Soil Carbon Sequestration in Long-Term Fertilization Under Jute-Rice-Wheat Agro-Ecosystem

Soil organic carbon (SOC) sequestration in response to long-term fertilizer management practices under jute-rice-wheat agro-ecosystem in alluvial soils was studied using a modeling approach. Fertilizer management practices included nitrogen (N), phosphorus (P) and potassium (K) fertilization, manure application, and root-stubble retention of all three crops. Soil carbon (C) model RothC was used to simulate the critical C input rates needed to maintain initial soil C level in long timescale (44 years). SOC change was significantly influenced by the long-term fertilizer management practices and the edaphic variable of initial SOC content. The effects of fertilizer combination “100%NPK+FYM” on SOC changes were most significant over “100%NPK” fertilization. If the 100% NPK fertilizer along with manure applied with stubble and roots retention of all crops, alluvial soils of such agro-ecosystem would act as a net C sink, and the average SOC density kept increasing from 18.18 Mg ha^?1 during 1972 to the current average of ～22 Mg ha^?1 during 2065 s. On an average, the critical C input was estimated to be 5.30 Mg C ha^?1 yr^?1, depending on local soil and climatic conditions. The critical C input could be effectively estimated using a summary model driven by current SOC level, mean annual temperature, precipitation, and soil clay content. Such information will provide a baseline for assessing soil C dynamics under potential changes in fertilizer and crop residues management practices, and thus enable development of management strategies for effectively mitigating climate change through soil C sequestration.     

Regional simulation of long-term organic carbon stock changes in cropland soils using the DNDC model: 1. Large-scale model validation against a spatially explicit data set

Because of the large spatial and temporal variability of soil organic carbon (SOC) dynamics, a modelling approach is crucial in detailed regional analyses. Several estimates of regional scale SOC sequestration potential have been made using dynamic soil organic matter (SOM) models which have been linked to spatial databases contained within a Geographic Information System. In all these previous studies, a large‐scale model validation, which provides information on the general model performance for the study area under concern, was impossible because of lack of data. A data set of over 190 000 SOC measurements, grouped as means per community and covering the period 1989–2000 was available for Flanders in northern Belgium. In order to validate the DNDC model at a large spatial scale, we used this data set along with detailed pH, soil texture and crop areas which were all available at the municipality scale to simulate SOC stocks for the entire study area during the period 1990–2000. A minor adjustment of the initial distribution of SOC in the model's SOC pool was necessary to fit the simulated SOC stock changes to the measured decrease of −475 kg OC ha⁻¹ year⁻¹ (0–30 cm). Although DNDC was able to simulate the SOC stock changes well for the whole study area, the simulated decrease in the SOC stocks was overestimated for communities predominantly having sandy textures and underestimated for communities with silt loam to silt textures. This study also urges caution with the application of SOM models at regional scales after limited validation or calibration at the field scale as these do not guarantee good simulation of spatial variation in SOC changes.     

Soil organic carbon dynamics at the regional scale as influenced by land use history: a case study in forest soils from southern Belgium

Land use change (LUC) is known to have a large impact on soil organic carbon (SOC) stocks. However, at a regional scale, our ability to explain SOC dynamics is limited due to the variability generated by inconsistent initial conditions between sample points, poor spatial information on previous land use/land management history and scarce SOC inventories. This study combines the resampling in 2003–2006 of an extensive soil survey in 1950–1960 with exhaustive historical data on LUC (1868–2006) to explain observed changes in the SOC stocks of temperate forest soils in the Belgian Ardennes. Results from resampling showed a significant loss of SOC between the two surveys, associated with a decrease in variability. The mean carbon content decreased from 40.4 to 34.5 g C kg^?1 (10.6 to 9.6 kg C m^?2), with a mean rate of C change (ΔSOC) of ?0.15 g C kg^?1 year^?1 (?0.023 kg C m^?2 year^?1). Soils with high SOC content tended to loose carbon while conversely soils with low SOC tended to gain carbon. Land use change history explained a significant part of past and current SOC stocks as well as ΔSOC during the last 50 years. We show that the use of spatially explicit historical data can help to quantitatively explain changes in SOC content at the regional scale.     

基于土壤剖面测定数据计算中国土壤有机碳贮量

Soil organic carbon (SOC) storage under different types of vegetations in China were estimated using measured data of 2 440 soil profiles to compare SOC density distribution between different estimates, to map the soil organic carbon stocks under different types of vegetation in China, and to analyze the relationships between soil organic carbon stocks and environmental variables using stepwise regression analyses. Soil organic carbon storage in China was estimated at 69.38 Gt (1015 g). There was a big difference in SOC densities for various vegetation types, with SOC distribution closely related to climatic patterns in general. Stepwise regression analyses of SOC against environmental variables showed that SOC generally increased with increasing precipitation and elevation, while it decreased with increasing temperature. Furthermore, the important factor controlling SOC accumulation for forests was elevation, while for temperate steppes mean annual temperature dominated. The more specific the vegetation type used in the regression analysis, the greater was the effect of environmental variables on SOC. However, compared to native vegetation, cultivation activities in the croplands reduced the influence of environmental variables on SOC.     

Soil organic carbon–stock changes in Flemish grassland soils from 1990 to 2000

Total soil organic‐carbon (SOC) stocks for grassland soils in Flanders (N Belgium) were determined for the Kyoto Protocol reference year 1990 and 2000 in order to investigate whether these soils have been CO₂ sinks or sources during that period. The stocks were calculated by means of detailed SOC datasets, which were available at the community scale for the whole of Flanders. The total SOC stocks for Flemish grassland soils (1 m depth) were estimated at 38 Mt SOC in 1990 and 34 Mt SOC in 2000. The loss of SOC resulted from a decrease in the SOC content of grassland soils (71%) and could also partly (29%) be explained by a decline in grassland area. Significant decreases in %SOC for the 0–6 cm depth layer were found for the 1990s for the coarser‐textured soils with SOC losses ranging between –0.3% and –0.5% over the 10 y period. Specific management practices that disturb the SOC balance such as conversion to temporary grassland and a reduction of animal‐manure application are hypothesized to have contributed to the observed loss of SOC stocks. We furthermore conducted an analysis of uncertainty of the 1990 and 2000 grassland SOC–stocks calculation using Monte Carlo analysis. Probability‐distribution functions were determined for each of the inputs of the SOC‐stock calculation, enabling us to assess the uncertainty on the 1990 and 2000 SOC stocks. The frequency distributions of these simulated stocks both closely approached lognormal distributions, and their 95%‐confidence intervals ranged between 150% and 50% of the calculated mean SOC stock. The standard error on the measured decrease in SOC stocks in Flemish grassland soils during the 1990s was calculated to be 7–8 Tg SOC, which is equivalent to twice this decrease. This clearly shows that large‐scale changes in SOC stocks are uncertainty‐ridden, even when they are based on detailed datasets.     

Estimating soil carbon dynamics in intercrop and sole crop agroecosystems using the Century model

Using process‐based models to predict changes in carbon (C) stocks enhances our knowledge on the long‐term dynamics of soil organic carbon (SOC) in various land management systems. The objective of this study was to apply the Century model to evaluate temporal SOC dynamics in two temperate intercrop systems [1:2 (one row of maize and two rows of soybeans); 2:3 intercrop (two rows of maize and three rows of soybean)] and in a maize and soybean sole crop. Upon initiation of intercropping, SOC increased by 47% after ≈ 100 years, whereas SOC in the maize sole crop increased by 21% and 2% in the soybean sole crop. The quantity of crop residue input was sufficient to increase the active (turnover time of months to years) SOC fraction in the intercrops and the maize sole crop, but not in the soybean sole crop. The slow fraction, with a turnover time of 20 to 50 years, increased in all crop systems and was the major driver of SOC accumulation. A 3 to 15% loss of SOC from the passive fraction, with a turnover time of 400 to 2000 years, in all crop systems showed the long‐term impact of land‐use conversion from historically undisturbed native grasslands to intensive agricultural production systems. This study provided an example of the potential of process‐based models like Century to illustrate possible effects of cereal–legume intercropping on SOC dynamics and that the model was able to predict SOC stocks within –7 to +4% of measured values. We conclude, however that further fine‐tuning of the model for application to cereal–legume intercrop systems is required in order to strengthen the relationship between measured and simulated values.     

Dynamics of maize straw residue 13C incorporation into aggregates of a Mollisol as affected by long-term fertilization

Journal of Soils and Sediments - Soil aggregates play a crucial role in the sequestration of soil organic carbon (SOC). Returning crop residues to soil is known to strongly influence soil C stocks,...     

CHANGES IN SOIL ORGANIC CARBON UNDER EUCALYPTUS PLANTATIONS IN BRAZIL: A COMPARATIVE ANALYSIS

Proper assessment of environmental quality or degradation requires knowledge of how terrestrial C pools respond to land use change. Forest plantations offer a considerable potential to sequester C in aboveground biomass. However, their impact on initial levels of soil organic carbon (SOC) varies from strong losses to gains, possibly affecting C balances in afforestation or reforestation initiatives. We compiled paired‐plot studies on how SOC stocks under native vegetation change after planting fast‐growth Eucalyptus species in Brazil, where these plantations are becoming increasingly important. SOC changes for the 0–20 and 0–40 cm depths varied between −25 and 42 Mg ha⁻¹, following a normal distribution centered near zero. After replacing native vegetation by Eucalyptus plantations, mean SOC changes were −1·5 and 0·3 Mg ha⁻¹ for the 0–20 and 0–40 cm depths, respectively. These are very low figures in comparison to C stocks usually sequestered in aboveground biomass and were statistically nonsignificant as demonstrated by a t‐test at p < 0·05. Similar low, nonsignificant SOC changes were estimated after data were stratified into first or second rotation cycles, soil texture and biome (savanna, rainforest or grassland). Although strong SOC losses or gains effectively occurred in some cases, their underpinning causes could not be generally identified in the present work and must be ascribed in a case basis, considering the full set of environmental and management conditions. We conclude that Eucalyptus spp. plantations in average have no net effect on SOC stocks in Brazil. Copyright © 2012 John Wiley & Sons, Ltd.     

耕作与轮作方式对黑土有机碳和全氮储量的影响

土壤有机碳(SOC)及全氮(TN)对土壤肥力、作物产量、农业可持续发展以及全球碳、氮循环等都具有重要影响。为探索不同耕作和轮作方式对耕层黑土SOC和TN储量的影响,本文以吉林省德惠市进行了8 a的田间定位试验中层黑土为研究对象,对免耕、垄作和秋翻三种耕作方式及玉米-大豆轮作和玉米连作两种轮作方式下SOC和TN在各土层的含量变化进行了分析,并采用等质量土壤有机质储量计算方法,对比分析了不同处理对0～30 cm SOC和TN储量的影响。结果表明,与试验开始前相比,玉米-大豆轮作系统中,秋翻下SOC和TN储量均有所降低;免耕显著增加了0～5 cm SOC及TN含量,但SOC在亚表层亏损,导致其储量并未增加;而垄作处理下SOC及TN含量在0～5、5～10 cm的均显著增加,0～30 cm储量亦分别增加了4.9%和10.7%。玉米连作系统的两种耕作处理(免耕和秋翻)下SOC和TN储量均有所增加,且TN储量增幅均高于玉米-大豆轮作系统,其中免耕下TN储量增幅是玉米-大豆轮作的3.2倍。所有处理下C/N均呈降低趋势,其中垄作0～5 cm C/N由12.05降至11.04,降低幅度分别是免耕和秋翻的3.2和2.8倍。综上可知,对质地黏重排水不良的中层黑土,玉米-大豆轮作系统下免耕并不是促进SOC固定的有效形式,而垄作则促进了黑土SOC和TN的积累,这不仅有利于土壤肥力的改善,而且是使农田黑土由CO2"源"变为"汇"的有效形式之一。与玉米-大豆轮作相比,玉米连作下三种耕作方式都有利于SOC和TN积累。     

Spatial variability and change in soil organic carbon stocks in response to recovery following land abandonment and erosion in mountainous drylands

This research investigates the impact of human activities on carbon (C) dynamics in a mountainous and semi‐arid environment. Despite the low C status of drylands, soil organic carbon (SOC) is the largest C pool in these systems and therefore may offer significant C sequestration potential in systems recovering from degradation. Nevertheless, quantification of this potential is limited by lack of knowledge concerning the magnitude of and controls on regional SOC stocks. Therefore, this study aimed to (i) investigate the variability of soil organic carbon in relation to recovery period and key soil and topographical variables, and (ii) quantify the effects of recovery period following abandonment on SOC stocks. Soil profiles were sampled in the Sierra de los Filabres (southeast Spain) in different land units along geomorphic and degradation gradients. SOC contents were modelled using recovery period and soil and topographical variables. Sample depth, topographic position, altitude, recovery period and stone content were identified as the main factors for predicting SOC concentrations. SOC stocks in 1 m depth of soil varied between 3.16 and 76.44 t/ha. Recovery period (years since abandonment), topographic position and altitude were used to predict and map SOC stocks in the top 0.2 m. The results show that C accumulates rapidly during the first 10–50 yr following abandonment; thereafter, the stocks evolve towards a steady‐state level. The erosion zones in the study area demonstrate greater potential to increase their SOC stocks when abandoned. Deposition zones have greater SOC values, although their C accumulation rate is lower compared with erosional landscapes in the first 10–50 yr following abandonment. Therefore, full understanding of the C sequestration potential of land use change in areas of complex topography requires knowledge of spatial variability in soil properties and in particular SOC.     

Ecosystem C and N dynamics affected by a modified spring barley trait with increased nitrogen use - a simulation case study

To what extent might a crop with increased plant N uptake efficiency and/or N demand increase plant biomass and soil carbon storage, decrease N leaching, and reduce the need for N fertilisation? This was assessed for a fertilised sandy loam site in central Sweden cultivated with spring barley for a four year period using a process based crop and soil simulation model (SOILN) calibrated to fit observations of field experiments with non-modified crops. Crop properties were changed in accordance with previous model applications to other crops with higher N uptake and utilisation efficiencies, to resemble potential effects of breeding. For the modified crops a doubling of daily uptake efficiency of soil mineral N and/or increase of radiation use efficiency by 30%, increased plant biomass by 3%–30%, decreased N leaching by 1%–30% and increased soil organic carbon (SOC) content by 1–12?g?C?m^?2 year^?1. The larger changes were mainly due to increased uptake efficiency. Fertilisation of the modified spring barley crop could be reduced while still producing the same plant biomass as the non-modified crop. The plant biomass to N leaching ratio of the modified crops increased. The simulated changes in plant biomass and SOC were sensitive to weather conditions suggesting that in situ experiments would need to cover a large range of weather conditions to evaluate the performance of new crop traits under climatic variability. The study suggests a strong need that field experiments are accompanied with model applications, when exploring the potential of the modified crops under variable conditions.     

耕作方式对双季稻田土壤有机碳储量的影响

Tillage practices can potentially afect soil organic carbon (SOC) accumulation in agricultural soils. A 4-year experiment was conducted to identify the influence of tillage practices on SOC sequestration in a double-cropped rice (Oryza sativa L.) field in Hunan Province of China. Three tillage treatments, no-till (NT), conventional plow tillage(PT), and rotary tillage(RT), were laid in a randomized complete block design. Concentrations of SOC and bulk density(BD) of the 0-80 cm soil layer were measured, and SOC stocks of the 0-20 and 0-80 cm soil layers were calculated on an equivalent soil mass(ESM) basis and fixed depth (FD) basis.Soil carbon budget(SCB) under diferent tillage systems were assessed on the basis of emissions of methane(CH4) and CO2 and the amount of carbon (C) removed by the rice harvest. After four years of experiment, the NT treatment sequestrated more SOC than the other treatments. The SOC stocks in the 0-80 cm layer under NT (on an ESM basis) was as high as 129.32 Mg C ha 1,significantly higher than those under PT and RT (P < 0.05). The order of SOC stocks in the 0-80 cm soil layer was NT > PT > RT,and the same order was observed for SCB; however, in the 0-20 cm soil layer, the RT treatment had a higher SOC stock than the PT treatment. Therefore, when comparing SOC stocks, only considering the top 20 cm of soil would lead to an incomplete evaluation for the tillage-induced efects on SOC stocks and SOC sequestrated in the subsoil layers should also be taken into consideration. The estimation of SOC stocks using the ESM instead of FD method would better reflect the actual changes in SOC stocks in the paddy filed, as the FD method amplified the tillage efects on SOC stocks. This study also indicated that NT plus straw retention on the soil surface was a viable option to increase SOC stocks in paddy soils.     

Changes in soil carbon and crop yield over 60 years in the Zurich Organic Fertilization Experiment,following land‐use change from grassland to cropland

Changes in land‐use and agricultural management affect soil organic C (SOC) storage and soil fertility. Grassland to cropland conversion is often accompanied by SOC losses. However, fertilization, crop rotation, and crop residue management can offset some SOC losses or even convert arable soils into C sinks. This paper presents the first assessment of changes in SOC stocks and crop yields in a 60‐year field trial, the Zurich Organic Fertilization Experiment A493 (ZOFE) in Switzerland. The experiment comprises 12 treatments with different organic, inorganic and combined fertilization regimes. Since conversion to arable land use in 1949, all treatments have lost SOC at annual rates of 0.10–0.25 t C ha^?1, with estimated mean annual C inputs from organic fertilizers and aboveground and belowground plant residues of 0.6–2.4 t C ha^?1. In all treatments, SOC losses are still in progress, indicating that a new equilibrium has not yet been reached. Crop yields have responded sensitively to advances in plant breeding and in fertilization. However, in ZOFE high yields can only be ensured when mineral fertilizer is applied at rates typical for modern agriculture, with yields of main crops (winter wheat, maize, potatoes, clover‐grass ley) decreasing by 25–50% when manure without additional mineral fertilizer is applied. ZOFE shows that land‐use change from non‐intensively managed grassland to cropland leads to soil C losses of 15–40%, even in rotations including legumes and intercrops, improved agricultural management and organic fertilizer application.     

Biochar application to soil for climate change mitigation by soil organic carbon sequestration

Pyrogenic carbon (C) is produced by incomplete combustion of fuels including organic matter (OM). Certain ranges in the combustion continuum are termed ‘black carbon' (BC). Because of its assumed persistence, surface soils in large parts of the world contain BC with up to 80% of surface soil organic C (SOC) stocks and up to 32% of subsoil SOC in agricultural soils consisting of BC. High SOC stocks and high levels of soil fertility in some ancient soils containing charcoal (e.g., terra preta de Índio) have recently been used as strategies for soil applications of biochar, an engineered BC material similar to charcoal but with the purposeful use as a soil conditioner (1) to mitigate increases in atmospheric carbon dioxide (CO₂) by SOC sequestration and (2) to enhance soil fertility. However, effects of biochar on soils and crop productivity cannot be generalized as they are biochar‐, plant‐ and site‐specific. For example, the largest potential increases in crop yields were reported in areas with highly weathered soils, such as those characterizing much of the humid tropics. Soils of high inherent fertility, characterizing much of the world's important agricultural areas, appear to be less likely to benefit from biochar. It has been hypothesized that both liming and aggregating/moistening effects of biochar improved crop productivity. Meta‐analyses of biochar effects on SOC sequestration have not yet been reported. To effectively mitigate climate change by SOC sequestration, a net removal of C and storage in soil relative to atmospheric CO₂ must occur and persist for several hundred years to a few millennia. At deeper soil depths, SOC is characterized by long turnover times, enhanced stabilization, and less vulnerability to loss by decomposition and erosion. In fact, some studies have reported preferential long‐term accumulation of BC at deeper depths. Thus, it is hypothesized that surface applied biochar‐C (1) must be translocated to subsoil layers and (2) result in deepening of SOC distribution for a notable contribution to climate change mitigation. Detailed studies are needed to understand how surface‐applied biochar can move to deeper soil depths, and how its application affects organic C input to deeper soil depths. Based on this knowledge, biochar systems for climate change mitigation through SOC sequestration can be designed. It is critically important to identify mechanisms underlying the sometimes observed negative effects of biochar application on biomass, yield and SOC as biochar may persist in soils for long periods of time as well as the impacts on downstream environments and the net climate impact when biochar particles become airborne.     

The soil organic carbon: Clay ratio in North Devon,UK: Implications for marketing soil carbon as an asset class

Building up stocks of agricultural soil organic carbon (SOC) can improve soil conditions as well as contribute to climate change mitigation. As a metric, the ratio of SOC to clay offers a better predictor of soil condition than SOC alone, potentially providing a benchmark for ecosystem service payments. We determined SOC:clay ratios for 50 fields in the North Devon UNESCO World Biosphere Reserve using 30 cm soil cores (divided into 0–10 cm and 10–30 cm depth samples), with soil bulk density, soil moisture and land-use history recorded for each field. All the arable soils exceeded the minimum desirable SOC:clay ratio threshold, and the ley grassland soils generally exceeded it but were inconsistent at 10–30 cm. Land use was the primary factor driving SOC:clay ratios at 0–10 cm, with permanent pasture fields having the highest ratios followed by ley grass and then arable fields. Approximately half of the fields sampled had potential for building up SOC stock at 10–30 cm. However, at this depth, the effect of land use is significantly reduced. Within-field variability in SOC and clay was low (coefficient of variation was ~10%) at both 0–10 cm and 10–30 cm, suggesting that SOC:clay ratios precisely characterized the fields. Due to the high SOC:clay ratios found, we conclude that there is limited opportunity to market additional carbon sequestration as an asset class in the North Devon Biosphere or similar areas. Instead, preserving existing SOC stocks would be a more suitable ecosystem service payment basis.     

Long-term effects of NPK fertilizers and organic manures on soil organic carbon and carbon management index under a double-cropping rice system in Southern China

The effects of manure and chemical fertilizer on soil bulk density, soil organic carbon (SOC), and the role of carbon management index (CMI) in soil quality evaluation were studied under a double-cropping rice system in a long-term experiment. The experiment included five fertilizer treatments: without fertilizer input (CK), chemical fertilizer alone (MF), rice straw residue plus chemical fertilizer (RF), 30% organic matter plus 70% chemical fertilizer (LOM), and 60% organic matter plus 40% chemical fertilizer (HOM). RF, LOM, HOM treatments increased SOC content relative to MF treatment in the paddy fields at 0–20 cm. RF, LOM, HOM treatments were more effective for increasing CMI, lability index, lability of C, and SOC stocks, as compared with MF treatment. Based on rice grain yield and carbon storage, integrated fertilization of chemical fertilizer and organic manure proved to be the most effective practices for improving crop productivity and SOC sequestration.     

Carbon and nitrogen stocks in a Brazilian clayey Oxisol: 13-year effects of integrated crop–livestock management systems

Integrated crop–livestock management systems (ICLS) have been increasingly recommended in Brazilian agroecosystems. However, knowledge of their effect on soil organic carbon (SOC) and total nitrogen (TN) concentrations and stocks is still limited. The study was undertaken to evaluate the effects of ICLS under two tillage and fertilization regimes on SOC and TN concentrations and stocks in the 0–30 cm soil layer, in comparison with continuous crops or pasture. The following soil management systems were studied: continuous pasture; continuous crop; 4 years’ crop followed by 4 years’ pasture and vice-versa. The adjacent native Cerrado area was used as a control. Under the rotation and continuous crop systems there were two levels of soil tillage (conventional and no-tillage) and fertility (maintenance and corrective fertility). The stock calculations were done using the equivalent soil mass approach. The land use systems had a significant effect on the concentrations of SOC and TN in the soil, but no effect was observed for the soil tillage and fertilizer regimes. For these two latter, some significant discrepancies appeared in the distribution of SOC and TN concentrations in the 0–30 cm layer. Carbon storage was 60.87 Mg ha⁻¹ under Cerrado, and ranged from 52.21 Mg ha⁻¹ under the ICLS rotation to 59.89 Mg ha⁻¹ with continuous cropping. The decrease in SOC stocks was approximately 8.5 and 7.5 Mg ha⁻¹, or 14 and 12%, for continuous pasture and ICLS respectively. No-tillage for 10 years after the conversion of conventional tillage to no-tillage under the continuous crop system, and 13 years of conventional tillage in continuous cropping did not result in significant changes in SOC stocks. The SOC and TN stocks in surface layers, using the equivalent soil mass approach rather than the equivalent depth, stress the differences induced by the calculation method. As soil compaction is the principal feature of variability of stocks determinations, the thickness should be avoid in these types of studies.     

Predicting changes in soil organic carbon in mediterranean and alpine forests during the Kyoto Protocol commitment periods using the CENTURY model

Six Italian research sites, representative of Mediterranean and mountain forests and equipped with eddy covariance towers, were used in this study to test the performance of the CENTURY 4.5 model in predicting the dynamics of soil organic carbon (SOC) changes during the commitment periods (CP) of the Kyoto Protocol (2008–2012; 2013–2017). We show that changes in SOC stocks over short periods of time are difficult to detect, and explore the potential for models to be used for reporting SOC changes for forests that will remain forests, under Article 3.4 of the Kyoto Protocol. As the eddy covariance flux sites have been active for 10 yr on average, being initiated over the period between 1996 and 1998, the model was evaluated by comparing the modelled SOC stocks with those directly measured at each site in different years. Since long term series of observed values for soil carbon were not available, the validation of other model outputs such as net primary production (NPP) and soil nitrogen stocks, gives some confidence in long term simulations. Once the model performance was evaluated, two climate change scenarios, A1F1 (world markets‐fossil fuel intensive) and B2 (local sustainability), were considered for prediction of C stock changes during the commitment periods of the Kyoto Protocol. In general, despite the need to consider the uncertainties in the direct measurements, at each site model fit with measured SOC stocks was good, with the simulated values within the standard deviation of the measurements. In this regard, the similarity between the SOC measured in 2008 and that predicted for the two forthcoming commitment periods points out the difficulty of detecting carbon stock changes by direct measurements, given the closeness in time to the present of the commitment periods. In any case, all sites show positive variations that are possibly related to the fertilization effects of increasing CO₂ and to longer growing seasons, since no change in management occurred. Compared with the SOC measured in 2008, at the end of the second commitment period, the modelled SOC variations were smaller than 2% in the Mediterranean forests and comprised between 2% and 7% in the mountain forests. These variations, although small, indicate it might be possible to statistically detect differences after 10 yr in mountain forests with a reasonable number of samples. In conclusion, this work shows that since SOC stock changes are minimal within both CP, models can be effective tools for estimating future changes in SOC amounts, as an alternative to, or in support of, direct measurements when a short period of time is considered.     

Environmental Factors Controlling Soil Organic Carbon Stocks in Two Contrasting Mediterranean Climatic Areas of Southern Spain

Managing soil carbon requires accurate estimates of soil organic carbon (SOC) stocks and its dynamics, at scales able to capture the influence of local factors on the carbon pool. This paper develops a spatially explicit methodology to quantify SOC stocks in two contrasting regions of Southern Spain: Sierra Norte de Sevilla (SN) and Cabo de Gata (CG). Also, it examines the relationship between SOC stocks and local environmental factors. Results showed that mean SOC stocks were 4·3 kg m⁻² in SN and 3·0 kg m⁻² in CG. Differences in SOC in both sites were not significant, suggesting that factors other than climate have a greater influence on SOC stocks. A correlation matrix revealed that SOC has the highest positive correlation with clay content and soil depth. Based on the land use, the largest SOC stocks were found in grassland soils (4·4 kg m⁻² in CG and 5·0 kg m⁻² in SN) and extensive crops (3·0 kg m⁻² in CG and 5·0 kg m⁻² in SN), and the smallest under shrubs (2·8 kg m⁻² in CG and 3·2 kg m⁻² in SN) and forests soils (4·2 kg m⁻² in SN). This SOC distribution is explained by the greatest soil depth under agricultural land uses, a common situation across the Mediterranean, where the deepest soils have been cultivated and natural vegetation mostly remains along the marginal sites. Accordingly, strategies to manage SOC stocks in southern Spain will have to acknowledge its high pedodiversity and long history of land use, refusing the adoption of standard global strategies. Copyright © 2015 John Wiley & Sons, Ltd.     

Modelling the Effect of Land Management Changes on Soil Organic Carbon Stocks in a Mediterranean Cultivated Field

Land management in agricultural lands has important effects on soil organic carbon (SOC) dynamics. These effects are particularly relevant in the Mediterranean region, where soils are fragile and prone to erosion. Increasing interest of modelling to simulate SOC dynamics and the significance of soil erosion on SOC redistribution have been linked to the development of some recent models. In this study, the SPEROS‐C model was implemented in a 1.6‐ha cereal field for a 150‐year period covering 100 years of minimum tillage by animal traction, 35 years of conventional tillage followed by 15 years of reduced tillage by chisel to evaluate the effects of changes in land management on SOC stocks and lateral carbon fluxes in a Mediterranean agroecosystem. The spatial patterns of measured and simulated SOC stocks were in good agreement, and their spatial variability appeared to be closely linked to soil redistribution. Changes in the magnitude of lateral SOC fluxes differed between land management showing that during the conventional tillage period the carbon losses is slightly higher (0.06 g C m⁻² yr⁻¹) compared to the period of reduced till using chisel (0.04 g C m⁻² yr⁻¹). Although the results showed that the SPEROS‐C model is a potential tool to evaluate erosion induced carbon fluxes and assess the relative contribution of different land management on SOC stocks in Mediterranean agroecosystems, the model was not able to fully represent the observed SOC stocks. Further research (e.g. input parameters) and model development will be needed to achieve more accurate results. Copyright © 2016 John Wiley & Sons, Ltd.