Soil physical characteristics of peat soils

Drainage and intensive use of fens lead to alterations in the physical characteristics of peat soils. This was demonstrated using parameters of water balance (available water capacity) and the evaluated unsaturated hydraulic conductivity. Deriving the distribution of the pore size from the water retention curve was flawed because of shrinkage due to drainage, especially at high soil water potentials. These errors became greater as the peat was less influenced by soil‐genetic processes. The water retention curves (desorption) evaluated in the field and the laboratory satisfactorily corresponded. However, the wetting‐ and drainage‐curves obtained in the field differed up to 30 vol.‐% water content at same soil water potentials. These differences were largely due to a wetting inhibition.     

Water retention of light expanded clay amendment

Abstract

Shallow‐drained horticultural soils utilized in containers, sporting areas, and landscape sites tend to retain excess water and thereby be poorly aerated as a consequence of capillary retention following irrigation or precipitation. This problem is usually corrected by soil physical amendment with coarse‐textured particulates to add large pores which drain and provide adequate aeration. A variety of materials are used for soil physical amendment. This study examined the water retention of one of the newer amendments used for this purpose, light expanded clay amendment (LECA), relative to its use in shallow‐drained soils. Although LECA is a porous material, its contribution to soil physical properties when used as an amendment were found to be similar to non‐porous amendments such as river sand or gravel because the internal water is not readily available for plant use.     

Universality of a surface tension—contact‐angle relation for hydrophobic soils of different texture

Wettability of soil affects a wide variety of processes in soils like infiltration, percolation, preferential flow, and surface runoff. Even though efforts have been made to determine contact angles and surface tension or energy of smooth surfaces, the determination on granular materials like soil particles remains unsolved. One objective of this study was to test the consistency of contact angles (CA) measured with the newly modified and easy‐to‐apply Wilhelmy plate method by using solid particles and liquids with defined variations of surface tension. A second objective was to derive basic physical surface properties for the irregularly shaped and chemically heterogeneous soil particles. Advancing contact angles were determined by using model soils varying in texture from clay to coarse sand to check the impact of grain size on the CA measurements. Varying the solid‐surface tension with dichlorodimethlylsilane treatments provided for pure‐water wetting stages ranging from wettable to extremely hydrophobic. The surface tensions of the liquids were varied from 72 mN m^–1 to 25 mN m^–1 by using water or water‐ethanol mixtures. The surface tensions of the model soils were determined with the zero degree–contact angle method following Zisman's critical–surface tension concept. Results show that the measured CA varied continuously with the variations of the surface tension of the liquid and the solid phase, respectively. A general interpretation of the results is possible by using the concept of the Equation of State Approach.     

Modeling finger development and persistence in initially dry porous media

The mechanism for the growth and persistence of gravity-driven fingered flow of water in initially dry porous media is described. A Galerkin finite element solution of the two-dimensional Richards equation with the associated parameter equations for capillary hysteresis in the water retention function is presented. A scheme for upstream weighting of internodal unsaturated hydraulic conductivities is applied to limit smearing of steep wetting fronts. The growth and persistence of a single finger in an initially dry porous media is simulated using this numerical solution scheme. To adequately simulate fingered flow, it was found that the upstream weighting factor had to be negative, meaning that the internodal unsaturated hydraulic conductivities were weighted more by the downstream node. It is shown that the growth and persistence of a finger is sensitive to the character of the porous media water retention functions. For porous media where the water-entry capillary pressure on the main wetting function is less than the air-entry capillary pressure on the main drainage function, a small perturbation will grow into a finger, and during sequential drainage and wetting the finger will persist. In contrast, for porous media where the water-entry capillary pressure on the main wetting function is greater than the air-entry capillary pressure on the main drainage function, the same small perturbation will dissipate by capillary diffusion. The finger widths derived from the numerical simulation are similar to those predicted by analytical theory.     

Change of soil hydrological properties of fens as a result of soil development

This study deals with the change and evaluation of hydrological properties of peat soils (Histosols) in the course of soil development. Ash content, volumetric water content, and dry bulk density, unsaturated hydraulic conductivity, water retention function, and wetting properties were measured for 84 fen sites in 19 fen regions of North‐Eastern Germany. Soil development resulted in porosity decrease. On the contrary, the macropore space and the capillary rise increased. With the start of consolidation processes and the development of segregation structure, a'noticeable reduction of the macropores and unsaturated hydraulic conductivity were observed. In course of soil development and decreasing of aggregate size, these processes reversed. Both parameters increased from segregation structure horizon to earthyfied fen and weak moorshyfied fen horizon, until they partly exceeded the starting values of pedogenetic almost unchanged fen in strongly moorshyfied stadium. Differences in wetting properties of peat could not be explained by the changes of peat properties in the course of soil development.     

Simulation of water retention and hydraulic conductivity in soil using a three‐dimensional network

The conduction of water by soil is fundamental to the way in which soils transport nutrients and pollutants into groundwater. The derivation of relations between water flow and void structure has relied on the implicit assumption that water flows through aligned unconnected cylindrical capillary tubes. We describe a three‐dimensionally interconnected model of void structure, called Pore‐Cor, which simulates the intrusion of a non‐wetting fluid and drainage of a wetting fluid. The model is calibrated by fitting it to the water retention curves of a sandy soil at four depths. The experimental drainage pressures are related to the radii of the entries to the voids by the Laplace equation. The necessities of using this equation, and of employing a simplified void geometry, introduce major approximations into the modelling. Nevertheless, the model is sufficiently precise and versatile to predict trends in other properties usefully. It is illustrated in this work by a close correlation between a predicted and experimental change in saturated hydraulic conductivity with depth, and a realistic unsaturated hydraulic conductivity curve. The saturated and unsaturated hydraulic values are shown to be much more realistic than those predicted by the aligned cylinders model. In addition, the simulations by Pore‐Cor indicate that the void network within the sandy soil is acting in a structured rather than a random manner. The Pore‐Cor model is currently being used to explain the matrix‐flow characteristics of tracers and pollutants.     

Soil physical properties of subsoils contaminated with light nonaqueous phase liquids (lNAPLs)

At 4 sub‐sites of a loess‐derived site, contaminated with light nonaqueous phase liquids (lNAPLs), in Thuringia (Central Germany) undisturbed core samples were obtained from depths down to almost 9 m for determining water retention characteristics. Due to bulk densities of 1.46—1.87 g cm^—3 and high water retention (˜ 19—24 % b.v.) at 15000 hPa the resulting water retention curves are relatively flat. This finding means that there exists only a small portion of pore volume participating in water transport. As known from literature, however, contaminants like lNAPLs decrease the surface tension of soil water or soil solution, resulting in that the soil solution is retained in pores of smaller size at the same matric potential as compared to pure or lNAPL‐free water. This fact must have consequences for the water regime of soils or soil material affected by organic contaminants like lNAPLs because of the changed water retention properties control deep percolation as well as capillary rise.     

An improved simulation of void structure, water retention and hydraulic conductivity in soil with the Pore-Cor three-dimensional network

We present a new method of characterizing the void structures of soils from water retention curves as the primary source of data. The method avoids the problems of other current approaches, which use smoothing curves and can miss the subtleties of soil structure, and usually ignore the shielding of large pores by the small connecting throats surrounding them. In the new method, software we have named ‘Pore‐Cor’ is used to generate simple three‐dimensional networks of voids that have the same water retention characteristics and porosities as the soils. To find the geometry of the required networks, we have introduced a Boltzmann‐annealed simplex which works in four parametric and three Boolean dimensions of parameter space. Also, a more robust measure of the difference between the experimental and simulated water retention curves has been developed. The method is applied to water retention curves for a wide range of English and Welsh soils, both experimental and generated from a pedotransfer function. The resulting simulated void structures have void sizes that change as expected across the soil texture diagram, have different structures as highlighted by the locations of retained water, but have connectivities (number of connecting throats per pore) that vary little. A wide range of other calculations of wetting and non‐wetting fluid transport properties, and calculations of the behaviour of fluid‐borne pollutants, are now possible. The main bar to further progress is a lack of sufficiently accurate and comprehensive data for water retention, and for saturated and unsaturated hydraulic conductivity.     

基于颗粒模型的风积砂层降雨入渗深度计算及验证

为了研究沙漠干旱区降雨对砂层非饱和带水分的贡献,该文对风积砂层水分入渗过程中的水分存在形式和运移机理进行了理论和力学分析。通过以触点水为主要储水单元的立方布局颗粒模型推导出水分入渗过程中湿润深度的解析表达式,并进行验证。物理和力学分析表明,砂颗粒表面很难形成较厚的薄膜水,砂层非饱和带水分大部分以触点水的形式存在。模型计算结果表明,水分入渗的湿润深度与入渗水量和触点水湿润角有关。模型验证表明,水分入渗湿润深度的解析表达式在风积砂层入渗深度计算中具有一定的适用性,但触点水湿润角与砂颗粒粒径的函数关系还有待进一步研究当设定触点水湿润角为π/4时,比例常数为11.5。该研究可为干旱区农业规划提供依据。     

Pore shape and organic compounds drive major changes in the hydrological characteristics of agricultural soils

A small increase in soil organic matter (SOM) content can change soil hydrological properties from a completely wettable to a partially water‐repellent state. Although considerable research describes hydrophobic compounds as a primary driver of this shift, the influence of pore shape has only been considered in a few studies and none of these has emphasized the role of different carbon compounds. Using a capillary bundle model of non‐cylindrical (wavy) capillaries, we described measured hydrological properties of five agricultural soils that have a small degree of water repellency and textures ranging from coarse sand to heavy clay. To isolate the influence of SOM, it was removed by combustion to provide an SOM‐free treatment. Water and methanol sorptivities quantified infiltration rates and soil‐water wetting angles in packed soil cores. Different cores were sectioned to measure wetting profiles and calculate diffusivity. The results from natural soils were supplemented by measurements carried out on model ‘soils’ consisting of quartz particles (50–200 µm) with four different hydrophobic states. Soil organic matter removal increased water sorptivity from about 60% for a coarse sandy soil (Haplic Arenosol) to about 290% for a heavy clay soil (Haplic Leptosol), corresponding to a decreased apparent wetting angle of 20–30°. Application of the wavy pore model suggests that the apparent wetting angle resulting from SOM removal can be several times smaller than its Young value. Generally, SOM removal increased water diffusivity values by one to two orders of magnitudes. The SOM components having the greatest impact on contact angle were hexanedioic acid and heneicosanoic acid (both hydrophilic) and docosane (hydrophobic).     

Modified technique to assess the wettability of soil aggregates: comparison with contact angles measured on crushed aggregates and bulk soil

Wettability parameters determined for individual soils often show a considerable variation depending on the kind of sample (aggregated or homogeneous material) and the method used. To investigate the causes of this variation, we assessed wettability of both intact and crushed aggregates and bulk soil using different methods. Wettability of intact aggregates was characterized by a modified technique where the specific infiltration rates of water and a completely wetting liquid were used to define a repellency index. Contact angles were determined on crushed aggregates and bulk soil using the Wilhelmy plate and capillary rise methods. The repellency index was found to be sensitive to slight differences in wettability and was in good agreement with Wilhelmy plate contact angles. Contact angles measured with the capillary rise method showed a strong deviation from those determined with the Wilhelmy plate method. This can be ascribed to the underlying assumptions of the capillary rise method (i.e. cylindrical and parallel capillaries) resulting in an over‐estimation of contact angle, particularly for the small‐sized particle fraction because of the impact of inertia and pore structure. No significant differences were found between intact and crushed aggregates whereas the bulk soil was slightly more water‐repellent, probably because of a somewhat larger organic carbon content. We conclude that the contact angle determined by the Wilhelmy plate method and the repellency index are appropriate parameters for characterizing soil water repellency because they detected small changes in wettability over a wide range extending from subcritical water repellency to hydrophobicity.     

Bestimmung von Benetzungswinkeln an verschiedenen Korn- und Aggregatfraktionen

Determination of wetting angles on different particle and aggregate size fractions With investigations of water tension, capillary rise and infiltration the wetting angles of soil are usually assumed to be zero degrees. This assumption however is very often not valid. The estimation of wetting angles in soils of different grain-size distribution must take into account the interaction of grain-sizes with pore sizes. Therefore a correcting factor was worked out using 12 separated grain fractions. This factor effectively eliminated the influence of grain-size distribution when applied to fractions in the range between 2000 and 35 μm at angles between 0 and ?90°. Some examples of results are given.     

室内基于土壤水分再分布过程推求紫色土导水参数

选择三峡库区3种不同质地的紫色土,室内通过土壤水分再分布试验,探讨基于土壤水分再分布过程推求导水参数对于紫色土的适用性.结果显示,结合土壤水分垂直和水平再分布过程推求的紫色土水分扩散率与实测值具有很好的一致性,但推求的非饱和导水率偏差较大.然而,选用单一的土壤水分再分布过程结合实测水分特征曲线推求的紫色土非饱和导水率与实测值具有良好的一致性.湿润锋湿度与湿润剖面平均湿度不同函数关系对推求非饱和导水率和水分扩散率差异不明显.此外,基于土壤水分再分布过程推求导水参数方法比较适合低湿土壤的非饱和导水参数推求.     

Soil Water Retention at Varying Matric Potentials following Repeated Wetting with Modestly Saline‐Sodic Water and Subsequent Air Drying

Abstract

Coal bed natural gas (CBNG) development in the Powder River (PR) Basin produces modestly saline, highly sodic wastewater. This study assessed impacts of wetting four textural groups [0–11%, 12–22%, 23–33%, and >33% clay [(g clay/100 g soil)×100%)] with simulated PR or CBNG water on water retention. Soils received the following treatments with each water quality: a single wetting event, five wetting and drying events, or five wetting and drying events followed by leaching with salt‐free water. Treated samples were then resaturated with the final treatment water and equilibrated to ?10, ?33, ?100, ?500, or ?1,500 kPa. At all potentials, soil water retention increased significantly with increasing clay content. Drought‐prone soils lost water‐holding capacity between saturation and field capacity with repeated wetting and drying, whereas finer textured soils withstood this treatment better and had increased water‐retention capacity at lower matric potentials.     

Effect of extraction techniques on soil pore‐water chemistry

Abstract

The retention of contaminants in soil and overburden is often estimated using a solid/liquid partition coefficient, Kd, which lumps all the processes into an empirical value. Determination of this value in unsaturated porous media requires the separation of the pore water from the solid phase. Soil pore‐water recovery and composition were investigated in three chemically and texturally different mineral soils and one organic soil. The removal of pore water was achieved through centrifugation at low (1000 to 2500 rpm) and ultra (10,000 to 20,000 rpm) speeds, ceramic plate extraction and immiscible displacement. Pore‐water recovery was highest using ceramic plate extraction and lowest with displacement. Pore‐water quality was not affected by centrifugation time. However, the pore‐water concentrations of F, Cl, NO₃, Fe, and Na suggest that the effect of centrifuge speed on the element or ion of interest should be determined prior to extraction. Ceramic plates retained both cations and anions, and the immiscible displacent depressed the pH of the soil slurry affecting the pore‐water composition. Comparisons between distilled water extracts, standardized to field capacity moisture, and the centrifugate for a sand and an organic soil indicated that with low solid/liquid ratios, pore‐water concentrations are influenced by dissolution or desorption. Therefore, Kd values based on centrifuged pore water will be lower than those based on extraction/ desorption.     

Do surface active substances from water repellent soils aid wetting?

Soil water repellency is usually unstable, as exemplified by the common method of quantifying repellency degree – the water drop penetration time (WDPT) test. Dynamic penetration and infiltration of water into repellent soils is generally attributed to either reduction of the solid‐liquid interfacial energy (γ_SL) or reduction of the liquid‐vapour interfacial energy (γ_LV), or both. The reduction of γ_SL can result from conformation changes, hydration, or rearrangement of organic molecules coating soil particle surfaces as a result of contact with water, while the reduction of γ_LV can result from dissolution of soil‐borne surface active organic compounds into the water drop. The purpose of this study was to explicitly test the role of the second mechanism in dynamic wetting processes in unstably repellent soils, by examining the drop penetration time (DPT) of water extracts from repellent soils obtained after varying extraction times and at different soil : water ratios. It was indeed found that soil extracts had lower surface tensions (γ_LV approx. 51–54 mN m⁻¹) than distilled water. However, DPT of the soil extracts in water repellent soils was generally the same or greater than that of water. Salt solutions with the same electrical conductivity and monovalent/divalent cation ratio as the soil extracts, but lacking surface active organic substances, had the same DPT as did the extracts. In contrast, DPT of ethanol solutions prepared with the same γ_LV, electrical conductivity, and monovalent/divalent cation ratio as the soil extracts, was much faster. Ethanol solutions are usually used as an agent to reduce γ_LV and as such, to reduce DPT. It is concluded that the surface‐active, soil‐derived organic substances in aqueous soil extracts do not contribute to wetting dynamics, and as such, this mechanism for explaining kinetics of water penetration into water repellent soils is rejected. It is also concluded that the rapid penetration of ethanol solutions must be due not only to changes in γ_LV, but to also to changes in either or both γ_SL and the solid‐vapour interfacial energy (γ_SV). These results stand in sharp contrast to well‐accepted logical paradigms.     

Influence of municipal waste compost amendment on soil water and evaporation

Abstract

Municipal Waste Compost was added to soils in the glasshouse and field to assess its impact upon soil physical properties. Application was by mulch and incorporation, and the amelioration of temperature, soil water content, unsaturated hydraulic conductivity, and evaporation were investigated. Incorporation in the glasshouse pot experiments increased early season evaporation, while compost applied by either means raised soil temperature. In later stages of drying, the presence of compost reduced the evaporation rate. In the field, compost addition to trials of maize (Zea mays van Melody) improved retention of soil water during a normally wet summer, but not during a very dry summer. Furthermore, soil temperature tended to be reduced by mulching. It is concluded that compost application is beneficial to soil water retention and its subsequent utilization by a crop in conditions of normal rainfall under a temperate climate. Furthermore, it is concluded that the common practice of extrapolating glasshouse‐derived information to field conditions creates serious problems, at least in soil physical experimentation.     

Estimation of comparative water transmission in two pairs of adjacent virgin and cultivated pedons in wisconsin

Hydraulic properties and soil morphology of principal soil horizons of paired virgin and cultivated pedons, each pair with identical soil classifications, were studied at two sites. The capacity of the two cultivated soils to transmit water under saturated conditions was reduced as compared with the virgin soil, whereas this capacity generally increased in unsaturated soil at corresponding moisture tensions. Compacted layers below the Ap had a drying effect on the overlying Ap at a wide range of flow rates, whereas a wetting effect resulted in Al horizons of the virgin pedons at similar flow rates, representing unsaturated flow. Extrapolation for interpretive purposes of hydraulic conductivity data measured in a representative pedon of a mapping unit to pedons in identical mapping units elsewhere has to proceed with care, as differences may be substantial.A rather wide range of physical properties is acceptable in a pedogenic soil unit when broad qualitative soil map interpretations are made. However, specific interpretations require more detailed data, as is illustrated with examples relating to soil suitability for on-site liquid waste disposal.     

Effect of Application of Surfactants on Hydraulic Properties of Soils

This study explores the effect of surfactants, commonly found in detergents, on the hydraulic properties of soils. The soil properties examined included hydraulic conductivity, infiltration characteristics, and effective suction at the wetting front, capillary rise and soil penetrability. Two agricultural soils—a loam and a sandy loam, and three surfactants—one anionic surfactant (Sulphonic) and two non-ionic surfactants (Rexol and Rexonic), were used in the study. Changes in hydraulic properties with the application of surfactants were compared with properties obtained with deionised water (control). The results showed that Sulphonic, the anionic surfactant, had a significant effect on hydraulic properties of both soils. Applications of Sulphonic caused decreases in the capillary rise and penetrability, and an increase in the solid–liquid contact angle, shape factor and sorptivity. Except for a slight decrease in hydraulic conductivity resulting from the application of Rexol, the non-ionic surfactants did not reveal significant impact on the hydraulic characteristics of test soils.