模拟酸雨对荔枝园土壤氮素迁移和土壤酸化的影响

采用短期室内淋溶方法研究了模拟酸雨对供试荔枝果园土壤全N、碱解N、硝态N、铵态N含量变化的影响。结果表明．各处理土壤淋出液的全N、硝态N、铵态N含量随着模拟酸雨酸度的增强而依次增加,其中pH2．5酸雨淋溶处理与其它处理间的淋出液含量差异显著,而pH≥4．5酸雨淋溶处理与对照（pH6．5）间的差异大部分不显著;各处理的土壤较淋溶前其全N、NOjN（pH2．5酸雨处理例外）、NH1＋-N的含量均有增加趋势。引进土壤的实际酸化速率H＋产生值衡量供试土壤的酸化,只有pH2．5的模拟酸雨淋溶促进了土壤的酸化,而pH≥3．5的模拟酸雨处理对土壤的酸化具有一定的缓冲作用,且土壤酸度减弱。     

模拟酸雨对果园土壤主要形态酸变化的影响研究

采用室内淋溶的方法研究了模拟酸雨对果园土壤pH（H2O）、pH（KCl）、交换性酸（EA）、交换性铝（EAl）、可滴定酸度（BNC）等各形态酸的变化影响,并依据淋溶前后各形态酸的含量评价了土壤酸度的变化。试验结果表明：以土壤pH（H2O）值作为供试土壤酸化指标,pH≤4．5的模拟酸雨淋溶促进了土壤酸化,而pH≥5．5的酸雨淋溶缓冲了土壤的酸化;以土壤pH（KCl）值、交换性酸（EA）、交换性铝（EAl）或可滴定酸度（BNC）作为土壤酸化的指标,pH2．5的酸雨淋溶促进了土壤酸化,而pH≥3．5的淋溶处理缓冲了土壤的酸化,土壤酸度减弱。     

模拟酸雨对砖红壤盐基离子迁移和释放的影响

对发育于玄武岩的砖红壤进行了室内模拟酸雨淋溶试验,结果表明：（1）酸雨淋溶土壤会引起土壤盐基离子的大量淋失。以土壤中的K＋最易于淋失,Ca^2＋、Mg^2＋的淋失量最大。酸雨pH愈低,Ca^2＋、Mg^2＋、K^＋的迁移量愈大。酸雨淋溶土壤的时间越长,盐基离子的迁移量越大。（2）土壤经≥5d的酸雨淋溶后,土壤交换性盐基离子的含量均随淋溶时间的增加而减少。酸雨的pH不同,则土壤交换性盐基离子所受的影响不同。（3）与原土壤相比较,短期（≤5d）的酸雨淋溶,可使土壤交换性Ca^2＋、K^＋以及强酸性（pH≤3.0）酸雨淋溶的交换性Mg^2＋增加;土壤被酸雨较长时间（≥10d）淋溶后,则会降低土壤交换性Ca^2＋、Mg^2＋、K^＋的含量;不同时间的酸雨淋溶,均会降低土壤交换性Na^＋的含量。（4）土壤经酸雨淋溶后,某些矿物会发生风化,释放出盐基离子,也会使部分交换性盐基离子转成非交换态。     

电动模拟土壤酸化及其交换性离子组成变化

土壤酸化及其环境效应研究是土壤环境领域的重要内容。自行设计了模拟土壤酸化的电动装置,该装置由直流电源、反应槽、石墨电极组成,并采用四种不同类型土壤,研究了电动模拟土壤酸化后土壤pH、交换性酸和交换性阳离子组成的变化。实验结果显示,经电动处理后土壤pH发生明显变化,土壤pH由阳极到阴极逐渐升高,pH变幅为水稻土燥红土红壤赤红壤,水稻土的pH变化比红壤更为明显;土壤交换性H+和Al~(3+)含量在阳极附近最高,交换性Al~(3+)占交换性酸总量达65%以上;交换性Ca~(2+)、Mg~(2+)、K~+和Na~+表现出离阳极越远,含量越大的规律,其中交换性Ca~(2+)和Mg~(2+)在模拟酸化后含量变化较大,而交换性K~+和Na~+的变化幅度相对较小。结果表明,电动处理可快速获得不同pH梯度的土壤样品,并模拟了土壤酸化过程中的阳离子迁移过程,是模拟土壤酸化及其效应研究的有效方法。     

模拟酸雨和几种低分子量有机酸淋溶对土壤交换性盐基的影响

采用原状土柱进行模拟淋溶实验,比较研究了模拟酸雨和几种低分子量有机酸对红壤交换性盐基的影响。结果表明:与去离子水对照相比,pH 3．5和pH 4．5模拟酸雨淋洗后,0-20 cm土层土壤交换性K 、Na 、 Ca2 和Mg2 含量增加了5．19％-14．65％,而这种增加主要发生在10-20 cm土层。100 μmol／L和10 mmol／L的柠檬酸、苹果酸和草酸淋洗后,0-20 cm土层土壤交换性K 、Na 、Ca2 和Mg2 含量与模拟酸雨淋洗后的结果相差不大,有的层次甚至还要稍低;而在20-50 cm土层则增加了10．42％-96.41％。有机酸淋洗后,土壤交换性盐基的增加受矿物溶解和盐基迁移两方面的影响,而下层的增加可能主要是盐基迁移的影响,由此可见有机酸或许加快了盐基离子向下迁移的速度和土壤酸化过程。     

模拟酸雨对荔枝果园土壤磷素等温吸附与解吸特性的影响

采用等温吸附试验方法研究了模拟酸雨对荔枝果园土壤磷的吸附与解吸特性的影响。试验结果表明,不同处理间土壤对磷的最大吸附量(Xm)为pH2.5>pH4.5>CK=pH6.5,其中pH2.5的酸雨淋溶处理对磷的最大吸附量(Xm)与其它处理间差异显著;土壤吸附磷的解吸量(Xd)分别与相应的吸附量(X)和原平衡溶液浓度(C)呈显著的指数相关和线性相关,随着土壤对吸附量的增加,土壤磷的解吸量呈指数增长。     

我国酸雨中盐基离子的重要性

从中国南方两城市与欧洲两城市酸雨化学组成的比较，南方森林土壤浸泡试验，MAGIC模型模拟预测3个方面讨论了我国酸雨中盐基离子的重要性，尤其是对土壤酸化过程的影响。结果表明，我国酸雨中高含量的盐基离子（Ca^2 、Mg^2 、NH4^ 等）既缓冲了酸雨本身的酸度，也缓解了土壤的酸化过程。虽然作用的效果相反，但盐基离子与酸性阴离子（SO4^2-、NO3^-等）一样，都是土壤酸化的重要影响因素。     

棕壤和褐土的酸淋溶特征

用室内模拟淋洗土柱的方法 ,对棕壤和褐土的酸淋容特征进行了研究。结果表明 ,p H低的酸雨使棕壤严重酸化且有活性铝测出 ,但对褐土的影响相对较轻。 4种盐基离子淋失总量与酸雨的氢离子浓度呈极显著的正相关关系 ,淋失量 Ca2 >Mg2 >Na >K ,其中 Na 对酸雨的酸度最不敏感。电导率的变化与盐基淋失量的变化有相同趋势 ,但不同处理之间的差别倍数大于盐基淋失差别的倍数 ,4种酸雨对土壤的危害程度为 p H2 >p H3>p H4、p H5 ,其中危害棕壤的程度高于褐土。     

幼龄荔枝园种植百喜草改良土壤效果的研究

当前,许多地区用种草法进行果园的水土保持。本文研究了幼龄荔枝园种植百喜草对土壤的改良作用,结果表明采用全园种植百喜草的模式不仅能够有效地改善土壤通透性,提高土壤微生物数量,增强土壤酶生物活性,而且使土壤理化性状受到改善。但如果种植不当,果树植株与草之间存在着相互争肥的现象,从而对幼龄荔枝植株的生长产生显著影响。     

Chemical response of soil leachate to alternative approaches to experimental acidification

Abstract

One approach to evaluating computer models which predict terrestrial‐aquatic ecosystem response to acid deposition is the experimental acidification of soils with subsequent comparisons among predicted and measured soil solution response. Using a soil microcosm experimental approach, comparisions between simulated acid rain (i.e. dilute H₂SO₄), dry NH₄NO₃, and prilled reduced S were made for suitability for large‐scale field experiments. Soil microcosms consisting of reconstructed soil profiles received a background simulated throughfall dosing over the six month treatment period. Results indicated that simulated throughfall, applied at twice the ambient rate, acidified soil leachates approximately 0.5 pH units over the treatment period. Along with the decline in leachate pH was an apparent release of base cations as well as Fe and Al. Over the length of the treatment period, very little of the prilled S dissolved and the simulated acid rain treatment did not have significant effects on leachate chemistry.     

模拟酸雨胁迫对赤红壤磷素形态特征的影响

通过田间小区模拟酸雨实验,研究酸雨胁迫下赤红壤不同磷素形态变化的方向和程度。结果表明,原位模拟酸雨影响下,一定强度（pH≥4.0）的酸雨胁迫能有效促进有效磷的释放,而当pH〈4.0强度酸雨胁迫时有效磷的释放随pH值降低逐渐受到抑制。随酸雨酸度的增强,土壤酸性磷酸酶和微生物量磷均呈现先升高后降低的变化趋势,可见一定强度酸雨胁迫能促进溶磷微生物和磷酸酶活性,而当高强度酸雨胁迫时土壤微生物活动逐渐受到抑制。无机磷组分中Al-P、Ca-P和Fe-P含量均随酸雨酸度的增强而降低,土壤O-P含量没有显著变化。相关分析发现,有效磷含量与微生物量磷、酸性磷酸酶呈极显著正相关,表明此时土壤有效磷变化与有机磷矿化关系最为密切。有效磷含量与各种形态无机磷（Al-P、O-P、Ca-P和Fe-P）含量之间也有较强的正相关性,表明土壤生态系统磷素转化是一个自我调节的动态平衡过程,且在一定条件下可以相互转化。     

Acidification of soils in five catchments in Norway

Soil plots were established in catchments within the frame of the Norwegian Monitoring Programme for Long-Range Transported Air Pollutants. Four soil plots of about 10 m by 20 m were established within each catchment in areas with relatively homogeneous soil and vegetation. Multiple soil cores were taken at 50 points in a grid from each plot (repeated 4 times) and the samples were pooled by depths. Each soil core was divided by soil horizon, by predefined depths or by a combination of these, usually giving one soil sample for each 2-cm-depth down to about 15 cm. The soil pH measured in water suspension varied for all soils between 3.5 and 4.9. Base saturation measured at pH 7 varied between 2% and 22% with the highest values in the upper, more humus rich layers. All of the monitored catchments include acid soils poor in base cations. After 8 years the plots were resampled using the same procedure as for the first sampling. In most of the plots a decreasing pH trend from the first to the second sampling was measured. However, the base saturation was generally higher in all plots at the second sampling compared with the first. There are no clear effects of the different pollution regimes in the various catchments. It must be emphasized, however, that 8 years is a short period for measuring long-term soil changes.     

寿光大棚土壤团聚体中交换性盐基离子组成与土壤团聚性关系

以山东寿光连作2,5,8,10年的大棚土壤为材料,临近露天麦地土壤为对照,研究土壤团聚体中交换性盐基离子组成变化与土壤团聚性关系。结果表明：交换性K＋、Na＋、Ca2＋和Mg2＋的平均含量在〉0.25mm大团聚体中分布比较均匀,均高于在〈0.25mm微团聚体中的含量。随着大棚种植年限延长,各粒径团聚体交换性K＋都呈逐渐增加的趋势,而交换性Na＋和Mg2＋呈现先上升后下降再回升的变化,交换性Ca2＋表现为先上升后下降的变化。其中,在0-10cm土层比在10-20cm土层变化更明显。各团聚体中,盐基离子平均含量为Ca2＋〉Mg2＋〉K＋〉Na＋。同时表明,（K＋＋Na＋）/（Ca2＋＋Mg2＋）的比值随土壤团聚体粒径的减小而增大。土壤中盐基离子储量和贡献率主要由团聚体的质量含量所决定,〉0.25mm的大团聚体贡献率可占88%～90%,其中以2～5mm团聚体储量最大。因此,生产中通过提高土壤大团聚体数量,可增强土壤的供肥保肥能力。     

热带亚热带酸性土壤硝化作用与氮淋溶特征

通过室内好气培养和土柱模拟淋洗培养试验,研究了氨基氮肥加入对热带亚热带4种不同性质和利用方式酸性土壤硝化、氮及盐基离子淋溶、土壤及淋出液酸化的影响。4种土壤分别为采自花岗岩发育的海南林地砖红壤(HR)、玄武岩发育的云南林地砖红壤(YR)、第四纪红黏土发育的江西旱地红壤(RU)和第四纪下蜀黄土发育的江苏旱地黄棕壤(YU)。结果表明:4种土壤硝化作用大小表现为YU>RU>YR>HR。HR主要以可溶性有机氮(DON)和NH₄⁺-N形态淋失,YU土壤的氮淋溶形态以NO₃^–-N为主,YR和RU土壤的氮淋溶形态NO₃^–-N、NH₄⁺-N和DON兼而有之。盐基离子总淋失量与NO₃^–-N淋失量显著正相关,但各盐基离子淋失由于离子本性和土壤性质差异并不完全一致。Ca²⁺在缓冲外源NH₄⁺-N硝化致酸和平衡...     

Soil Chemical Attributes of Amazonas State,Brazil

Amazonas State is the largest state in Brazil and mainly covered by tropical forest. Because of the importance of the tropical forest in maintaining soil health and a clean environment, conservation of the Amazon forest is a national priority. However, sustainable agriculture development is necessary in the state for the welfare of the local population. Maintaining soil fertility at an adequate level is an important component of sustainable farming. Very little information is available about soil fertility of Amazonas State. The objective of the present study was to evaluate chemical soil properties of Amazonas State of Brazil. Results include chemical properties of 3,340 samples, covering 62 municipalities of the state collected at 0–20 cm deep during 30 years (1975–2005). Chemical properties [phosphorus (P), potassium (K) extracted with Mehlich 1, calcium (Ca), magnesium (Mg), aluminum (Al) extracted with potassium chloride (KCl) 1.0?mol L^?1, potential acidity (H + Al) extracted with calcium acetate, and base saturation] presented great variation, except cation exchange capacity (CEC) and pH (water). Most of the soil samples were characterized as having high acidity; medium level of organic‐matter content; low levels of P, K, Ca, and Mg; and high levels of Al and H + Al. Overall, base saturation was less than 20%, a value considered very low for most of annual crops. Soils from upland areas were more acidic and have poor fertility compared with lowland soils. To maintain sustainability of cropping systems, use of an adequate level of liming and chemical fertilizers are necessary on these soils.