Untersuchungen über die Freisetzung der Bioelemente aus der organischen Substanz der Humusauflage in einem Buchenbestand

Investigations on the Transfer of Bioelements from Organic Matter to Soil Solution in the Humus Layer of a Beech Stand Monthly and annual fluxes of bioelements were measured in two levels: (a) at the soil surface (= input) and (b) at the lower boundary of the humus layer (= output) by determination of amount and concentration of the precipitation (canopy drip), of the litter and of the seepage. Seepage was collected with funnel lysimeters. By comparison of both fluxes (input-output-analysis) for some bioelements mathematical equations could be derived which describe the transfer of these elements from organic matter to soil solution. The results are explained as consequence of the different bonds of the elements in leaf tissues and in humus substances.     

Kurzmitteilung Einfluß der Qualität der organischen Substanz auf die Konsistenz landwirtschaftlicher Böden

Influence of organic matter quality on consistency of agricultural soils The soil organic matter of two samples similar in the texture and approximately in the organic C contents, but very differently in the consistency properties, were investigated by pyrolysis-field ionization mass spectrometry (Py-FIMS). The shifts of the values of the liquid and plastic limits towards higher moisture contents are explained by a different quality of soil organic matter, in particular by higher amounts of longchained lipids (C_8-32 alkanes, alkenes, fatty acids), N-compounds and lignin dimers.     

Einfluß von Bodenreaktion,Redoxbedingungen und organischer Substanz auf die Phosphatgehalte der Bodenlösung

Influence of soil reaction, redox conditions and organic matter on the phosphate content of soil solutions Samples of seven agriculturally used soils of different composition (A_p-horizons), one marine underwater soil and two garbage composts were adjusted in suspensions (soil-water-ratio 1:3) to different pH values between 3 and 8 by additions of NaOH or HCl. By a different degree of aeration the redox potential was kept constant at selected values between +600 and ?300 mV. After an incubation period of 22–24 days under controlled E_h-pH-conditions the content of total phosphate and orthophosphate was measured in the equilibrium solutions. At oxidizing conditions all soil and compost samples show the lowest phosphate content in solution at pH S6. At higher and lower pH values the phosphate content increases. The results indicate that the phosphate concentration is determined by adsorption/desorption processes – mainly connected with iron oxides – and not by dissolution or precipitation of definite phosphorus compounds. Under reducing conditions the phosphate content increases in the equilibrium solutions of all samples. Especially in samples with high content of sulphides a considerable increase of the phosphate concentration could be measured at Eh values below +300 mV at pH 5, +200 mV at pH 6, and ± 0 mV at pH7 and 8. Below these values phosphate containing iron(II1) oxides were reduced and – with further decreasing redox potentials – transformed to iron sulphides. In samples without sulphide formation the phosphate mobilization is much lower. With increasing amount of soluble organic matter the phosphate content of the solutions also increases because of phosphate desorption by organic anions or complexation of aluminium and iron from phosphate adsorbing compounds. But also the content of soluble organically bound phosphate increases and may amount to 70 % of the total phosphate content in solution.     

Einfluß von Bodeneigenschaften,Bodennutzung und Bodentemperatur auf die N-Mobilisierung von Kulturböden

Influence of soil characteristics, agricultural use and soil temperature on the N-mobilization of cultivated soils A new N-mobilization model, which considers also the short term and seasonal N-supplying capacity of soil is presented. At a fixed time the potential mobilizable N (N-MOB) is a sum of difficultly mobilizable N (N-MOB_s) originating from the pool of difficultly mobilizable N (N_s) and the easily mobilizable N (N-MOB₁) originating from the pool of easily mobilizable N (N₁). It is possible to characterize soil according to their M₁, N-MOB_s and v (N-MOB_s per day) values. Usefulness of these parameters in N-nutrition and ground water burden from N has been discussed. Basic parameters of this model have been experimentally determined independently with the help of two different experiments i. e. laboratory incubation and column lysimeter using surface soil samples. The easily mobilizable N pool (N₁) values were found in the range of 142 to 814 kg N ha^?1 which corresponded to 1.2 to 7.4 % of organic N content of these soils. The difficultly mobilizable N per day (i. e. v = N-MOB_s per day) in an incubation experiment (35°C) were found in the range of 1.5 to 24kg N ha^?1. However, in the column lysimeter experiment, in contrast, these values at 10°C ranged between 0.05 to 0.9 kg N ha^?1. These values correspond to N-MOB_s values in the range of 11–182 kg N·ha^?1 for a period of 200 days which approximate to a vegetation period. For practical purposes, the N₁ and v values could be calculated by just measuring 3–4 points after 14 days of incubation at 35°C. The results show that N-MOB_s values strongly correlated compared to N₁ values to total N, organic carbon and clay content and non significantly to pH and silt content. The results of an laboratory incubation experiment carried out to assess the effect of temperature on N-mobilization show that even at 0°C there was N-mobilization. The results revealed that in the temperature range of 0–8°C (a range of soil temp. usually observed in winter months) and in the range of 25–40°C (range of summer months temp. for surface arable soil), a small change in the soil temperature would result in enormous increase in the quantity of mobilized N. The highest mobilized N quantity was found above 60°C.     

Einfluß chemischer Bodeneigenschaften auf Ausmaß und Zusammensetzung der Denitrifikationsverluste drei verschiedener Bakterien

Effect of soil properties on the quantity and quality of denitrification with different bacteria The influence of 4 different soils on the intensity and quality of gaseous denitrification losses from 3 bacteria (Aeromonas “denitrificans” S224, Azospirillum lipoferum DSM 1843 and Bacillus licheniformis ATCC 14580) was examined in model experiments at complete anaerobic conditions at the expense of a relatively high nitrate concentration (300 μg NO₃^? N/g dry soil) at standard conditions (30°C, 80% WHC). The soils (Ah-material) were obtained from gleyo-eutric Fluvisol (A), orthic Luvisol (L), calcaric Fluvisol (AR) and eutric Cambisol (KB) and represented different chemical properties. Gas production (CO₂, NO, N₂O, N₂ and CH₄) was analyzed by gaschromatography in regular intervals, whereas changes in N_t, C_t, water extractable organic carbon (C), nitrate, nitrite, ammonium, pH (H₂O) were determined at the end of each experiment. The intensity and composition of denitrification (NO, N₂O, N₂) differed considerably from organism to organism and from soil to soil. With A. “denitrificans” NO was released from the calcaric Fluvisol and orthic Luvisol, whereas B. licheniformis produced this gas only from the Cambisol. A. lipoferum did not produce NO in any of the soils tested. N₂O was liberated by A. “denitrificans” in all soils, but A. lipoferum produced it only in the Fluvisol and B. licheniformis exclusively in the Cambisol. Apparently, the production of NO and N₂O as products of incomplete denitrification at relatively high nitrate concentration is determined primarily by the organism in question and in the second place by the chemical properties of the soil. The main properties that govern the quality of denitrification in soils are discussed.     

Einfluß verschiedener Bodeneigenschaften auf die mikrobielle Toxizität von Blei und Cadmium

Effects of different soil properties on the microbial toxicity of lead and cadmium Effects of different soil properties on the microbial toxicity of lead and cadmium were investigated in laboratory experiments on ten arable and nine preserve area soils. Microbial activity was measured by means of the dehydrogenase and the arginine-ammonification tests. The latter was not suitable to show the microbial toxicity of both metals. Effects of lead on dehydrogenase activity were mainly influenced by its concentration in soil solution (r = 0,79). Thus, all soil properties which determined the adsorption of lead correlated significantly with the relative dehydrogenase activities of the contaminated soils. The most important abiotic factors influencing the toxicity of lead were the soil pH and the CEC. Cd solubility and Cd toxicity were influenced by soil pH in a contrary way. Low Cd concentrations caused greater inhibitions of dehydrogenase activity at neutral and slightly alkaline soil reaction than under acidic conditions. Therefore, correlations between Cd concentrations of soil solutions or clay content and dehydrogenase activity were only significant if partial correlation analysis (constant pH) was used.     

Die Ermittlung der Porengrößenverteilung aus der Körnung,dem Gehalt an organischer Substanz und der Lagerungsdichte

The estimation of pore size distribution from texture, organic matter content and bulk density Using regression analysis the dependence of the pore size distribution of soils on the compactness and percentage of organic matter, clay and silt was studied on 450 soil horizons. From the results nomograms for determination of the pore size distribution were constructed. The average deviation between pore size distribution as read from the nomograms compared and determined in the laboratory is ～ ± 3 Vol.-%.     

Der Einfluß der natürlichen organischen Substanzen auf die Metallverteilung zwischen Boden und Bodenlösung in einem sauren Waldboden

The influence of organic matter in the translocation of metals between soil and soil solution of an acid forest soil Water extracts were prepared from soil samples which were collected from a soil profile showing very little variation in the texture down to a depth of 120 cm and thus only little translocation of clay in the soil profile. The aim of the study was to describe the distribution between soil and soil solution of several metals like Cu, Pb, Cd, Zn, Al and Mn as a function of humic substances, electrolyte concentration and pH. From the experimental results the following hypothesis on the reaction mechanisms involving metals and humus derived substances has been deduced. The metals Cu, Fe, Al and Pb are mobilized through complexation by soluble humus substances in addition to the usual pH dependent desorption and dissolution of hydroxides. This mobilization determines the solution concentration of Cu and Fe at pH > 3.7 and Al and Pb at pH > 4.2. Al, Fe and Pb are complexed selectively by high molecular weight humus derived substances which undergo adsorption on soil mineral surfaces. Cu interacts with low molecular weight humus derived substances which are not easily adsorbed by the mineral surfaces. Zn, Cd and Mn primarily undergo sorption and are thus controlled by pH and electrolyte concentration of solutions because their complexation with humus derived substances seems to be weak or nonexistant. It is further postulated that the humus derived substances mobilize Al³⁺ and Fe³⁺ ions. By this, other metals like Cd, Zn, Mn, Ca and Mg can occupy the free exchange sites.     

Der Einfluß der Expositionszeit auf die Höhe der Bodenatmung bei Anwendung der Lundegardhmethode

The influence of exposure time on the magnitude of soil respiration under employment of the Lundegardh-procedure To assess the role of carbon-rich soils under a potential climate change much more data are needed then currently available. These have to be collected also under conditions, where only limited technical and personal resources are available. Therefore the easy to be accomplished Lundegardh-procedure, which is accepted as a standard procedure for exposure times up to 24 hours (Anderson, 1982), was tested for its suitability to longer periods of exposure. For this purpose six Lundegardh-traps were installed on seven consecutive days (treatment B), and the means of the six repetitions added to a weekly value. In the immediate vicinity to the former, six Lundegardh-traps were installed for periods from one to seven days (treatment A) This was done during the warm season as well as in the winter. The comparison of the treatments A and B revealed a linear correlation, which allows to substitute cumulated daily values by values of traps, that have been installed for several days. However, the “chamber-effect”, an overestimation of respiration by the traps installed for more than 24 hours found by Tesarova and Gloser (1976) has to be considered. In the summer, the same degree of overestimation (16%) was found as reported by Tesarova and Gloser (1976). In the winter, far lower absolute values and therefore higher statistical importance of extremes led to an overestimation of 46%.     

Ein Verfahren zur Messung der Verlagerungsrichtung von gelösten Pflanzenschutzmitteln im bewachsenen Boden

A procedure to measure the direction of translocation of solved pesticides in planted soil In an experimental pot, which permits the airtight isolation of the root region, the rooted and non-rooted soil compartment are separated by stainless steel wire nets. The translocation and mineralisation of a pesticide can be studied by alternative application of radioactive labelled compounds to either one of the compartments. As an example results with ¹⁴C-atrazine are discussed.     

Einfluß von Kationenaustauscherharz auf die Schwermetallaufnahme von Reben und anderen Kulturpflanzen aus kontaminierten Böden

The effect of a cation exchange resin on the uptake of heavy metals by grapevines and other cultivated plants grown in contaminated soils The effect of a cation exchange resin on the growth and heavy metal content of grapevine, sun flower, cress, wheat and Italian rye-grass was investigated in potted vineyard soil, contaminated by the long application of Cu-containing pesticides (total Cu content of the soil: 628 ppm), or a soil contaminated artificially with 20 ppm Cd. Roots of cress seedlings grown in a vineyard soil mixed with a cation exchange resin were 2.2 times longer than in the untreated soil. Rye-grass was not injured, whereas grapevine, sun flower and wheat showed varying degrees of growth reduction, chlorosis and necrosis when grown in untreated vineyard soil. However, wheat and sunflower grown in vineyard soil containing a cation exchange resin showed no injury and grapevines exhibited markedly reduced symptoms. The Cu content of the test plants decreased as follows: The Zn and Cd content of the plants also decreased considerably, whereas their Fe and Mn content was not influenced. Grapevine, grown in a calcareous soil contaminated with 20 ppm Cd, contained 447 ppm Cd in the roots (untreated: 1,9 ppm) and 0,20 ppm Cd in the leaves (untreated: 0,04 ppm). The Cd content of the roots declined to 113ppm, that of the leaves to 0,15 ppm when grown in the contaminated soil containing a cation exchanger.     

Einfluß der Probenvorbereitung auf die Adsorption von Cd und Cu in sauren Waldböden

Influence of Soil Sample Preparation on Cd and Cu Adsorption in Acid Forest Soils The influence of soil sample preparation on Cd and Cu adsorption was investigated using six acid forest soil samples and comparing adsorption isotherms for fresh and air-dried samples. While no influence of sample preparation on Cd adsorption capacity was found, air-drying resulted in a significant decrease in Cu adsorption density in all six soil samples under investigation at ecotoxicologically relevant concentrations in the soil solution.     

Einfluß der Saugspannung auf den Wasserentzug durch die Wurzeln einer Grasvegetation

Relations between root water uptake and soil moisture tension . The root water uptake Q expressed as sink term of the continuity equation was computed using exclusivly field measured data of a post-irrigation water transport study. The experiment was carried out in an undisturbed Loess soil monolith. The soil moisture redistribution influenced by the evapotranspiration of the grass cover and the soil moisture characteristics were measured independently using the identical experimental layout. The data show a clear relationship between the root water uptake Q and the soil moisture tension S. Within the tension range of approx. 0–100 mbar the uptake Q decreases drastically with water desaturation. Within the upper part of the rooting zone this decrease is more pronounced and starts at a lower tension.     

Zur Dynamik gelöster organischer Substanzen (DOM) in Fichtenökosystemen - Ergebnisse analytischer DOM-Fraktionierung

Dissolved organic matter (DOM) dynamics in spruce forested sites - examinations by analytical DOM fractionation Dissolved organic matter from two spruce forested sites in the Fichtelgebirge (Germany) was divided into different chemical and functional fractions, and the budgets of the fractions obtained were calculated. For both sites hydrophobic acids (HoS), hydrophilic acids (HiS), hydrophobic neutrals (HoN), hydrophilic neutrals (HiN), and hydrophilic bases (HiB) are discriminated concerning their dynamics in the compartments. Most of the HiN and HoN are mobilized by leaching from the forest canopy. Both neutral fractions are netto retained in the forest floor as well as in the mineral soil. In contrast, HoS and HiS are mainly released in the organic layers with a total input of organic acids from the forest floor into the mineral soil of ca 100 kg C (HoS) ha^?1 a^?1, and 50 kg C (HiS) ha^?1 a^?1, respectively. HoS are selectively better retained in the mineral horizons, leading to a mineral soil output of 2.4 – 4.4 kg C (HoS) ha^?1 a^?1, and 2.7 – 6.5 kg C (HiS) ha^?1 a^?1, respectively. It is concluded that the different mobility of the DOM fractions has implications for the mobilization and transport of organic pollutants and heavy metals.     

Der Einfluß der Fauna auf die Stoffverlagerung sowie die Homogenität und die Durchlässigkeit von Böden

The influence of the fauna on displacement and on homogeneity and permeability of soils The influence of the most important soil animals (mammals, ants, termites, woodlice and earthworms) on displacement and on homogeneity and permeability of soils is discussed in reference to both older and more recent literature. Nearly all soil animals cause displacement of organic and mineral soil particles. The quantity, intensity and direction of this activity depends upon the morphological characters of the species involved. The homogeneity of soils is positively influenced only by the earthworms (and related forms) whereas the activity of the other soil fauna mostly has a contrary effect as far as shorter periods are concerned. The permeability of soils increases in different dimensions due to the activity of all species discussed. Permanent vegetation and non-tilling for the most part favour the activity of the soil fauna. Recent field experiments dealing with minimum or zero tillage have made this fact fairly evident.     

Einfluß der Löslichkeit verschiedener Phosphatdüngemittel auf die Phosphataufnahme und den Ertrag von Sommerweizen

Solubility of various phosphate fertilizers in a brown podzolic soil and their effect on phosphate uptake and yield of spring wheat. The solubility of various phosphate fertilizers (Superphosphate, Rhenaniaphosphate, Novaphos, Carolonphosphate and Hyperphosphate) was studied in an incubation experiment, and P uptake and yield effect of these fertilizers were investigated in a pot experiment. The soil used was a carbonate free brown podzolic earth (C horizon) with a neutral pH and low in available phosphate and humus. The quantities of P extracted from the soil by the EUF technique were the lower, the higher the amount of non processed phosphate of the incubated P fertilizers. This clear differentiation in the solubility of the various P-fertilizers was not obtained by the DL extraction. The P uptake of plants was highly correlated with the P quantities extracted by EUF (r = 0,95***), while the correlation between P uptake and the P of the DL extract was less narrow (r = 0,64*). The yield, particularly the grain yield, decreased with an increase of the non processed P in the fertilizers tested. Grain yield and EUF extractable P were highly correlated (r = 0,86***); while the relationship between grain yield and the DL extractable P was poorer (r = 0.62*). The experiments have shown that mainly the easily soluble phosphate is of decisive importance for the yield formation.