Preparation of Copper Nanoparticles Coated Cotton Fabrics with Durable Antibacterial Properties

When copper nanoparticles (Cu NPs) were applied as an antimicrobial agent to finish cotton fabrics, there are two issues should be solved: the oxidization and the weak adsorbability onto cotton fiber surface. In the present work, we developed a new method that can achieve both immobilization and protection of the Cu NPs at the same time. As an effective binder, thioglycolic acid (TGA) was covalently linked to cotton fiber surface via an esterification with the hydroxyl groups of cellulose, then Cu NPs were introduced on the fabric surface in the presence of a protective reagent, citric acid. Due to the doubled stabilization acts of TGA and citric acid, the Cu NPs immobilized on the fabric surface showed an excellent antibacterial effect and outstanding laundering durability. Even after 50 consecutive laundering tests, the modified cotton fabrics still showed satisfactory antibacterial ability against both S. aureus and E. coli, which the bacterial reduction rates are all higher than 96 %. It is believed that this methodology has potential applications in a wide variety of textile productions such as sportswear, socks, and medical textiles.     

纳米苎麻远红外针织物功能性及服用性能研究

通过对纳米苎麻针织物的远红外发射率、红外照射温升、透气性、湿热传递性、保温性、冷暖感、悬垂性等指标进行测试,并对各指标及其相互间关系进行分析,为苎麻类功能性针织品的开发提供科学依据.     

纳米苎麻远红外针织物功能性及服用性能研究

通过对纳米苎麻针织物的远红外发射率、红外照射温升、透气性、湿热传递性、保温性、冷暖感、悬垂性等指标进行测试，并对各指标及其相互间关系进行分析，为苎麻类功能性针织品的开发提供科学依据。     

The Effects of Fabric and Conductive Wire Properties on Electromagnetic Shielding Effectiveness and Surface Resistivity of Interlock Knitted Fabrics

Our aim in this study was to investigate the effects of course density, yarn linear density and thickness and type of conductive wire on electromagnetic shielding effectiveness. Metal/cotton conductive composite yarns were produced by the core-spun technique on the ring spinning machine, involving stainless steel, copper and silver coated copper wires with 40 μm, 50 μm, 60 μm thicknesses and Ne10/1 and Ne20/1 count yarns. The interlock fabrics were knitted on a 7G flat knitting machine with the three different machine settings. The EMSE and the surface resistivity of knitted fabrics were measured by the co-axial transmission line method according to the ASTM-D4935-10 standard in the frequency range from 15 to 3000 MHz and by the ASTM D257-07 standard, respectively. It was observed that all fabrics shielded around 95 % of electromagnetic waves at low frequencies, 80 % at medium frequencies and 70 % at high frequencies. Increasing the course density and thickness of conductive wire in interlock knitted fabrics increased the EMSE correspondingly. The knitted fabrics that had been produced with high yarn count showed greater EMSE because there was less isolation. The effect of the metal wire type was highly significant between 15 and 600 MHz.     

Superhydrophobic and Antibacterial Properties of Cotton Fabrics Treated with PVDF and nano-ZnO through Phase Inversion Process

Cotton fabrics exhibiting superhydrophobic and antibacterial properties were prepared through a non-solvent induced phase separation method using hydrophobic poly(vinylidene fluoride) (PVDF) and its hybrids with photocatalytic zinc oxide nanoparticles (nano-ZnO) as surface modifying agents for cotton fabric. The effects of coagulating medium and temperature on microstructural morphology and surface hydrophobictity of the cotton fabrics were investigated by FE-SEM observation and contact angle measurement. Superhydrophobic cotton fabrics exhibiting water contact angle higher than 150 ° could be obtained by coating the fabrics with solutions of PVDF and nano-ZnO followed by coagulation in ethanol as non-solvent. This phenomenon is considered to be originated from both chemically hydrophobic PVDF layer and physical micro- and nano-bumps formed on the surface of cotton fabric, which are essential requirements for Lotus effect. Moreover, antibacterial properties could be synergistically obtained by utilizing photocatalytic effect of nano-ZnO.     

Functional Antibacterial Finishing of Woolen Fabrics Using Ultrasound Technology

The growing concern for the personal health and hygiene has created the necessity of acquiring wool fabric antibacterial activity. Silicon dioxide nanoparticles (SiO₂ NPs) have appropriate features to enhance the functional properties of wool fabrics, especially with polymer application. In this study efficient coating using polyethylene glycol (PEG₂₀₀₀) and SiO₂ NPs were used for imparting antibacterial properties to treated fabrics. All the treatments were carried out using both conventional and ultrasound techniques. The physical and chemical properties were evaluated using FTIR, XRD, and SEM. The result indicated that treated wool fabrics by PEG/SiO₂ NPs improved the dyeability and antibacterial of the fabrics and also enhanced its mechanical properties. Furthermore, it is believed that the ultrasound radiation causes homogeneous distribution of cross-links and polymerization throughout the wool surface. This offers considerable advantages compared to conventional treatment.     

麻盖涤吸湿快干针织面料性能及整理工艺研究

以纯苎麻纱和细旦涤纶为原料编织麻盖涤双面针织物;用亲水性硅油、水性聚氨酯、纤维素酶等进行吸湿快干、柔软以及消除刺痒感的整理。结果表明:麻盖涤针织面料的吸湿快干性能比棉盖涤好,通过应用合适的整理剂和整理工艺能有效地解决麻盖涤针织物手感和刺痒感问题。本文还对纯苎麻纱针织织造中断纱爆孔问题提出了解决的措施。     

麻盖涤吸湿快干针织面料性能及整理工艺研究

以纯苎麻纱和细旦涤纶为原料编织麻盖涤双面针织物；用亲水性硅油、水性聚氨酯、纤维紊酶等进行吸湿快干、柔软以及消除刺痒感的整理。结果表明：麻盖涤针织面料的吸湿快干性能比棉盖涤好，通过应用合适的整理剂和整理工艺能有效地解决麻盖涤针织物手感和刺痒感问题。本文还对纯苎麻纱针织织造中断纱爆孔问题提出了解决的措施。     

Effects of Aluminum Deposition on the Functional Properties of the Meta-aramid Fabrics

Meta-aramid fabrics were deposited with aluminum to examine the effects of aluminum deposition on the functional properties of meta-aramid fabrics. Various functional properties of the aluminum deposited meta-aramid fabrics were assessed with sputtering processing parameters such as chamber pressure and sputtering power. SEM-EDX was utilized to investigate surface morphology and compositions of the deposited meta-aramid fabrics. The optical, thermal, electric, and abrasive properties of the deposited meta-aramid fabrics were measured by color reader, KES-F7 thermo-Lab 2 system, milliohm meter, and abrasion testing machine. The obtained results indicated the optical, thermal, electric, and abrasive properties of the deposited meta-aramid fabrics were influenced clearly by deposition processing parameters. The light reflectance, thermal conductivity, electric resistance, and abrasion strength of the aluminum deposited meta-aramid fabrics were shown to be a maximum at a chamber pressure and a sputtering pressure, and the optimum deposit condition could be established.     

Effect of Silver Particle size on color and Antibacterial properties of silk and cotton Fabrics

In this study silver nanoparticles with different particle sizes and hence colors were synthesized on silk and cotton fabrics through reduction of silver nitrate. Particle sizes of the silver colloids were measured by dynamic light scattering (DLS). The structure and properties of the treated fabrics were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and UV-Vis reflectance spectroscopy. Various characteristics of the treated fabrics including antibacterial activities against a Gram positive (Staphylococcus aureus) and a Gram negative (Escherichia coli) bacteria, color effect, wash and light fastness, water absorption, fabric rigidity, and UV blocking properties were also assessed. The results indicated that the treated fabrics displayed different colors in the presence of silver nanoparticles with different particle sizes and exhibited good and durable fastness properties. Also, the size of the silver particles had a tangible effect on antibacterial activity of treated fabrics and its antibacterial performance was improved by decreasing the size of particles. Moreover, this process imparted significantly UV blocking activity to fabric samples.     

Upgrading of UV Protection Properties of Several Textile Fabrics by Their Dyeing with Grape Pomace Colorants

The desire to offer clothes protective properties against the harmful UV rays continues to attract the interest of researchers. Several works have been elaborated in this topic and have proved that the clothes do not protect sufficiently against the solar ultraviolet radiation. Their protectiveness depends on the fiber type, the fabric composition, the fabric construction and the dyeing method. This research presents a novel approach which target the improvement of the textile protective properties against UV rays by their dyeing with grape pomace aqueous extract. These properties were tested in combination with several fabrics (natural and synthetic) and mordants (potassium alum and ferrous sulphate). Through this study, it has been shown that the UV-protective properties of the several dyed fibers were upgraded after dyeing with the grape pomace extract, and is intensely relying on the types of fibers and mordants.     

Preparation and Properties of Antistatic Polyethylene Film Coated Polypropylene Non-woven Fabrics

In this paper, antistatic PE/PP coated non-woven fabrics were prepared by the coating process of the antistatic finished PE films and PP non-woven fabrics using the heat pressing process of the hot melt adhesives. The antistatic finishing of polyethylene (PE) films and polypropylene (PP) non-woven fabrics were processed by one face foam finishing and dip-pad finishing process, respectively. The antistatic properties of PE/PP coated non-woven fabrics which were influenced by the antistatic finishing processes and the thickness of PE films were investigated. The static charges transmission mechanism of these coated non-woven fabrics was illustrated. The results revealed that the static charges were transferred and dissipated by forming the continuous conductive path and network between the film-adhesive and adhesive-fabric due to the hot melt adhesion and squeezing of the antistatic agents existing inside of of the non-woven fabrics matrix and on the film surface. The antistatic properties of coated non-woven fabrics were improved with the increasing of the antistatic agent concentration on the finishing solution. And the antistatic properties of PE films were greatly influenced by the film thickness, the thinner of PE films the much more obvious improvement of the film surface antistatic properties. The finishing process wouldn’t reduce the peeling strength of the coated non-woven fabrics. The antistatic properties of the PE/PP coated non-woven fabrics possessed high washing durability due to the crosslinking fixation effect of the hot melt adhesives which wouldn’t be weakened after several times washing.     

Photooxidation Properties of Photosensitizer/Direct Dye Patterned Polyester/Cotton Fabrics

Towards the goal of developing anti-infective textiles based on a photodynamic inactivation mechanism, here we present the design, dyeing procedure, characterization, substrate photooxidation studies, and antibacterial efficacy of methylene blue-dyed polyester fabrics, termed MB-polyester. Dye-uptake and apparent K/S (absorption and scattering coefficient) values as a function of MB concentration % (o.w.f) were determined, and were found to correlate. Photooxidation studies employing the model substrate 1,5-dihydroxynaphthalene (1,5-DHN) revealed that the MB-polyester fabrics were able to generate singlet oxygen in an illumination time-dependent manner. Antibacterial efficacy was evaluated against Staphylococcus aureus (ATCC-29213), with our best results achieving a 99.89 % (~3 log units) reduction in Colony-Forming Units (CFU)/mL after only 30 min illumination (Xenon lamp, 3500 mW/cm², 420–780 nm). On the basis of these results with MB-polyester, we subsequently designed patterned dual-dyed polyester/cotton fabrics, wherein an alternating pattern of MBdyed polyester was combined with direct dyes-dyed cotton, and showed that their ability to sensitize singlet oxygen (¹O²) in the photooxidation reaction of 1,5-DHN was maintained. Taken together, these findings suggest that MB is a suitable photosensitizer (PS) against S. aureus for the practical development of low-cost polyester-based antimicrobial textiles, and can potentially be used in the production of diverse form-patterned textiles that possess a photodynamic antimicrobial inactivation mechanism.     

One Step Thermochromic Pigment Printing and Ag NPs Antibacterial Functional Finishing of Cotton and Cotton/PET Fabrics

One step thermochromic pigment printing and antibacterial functionality of cotton (100 %) and cotton/polyester blend (50/50 %) were demonstrated in this study. The improvement in antimicrobial activity against G+ve (Bacillus cereus) and G-ve (E. coli), and pigment printability were achieved by inclusion of Ag-NPs (30 g/kg) into pigment printing paste followed by printing and microwave curing at 700 W for 5 min. Modes of interactions were proposed, and surface modification was also confirmed by SEM and EDX analysis that proved the presence of Ag-NPs in cotton and cotton/ polyester blended samples. The results indicated that the colour fastness to wash and rubbing was excellent, the surface roughness reduced, and exhibited good antibacterial activity against Bacillus cereus and E. coli bacteria.     

Study on the Reduction Properties of Thiourea Dioxide and Its Application in Discharge Printing of Polyester Fabrics

The thiourea dioxide (TDO) was tentatively applied as a reductive discharging agent onto the discharge printing of polyester fabrics. The effect of aqueous solution temperature on the reducing capacity of TDO was thoroughly investigated by measuring oxidation-reduction potentials and hydrolysis kinetic curves. The effects of TDO on disperse dyes in aqueous solution and disperse dyes printed on the surfaces of glass substrates or polyester fabrics were investigated by analyzing the color changes before and after TDO discharge treatment. It was confirmed that TDO reduction became stronger with increasing aqueous solution temperature. TDO could destroy the chromogenic groups of the selected azo-dyes in aqueous solution and on the surfaces of glass substrates. Different from cotton and silk fabrics, the discharge effect of TDO directly depended on the compact structure of the polyester fibers. When a discharge accelerant was added into white discharge pastes with TDO, the compact structure of polyester fibers was opened up to achieve a good discharge effect. This study provides a new method for TDO development and a new strategy for the discharge printing of polyester fabrics.     

Polyvinylpyrrolidone/Carbon Nanotube/Cotton Functional Nanocomposite: Preparation and Characterization of Properties

In the last decade, preparation of multifunctional composites have attracted researchers around the World for multi-purpose application. In this regard, we produced polyvinylpyrrolidone/carbon nanotubes/cotton (PVP/CNTs/cotton) nanocomposite by coating cotton fabric via pad-dry-cure under UV irradiation. Several characterization methods were used to investigate the functionality and durability including scanning electron microscopy, thermo-gravimetric analysis, flammability test, reflectance spectroscopy, tensile strength test, water absorption and antibacterial analysis. The interactions among PVP molecular chains, CNT particles and cellulose were confirmed by Raman spectroscopy. We observed a uniform coating of PVP/CNTs on the fiber surface. An advantage of our developed method was the strong interfacial interaction among compositions, high durability along with multifunctional properties. PVP/CNT nanocomposite was able not only to improve the thermal stability of cotton, but also provided a reduced flammability and good antibacterial properties. Here, we confirm a simple and versatile method for fabrication of PVP/CNTs/cellulose nanocomposite for multi-purpose applications.     

Investigation on the Biodegradability and Antibacterial Properties of Nanohybrid Suture Based on Silver Incorporated PGA-PLGA Nanofibers

Polyglycolic acid-poly lactic glycolic acid (PGA-PLGA) electrospun nanofibers containing silver nanoparticles have been produced and twisted into the nanofibrous yarn. The morphology of nanofibers and produced yarns, as well as the mechanical properties of the yarns, were investigated. Furthermore, in vitro antibacterial properties and in vitro degradation behavior of yarns containing various silver nanoparticles were studied. SEM images confirmed that the addition of the silver nanoparticles into the polymer solution increases the fiber diameters. The result of the mechanical test of the yarns alone and used in two different forms of the knots was measured and results showed that the strength of the yarns without the knot was significantly more than that of others. The biodegradability test showed that the mechanical properties and the weight of the yarns were quickly reduced after subjecting to in vitro condition. The result of the antibacterial test indicated that the nanofiber yarns containing %3 silver nanoparticles were the most appropriate sample with a considerably antibacterial activity against both gram-positive bacterium Staphylococcus aureus and gram-negative bacterium Escherichia Coli with inhibition zones of 8.1 and 9.5 mm, respectively; which demonstrated that silver nanoparticles retained their effectiveness after the electrospinning process. Therefore the nanofibrous yarns containing silver nanoparticles could be successfully produced by the electrospinning process with the proper antibacterial property as a candidate for the surgical sutures.     

大麻织物的抗紫外线性能评价

测试了不同厚度、不同覆盖系数、不同组织结构和颜色的大麻织物紫外线透过率和抗紫外指数(UPF值),分析了厚度、覆盖系数、组织结构和颜色对大麻织物的抗紫外线性能的影响,指出大麻织物越厚,其紫外线透过率越小,UPF值愈大;覆盖系数增加,紫外线透过率减小,UPF值随之增大;在厚度和覆盖系数相同时,缎纹组织大麻织物的抗紫外线性能最好,斜纹组织大麻织物次之,平纹组织大麻织物再次之.深色大麻织物的抗紫外线性能好,浅色的较差.随着大麻织物颜色饱和度增加,其紫外线透过率相应减小,UPF值相应增加,抗紫外线性能越好.     

大麻织物的抗紫外线性能评价

测试了不同厚度、不同覆盖系数、不同组织结构和颜色的大麻织物紫外线透过率和抗紫外指数（UPF值），分析了厚度、覆盖系数、组织结构和颜色对大麻织物的抗紫外线性能的影响，指出大麻织物越厚，其紫外线透过率越小，UPF值愈大；覆盖系数增加，紫外线透过率减小，UPF值随之增大；在厚度和覆盖系数相同时，缎纹组织大麻织物的抗紫外线性能最好，斜纹组织大麻织物次之，平纹组织大麻织物再次之。深色大麻织物的抗紫外线性能好，浅色的较差。随着大麻织物颜色饱和度增加，其紫外线透过率相应减小，UPF值相应增加，抗紫外线性能越好。     

Flame-Retardant and Wear Comfort Properties of Modacrylic/FR-Rayon/Anti-static PET Blend Yarns and Their Woven Fabrics for Clothing

This study examined the flame retardant, anti-static, and wear comfort properties of woven fabrics from two types of yarns composed of modacrylic, FR-rayon, cotton, and anti-static PET fibers. The FR-rayon-blended modacrylic fabric mixed with anti-static PET fibers exhibited better flame-retardant and anti-static properties than those of the cotton-blended modacrylic fabric. In addition, the absorption and drying properties of the FR-rayon-blended modacrylic fabric were superior to those of the cotton-blended modacrylic fabric. The thermal conductivity of the FR-rayon-blended fabric was lower than that of the cotton-blended one, whereas the water vapor permeability was slightly higher than that of the cotton-blended one. These wear comfort properties of the FR-rayon-blended fabric were attributed to the micro-pores and longer fiber length of the FR-rayon fibers, as well as their yarn and fabric structural parameters. This study suggests that FR-rayon-blended modacrylic fabric has better flame-retardant and anti-static properties in both twill and rip weaves with good warmth keepability, and higher water and vapor transmission properties than cotton-blended one. In addition, the FR-rayon-blended modacrylic clothing exhibited a better wear comfort feel than the cotton-blended one due to the lower microclimate humidity. This means that FR-rayon-blended modacrylic fabric makes it more comfortable to wear than cotton-blended one.