content in macroaggregates (> 1 mm) was greater compared to microaggregates, and it declined with decrease in size of microaggregates. This difference in organic C content between macro‐ and microaggregates was more with higher N dose and FYM treated plots. The effect of residual FYM on MWD and organic C content of the soil after wheat harvest was not significant. The effect was less in deeper layers compared to surface layers of the soil. MWD was significantly correlated with the SOC content for the top two layers.     

Application of the DNDC model to predict N2O emissions from sandy arable soils with differing fertilization in a long‐term experiment

Modeling crop growth and soil N dynamics is difficult due to the complex nature of soil–plant systems. In several studies, the DNDC model has been claimed to be well‐suited for this purpose whereas in other studies applications of the model were less successful. Objectives of this study were to test a calibration and validation scheme for DNDC‐model applications to describe a field experiment with spring wheat on a sandy soil near Darmstadt (SW Germany) using different fertilizer types (either application of mineral fertilizer and straw—MSI; or application of farmyard manure—FYM) and rates (low—MSI_L, FYM_L; and medium—MSI_M, FYM_M). The model test is based on a model parameterization to best describe the case MSI_L and applies this parameterization for a retrospective simulation of the other cases (MSI_M, FYM_L, FYM_M) including crop growth and N₂O emissions. Soil water contents were not accurately simulated using either the DNDC default values for a loamy sand or for the next finer texture class or using results from the pedotransfer function provided by ROSETTA. After successful calibration of the soil water flow model using a soil texture class that led to the best fit of the measured water content data, grain yield of spring wheat and cumulative N₂O emission were slightly underestimated by DNDC and were between 91% and 86% of the measured data. A subsequent calibration of the yields and cumulative N₂O emissions from soils of the MSI_L treatment gave a good prediction of crop growth and N₂O emissions in the MSI_M treatment, but a marked underestimation of yields of the FYM treatments. Cumulative N₂O emissions were predicted well for all MSI and FYM treatments, but seasonal dynamics were not. Overall, our results indicated that for the sandy soil in Germany, site‐specific calibration was essentially required for the soil hydrology and that a calibration was useful for a subsequent prediction where greater amounts of the same fertilizer were used, but not useful for a prediction with a different fertilizer type.     

Modelling soil organic carbon concentration of mineral soils in arable land using legacy soil data

Soil organic carbon (SOC) concentration is an essential factor in biomass production and soil functioning. SOC concentration values are often obtained by prediction but the prediction accuracy depends much on the method used. Currently, there is a lack of evidence in the soil science literature as to the advantages and shortcomings of the different commonly used prediction methods. Therefore, we compared and evaluated the merits of the median approach, analysis of covariance, mixed models and random forests in the context of prediction of SOC concentrations of mineral soils under arable management in the A‐horizon. Three soil properties were used in all of the developed models: soil type, physical clay content (particle size <0.01 mm) and A‐horizon thickness. We found that the mixed model predicted SOC concentrations with the smallest mean squared error (0.05%²), suggesting that a mixed‐model approach is appropriate if the study design has a hierarchical structure as in our scenario. We used the Estonian National Soil Monitoring data on arable lands to predict SOC concentrations of mineral soils. Subsequently, the model with the best prediction accuracy was applied to the Estonian digital soil map for the case study area of Tartu County where the SOC predictions ranged from 0.6 to 4.8%. Our study indicates that predictions using legacy soil maps can be used in national inventories and for up‐scaling estimates of carbon concentrations from county to country scales.