Interstellar polycyclic aromatic hydrocarbons and carbon in interplanetary dust particles and meteorites

Both interplanetary dust particles (IDP(s)) and meteorites may contain material that is similar to polycyclic aromatic hydrocarbons(PAH(s)). The Raman spectra of IDP(s) and meteorites show features that are similar in position and relative strength to interstellar infrared emission features that have been attributed to vibrational transitions in free, molecular-sized PAH(s). The Raman spectra of some IDP(s) also show red photoluminescence that is similar to the excess red emission seen in some astronomical objects and that has also been attributed to PAH(s) and hydrogenated amorphous carbon. Moreover, a part of the carbonaceous phase in IDP(s) and meteorites contains deuterium to hydrogen ratios that are greater than those for terrestrial samples. Deuterium enrichment is expected in small free PAH(s) that are exposed to ultraviolet radiation in the interstellar medium. Taken together, these observations suggest that some of the carbonaceous material in IDP(s) and meteorites may have been produced in circumstellar dust shells and only slightly modified in interstellar space.     

Silicon Isotopic Composition in Large Meteoritic SiC Particles and 22Na Origin of 22Ne

Large silicon carbide (SiC) particles extracted from acid-insoluble residues of carbonaceous chondrites are isotopically anomalous in both silicon and carbon and contain isotopically extreme noble gases. These particles are thought to have originated in mass outflows from red giant stars and to have existed in the interstellar medium at the time the solar system formed from an interstellar cloud. Calculations show that the silicon isotope correlations in those large SiC particles can be generated only in the most massive carbon stars. Consequently, the almost pure neon-22 ((22)Ne) in those particles must be interpreted as the condensation of radioactive sodium-22 ((22)Na) in the particles as they flowed away from the stars. The (22)Na is produced through proton capture by (21)Ne at the base of the surface convection zone. Neon-22 does not exist abundantly in helium shells hot enough to burn magnesium, which is necessary to establish the measured silicon isotopic composition.     

养殖专用紫外光源辐照试验研究

家禽是在自然环境下进化而来,转为室内圈养,必然得不到充足的阳光,因而造成严重缺光,其中最缺的光谱波段是太阳投射到地面的紫外线。针对上述问题,本研究首先设计研制了养殖专用紫外光源,以专门弥补阳光中所含对家禽机体最有生物作用的中长波紫外线,进而对部分圈养家禽进行了紫外辐照试验研究。     

The abundance of heavy elements in interstellar gas

The Goddard high-resolution spectrograph aboard the Hubble Space Telescope has been used to produce interstellar abundance measures of gallium, germanium, arsenic, krypton, tin, thallium, and lead, the heaviest elements detected in interstellar gas. These heavy elements arise from stellar nuclear processes (slow- and rapid-process neutron capture) that are different from those that produce zinc and the lighter elements previously observed. These data allow investigators to study how the heavy elements chemically interact with interstellar dust and to compare interstellar heavy element abundances in the current galactic epoch to those present at the time of the formation of the solar system. For example, the data indicate that the abundance of atoms in interstellar dust cannot be explained by simple condensation models alone and must be heavily influenced by chemistry in the interstellar medium. Also, the data for some elements suggest that their true galactic cosmic abundances may be different from the "fossil" abundances incorporated into the solar system 4.6 billion years ago.     

Extreme-Ultraviolet Flux from the Virgo Cluster: Further Evidence for a 500,000-Kelvin Component

A surprising discovery in x-ray astronomy was that clusters of galaxies often contain vast quantities of hot (20 million kelvin) diffuse gas. Substantial diffuse extreme-ultraviolet (EUV) emission has recently been detected in the Virgo cluster of galaxies. Depending on the character of the interstellar medium in our galaxy, this emission could be either an aspect of the hot cluster gas or a previously undetected 500,000-kelvin component. Analysis of the observational data in combination with our current knowledge of the interstellar medium revealed that the EUV flux cannot be an effect of the interstellar medium. Hence, a warm cluster component appears likely.     

Far-ultraviolet astronomy on the astro-1 space shuttle mission

The Astro-1 mission obtained observations related to a wide variety of current problems in astronomy during a 9-day flight of the space shuttle Columbia. Early results from one of the instruments, the Hopkins Ultraviolet Telescope, are reviewed here. Among these are new insights concerning the origin of the ultraviolet light from the old stellar population in elliptical galaxies, new evidence for a hot, gaseous corona surrounding the Milky Way, improved views of the physical conditions in active galactic nuclei, and a measurement of the ionization state of the local interstellar medium.     

Interstellar shock waves

An understanding of interstellar shock waves is crucial in determining the structure of the interstellar medium. By causing the gas to radiate, interstellar shocks provide astronomers with valuable diagnostics on both the physical conditions in the interstellar medium and the energy source that produced the shock. The complexity of the interstellar plasma-its degree of ionization, its molecular content, the presence of small dust grains and cosmic rays, and the magnetic field-leads to a rich variety of structures for interstellar shocks, which are being actively investigated both observationally and theoretically.     

Cyclopropenylidenes: from interstellar space to an isolated derivative in the laboratory

Like many of the molecular species that have been detected in the interstellar medium, the singlet carbene cyclopropenylidene (C3H2) has been presumed to be too unstable to isolate in the laboratory. However, by appending pi-electron-donating amino groups to the triangular skeleton, we prepared a cyclopropenylidene derivative that is stable at room temperature. In contrast to previously isolated carbenes, this compound does not require a heteroatom adjacent to the electron-deficient carbon to confer stability. Despite the presence of amino groups, the geometric parameters of the cyclic skeleton, revealed by x-ray crystallography, are only slightly perturbed relative to those of the calculated structure of unsubstituted cyclopropenylidene. Stable cyclopropenylidene derivatives might thus serve as models for a better understanding of the formation of carbon-bearing molecules in the interstellar medium.     

Radio Observations of Interstellar Hydroxyl Radicals: Have we discovered a gigantic maser, or could we be detecting interstellar communications?

The discovery of the radio frequency lines of OH gave the first positive evidence of the existence of OH in the interstellar medium. In the 3(1/2) years that have intervened, many observations have revealed totally unexpected anomalies in the radio-spectral properties of interstellar OH. As a result, no reliable astrophysical information has been derived from the OH observations, but a large body of information is waiting to be unraveled. The interpretations of the data which have been made, such as the values derived for OH/H abundance ratios or for the kinetic temperatures of interstellar gas clouds, must be viewed with caution. They may turn out to be drastically in error, once the origin of the OH emission and absorption is fully understood.     

Extreme ultraviolet observations from the voyager 2 encounter with saturn

Combined analysis of helium (584 angstroms) airglow and the atmospheric occultations of the star delta Scorpii imply a vertical mixing parameter in Saturn's upper atmosphere of K (eddy diffusion coefficient) approximately 8 x 10(7) square centimeters per second, an order of magnitude more vigorous than mixing in Jupiter's upper atmosphere. Atmospheric H(2) band absorption of starlight yields a preliminary temperature of 400 K in the exosphere and a temperature near the homopause of approximately 200 K. The energy source for the mid-latitude H(2) band emission still remains a puzzle. Certain auroral emissions can be fully explained in terms of electron impact on H(2), and auroral morphology suggests a link between the aurora and the Saturn kilometric radiation. Absolute optical depths have been determined for the entire C ring andparts of the A and B rings. A new eccentric ringlet has been detected in the C ring. The extreme ultraviolet reflectance of the rings is fairly uniform at 3.5 to 5 percent. Collisions may control the distribution of H in Titan's H torus, which has a total vertical extent of approximately 14 Saturn radii normal to the orbit plane.     

Steering attosecond electron wave packets with light

Photoelectrons excited by extreme ultraviolet or x-ray photons in the presence of a strong laser field generally suffer a spread of their energies due to the absorption and emission of laser photons. We demonstrate that if the emitted electron wave packet is temporally confined to a small fraction of the oscillation period of the interacting light wave, its energy spectrum can be up- or downshifted by many times the laser photon energy without substantial broadening. The light wave can accelerate or decelerate the electron's drift velocity, i.e., steer the electron wave packet like a classical particle. This capability strictly relies on a sub-femtosecond duration of the ionizing x-ray pulse and on its timing to the phase of the light wave with a similar accuracy, offering a simple and potentially single-shot diagnostic tool for attosecond pump-probe spectroscopy.     

Observational properties of pulsars

Pulsars are remarkable clocklike celestial sources that are believed to be rotating neutron stars formed in supernova explosions. They are valuable tools for investigations into topics such as neutron star interiors, globular cluster dynamics, the structure of the interstellar medium, and gravitational physics. Searches at radio and x-ray wavelengths over the past 5 years have resulted in a large increase in the number of known pulsars and the discovery of new populations of pulsars, posing challenges to theories of binary and stellar evolution. Recent images at radio, optical, and x-ray wavelengths have revealed structures resulting from the interaction of pulsar winds with the surrounding interstellar medium, giving new insights into the physics of pulsars.     

A carbonate-rich, hydrated, interplanetary dust particle: possible residue from protostellar clouds

Transmission electron microscopy of a hydrated interplanetary dust particle (IDP) indicates that it contains abundant magnesium-iron carbonates, primarily breunnerite and magnesian siderite. This IDP displays a strong absorption band at 6.8 micrometers in its infrared spectrum, similar to that in certain protostellar spectra. The carbonates probably account for the 6.8-micrometer band in the IDP spectrum, suggesting that carbonate also may occur in interstellar dust and be the source of the controversial 6.8-micrometer feature from the protostellar spectra.     

纳米材料对水团簇的影响

[目的]为纳米材料在生物领域的应用提供依据。[方法]通过紫外吸收光谱和核磁共振图谱研究纳米材料处理水分子团簇的变化。[结果]在190~325 nm波段,纳米材料处理水的紫外吸收光谱的光吸收增强,表明水分子的结构和能态发生了变化;水的17O-NMR半峰宽变窄,化学位移减小,向低场移动。[结论]水经纳米材料处理后分子团变小,活性提高。     

An astronomical 2175 angstrom feature in interplanetary dust particles

The 2175 angstrom extinction feature is the strongest (visible-ultraviolet) spectral signature of dust in the interstellar medium. Forty years after its discovery, the origin of the feature and the nature of the carrier(s) remain controversial. Using a transmission electron microscope, we detected a 5.7-electron volt (2175 angstrom) feature in interstellar grains embedded within interplanetary dust particles (IDPs). The carriers are organic carbon and amorphous silicates that are abundant in IDPs and in the interstellar medium. These multiple carriers may explain the enigmatic invariant central wavelength and variable bandwidth of the astronomical 2175 angstrom feature.     

The heliosphere's interstellar interaction: no bow shock

As the Sun moves through the local interstellar medium, its supersonic, ionized solar wind carves out a cavity called the heliosphere. Recent observations from the Interstellar Boundary Explorer (IBEX) spacecraft show that the relative motion of the Sun with respect to the interstellar medium is slower and in a somewhat different direction than previously thought. Here, we provide combined consensus values for this velocity vector and show that they have important implications for the global interstellar interaction. In particular, the velocity is almost certainly slower than the fast magnetosonic speed, with no bow shock forming ahead of the heliosphere, as was widely expected in the past.     

Interstellar matter and chemical evolution

The determination of chemical abundances of the interstellar medium is related to three different areas of astronomy: pregalactic conditions, stellar evolution, and chemical evolution of galaxies. The observed abundances permit the testing of theories associated with these areas. Knowledge of the abundances of helium, carbon, nitrogen, and neon relative to the abundance of hydrogen in the interstellar medium puts limits on current models of cosmology, stellar evolution, and galactic evolution.     

Disulfate ion as an intermediate to sulfuric Acid in Acid rain formation

The oxidation of the bisulfite ion by dissolved oxygen to produce sulfate ion involves the formation of a previously undetected intermediate. This intermediate has a fairly strong Raman band at 1090 wave numbers and a weak Raman band at 740 wave numbers, both of which are probably due to sulfur-oxygen stretches. The intermediate is proposed to be the disulfate ion S(2)O(7)(2-), which hydrolyzes into H(+) and either SO(4)(2-) or HSO(4)(2-) with a half-life of about 52 seconds at 25 degrees C.     

Dark auroral oval on saturn discovered in hubble space telescope ultraviolet images

Hubble Space Telescope ultraviolet images of Saturn obtained with the Faint Object Camera near 220 nanometers reveal a dark oval encircling the north magnetic pole of the planet. The opacity has an equivalent width of approximately 11 degrees in latitude and is centered around approximately 79 degrees N. The oval shape of the dark structure and its coincidence with the aurora detected by the Voyager Ultraviolet Spectrometer suggest that the aerosol formation is related to the auroral activity.     

Infrared spectroscopy of comet 81P/Wild 2 samples returned by Stardust

Infrared spectra of material captured from comet 81P/Wild 2 by the Stardust spacecraft reveal indigenous aliphatic hydrocarbons similar to those in interplanetary dust particles thought to be derived from comets, but with longer chain lengths than those observed in the diffuse interstellar medium. Similarly, the Stardust samples contain abundant amorphous silicates in addition to crystalline silicates such as olivine and pyroxene. The presence of crystalline silicates in Wild 2 is consistent with mixing of solar system and interstellar matter. No hydrous silicates or carbonate minerals were detected, which suggests a lack of aqueous processing of Wild 2 dust.