Compressive properties of some Swedish and Danish structured agricultural soils measured in uniaxial compression tests

Soil compaction is recognized as a threat to long‐term productivity of agricultural soils and as a cause of environmental problems such as flooding. The use of models to establish strategies for prevention of soil compaction is hampered by lack of model input parameters describing soil mechanical properties. This paper presents the compressive properties N (specific volume at σ = 1 kPa on the virgin compression line), C_c (compression index) and C_r (recompression index) obtained from uniaxial compression testing of 69 individual soil layers and investigates the relationships between these properties and readily quantifiable soil parameters. No correlation was found between compressive properties and soil texture. Instead, N, C_c and C_r were positively correlated to the initial specific volume (v₀). This suggests that compressive properties are more strongly affected by soil structure than by soil texture. Dependency of compressive properties on v₀ could not be expected from classical soil compressive behaviour theory but suggests modifications to the theory of soil unloading‐reloading behaviour. We suggest that the latter is dependent on time between unloading and reloading.     

An investigation of the re-expansion of unsaturated, structured soils during cyclic static loading

A procedure is presented that quantifies soil resilience to compressive stress, through elastic deformation or re-expansion after stress removal, with a single numerical index. This was achieved by comparing the three parameter coefficients of static-loaded and rebound compression lines (normal stress range = 0–1.0 MPa) which had been fitted to a non-linear density-stress model equation. The difference between the static-loaded and rebound values of one of these coefficients was significantly correlated to the clay and organic matter contents, the gravimetric moisture content and the initial dry bulk density of the 33 soils sampled as intact cores at field moisture content (coefficients of determination=0.533–0.973, P<0.05). The magnitude of the sample rebound observed varied between 0.018 and 0.075 Mg m⁻³ at the maximum applied stress of 1.0 MPa. This is likely to be a significant component of the error in prediction inherent in compaction models based on static-loaded compression data. The data further support the segregation of soils into groupings of comparable mechanical behaviour for soil compaction modelling purposes. The implications of these findings for improving soil resilience to compressive stress through soil and crop management are discussed.     

Guidelines for safe trafficking and cultivation, and resistance–density–moisture relations of three disturbed soils from Alberta

The Atterberg limits and the Proctor compaction test are used by engineers for classifying soils and for predicting stability of building foundations. Field capacity and wilting point (agronomic limits) are used to indicate available water for plant uptake. Few studies have related the engineering criteria to the agronomic ones with regard to compaction hazard for soils. This study investigated the relationships between Atterberg limits, agronomic limits and the critical moisture content (moisture content at Proctor maximum density) for three disturbed soils (sandy loam and clay loam soils from a reclaimed Highvale mine site, and a silt loam soil from a grazing site at Lacombe) of different textures. Relationships between bulk density, moisture content and penetration resistance for these soils were also investigated. For the sandy loam and loam soils, the field capacity was close to the critical moisture content but lower than the plastic limit. Therefore, cultivation of these two soils at moisture contents close to field capacity should be avoided since maximum densification occurs at these moisture contents. Overall, the critical moisture content or field capacity would be a better guide for trafficking of sandy loam and loam textured soils than the Atterberg limits. For the clay loam, field capacity was within the plastic range. Thus trafficking this soil at field capacity would cause severe compaction. In conclusion, either field capacity or plastic limit, whichever is less, can be used as a guide to avoid trafficking at this moisture content and beyond. For the sandy loam and loam soils penetration resistance significantly increased only with increased bulk density (P≤0.05). For the clay loam soil, penetration resistance was positively related to bulk density and negatively related to moisture content.     

A relatively simple scaling method for describing the unsaturated hydraulic functions of stony soils

Few if any methods exist to estimate the effects of stone content (stoniness) on the unsaturated soil hydraulic properties. A relatively simple scaling method is presented to estimate the hydraulic conductivity of unsaturated stony soils having different stone contents. A key assumption of the method is that van Genuchten's water retention parameters α and n of the fine soil fraction are the same as those of the stony soil. The method further assumes a linearly decreasing relationship between the saturated hydraulic conductivity and the stone content, based on previous numerical simulations. Using the proposed method, it is possible to calculate the hydraulic conductivity of unsaturated stony soils, knowing the saturated hydraulic conductivity of the fine soil fraction, the retention curve of the fine soil fraction, and the particular stoniness of the soil.     

Interpretation of uniaxial,confined compression test data for agricultural topsoils

Traditionally, soil strength is estimated from uniaxial, confined compression tests by procedures adopted from classical soil mechanics. The heterogeneity of agricultural topsoil calls for an alternative approach. Undisturbed soil cores were collected in the plough layer of 14 soils in arable agriculture. Soil texture ranged from coarse sandy to silty loam soils with a maximum of 20% clay. The samples were drained to either of six matric potentials in the range from − 30 to − 300 hPa. Uniaxial, confined compression was applied to ∼800 kPa with strain-controlled stress application (1 mm min⁻¹). Measured strain was fitted to stress by the Morgan-Mercer-Flodin (MMF) model. The model fitted data remarkably well for all samples. Three fitting parameters of the model reflected physical characteristics of soil reaction to stress. The estimates of soil compressibility calculated from the model at 10 kPa (C₁₀) correlated closely and linearly to the C_s index considered to reflect elastic deformation in classical studies of soil compression tests. Soil bulk density and content of soil organic matter decreased C₁₀ as well as compressibility at 100 (C₁₀₀) and 400 kPa (C₄₀₀). A complex pattern in the effects of soil texture and soil moisture on compressibility was revealed. The pattern in strain-stress data is interpreted as a reflection of a gradual transition from elastic to plastic deformation of the mixture of structural units. The MMF model is suggested for interpretation of strain-stress data from uniaxial, confined compression tests. This implies use of stress in a linear scale.     

Time‐resolved in‐situ pH measurement in differently treated,saturated and unsaturated soils

The pH‐value is of utmost relevance for soil properties and functioning. Hence, a time‐resolved in‐situ measurement is mandatory but lacking. As an alternative, a two‐probe pH electrode with gel‐covered reference electrode was newly constructed and tested for a continuous, in‐situ pH recording in saturated and unsaturated soil. This was done using samples from a set of 14 soils with different composition and pH$ _{\rm CaCl_2} $ ranging from 3.5 to 7.5 in batch and repacked soil column experiments. In the latter, changes in pH and redox potential were monitored upon transport of citrate‐phosphate buffer and pig slurry through the soil columns. The pH measurements were largely stable even upon substantial shifts in soil moisture content down to air‐dry conditions. The results of the pH measurements agreed with standard methods using settled soil suspensions in electrolyte solutions and the conventional combination (single‐probe) pH electrode. Testing the suspension effect, it was found that measuring pH directly in the soil is recommended. The pH measured in‐situ was closest to pH values determined in 0.01 M CaCl₂ suspensions according to DIN ISO 10390 (DIN, 2005 ). The transport of citrate buffer and pig slurry as pH active substances through soil induced strong effects on the pH and in part on the redox potential; the reversible effects lasted over days, which may affect the mobility and speciation of nutrients and pollutants as well as microbial processes.     

Estimation of bulk density of waterlogged soils from basic properties

Pedotransfer functions (PTFs) to predict bulk density (BD) from basic soil data are presented. Available data pertaining to seasonally impounded shrink–swell soils of Jabalpur district in the Madhya Pradesh state of India were used for the study. The data included horizon-wise information of 41 soil profiles in the study area covering nearly 5 million ha. Six independent variables, namely textural data (sand, silt and clay), field capacity (FC), permanent wilting point (PWP) and organic carbon content (OC) were used as input in hierarchical steps to establish dependencies, with bulk density as the dependent variable, using statistical regression and artificial neural networks. The PTFs derived using neural networks [average root mean square error (RMSE) 0.05] were relatively better than statistical regression PTFs (average RMSE > 0.1). The best-performing PTFs required input data on sand, silt content, FC and PWP, with lowest prediction errors (RMSE 0.01, maximum absolute error (MAE) 0.01) and highest values of index of agreement (d, 0.95) and R ² (0.65). Use of measures of structure, as well as information on pore structure, was found to be essential to derive acceptable PTFs. Inclusion of OC as an input variable showed relatively better fitting to the training data set, implying an underlying relationship between OC and BD, but the neural networks could not mimic the relationship when tested against subset.     

Benzene polycarboxylic acids—A ubiquitous class of compounds in soils

Black carbon (BC) occurs ubiquitously in the environment. Its oxidation in the laboratory yields a suite of benzene polycarboxylic acids (BPCAs), suggesting similar oxidation products in soils. Since only for a few soils the occurrence of BPCAs in the free form has been documented, screening for them in a broad range of contrasting soils was conducted. They were extracted from soil samples with 0.5 M NaOH and quantified using gas chromatography–mass spectrometry. As expected, BPCAs turned out to be as ubiquitous as BC. They were detected not only in every soil sample investigated so far, but also in samples from drill cores up to a depth of 10 m and in recently deposited calcareous tufa. The concentrations covered a range similar to that of some phenolic acids. The range exceeded those reported for low‐molecular‐weight aliphatic acids or simple sugars in soils. The distribution of BPCAs in soil profiles indicated a considerable potential of translocation within, and export from, soil, in particular of benzene hexacarboxylic (mellitic) acid. Mellitic acid may therefore be present in almost any geochemical sample affected by seepage water from soils. Its high water solubility and strong metal‐complexing ability suggest it may be involved in metal‐transport processes, at least on geological timescales.     

Nitrous oxide emissions from arable soils in Germany — An evaluation of six long‐term field experiments

In this study emissions of N₂O from arable soils are summarized using data from long‐term N₂O monitoring experiments. The field experiments were conducted at six sites in Germany between 1992 and 1997. The annual N‐application rate ranged from 0 to 350 kg N ha^—1. Mineral and organic N‐fertilizer applications were temporarily split adapted to the growth stage of each crop. N‐fertilizer input and N‐yield by the crops were used to calculate the In/Out‐balance. The closed chamber technique was applied to monitor the N₂O fluxes from soil into the atmosphere. If possible, plants were included in the covers. Annual N₂O emission values were based on flux rate measurements of an entire year. The annual N₂O losses ranged from 0.53 to 16.78 kg N₂O‐N ha^—1 with higher N₂O emissions from organically fertilized plots as compared to minerally fertilized plots. Approximately 50% of the total annual emissions occurred during winter. No significant relationship between annual N₂O emissions and the respective N‐fertilization rate was found. This was attributed to site‐ and crop‐specific effects on N₂O emission. The calculation of the N₂O emission per unit N‐yield from winter cereal plots indicates that the site effect on N₂O emission is more important than the effect of N‐fertilization. From unfertilized soils at the sites Braunschweig and Timmerlah a N‐yield of 60.0 kg N ha^—1 a^—1 and N₂O emissions of 2 kg N ha^—1 a^—1 were measured. This high background emission was assigned to the amount and turnover of soil organic matter. For a crop rotation at the sites Braunschweig and Timmerlah the N In/Out‐balance over a period of four years was identified as a suitable predictor of N₂O emissions. This parameter characterizes the efficiency of N‐fertilization for crop production and allows for N‐mineralization from the soil.     

The Warrumbungle Post‐Fire Recovery Project—raising the profile of soils

The impacts of a wildfire and subsequent rainfall event in 2013 in the Warrumbungle National Park in New South Wales, Australia were examined in a project designed to provide information on post‐fire recovery expectations and options to land managers. A coherent suite of sub‐projects was implemented, including soil mapping, and studies on soil organic carbon (SOC) and nitrogen (N), erosion rates, groundcover recovery and stream responses. It was found that the loss of SOC and N increased with fire severity, with the greatest losses from severely burnt sandstone ridges. Approximately 2.4 million t of SOC and ~74,000 t of N were lost from soil to a depth of 10 cm across the 56,290 ha affected. Soil loss from slopes during the subsequent rainfall event was modelled up to 25 t ha^?1, compared to a long‐term mean annual soil loss of 1.06 t ha^?1 year^?1. Groundcover averages generally increased after the fire until spring 2015, by which time rates of soil loss returned to near pre‐fire levels. Streams were filled with sand to bank full levels after the fire and rainfall. Rainfall events in 2015–2016 shifted creek systems into a major erosive phase, with incision through the post‐fire sandy bedload deposits, an erosive phase likely related to loss of topsoils over much of the catchment. The effectiveness of the research was secured by a close engagement with park managers in issue identification and a communications programme. Management outcomes flowing from the research included installation of erosion control works, redesign of access and monitoring of key mass movement hazard areas.     

Estimation of the biological activity of peat soils from the specific electrical resistance

The parameters of the potential biological activity (respiration, methanogenesis, nitrogen fixation, and denitrification) of drained peat soils were analyzed as depending on their morphological, chemical, and electrical properties. A high positive correlation was found between the potential respiration of the soil and its electrical resistance, because these parameters depended on the same soil properties: the ash content, the cation exchange capacity, etc. The correlation was disturbed under a significant adverse impact of the soil water-air regime on the microbial community, which was difficult to detect from the resistance. No correlation of anaerobic methanogenesis and denitrification with the resistance was found. The revealed relationships can find wide use in the study of the spatial distribution of the potential biological activity of soils, which will allow deriving more correct and representative data.     

Higher levels of description—approaches to the micromorphological characterisation of Russian soils

Several attempts were made in the past to identify high-level soil microfabrics, following the ideas of Kubiëna. They resulted in proposals to identify specific fabric types, soil materials, somas, formations, or morphotypes, based on the combinations of micromorphological characteristics of the studied horizons of soils. These units present complex (integrated, typical, and central) micromorphological images of soil horizons or materials. Using the available information on Russian soils, the author defined the “micromorphotypes” of soil horizons by illustrating this approach by two examples of simple and complicated genetic horizons. Emphasis was put on genetic and diagnostic aspects of micromorphological interpretations, which is traditional for Russian micromorphological studies. Moreover, the definition of “micromorphotypes” was derived from the ideas of diagnostic horizons, which serve as a base for the new Russian soil classification system. Examples of “micromorphotypes” are discussed for a Chernozem and major mineral horizons of loamy soils with textural profile (correlated with Albeluvisols in the WRB system). They illustrate the morphogenetic principles applied, and also bring to light some problems concerning the choice and hierarchy of criteria used for a number of soils.This “micromorphotypes” approach may contribute to the diagnostics of horizons for soil classification, for detection of human impacts, and for the identification of paleosols and their diagenetic changes. To facilitate contacts with nonprofessionals in micromorphology, a simple terminology and a priority of pedogenic principles seem to be preferable.     

Modelling of colloid leaching from unsaturated, aggregated soil

The migration of colloids in soils can enhance the leaching of strongly sorbing contaminants. We present a model for the simulation of colloid leaching from unsaturated, aggregated soil media under stationary flow. Transport in the intra-aggregate pores is simulated by convection–dispersion, and transport in the interaggregate pores, and a stagnant layer of water surrounding the aggregates, is simulated by diffusion. The model describes the release of colloids from soil aggregates, sorption and desorption processes at the air–water interfaces, and flocculation and subsequent straining from the flowing water. All three processes were simulated as functions of ionic strength. Transport of ions in intra-aggregate pores was simulated by Fickian diffusion. The model was calibrated against experimental results of colloid leaching from columns packed with natural soil aggregates. The aggregates were of two soils differing in organic matter content. On each soil a single calibrated parameter set could describe the experiments with the three ionic strengths. The parameters for release of colloids from the aggregate surface and the sorption properties of the air–water interface were different for the two soils. The key parameters for leaching were the thickness of the stagnant layer of water surrounding the aggregates, the mechanical dispersion, the maximum concentration of colloids at the surface of the aggregates, the sorption capacity and rate coefficient of the colloids at the air–water interface, and the colloid diffusion coefficient. Simulations were also done with two additional irrigation intensities at one ionic strength. Simulated leaching was greater than measured leaching at both irrigation intensities, but the diffusion-controlled release of colloids from the aggregates was simulated correctly.     

An approach to rheometry in soil mechanics—Structural changes in bentonite, clayey and silty soils

Rheology is regarded as the science of flow behaviour, where, based on isothermic equations, the deformation of fluids and plastic bodies subjected to external stresses may be described. Hooke's law of elasticity, Newton's law for ideal fluids (viscosity), Mohr-Coulomb's equation, and finally, Bingham's yielding are well known relationships and parameters in the field of rheology.

Rheometry is a well established measurement technique to determine the specific rheological properties of fluid and plastic bodies. However, the application of this technique in soil mechanical investigations is yet relatively uncommon. In order to explain point contact processes and strength an extrapolation of such findings to data of triaxial, direct shear or oedometer tests is still missing. Thus, this paper aims to introduce rheometry as a suitable method to determine the mechanical behaviour of soils and mineral suspensions when subjected to external stresses. To do this a Na-bentonite, Ibeco Seal-80 (IS-80) has been used as a testing material, and the suspensions were equilibrated with NaCl solutions in different concentrations in order to determine the ionic strength effects on interparticle strength and changes in mechanical properties. Furthermore a vertisol, a clayey oxisol, both from Brazil, and loess material from Israel, saturated with NaCl in several concentrations were analysed.

A parallel-plate-rheometer MCR 300 (Modular Compact Rheometer, Paar Physica, Ostfildern, Germany) has been used to conduct oscillatory tests. From the stress–strain relationship parameters and specific characteristics as thixotropy, storage modulus G′ and loss modulus G″, viscosity η, yield stress τ_y and the linear viscoelastic deformation (LVE) range including a limiting value γ_L were determined and calculated, respectively. With aspect to salt effects, amplitude sweep tests on CaCO₃ rich Avdat loess show an increasing stability due to higher NaCl concentrations. In a comparative test of Avdat loess and Ibeco Seal-80, turbulent versus sliding shear behaviour could be illustrated. To demonstrate clay mineralogy effects or textural effects clay rich substrates from Brazil, a smectitic vertisol and a kaolinitic oxisol were compared, showing a higher level of stored elasticity (stability) in case of smectites and a lower value in regard to kaolinites. These preliminary results of amplitude sweep tests show that rheometry is a potential method of investigating microstructural characteristics of mineral suspensions and of clayey or silty soils.     

Stabilization of organic matter by soil minerals — investigations of density and particle‐size fractions from two acid forest soils

We tested the hypothesis whether organic matter in subsoils is a large contributor to organic carbon (OC) in terrestrial ecosystems and if survival of organic matter in subsoils is the result of an association with the soil mineral matrix. We approached this by analyzing two forest soil profiles, a Haplic Podzol and a Dystric Cambisol, for the depth distribution of OC, its distribution among density and particle‐size fractions, and the extractability of OC after destruction of the mineral phase by treatment with hydrofluoric acid (HF). The results were related to indicators of the soil mineralogy and the specific surface area. Finally, scanning electron microscopy combined with energy dispersive X‐ray spectroscopy (SEM‐EDX) was used to visualize the location of OC at mineral surfaces and associations with elements of mineral phases. The subsoils (B and C horizons) contained 40—50% of the soil OC including the organic forest floor layers. With increasing depth of soil profiles (1) the radiocarbon ages increased, and (2) increasing portions of OC were either HF‐soluble, or located in the density fraction d >1.6 g cm^—3, or in the clay fraction. The proportions of OC in the density fraction d >1.6 g cm^—3 were closely correlated to the contents of oxalate and dithionite‐citrate‐bicarbonate‐extractable Fe (r² = 0.93 and 0.88, P <0.001). SEM‐EDX analyses suggested associations of OC with aluminum whereas silicon‐enriched regions were poor in OC. The specific surface area and the microporosity of the soil mineral matrix after destruction of organic matter were less closely correlated to OC than the extractable iron fractions. This is possibly due to variable surface loadings, depending on different OC inputs with depth. Our results imply that subsoils are important for the storage of OC in terrestrial ecosystems because of intimate association of organic matter with secondary hydrous aluminum and iron phases leading to stabilization against biological degradation.     

The effect of water movement on the transport of dicyandiamide,ammonium and urea in unsaturated soils

A laboratory experiment was conducted to investigate the relative mobility of dicyandiamide (DCD) and jointly applied ammoniacal salts or urea in three different soils of lower Egypt, and to determine the extent to which DCD separates from N-fertilizer in unsaturated soil undergoing leaching. The experimental results suggest that, under conditions of water flow, DCD is readily separated from NH₄⁺ but parts from urea to a far lesser extent. The large difference in mobility between DCD and NH₄⁺ should severely limit the effectiveness of DCD as a nitrification inhibitor in the three soils considered when applied in conjunction with ammoniacal salts. In two out of three cases, the situation is similarly unfavorable in the case of joint DCD and urea application. However, the observation that DCD, in a low CEC sandy loam, moves within the soil solution at a slightly lower rate than urea suggests that joint application with urea would keep at least part of the DCD in contact with the NH₄⁺ ions and, therefore, would preserve some of the effectiveness of DCD under leaching conditions in this soil.     

Universality of a surface tension—contact‐angle relation for hydrophobic soils of different texture

Wettability of soil affects a wide variety of processes in soils like infiltration, percolation, preferential flow, and surface runoff. Even though efforts have been made to determine contact angles and surface tension or energy of smooth surfaces, the determination on granular materials like soil particles remains unsolved. One objective of this study was to test the consistency of contact angles (CA) measured with the newly modified and easy‐to‐apply Wilhelmy plate method by using solid particles and liquids with defined variations of surface tension. A second objective was to derive basic physical surface properties for the irregularly shaped and chemically heterogeneous soil particles. Advancing contact angles were determined by using model soils varying in texture from clay to coarse sand to check the impact of grain size on the CA measurements. Varying the solid‐surface tension with dichlorodimethlylsilane treatments provided for pure‐water wetting stages ranging from wettable to extremely hydrophobic. The surface tensions of the liquids were varied from 72 mN m^–1 to 25 mN m^–1 by using water or water‐ethanol mixtures. The surface tensions of the model soils were determined with the zero degree–contact angle method following Zisman's critical–surface tension concept. Results show that the measured CA varied continuously with the variations of the surface tension of the liquid and the solid phase, respectively. A general interpretation of the results is possible by using the concept of the Equation of State Approach.