Leachability of Nitrate from Sandy Soil using Waste Amendments

Environmental issues associated with intensive use of nitrogenous fertilizers have generated an interest in alternative management systems. An experiment was conducted to mitigate nitrate leaching from sandy soil using different waste materials such as charcoal, manure, sawdust, wood ash, and control (no amendment). Urea was applied at the rate of 300 kg nitrogen (N) ha^?1. Nitrate was determined during six leaching events. During an incubation experiment, nitrate release was also determined in soil amended with charcoal at the rates of 0, 10, 20, and 40 t ha^?1. Urea was applied at the rates of 0, 100, 200, 400, and 1000 ppm N. Results indicated that urea application increased nitrate (NO₃) concentration in leachate. Soil amendments substantially reduced NO₃ in leachates irrespective of the type of material used. Waste amendments differed for NO₃ leaching as follows: charcoal < wood ash < sawdust < manure. Leaching of NO₃ enhanced up to the fourth leaching event and thereafter reduced significantly. Nitrate retention in soil varied among material in the order of manure > charcoal > wood ash > sawdust. Nitrate accumulation occurred in the lower layer (25–50 cm) of soil column after the leaching process. Application of charcoal retained greater NO₃ level as compared to control soil during an incubation. Enhanced urea applications also enhanced NO₃ release. This experiment suggests that waste material can be viably recycled to mitigate NO₃ concentration in water.     

Nitrate leaching from reseeded pasture

Abstract. Nitrate leaching and soil mineral N status under grassland were measured on three contrasting soils, spanning winters 1995/96, 1996/97 and 1997/98, in Western England. The soils investigated were a freely draining silty clay loam (Rosemaund), a well drained loam (IGER 1) and a poorly drained clay loam (IGER 2). The effects of reseeding (ploughing and resowing grass) at IGER 1 and IGER 2 in autumn 1995 or 1996 were compared with undisturbed pasture. Reseeding at Rosemaund, in autumns 1995 or 1996, or spring 1996 was compared with undisturbed pasture of 3 sward ages (2, 5, >50 years).
Nitrate-N leaching losses during the winter immediately following autumn reseeding ranged between 60 and 350 kg N ha^–1 in 1995/96, depending on soil type, sward management history and rainfall. Losses were much less in the following winter when treatments were repeated (10–107 kg N ha^–1).
Reseeding in spring had little effect on soil mineral N content or leaching losses in the following autumn, compared with undisturbed pasture. Similarly, leaching losses from autumn reseeds in the second winter after cultivation were the same as undisturbed pasture (1-19 kg N ha^–1). The effect of ploughing grassland for reseeding was relatively short-term, in contrast to the effect of repeated annual cultivation associated with arable rotations.     

夏季休闲期不同年限日光温室土壤硝态氮淋溶状况

连续2 a（2006和2007年）研究了夏季休闲前后陕西杨凌示范区13个日光温室0～200 cm土壤剖面氮素的动态变化,以评价夏季休闲期间日光温室栽培下土壤累积硝态氮的淋溶情况。结果表明：日光温室蔬菜收获后不同年限温室0～200 cm土壤剖面累积了大量的硝态氮,2006和2007年不同年限日光温室土壤剖面硝态氮的平均残留量分别为 667.6和781.8 kg/hm2。休闲近2个月后,休闲期间降雨量低的2006年（65 mm）不同温室土壤硝态氮含量及电导率与休闲前相比明显增加;而降雨量高的2007年（214 mm）,土壤剖面残留的硝态氮及电导率显著降低,说明发生硝态氮的淋溶,13个日光温室0～200 cm 土壤剖面硝态氮较夏季休闲前降低量在223.8～658.0 kg/hm2之间,平均为298.5 kg/hm2。不同年限日光温室0～200 cm 土壤剖面硝态氮降低量相比,1998年温室＞2004年温室＞2002年温室,其中1998年的温室土壤剖面硝态氮降低量平均达355.1 kg/hm2。可见,夏季休闲期间的降雨量是影响日光温室栽培土壤累积大量硝态氮发生淋溶损失的主要因素。     

华北平原水浇玉米-小麦轮作农田硝态氮的淋失

Soil water deep drainage and nitrate (NO3^-) leaching losses below the root zone were investigated in a 1 ha wheatmaize rotation field under traditional agricultural management that local farmers generally follow in the North China Plain, using the soil water balance method and NO3-N concentration in suction samples. Water drainage, and NO3-N distribution and leaching losses exhibited pronounced spatial and temporal variability. Soil water deep drainage and NO3- N leaching loss mostly occurred during the summer maize growing season (rainy season), which coincided with irrigations and significant rainfall. On average, soil water deep drainage was 39 and 90 mm in the 1998/1999 and 1999/2000 cropping years, correspondingly, accounting for 10% and 19% of the total irrigation plus rainfall, respectively. The NO3-N leaching loss from soil and fertilizer N below the root zone ranged from 6 to 17 (averaging 12) and 30 to 84 (averaging 61) kg N ha^-1 in 1998/1999 and 1999/2000, correspondingly, equivalent to 1.4%-4.1% and 7.3%-20.3% of N fertilizer applied,respectively. The results indicated that water and fertilizer inputs could be greatly reduced, thus improving water and nutrient use efficiency in this region.     

Nitrogen fertilization and nitrate leaching into groundwater on arable sandy soils

Nitrate leaching depending on N fertilization and different crop rotations was studied at two sites with sandy soils in N Germany between 1995 and 2000. The leaching of NO was calculated by using a numerical soil‐water and N model and regularly measured N_min values as input data. Also the variability of N_min values on the sandy soils was determined along transects. They reveal the high variability of the N_min values and show that it is not possible to confirm a significant N_min difference between fertilizer treatments using the normal N_min‐sampling intensity. Nitrate‐leaching calculations of five leaching periods showed that even strongly reduced N‐fertilizer applications did not result in a substantially lower NO leaching into the groundwater. Strong yield reductions of even more than 50%, however, were immediately measured. Mean NO concentrations in the groundwater recharge are >50 mg L^–1 and are mainly due to mineralization from soil organic matter. Obviously, the adjustment of the N cycle in the soil to a new equilibrium and a reduced NO ‐leaching rate as a consequence of lower N inputs need a much longer time span. Catch crops are the most efficient way to reduce the NO concentrations in the groundwater recharge of sandy soils. Their success, however, strongly depends on the site‐specific development possibilities of the catch crop. Even with all possible measures implemented, it will be almost impossible to reach NO concentrations <50 mg L^–1 in sandy soils. The only way to realize this goal on a regional scale could be by increasing areas with lower nitrate concentrations in the groundwater recharge like grassland and forests.     

Nitrate leaching following autumn and winter application of animal manures to grassland

Abstract. Under a UK Government consultation procedure announced in 2001, it was proposed that measures agreed within already designated Nitrate Vulnerable Zones (NVZ 's) would be extended to include a considerably increased area of England, Wales and Scotland. Since existing NVZ 's in the UK have included relatively little grassland, it is important to examine how nitrate losses from grassland areas, especially from animal manures, one of the major potential sources of nitrate loss, can be minimized. Experiments were carried out on freely draining grassland soils at four sites (Devon, Hampshire, Shropshire and N Yorkshire) representative of a wide range of climatic and farming conditions across lowland England, over a four year period, 1990/91 to 1993/94. Slurry was applied to experimental plots over a range of times (including June and then monthly, from September to January) at a target rate of 200 kg N ha^–1. Nitrogen leaching over the four years ranged from 0 to >50% of applied slurry N, with the largest losses occurring following applications in the September to November period. The use of a nitrification inhibitor with slurry applied in November failed to provide consistent reduction in nitrate leaching.
A strategy to reduce the risk of N leaching from manures applied to freely draining grassland soils must take account of the characteristics of the manure, in particular its N content, the application rate and the amount of excess rainfall following application. The experimental results suggest that slurry applications to freely draining grassland, in September, October and November should generally be avoided, the rationale for this being dependent on the amount of excess rainfall subsequent to application. Farmyard manure represents a lower risk and does not justify the restrictions on application timing that appear to be necessary with slurry.     

Nitrate leaching from organic arable crop rotations: effects of location, manure and catch crop

Abstract. Nitrate leaching from crop rotations supporting organic grain production was investigated from 1997 to 2000 in a field experiment at three locations in Denmark on different soil types. Three experimental factors were included in the experiment in a factorial design: (1) proportion of N₂-fixing crops in the rotation (crop rotation), (2) catch crop (with and without), and (3) manure (with and without). Three, four-course rotations were compared, two at each location. The nitrate leaching was measured using ceramic suction cells. Leaching losses from the crop rotation with grass–clover green manure and without catch crops were 104, 54 and 35 kg N ha⁻¹ yr⁻¹ on the coarse sand, the loamy sand, and the sandy loam, respectively. There was no effect of manure application or time of ploughing-in the grass–clover green manure crop on the accumulated nitrate leaching from the entire rotation. Catch crops reduced nitrate leaching significantly, by 30–38%, on the sandy soils. At all locations catch crops reduced the annual averaged nitrate concentration to meet drinking water quality standards in the crop rotation with green manure. On the coarse sand there was a time lag between the onset of drainage and the start of N-uptake by the catch crop.     

Nitrate leaching from a small catchment in central England

Abstract. Flow and nitrate concentrations were measured weekly for four years at twelve stream-water monitoring sites in a catchment in the English Midlands designated as a Nitrate Advisory Area. Farm surveys and satellite images have provided soil and land use information. Measurements show the nitrate load to be dominated by discharge, with large variability due to differing weather conditions from year to year. Within-year variability in nitrate concentrations is also related to weather conditions, with high concentrations when field capacity is reached if this occurs late in the year. There is also clear evidence of dilution of nitrate during intense storms. The effect of changing weather conditions makes it impossible to identify catchment-scale changes in leaching due to changes in agricultural practice over a period as short as four years. Measurements from a major spring in the catchment show an increasing trend in nitrate concentrations through the period. There is some evidence that the greatest N leaching to streams in the catchment is associated with intensive grassland on soils which are naturally poorly drained.     

重庆市主要土壤类型硝态氮淋失及其影响因素

采用SRC(Soil-Resin-Core)装置,研究了重庆市主要土壤类型硝态氮淋失的差异以及硝态氮淋失与硝态氮含量、有效氮含量、降雨和气温等4个方面的关系。结果表明:酸性紫色土的硝态氮淋失量最大,而黄壤与碱性紫色土的硝态氮淋失量较小。酸性紫色土硝态氮含量、有效氮含量与硝态氮淋失量之间显著相关,而黄壤和碱性紫色土的硝态氮含量、有效氮含量与硝态氮淋失量之间没有显著的相关性。降雨量、气温也是引起硝态氮淋失的原因。农田施肥对地下水的污染受施肥量、施肥次数、降雨量和气温等综合作用的影响,可采取控制氮肥用量,减少施用人粪尿,避免在降雨量大的时期追肥的措施。     

施用羊粪条件下人工草地土壤硝态氮淋失量研究

采用SRC（Soil-Resin-Core）装置，研究了三峡库区草畜配套体系中羊粪还田量与硝态氮淋失量的关系。研究结果表明，有机肥本身即可产生硝态氮在土壤中的累积，羊粪施肥量越高，土壤硝态氮累积量和全氮含量就越高。随着施肥次数的增加，全氮含量整体呈上升趋势，硝态氮含量因降雨、气温和牧草生长等因素的影响，存在明显的季节性。元月份土壤中的硝态氮含量显著高于其它季节。相关分析表明：土壤全氮和硝态氮含量影响20cm土层中硝态氮的淋失量，三者之间呈显著正相关关系；施肥提高了人工草地的产草量，但施肥量过高，草地产量下降，增加了氮素损失的可能性。在一定的产草量下，人工草地可容纳的羊粪量高于单位土地面积承载羊只所产生的羊粪量。说明在三峡库区发展集约化的种草养羊业，羊粪直接还田，从资源环境的角度分析是可行的。     

Nitrate leaching and residual soil nitrogen supply following outdoor pig farming

Abstract. Large nitrogen (N) inputs to outdoor pig farms in the UK can lead to high nitrate leaching losses and accumulation of surplus N in soil. We investigated the residual effects of three contrasting outdoor pig systems as compared to an arable control on nitrate leaching and soil N supply for subsequent spring cereal crops grown on a sandy loam soil during 1997/98 and 1998/99 harvest seasons. Previously, the pig systems had been stocked for 2 years from October 1995 and were designated current commercial practice (CCP, 25 sows ha^?1 on stubble), improved management practice (IMP, 18 sows ha^?1 on undersown stubble) and best management practice (BMP, 12 sows ha^?1 on established grass). Estimated soil N surpluses by the end of stocking in September 1997 were 576, 398, 265 and 27 kg ha^?1 N for the CCP, IMP, BMP and continuous arable control, respectively. Nitrate leaching losses in the first winter were 235, 198, 137 and 38 kg ha^?1 N from the former CCP, IMP and BMP systems and the arable control, respectively. These losses from the former pig systems were equivalent to 41–52% of the estimated soil N surpluses. Leaching losses were much smaller in the second winter at 21, 14, 23 and 19 kg ha^?1 N, respectively. Cultivation timing had no effect (P>0.05) on leaching losses in year 1, but cultivation in October compared with December increased nitrate leaching by a mean of 14 kg ha^?1 N across all treatments in year 2. Leaching losses over the two winters were correlated (P<0.001) with autumn soil mineral N (SMN) contents. In both seasons, spring SMN, grain yields and N offtakes at harvest were similar (P>0.05) for the three previous pig systems and the arable control, and cultivation timing had no effect (P>0.05) on grain yields and crop N offtake. This systems study has shown that nitrate leaching losses during the first winter after outdoor pig farming can be large, with no residual available N benefits to following cereal crops unless that first winter is much drier than average.     

Changes in N leaching and crop production as a result of measures to reduce N losses to water in a 6‐yr crop rotation

The effects of various measures introduced to increase nitrogen (N)‐use efficiency and reduce N losses to water in a 6‐yr crop rotation (winter wheat, spring barley, green manure, winter wheat, spring barley, spring oilseed rape) were examined with respect to N leaching, soil mineral N (SMN) accumulation and grain yield. An N‐use efficient system (NUE) with delayed tillage until late autumn and spring, direct drilling of winter wheat, earlier sowing of winter and spring crops and use of a catch crop in winter wheat was compared with a conventional system (CON) in a field experiment with six separately tile‐drained plots in south‐western Sweden during the period 1999–2011 (two crop rotation cycles). Total leaching of NO₃‐N from the NUE system was significantly 46 and 33% lower than in the CON system during the first and second crop rotation cycle, respectively, with the most pronounced differences apparently related to management strategies for winter wheat. Differences in NO₃‐N leaching largely reflected differences in SMN during autumn and winter. There was a tendency for lower yields in the NUE system, probably due to problems with couch grass. Overall, the measures for conserving N, when frequently used within a crop rotation, effectively reduced NO₃ concentrations in drainage water and NO₃‐N leaching losses, without severely affecting yield.     

Nitrate leaching loss following application of organic manures to sandy soils in arable cropping.

Abstract. Experiments were set up at two sites to measure nitrogen (N) leaching loss from applications of separated pig/cattle slurry and cattle farmyard manure(FYM), during winters 1990/91–1993/94 (site A) and from broiler litter and FYM, during winters 1990/91–1992/93 (site B). The manures were applied at a target rate of 200 kg ha^-1 total N during the autumn and winter to overwinter fallow or top dressed onto winter rye. The total N in leachate was calculated from leachate N concentrations, in samples collected using ceramic cups buried at 90 cm, and an estimate of drainage volume. Nitrogen losses were greatest following manure applications in September, October and November but losses following applications in December or January were not significantly elevated above those from untreated controls. Losses were consistently lower from FYM than from broiler litter or separated slurry. The presence of a cover crop (winter rye) significantly reduced overall N leaching compared with the fallow, but only reduced the manure N leaching losses at one site during one winter when a high proportion of drainage occurred late. The incorporation of a nitrification inhibitor (DCD) with manures applied in October did not significantly reduce the manure N leaching.     

Nitrate leaching from organic farms and conventional farms following best practice

Abstract. This paper compares nitrate leaching losses from organic farms, which depended on legumes for their nitrogen inputs (66 site years) with those from conventional farms using fertilizers under similar cropping and climatic conditions (188 site years). The conventional farms were within Nitrate Sensitive Areas in England, but sites following special practices associated with that scheme were excluded. Nitrate losses during the organic ley phase (including the winter of ploughing out) were similar (45 kg N ha^–1) to those from conventional long-term grass receiving fertilizer N inputs of less than 200 kg N ha^–1 (44 kg N ha^–1) and from the grass phase of conventional ley-arable rotations (50 kg N ha^–1). Losses from conventional grass receiving higher N inputs were greater than from organic or less intensive grass. Nitrate losses following arable crops averaged 47 and 58 kg N ha^–1 for the organic and conventional systems respectively, with part of the difference being due to the greater proportion of non-cereal break crops in the latter. Thus under similar cropping, losses from organic systems are similar to or slightly smaller than those from conventional farms following best practice.     

Nitrate leaching in forest soils: an analysis of long‐term monitoring sites in Germany

Elevated atmospheric inputs of NH₄⁺ and NO₃^– have caused N saturation of many forest ecosystems in Central Europe, but the fate of deposited N that is not bounded by trees remains largely unknown. It is expected that an increase of NO₃^– leaching from forest soils may harm the quality of groundwater in many regions. The objective of this study was to analyze the input and output of NH₄⁺ and NO₃^– at 57 sites with mature forest stands in Germany. These long‐term study sites are part of the European Level II program and comprise 17 beech, 14 spruce, 17 pine, and 9 oak stands. The chloride balance method was used to calculate seepage fluxes and inorganic N leaching below the rooting zone for the period from 1996 to 2001. Nitrogen input by throughfall was significantly different among most forest types, and was in the order: spruce > beech/oak > pine. These differences can be largely explained by the amount of precipitation and, thus, it mirrors the regional and climatic distribution of these forest types in Germany. Mean long‐term N output with seepage was log‐normal distributed, and ranged between 0 and 26.5 kg N ha^–1 yr^–1, whereby 29 % of the sites released more than 5 kg N ha^–1 yr ^–1. Leaching of inorganic N was only significantly lower in the pine stands (P < 0.05) compared with leaching rates of the spruce stands. Median N output : input ratio ranged between 0.04 and 0.11 for the beech, oak, and pine stands, while the input : output ratio of the spruce stands was 0.24, suggesting a higher risk of NO₃^– leaching in spruce forests. Following log‐transformation of the data, N input explained 38 % of the variance in N output. The stratification of the data by the C : N ratio of the O horizon or the top mineral soil revealed that forests soils with a C : N ratio < 25 released significantly more NO₃^– (median of 4.6 kg N ha^–1 yr^–1) than forests with a C : N ratio > 25 (median of 0.8 kg N ha^–1 yr^–1). The stratification improved the correlation between N input and N output for sites with C : N ratios < 25 (r² = 0.47) while the correlation for sites with C : N ratios > 25 was weaker (r = 0.21) compared with the complete data set. Our results suggest that NO₃^– leaching may increase in soils with wide C : N ratios when N deposition remains on a high level and that the potential to store inorganic N decreases with C : N ratios in the O horizons becoming more narrow.     

Nitrate leaching from an organic dairy crop rotation: the effects of manure type, nitrogen input and improved crop rotation

Abstract. Four management systems combining high and low livestock densities (0.7 and 1.4 livestock units ha⁻¹) and different types of organic manure (slurry and straw based FYM) were applied to an organic dairy crop rotation (undersown barley – grass–clover – grass–clover – barley/pea – oats – fodder beet) between 1998 and 2001. The effects of the management systems on crop yields and nitrate leaching were measured. In all four years, nitrate leaching, as determined using ceramic suction cups, was higher in the three crops following ploughing of grass–clover than under the barley or grass–clover. Overall, no significant differences in nitrate leaching were observed between the management systems. However, the replacement of the winter wheat crop used in the earlier experimental period (1994–97) by spring oats with catch crops in both the preceding and succeeding winters reduced nitrate leaching compared with the earlier rotation. Increasing the livestock density, which increased manure application by c. 60 kg total N ha⁻¹, increased crop yields by 7 and 9% on average for FYM and slurry, respectively. Yields were 3–5% lower where FYM was used instead of slurry. The experiment confirmed the overriding importance of grassland N management, particularly the cultivation of the ley, in organic dairy crop rotations.     

几种新型氮肥对叶菜硝酸盐累积和土壤硝态氮淋洗的影响

应用土柱模拟试验的方法,研究了在高肥力菜田土壤条件下,施用几种新型氮肥对两茬叶菜硝酸盐积累和土壤硝态氮淋洗的影响。结果表明,在高肥力菜田土壤上,施用几种新型氮肥都未能明显提高第一茬油菜的生物量,硫硝铵（A SN）却降低了生物量,而第二茬菠菜不施肥处理生物量下降。尿素＋硝化抑制剂DM PP（En tec46）、尿素＋硝化抑制剂DCD（U＋DCD）和有机无机复混肥（OIF）3种氮肥显著降低了油菜硝酸盐含量。尿素＋玉米秸秆（U＋M S）和硫硝铵＋硝化抑制剂DM PP（En tec26）减少了土壤NO3^--N的向下淋洗,而尿素＋保水剂（U＋SAP）增加土壤NO3^--N的向下淋洗。