The oceans: growth and oxygen isotope evolution

A study of the evolution of the oxygen-18/oxygen-16 ratio of the oceans suggests that this ratio is unlikely to have remained constant with time. Our models suiggest that early formation of the oceans is more likely than linear growth.     

Osmium isotope evidence for an s-process carrier in primitive chondrites

Osmium extracted from unequilibrated bulk chondrites has isotope anomalies consistent with an insoluble s-process carrier, termed Os(i) here. Osmium from metamorphosed bulk chondrites does not have isotope anomalies, implying that the Os(i) carrier was destroyed by metamorphism. The isotopic homogeneity of metamorphosed bulk chondrites is consistent with extremely effective mixing of presolar grains from varied sources in the nebula. Osmium in the Os(i) carrier is likely from nucleosynthetic sites with a neutron density about two to four times as high as that of the average solar s-process Os.     

Neodymium isotope evidence for a chondritic composition of the Moon

Samarium-neodymium isotope data for six lunar basalts show that the bulk Moon has a 142Nd/144Nd ratio that is indistinguishable from that of chondritic meteorites but is 20 parts per million less than most samples from Earth. The Sm/Nd formation interval of the lunar mantle from these data is 215(-21)(+23) million years after the onset of solar system condensation. Because both Earth and the Moon likely formed in the same region of the solar nebula, Earth should also have a chondritic bulk composition. In order to mass balance the Nd budget, these constraints require that a complementary reservoir with a lower 142Nd/144Nd value resides in Earth's mantle.     

Neodymium and strontium isotope evidence for crustal contamination of continental volcanics

Combined neodymium and strontium isotope studies on Tertiary volcanics from northwest Scotland indicate that their parental mantle isotopic compositions have been substantially modified in many instances by contamination with the Precambrian continental crust through which they were erupted. The occurrence of samarium-neodymium and rubidium-strontium "pseudoisochrons" of different ages in these contaminated continental volcanics indicates that they are artifacts of the contamination processes and have no temporal significance with respect to mantle fractionation events.     

Soil carbon isotope evidence for holocene habitat change in the kenya rift valley

In eastern Africa the altitude of the boundary between montane forest and lowland savanna grassland changed substantially in response to climate change during the later Holocene, but this is not clearly reflected in regional pollen records. The carbon-13 to carbon-12 ratios of tropical grasses are higher than those of most other plants, and this difference is preserved in soil organic carbon stable isotope ratios. Soil organic matter (13)C/(12)C ratios in profiles along an altitude transect in the central Rift Valley of Kenya suggest that the forest-savanna boundary advanced more than 300 meters in altitude. This could have implications for understanding the effects of climate change on the configuration of floral zones, prehistoric hunter-gatherer land-use patterns, and the timing of the advent of Neolithic food production.     

Possible ancient oceans on Mars: evidence from Mars Orbiter Laser Altimeter data

High-resolution altimetric data define the detailed topography of the northern lowlands of Mars, and a range of data is consistent with the hypothesis that a lowland-encircling geologic contact represents the ancient shoreline of a large standing body of water present in middle Mars history. The contact altitude is close to an equipotential line, the topography is smoother at all scales below the contact than above it, the volume enclosed by this contact is within the range of estimates of available water on Mars, and a series of extensive terraces parallel the contact in many places.     

Silicon isotope evidence against an enstatite chondrite Earth

The compositions of Earth materials are strikingly similar to those of enstatite chondrite meteorites in many isotope systems. Although this suggests that Earth largely accreted from enstatite chondrites, definitive proof of this model has been lacking. By comparing the silicon (Si) isotope signatures of several extraterrestrial materials with terrestrial samples, we show that they cannot be explained by core-formation scenarios involving a bulk Earth of enstatite chondrite composition. Si isotope similarities between the bulk silicate Earth and the Moon preclude the existence of a hidden reservoir in the lower mantle, a necessary condition of the enstatite chondrite model, and require an equilibrium process after the Moon-forming impact. A three-end-member chondritic mixing model for Earth reconciles the Si isotope similarities between enstatite chondrites and Earth.     

Large groundwater strontium flux to the oceans from the Bengal Basin and the marine strontium isotope record

Strontium concentration and isotopic data for subsurface flowing groundwaters of the Ganges-Brahmaputra (G-B) delta in the Bengal Basin demonstrate that this is a potentially significant source of strontium to the oceans, equal in magnitude to the dissolved strontium concentration carried to the oceans by the G-B river waters. The strontium concentrations of groundwaters are higher by a factor of about 10 than typical G-B river waters and they have similar 87Sr/86Sr ratio to the river waters. These new data suggest that the present contribution of the G-B system to the rise in 87Sr/86Sr ratio in seawater is higher by at least a factor of 2 to 5 than the average over the past 40 million years.     

Sr-Nd-Pb isotope evidence for ice-sheet presence on southern Greenland during the Last Interglacial

To ascertain the response of the southern Greenland Ice Sheet (GIS) to a boreal summer climate warmer than at present, we explored whether southern Greenland was deglaciated during the Last Interglacial (LIG), using the Sr-Nd-Pb isotope ratios of silt-sized sediment discharged from southern Greenland. Our isotope data indicate that no single southern Greenland geologic terrane was completely deglaciated during the LIG, similar to the Holocene. Differences in sediment sources during the LIG relative to the early Holocene denote, however, greater southern GIS retreat during the LIG. These results allow the evaluation of a suite of GIS models and are consistent with a GIS contribution of 1.6 to 2.2 meters to the ≥4-meter LIG sea-level highstand, requiring a significant sea-level contribution from the Antarctic Ice Sheet.     

Chemostratigraphic evidence of Deccan volcanism from the marine osmium isotope record

Continental flood basalt (CFB) volcanism is hypothesized to have played a causative role in global climate change and mass extinctions. Uncertainties associated with radiometric dating preclude a clear chronological assessment of the environmental consequences of CFB volcanism. Our results document a 25% decline in the marine 187Os/188Os record that predates the Cretaceous-Tertiary boundary (KTB) and coincides with late Maastrichtian warming. We argue that this decline provides a chemostratigraphic marker of Deccan volcanism and thus constitutes compelling evidence that the main environmental consequence of Deccan volcanism was a transient global warming event of 3 degrees to 5 degrees C that is fully resolved from the KTB mass extinction.     

Expanding oxygen-minimum zones in the tropical oceans

Oxygen-poor waters occupy large volumes of the intermediate-depth eastern tropical oceans. Oxygen-poor conditions have far-reaching impacts on ecosystems because important mobile macroorganisms avoid or cannot survive in hypoxic zones. Climate models predict declines in oceanic dissolved oxygen produced by global warming. We constructed 50-year time series of dissolved-oxygen concentration for select tropical oceanic regions by augmenting a historical database with recent measurements. These time series reveal vertical expansion of the intermediate-depth low-oxygen zones in the eastern tropical Atlantic and the equatorial Pacific during the past 50 years. The oxygen decrease in the 300- to 700-m layer is 0.09 to 0.34 micromoles per kilogram per year. Reduced oxygen levels may have dramatic consequences for ecosystems and coastal economies.     

畜禽钼中毒

畜禽钼中毒是由于畜禽采食了高钼饲料或因工业污染土壤﹑饲料﹑饮水引起的一种畜禽微量元素中毒病。钼是机体必需微量元素,但过量钼往往与铜﹑磷﹑钨﹑锰等矿物元素有颉颃作用,引起矿物元素缺乏,从而发生相应的缺乏症状。钼中毒主要以持续性腹泻﹑消瘦﹑贫血为特征,多发生于反刍动物,以牛最为敏感,羊次之,猪和家禽很少发生。     

High frequency of horizontal gene transfer in the oceans

Oceanic bacteria perform many environmental functions, including biogeochemical cycling of many elements, metabolizing of greenhouse gases, functioning in oceanic food webs (microbial loop), and producing valuable natural products and viruses. We demonstrate that the widespread capability of marine bacteria to participate in horizontal gene transfer (HGT) in coastal and oceanic environments may be the result of gene transfer agents (GTAs), viral-like particles produced by α-Proteobacteria. We documented GTA-mediated gene transfer frequencies a thousand to a hundred million times higher than prior estimates of HGT in the oceans, with as high as 47% of the culturable natural microbial community confirmed as gene recipients. These findings suggest a plausible mechanism by which marine bacteria acquire novel traits, thus ensuring resilience in the face of environmental change.     

Photosynthesis-induced biofilm calcification and calcium concentrations in Phanerozoic oceans

Photosynthetic carbon assimilation is commonly invoked as the cause of calcium carbonate precipitation in cyanobacterial biofilms that results in the formation of calcareous stromatolites. However, biofilm calcification patterns in recent lakes and simulation of photosynthetically induced rise in calcium carbonate supersaturation demonstrate that this mechanism applies only in settings low in dissolved inorganic carbon and high in calcium. Taking into account paleo-partial pressure curves for carbon dioxide, we show that Phanerozoic oceans sustaining calcified cyanobacteria must have had considerably higher calcium concentrations than oceans of today. In turn, the enigmatic lack of calcified cyanobacteria in stromatolite-bearing Precambrian sequences can now be explained as a result of high dissolved inorganic carbon concentrations.