The nature of the 660-kilometer discontinuity in Earth's mantle from global seismic observations of PP precursors

The 660-kilometer discontinuity, which separates Earth's upper and lower mantle, has been detected routinely on a global scale in underside reflections of precursors to SS shear waves. Here, we report observations of this discontinuity in many different regions, using precursors to compressional PP waves. The apparent absence of such precursors in previous studies had posed major problems for models of mantle composition. We find a complicated structure, showing single and double reflections ranging in depth from 640 to 720 kilometers, that requires the existence of multiple phase transitions at the base of the transition zone. The results are consistent with a pyrolite mantle composition.     

Splitting of the 520-kilometer seismic discontinuity and chemical heterogeneity in the mantle

Seismic studies indicate that beneath some regions the 520-kilometer seismic discontinuity in Earth's mantle splits into two separate discontinuities (at approximately 500 kilometers and approximately 560 kilometers). The discontinuity near 500 kilometers is most likely caused by the (Mg,Fe)2SiO4 beta-to-gamma phase transformation. We show that the formation of CaSiO3 perovskite from garnet can cause the deeper discontinuity, and by determining the temperature dependence for this reaction we demonstrate that regional variations in splitting of the discontinuity arise from variability in the calcium concentration of the mantle rather than from temperature changes. This discontinuity therefore is sensitive to large-scale chemical heterogeneity. Its occurrence and variability yield regional information on the fertility of the mantle or the proportion of recycled oceanic crust.     

Seismic observations of splitting of the mid-transition zone discontinuity in Earth's mantle

The transition zone of Earth's mantle is delineated by globally observed discontinuities in seismic properties at depths of about 410 and 660 kilometers. Here, we investigate the detailed structure between 410 and 660 kilometers depth, by making use of regional stacks of precursors to the SS phase. The previously observed discontinuity at about 520 kilometers depth is confirmed in many regions, but is found to be absent in others. There are a number of regions in which we find two discontinuities at about 500 and 560 kilometers depth, an effect which can be interpreted as a "splitting" of the 520 kilometer discontinuity. These observations provide seismic constraints on the sharpness and observability of mineralogical phase transitions in the mantle transition zone.     

Water in Earth's lower mantle

Secondary ion mass spectrometry measurements show that Earth's representative lower mantle minerals synthesized in a natural peridotitic composition can dissolve considerable amounts of hydrogen. Both MgSiO3-rich perovskite and magnesiowüstite contain about 0.2 weight percent (wt%) H2O, and CaSiO3-rich perovskite contains about 0.4 wt% H2O. The OH absorption bands in Mg-perovskite and magnesiowüstite were also confirmed with the use of infrared microspectroscopic measurements. Earth's lower mantle may store about five times more H2O than the oceans.     

Solidus of Earth's deep mantle

The solidus of a pyrolite-like composition, approximating that of the lower mantle, was measured up to 59 gigapascals by using CO2 laser heating in a diamond anvil cell. The solidus temperatures are at least 700 kelvin below the melting temperatures of magnesiowustite, which in the deep mantle has the lowest melting temperatures of the three major components-magnesiowustite, Mg-Si-perovskite, and Ca-Si-perovskite. The solidus in the deep mantle is more than 1500 kelvin above the average present-day geotherm, but at the core-mantle boundary it is near the core temperature. Thus, partial melting of the mantle is possible at the core-mantle boundary.     

A detailed map of the 660-kilometer discontinuity beneath the izu-bonin subduction zone

Dynamical processes in the Earth's mantle, such as cold downwelling at subduction zones, cause deformations of the solid-state phase change that produces a seismic discontinuity near a depth of 660 kilometers. Observations of short-period, shear-to-compressional wave conversions produced at the discontinuity yield a detailed map of deformation beneath the Izu-Bonin subduction zone. The discontinuity is depressed by about 60 kilometers beneath the coldest part of the subducted slab, with a deformation profile consistent with the expected thermal signature of the slab, the experimentally determined Clapeyron slope of the phase transition, and the regional tectonic history.     

Double flood basalts and plume head separation at the 660-kilometer discontinuity

Several of the world's flood basalt provinces display two distinct times of major eruptions separated by between 20 million and 90 million years. These double flood basalts may occur because a starting mantle plume head can separate from its trailing conduit upon passing the interface between the upper mantle and the lower mantle. This detached plume head eventually triggers the first flood basalt event. The remaining conduit forms a new plume head, which causes the second eruptive event. The second plume head is predicted to arrive at the lithosphere at least 10 million years after the first plume head, in general agreement with observations regarding double flood basalts.     

Plutonium-fission xenon found in Earth's mantle

Data from mid-ocean ridge basalt glasses indicate that the short-lived radionuclide plutonium-244 that was present during an early stage of the development of the solar system is responsible for roughly 30 percent of the fissiogenic xenon excesses in the interior of Earth today. The rest of the fissiogenic xenon can be ascribed to the spontaneous fission of still live uranium-238. This result, in combination with the refined determination of xenon-129 excesses from extinct iodine-129, implies that the accretion of Earth was finished roughly 50 million to 70 million years after solar system formation and that the atmosphere was formed by mantle degassing.     

Variable azimuthal anisotropy in Earth's lowermost mantle

A persistent reversal in the expected polarity of the initiation of vertically polarized shear waves that graze the D' layer (the layer at the boundary between the outer core and the lower mantle of Earth) in some regions starts at the arrival time of horizontally polarized shear waves. Full waveform modeling of the split shear waves for paths beneath the Caribbean requires azimuthal anisotropy at the base of the mantle. Models with laterally coherent patterns of transverse isotropy with the hexagonal symmetry axis of the mineral phases tilted from the vertical by as much as 20 degrees are consistent with the data. Small-scale convection cells within the mantle above the D' layer may cause the observed variations by inducing laterally variable crystallographic or shape-preferred orientation in minerals in the D' layer.     

Structure and dynamics of Earth's lower mantle

Processes within the lowest several hundred kilometers of Earth's rocky mantle play a critical role in the evolution of the planet. Understanding Earth's lower mantle requires putting recent seismic and mineral physics discoveries into a self-consistent, geodynamically feasible context. Two nearly antipodal large low-shear-velocity provinces in the deep mantle likely represent chemically distinct and denser material. High-resolution seismological studies have revealed laterally varying seismic velocity discontinuities in the deepest few hundred kilometers, consistent with a phase transition from perovskite to post-perovskite. In the deepest tens of kilometers of the mantle, isolated pockets of ultralow seismic velocities may denote Earth's deepest magma chamber.     

The chlorine isotope composition of Earth's mantle

Chlorine stable isotope compositions (delta37Cl) of 22 mid-ocean ridge basalts (MORBs) correlate with Cl content. The high-delta37Cl, Cl-rich basalts are highly contaminated by Cl-rich materials (seawater, brines, or altered rocks). The low-delta37Cl, Cl-poor basalts approach the composition of uncontaminated, mantle-derived magmas. Thus, most or all oceanic lavas are contaminated to some extent during their emplacement. MORB-source mantle has delta37Cl 相似文献   

Seismic evidence for olivine phase changes at the 410- and 660-kilometer discontinuities

The view that the seismic discontinuities bounding the mantle transition zone at 410- and 660-kilometer depths are caused by isochemical phase transformations of the olivine structure is debated. Combining converted-wave measurements in East Asia and Australia with seismic velocities from regional tomography studies, we observe a correlation of the thickness of, and wavespeed variations within, the transition zone that is consistent with olivine structural transformations. Moreover, the seismologically inferred Clapeyron slopes are in agreement with the mineralogical Clapeyron slopes of the (Mg,Fe)2SiO4 spinel and postspinel transformations.     

Evidence for a ubiquitous seismic discontinuity at the base of the mantle

A sharp discontinuity at the base of Earth's mantle has been suggested from seismic waveform studies; the observed travel time and amplitude variations have been interpreted as changes in the depth of a spatially intermittent discontinuity. Most of the observed variations in travel times and the spatial intermittance of the seismic triplication can be reproduced by a ubiquitous first-order discontinuity superimposed on global seismic velocity structure derived from tomography. The observations can be modeled by a solid-solid phase transition that has a 200-kilometer elevation above the core-mantle boundary under adiabatic temperatures and a Clapeyron slope of about 6 megapascal per kelvin.     

Dislocation damping and anisotropic seismic wave attenuation in Earth's upper mantle

Crystal defects form during tectonic deformation and are reactivated by the shear stress associated with passing seismic waves. Although these defects, known as dislocations, potentially contribute to the attenuation of seismic waves in Earth's upper mantle, evidence for dislocation damping from laboratory studies has been circumstantial. We experimentally determined the shear modulus and associated strain-energy dissipation in pre-deformed synthetic olivine aggregates under high pressures and temperatures. Enhanced high-temperature background dissipation occurred in specimens pre-deformed by dislocation creep in either compression or torsion, the enhancement being greater for prior deformation in torsion. These observations suggest the possibility of anisotropic attenuation in relatively coarse-grained rocks where olivine is or was deformed at relatively high stress by dislocation creep in Earth's upper mantle.     

The Emperor Seamounts: southward motion of the Hawaiian hotspot plume in Earth's mantle

The Hawaiian-Emperor hotspot track has a prominent bend, which has served as the basis for the theory that the Hawaiian hotspot, fixed in the deep mantle, traced a change in plate motion. However, paleomagnetic and radiometric age data from samples recovered by ocean drilling define an age-progressive paleolatitude history, indicating that the Emperor Seamount trend was principally formed by the rapid motion (over 40 millimeters per year) of the Hawaiian hotspot plume during Late Cretaceous to early-Tertiary times (81 to 47 million years ago). Evidence for motion of the Hawaiian plume affects models of mantle convection and plate tectonics, changing our understanding of terrestrial dynamics.     

Inferences on flow at the base of Earth's mantle based on seismic anisotropy

We applied global waveform tomography to model radial anisotropy in the whole mantle. We found that in the last few hundred kilometers near the core-mantle boundary, horizontally polarized S-wave velocities (VSH) are, on average, faster (by approximately 1%) than vertically polarized S-wave velocities (VSV), suggesting a large-scale predominance of horizontal shear. This confirms that the D" region at the base of the mantle is also a mechanical boundary layer for mantle convection. A notable exception to this average signature can be found at the base of the two broad low-velocity regions under the Pacific Ocean and under Africa, often referred to as "superplumes," where the anisotropic pattern indicates the onset of vertical flow.     

Compositional heterogeneity in the bottom 1000 kilometers of Earth's mantle: toward a hybrid convection model

Tomographic imaging indicates that slabs of subducted lithosphere can sink deep into Earth's lower mantle. The view that convective flow is stratified at 660-kilometer depth and preserves a relatively pristine lower mantle is therefore not tenable. However, a range of geophysical evidence indicates that compositionally distinct, hence convectively isolated, mantle domains may exist in the bottom 1000 kilometers of the mantle. Survival of these domains, which are perhaps related to local iron enrichment and silicate-to-oxide transformations, implies that mantle convection is more complex than envisaged by conventional end-member flow models.     

Oxygen diffusion in perovskite: implications for electrical conductivity in the lower mantle

Experimental determination of oxygen self-diffusion in CaTiO(3) perovskite, a structural analog of (Mg,Fe)SiO(3) perovskite, confirms a theoretical relation between diffusion constants and anion porosity. Oxygen diffusion rates in (Mg,Fe)SiO(3) perovskite calculated with this relation increase by about eight orders of magnitude through the lower mantle. Electrical conductivity values calculated from these diffusion rates are consistent with inferred conductivity values for the lower mantle. This result suggests that the dominant conductivity mechanism in the deep mantle is ionic.